Arsenic and metal contamination of water resources from mining wastes in Korea   总被引：5，自引：1，他引：5  

N. C. Woo  M. J. Choi 《Environmental Geology》2001,40(3):305-311

 Water resources near a gold-mine waste site were studied for the distribution and contents of contaminants, and their behavior in the surface and groundwater systems. Arsenic, cadmium, and manganese were identified with levels exceeding the drinking water guidelines of WHO (World Health Organization), and their distribution depended upon the differences in source materials and in spatial pH variations. Originating from arsenopyrite, concentrations of dissolved arsenic were controlled by sorption with amorphous iron (Fe(OH)₃) and carbonate minerals. Cadmium and manganese were derived from the mineral phase including sphalerite (ZnS), otavite (CdCO₃), and rhodochrosite (MnCO₃); their concentrations in water resources were limited by the solubility of mineral phases. All of these processes are significantly pH-dependent, implying that a small decline in pH could result in a drastic increase in contaminant concentrations and become a pollution threat to the water resources of the Gubong area. Received: 13 December 1999 · Accepted: 21 March 2000  相似文献   

Hydrodynamics and sedimentation induced by large-scale coastal developments in the Keum River Estuary, Korea   总被引：1，自引：0，他引：1  

T.I. Kim  B.H. Choi  S.W. Lee 《Estuarine, Coastal and Shelf Science》2006,68(3-4):515

The macro-tidal Keum River Estuary located in the eastern Yellow Sea has been suffering siltation and morphological change since 1994. To understand the effects of the large-scale coastal developments on the sedimentation processes in the estuary, hydrodynamic and sedimentary data collected from 1985 to 2002 were analyzed and numerical experiments of hydrodynamics were performed. The sedimentation rate in the estuary increased by a factor of 1.9, from 3.5 × 10⁶ to 6.7 × 10⁶ m³ y⁻¹, after the construction of a dam in the upper reaches of the estuary in 1994. Large part of the estuary is veneered by the muddy sediments noticeably, which were rarely found before dam construction. Since then, siltation has concentrated in the upper estuary rather than the lower. The upstream transport and accumulation of fine-grained sediments is due to: (1) the change to flood-dominance in the main channel, i.e. the relative intensification of flood current and the flood-directed residual current; and (2) the decrease in transport capacity in the upper estuary, i.e. the marked decrease in current velocity, which was induced by dam construction. The former has resulted in the ebb-dominance of the Gaeya channel, a distributary in the north of the main channel. The tidal pumping of fine sediments was reinforced not by the freshwater/saltwater interaction but by the residual tidal circulation. The sediment fluxes observed in 2001–2002 demonstrate year-round net inflow both at the entrance of the jetties and at the Gaeya channel, which implies that the sediments delivered by the Keum River are entirely confined to the estuary, incapable of escaping to the sea. The net inward transport of fine sediments may accumulate pollutants adsorbed to or absorbed in the sediment grains in the estuary, thus deteriorating the benthic environment gradually and the water quality eventually.  相似文献   

A synchronously coupled tide–wave–surge model of the Yellow Sea     

Byung Ho Choi  Hyun Min Eum  Seung Buhm Woo 《Coastal Engineering》2003,47(4):381-398

A coupled wave–tide–surge model has been established in this study in order to investigate the effect of tides, storm surges, and wind waves interactions during a winter monsoon on November 1983 in the Yellow Sea. The coupled model is based on the synchronous dynamic coupling of a third-generation wave model, WAM-Cycle 4, and the two-dimensional tide–surge model. The surface stress generated by interactions between wind and waves is calculated using the WAM-Cycle 4 directly based on an analytical approximation of the results obtained from the quasi-linear theory of wave generation. The changes of bottom friction factor generated by waves and current interactions are calculated by using simplified bottom boundary layer model. The model simulations showed that bottom velocity and effective bottom drag coefficient induced by combination of wave and current were increased in shallow waters of up to 50 m in the Yellow Sea during the wintertime strong storm conditions.  相似文献   

Characterization of proteins in the muscle of<Emphasis Type="Italic">limanda yokohamae</Emphasis> from the masan bay,Korea     

Soo Woon Kim  Sam Moon Kim  Dong Kun Lee  Hyo Bang Moon  Hee Gu Choi  Chang Keun Kang  Eun Sang Choe 《Ocean Science Journal》2007,42(2):129-134

Increasing industrial development in the Masan Bay area of Korea over the past decades increased the risk for the survival of marine organisms in the bay area by the deterioration of the water quality. Since living organisms have the ability to adapt contamination-associated stimuli by the alteration of gene expression, changes in proteins can be used as an important criterion for assessing the levels of environmental conditions. In this study, therefore, alterations of the expression of proteins in the muscle ofLimanda yokohamae from Dukdong and Dotsum in the bay area were surveyed and characterized as compared with Haegumgang, which served as a control site. The results demonstrated that the twenty spots detected from Dukdong and Dotsum were similar to each other. Fifteen proteins were found to be predicted or undefined proteins, while five proteins were identified as heavy polypeptide 11 of myosin, apolipoprotein A-I, fibroblast growth factor 17b precursor, G protein-coupled receptor kinase 1 b and bonnie and clyde. These data suggest that local fish in the bay area have dysfunction in muscle physiology including contraction, lipid metabolism, proliferation and differentiation and nervous system.  相似文献   

Nonlinear wave profiles of wave–wave interaction in a finite water depth by fixed point approach     

T.S. Jang  S.H. Kwon  H.S. Choi 《Ocean Engineering》2007,34(3-4):451-459

In this paper, a superposition of two periodic wave profiles in a finite water depth was investigated. This paper is focused on the improvement of a wave profile on the linear superposition of two waves. This improvement was realized by introducing an iterative method, which was based on a fixed point approach. Application of the fixed point approach to the wave superposition made it possible to obtain a wave profile of wave–wave interaction. The improved result of the wave profile was in good agreement with that of the nonlinear perturbation solution of the second order. It was interesting that the improved result revealed the higher-order nonlinear frequencies for two interacting Stokes waves while Dalzell's solution by a perturbation method could not predict them.  相似文献   

Nonlinear mooring line induced slow drift motion of an ALP-tanker     

H.S. Choi  J.Y.K. Lou 《Ocean Engineering》1993,20(3)

A tanker moored to an articulated loading platform (ALP) is modeled by a 2-DOF system. The mooring line between the ALP and tanker is represented by an unsymmetric, piecewise-nonlinear restoring function. Forced vibrations of this system are investigated using direct numerical integration. The highly nonlinear characteristics, including multiple solution, subharmonics, and bifurcations are discussed. Slow drift oscillation could occur under harmonic excitations due to nonlinearities of the systems. The sensitivity of the dynamic response of the strong nonlinear system with respect to system parameters and initial conditions is examined.  相似文献   

Maximum daily rainfall in South Korea   总被引：3，自引：0，他引：3  

Saralees Nadarajah  Dongseok Choi 《Journal of Earth System Science》2007,116(4):311-320

Annual maxima of daily rainfall for the years 1961–2001 are modeled for five locations in South Korea (chosen to give a good geographical representation of the country). The generalized extreme value distribution is fitted to data from each location to describe the extremes of rainfall and to predict its future behavior. We find evidence to suggest that the Gumbel distribution provides the most reasonable model for four of the five locations considered. We explore the possibility of trends in the data but find no evidence suggesting trends. We derive estimates of 10, 50, 100, 1000, 5000, 10,000, 50,000 and 100,000 year return levels for daily rainfall and describe how they vary with the locations. This paper provides the first application of extreme value distributions to rainfall data from South Korea.  相似文献   

Computation of Tsunamis in the East (Japan) Sea Using Dynamically Interfaced Nested Model     

B. H. Choi  E. Pelinovsky  S. J. Hong  S. B. Woo 《Pure and Applied Geophysics》2003,160(8):1383-1414

-- A study of 1983 and 1993 tsunami events in the East (Japan) Sea using multigrid dynamically-interfaced finite difference models was performed to produce detailed features of coastal inundations along the eastern coast of Korea. The computational domain is composed of several subregions with different grid sizes connected in parallel or inclined directions. The innermost subregion represents the coastal alignment reasonably well and has a grid size of about 30 meters. Numerical simulations have been performed in the framework of shallow-water equations (linear, as well as nonlinear) over the plane or spherical coordinate system, depending on the dimensions of the subregion. Results of simulations show the general agreements with the observed data of the runup height for both tsunamis. The evolution of the distribution function of tsunami heights is studied numerically and it shows a tendency to the log-normal curve for a long distance from the source.  相似文献   

The Impacts of Socioeconomic Development and Climate Change on Severe Weather Catastrophe Losses: Mid-Atlantic Region (MAR) and the U.S.     

Onelack Choi  Ann Fisher 《Climatic change》2003,58(1-2):149-170

One strand of research relates the magnitude of severe weather disasters to climatic and human development factors; another highlights dramatic growth in catastrophe losses. However, there have been few attempts to put the two strands together. Here we use an explicit modeling framework to determine the contribution of climate variability relative to human factors in reported catastrophe losses. We then examine how future climate change can be expected to affect losses from natural disasters. Simultaneous regression models are constructed from three equations in which the dependent variables are U.S. flood loss, U.S. hurricane loss and U.S. catastrophe loss. Then two kinds of simulation under two climate change scenarios explore how climate change would affect losses. The climate change scenarios respectively project 13.5% and 21.5% increases in annual precipitation. The first simulation increases only the mean value of annual precipitation; the second simulation assumes that the mean and standard deviation of annual precipitation change in the same proportion. Results show that the growth in reported losses from weather-related natural disasters is due mainly to three socioeconomic factors: inflation, population growth and growth in per capita real wealth. However, weather variables such as precipitation and the number of hurricanes per period also clearly affect losses. The three stage least squares (3SLS) simultaneous equation model shows that a 1% increase in annual precipitation would enlarge catastrophe loss by as much as 2.8%. These findings are suggestive as planning signals to decision makers.  相似文献   

Main-group pallasites: chemical composition, relationship to IIIAB irons, and origin     

John T. Wasson  Byeon-Gak Choi 《Geochimica et cosmochimica acta》2003,67(16):3079-3096

We used neutron activation to characterize the metal of 33 main-group pallasites (PMG), widely held to be samples of a core-mantle interface. Most PMG cluster in a narrow range of metal and silicate compositions, but 6 are assigned to an anomalous subset (PMG-am) because of their deviant metal compositions, and 4 others to another anomalous subset (PMG-as) because of their appreciably higher olivine Fa contents. Metal compositions in all PMG are closely related to those in evolved IIIAB irons, and are generally consistent with their formation in the IIIAB parent asteroid. On element-Au diagrams for incompatible elements the normal PMG plot near an extrapolation of IIIAB trends to higher Au concentrations. On element-Au plots of compatible elements such as Ir or Pt the loci of PMG spread out over a broader region explainable by mixing of evolved IIIAB magma with early-crystallized core or mantle-residue solids.Two features of PMG require special models: (1) Ga and Ge contents are generally high (≈1.5×) compared to the IIIAB-based mixing model: and (2) the FeO/(FeO + MgO) ratios span a surprisingly wide range, from 0.11-0.14 in normal PMG to 0.16 to 0.18 in PMG-as This range is larger than expected in a cumulate layer at the base of a mantle. We suggest that both features may be related to the interaction of PMG precursors with a highly evolved magmatic gas phase, and that some or all of these anomalies may have resulted from vapor deposits in voids near the core-mantle interface.An important boundary condition for understanding the detailed PMG origin at the core-mantle interface is the large difference between the solidus temperature of Fa11 olivine (≈2000 K) and the liquidus temperature of an evolved IIIAB melt containing >100 mg/g S and some P (≈1600 K). Following the mixing event that formed the PMG it is therefore reasonable that there would have been olivine rubble floating on top of the IIIAB-like magma, but with appreciable void space present just above the upper level reached by the magma. These voids would have contained gases released from the magma during its flow into the PMG region. We suggest that Ga and Ge, the two most volatile siderophiles in our element set, were added to PMG metal from the magmatic gas. We also suggest that the magmatic gas was oxidizing and that the PMG having high olivine fayalite contents formed in regions where the ratio of void to olivine was high, and that some metallic Fe was oxidized and entered the olivine (or the phosphoran olivine). In support of the latter idea is the observation that both Ni and Co are elevated in the PMG-as (Fa≥16) compared to values predicted by IIIAB trends.We analyzed two Eagle-Station pallasites (PES); after correction for weathering effects in Cold Bay, its composition is found to closely resemble that of Eagle Station but to represent a more evolved composition (i.e., lower Ir, higher Au). Vermillion and Yamato 8451 have been called pyroxene pallasites but have metal compositions (unrelated to those of the PMG or PES) that are too different from each other to even allow assignment to the same grouplet.  相似文献