腰英台气田天然气水合物防治     

段宝林  钱卫明 《海洋地质译丛》2008,(1):78-81

松辽盆地南部长岭断陷腰英台深层构造腰深1井井筒及输气管线发生水合物堵塞现象,分析认为天然气水合物是导致堵塞的原因。天然气水合物是在一定温度和压力条件下由天然气中烃分子与游离水结合而形成。计算出腰深1井水合物添加甲醇的合理量,通过从油管和套管添加甲醇,使该井恢复了正常生产,日产气量（6～12）×10^4m^3。防堵的关键是注入甲醇和连续平稳生产。  相似文献   

天然气水合物的上界面——硫酸盐还原-甲烷厌氧氧化界面   总被引：3，自引：0，他引：3  

栾锡武 《海洋地质与第四纪地质》2009,(2)

定义了海域天然气水合物成矿带的上界面。指出在地球深部存在最原始的、从根本上不依靠光合作用来生存的生命系统。根据对ODP岩心样品中微生物数量的统计,海底以下沉积层中的生物数量可能占据全球原核生物总量的70%,其生物总碳量和地球表面所有植物的碳总量相当。地球内部如此巨大的生物总量应该在地壳中的气体分布等方面起着重要作用。甲烷在地壳层中广泛存在,并主要是微生物成因的。微生物产甲烷的途径主要有两个,一是二氧化碳还原,另一个是醋酸盐发酵。相应地,参与产甲烷的微生物菌群主要是产甲烷菌和食醋酸菌。甲烷在沉积层中的厌氧氧化是一个不争的事实。该过程发生在海底以下一个非常局限的区带,称为硫酸盐还原-甲烷厌氧氧化区带。通常,这个区带很窄,仅为一个面,因此,硫酸盐还原-甲烷厌氧氧化区带又称硫酸盐还原-甲烷厌氧氧化界面。这是一个基本的生物地球化学界面,在功能上它起到屏蔽甲烷向海底和大气逸散的作用,是一个巨大的甲烷汇。甲烷的厌氧氧化同样是一个由微生物介导的过程,参与此过程的微生物主要是食甲烷古菌和硫酸盐还原菌。硫酸盐还原-甲烷厌氧氧化界面在海洋沉积层中一般深可达海底以下上百米,浅可至海底。此界面为天然气水合物的上界面,该界面以上没有甲烷...  相似文献   

南海东沙东北部甲烷缺氧氧化作用的生物标志化合物及其碳同位素组成   总被引：5，自引：0，他引：5  

于晓果  韩喜球  李宏亮  金肖兵  龚建明  ErwinSUESS  黄永样  吴能友  苏新 《海洋学报》2008,30(3):77-84

南海东沙东北部碳酸盐岩和泥质沉积物中的生物标志化合物组合及其碳同位素组成分析表明,研究区内甲烷缺氧氧化作用(anaerobic oxidation of methane-AOM)发育.研究区内碳酸盐岩中含丰富的AOM标志化合物,2,6,11,15-四甲基十六烷(Crocetane-Cr.)、2,6,10,15,19-五甲基番茄烷(Pentamethylicosane-PMI)和2,6,10,15,19,23-六甲基二十四烷(Squalane-Sq角鲨烷)的13C亏损强烈(δ13C值介于-74.2‰~-119.0‰PDB之间),表明碳酸盐岩形成于AOM,同时反映该研究区曾发生过强烈、持续的富CH₄流体释放活动.柱状泥质沉积物中,AOM生物标志化合物在硫酸岩-甲烷过渡带(SMI-Sulfate-Methane Interface)边界附近相对丰度高,SMI之上样品中含量低,或未检出,表明现代环境在SMI附近有大量嗜甲烷微生物生长,使得深部上升的甲烷被大量消耗,很少有甲烷逸出海底.AOM生物标志化合物可用来指示SMI边界.不同站位、不同岩性AOM生物标志化合物组成(包括碳同位素组成)的差异反映了嗜甲烷古细菌组成的不同.  相似文献   

Dissolved inorganic carbon (DIC) and its carbon isotopic composition in sediment pore waters from the Shenhu area,northern South China Sea   总被引：2，自引：0，他引：2  

Tao Yang  Shao-Yong Jiang  Jing-Hong Yang  Ge Lu  Neng-You Wu  Jian Liu  Dao-Hua Chen 《Journal of Oceanography》2008,64(2):303-310

The Shenhu area is one of the most favorable places for the occurrence of gas hydrates in the northern continental slope of the South China Sea. Pore water samples were collected in two piston cores (SH-A and SH-B) from this area, and the concentrations of sulfate and dissolved inorganic carbon (DIC) and its carbon isotopic composition were measured. The data revealed large DIC variations and very negative δ ¹³C-DIC values. Two reaction zones, 0–3 mbsf and below 3 mbsf, are identified in the sediment system. At site SH-A, the upper zone (0–3 mbsf) shows relatively constant sulfate and DIC concentrations and δ ¹³C-DIC values, possibly due to bioturbation and fluid advection. The lower zone (below 3 mbsf) displays good linear gradients for sulfate and DIC concentrations, and δ ¹³C-DIC values. At site SH-B, both zones show linear gradients, but the decreasing gradients for δ ¹³C-DIC and SO₄ ²⁻ in the lower zone below 3 mbsf are greater than those from the upper zone, 0–3 mbsf. The calculated sulfate-methane interface (SMI) depths of the two cores are 10.0 m and 11.1 m, respectively. The depth profiles of both DIC and δ ¹³C-DIC showed similar characteristics as those in other gas hydrate locations in the world oceans, such as the Blake Ridge. Overall, our results indicate an anaerobic methane oxidation (AMO) process in the sediments with large methane flux from depth in the studied area, which might be linked to the formation of gas hydrates in this area.  相似文献   

Geochemistry of pore waters from the Xisha Trough, northern South China Sea and their implications for gas hydrates   总被引：2，自引：0，他引：2  

Shao-Yong Jiang  Tao Yang  Lu Ge  Jing-Hong Yang  Hong-Fei Ling  Neng-You Wu  Jian Liu  Dao-Hua Chen 《Journal of Oceanography》2008,64(3):459-470

This paper reports all available geochemical data on sediments and pore waters from the Xisha Trough on the northern continental margin of the South China Sea. The methane concentrations in marine sediments display a downhole increasing trend and their carbon isotopic compositions (δ ¹³C = −25 to −51‰) indicate a thermogenic origin. Pore water Cl⁻ concentrations show a range from 537 to 730 mM, and the high Cl⁻ samples also have higher concentrations of Br⁻, Na⁺, K⁺, and Mg²⁺, implying mixing between normal seawater and brine in the basin. The SO₄ ²⁻ concentrations of pore waters vary from 19.9 to 36.8 mM, and show a downhole decreasing trend. Calculated SMI (sulfate-methane interfaces) depths and sulfate gradients are between 21 and 47 mbsf, and between −0.7 and −1.7 mM/m, respectively, which are similar to values in gas hydrate locations worldwide and suggest a high methane flux in the basin. Overall, the geochemical data, together with geological and geophysical evidence, such as the high sedimentation rates, high organic carbon contents, thick sediment piles, salt and mud diapirs, active faulting, abundant thermogenic gases, and occurrence of huge bottom simulating reflector (BSR), are suggestive of a favorable condition for occurrence of gas hydrates in this region.  相似文献   

南海东北部陆坡与恒春海脊天然气水合物分布的地震反射对比     

尚继宏  李家彪  章家保 《海洋通报(英文版)》2008,10(1):64-74

经过对"探宝号"调查船在2001年8月在南海东北部陆坡及台湾南部恒春海脊海域采集的多道地震剖面资料进行的地震反射波数据分析、研究和解释,结果表明:(1)南海东北部陆坡段区域和台湾南部恒春海脊海域地震剖面上均显示有被作为天然气水合物存在标志的BSR,但两区域构造成因、形式和相关地质环境的不同造成了此两处的天然气水合物成因及过程的不同.(2)南海东北部陆坡区域的水合物形成与该区广泛发育的断裂带、滑塌构造体及其所形成的压力场屏蔽环境有关,而台湾南部恒春海脊海域的天然气水合物的形成则与马尼拉海沟俯冲带相关的逆冲推覆构造、增生楔等及其所对应的海底流体疏导体系有关.(3)南海陆缘区域广泛发育有各种断裂带、滑塌构造体、泥底辟、俯冲带、增生楔等,且温压环境合适,是天然气水合物矿藏极有可能广泛分布的区域.  相似文献   

海上E区天然气水合物地质、地震、地球化学特征综合研究与成藏远景预测   总被引：12，自引：3，他引：9       下载免费PDF全文

孙春岩  牛滨华  文鹏飞  黄永样  王宏语  黄新武  李佳 《地球物理学报》2004,47(6):1076-1085

本文提出一种将地质、地震、地球化学分析相结合的方法,以研究海区天然气水合物的成藏条件,首先用物源、构造、沉积和地温等资料进行地质分析,确定海区天然气水合物成藏的地质条件;然后根据对水合物的地震属性（BSR,AVO,BZ等）分析和正演模拟研究,预测水合物及其游离气的存在,结合地质条件,圈定出水合物成藏的有利区带;最后结合对水合物主要成分（甲烷及烃类等）的地球化学异常分析,对研究区天然气水合物成藏的远景作出评价．野外实践结果表明,这种综合研究方法是有效可行的,为海区天然气水合物勘探提供了一种新的研究途径．  相似文献   

沉积物孔隙毛细管压力与甲烷水合物饱和度关系研究   总被引：1，自引：1，他引：0  

孙始财  刘昌岭  业渝光  刘玉峰 《海洋学报(英文版)》2014,33(10):30-36

To better understand the relationship between the pore capillary pressure and hydrate saturation in sediments, a new method was proposed. First, the phase equilibria of methane hydrate in fine-grained silica sands were measured. As to the equilibrium data, the pore capillary pressure and saturation of methane hydrate were calculated. The results showed that the phase equilibria of methane hydrates in fine-grained silica sands changed due to the depressed activity of pore water caused by the surface group and negatively charged characteristic of silica particles as well as the capillary pressure in small pores together. The capillary pressure increased with the increase of methane hydrate saturation due to the decrease of the available pore space. However, the capillary-saturation relationship could not yet be described quantitatively because of the stochastic habit of hydrate growth.  相似文献   

Gas hydrate identified in sand-rich inferred sedimentary section using downhole logging and seismic data in Shenhu area,South China Sea     

《Marine and Petroleum Geology》2014

Downhole wireline log (DWL) data was acquired from eight drill sites during China's first gas hydrate drilling expedition (GMGS-1) in 2007. Initial analyses of the acquired well log data suggested that there were no significant gas hydrate occurrences at Site SH4. However, the re-examination of the DWL data from Site SH4 indicated that there are two intervals of high resistivity, which could be indicative of gas hydrate. One interval of high resistivity at depth of 171–175 m below seafloor (mbsf) is associated with a high compressional- wave (P-wave) velocities and low gamma ray log values, which suggests the presence of gas hydrate in a potentially sand-rich (low clay content) sedimentary section. The second high resistivity interval at depth of 175–180 mbsf is associated with low P-wave velocities and low gamma values, which suggests the presence of free gas in a potentially sand-rich (low clay content) sedimentary section. Because the occurrence of free gas is much shallower than the expected from the regional depth of the bottom simulating reflector (BSR), the free gas could be from the dissociation of gas hydrate during drilling or there may be a local anomaly in the depth to the base of the gas hydrate stability zone. In order to determine whether the low P-wave velocity with high resistivity is caused by in-situ free gas or dissociated free gas from the gas hydrate, the surface seismic data were also used in this analysis. The log analysis incorporating the surface seismic data through the construction of synthetic seismograms using various models indicated the presence of free gas directly in contact with an overlying gas hydrate-bearing section. The occurrence of the anomalous base of gas hydrate stability at Site SH4 could be caused by a local heat flow conditions. This paper documents the first observation of gas hydrate in what is believed to be a sand-rich sediment in Shenhu area of the South China Sea.  相似文献   

天然气水合物和地热资源组合评价方法     

张宪政  肖宏跃  陈思宇 《海洋地质前沿》2014,30(6):66-70

近年来的研究表明,海洋中天然气水合物的成藏和分布受温度的影响较大,一些海域中的天然气水合物资源与地热资源同时存在且有一定的分布规律。在利用地热开采天然气水合物基础上把2种资源结合起来利用,将会对海洋天然气水合物的开发有重要意义。参考组合评价相关经验公式,基于该开采方法对天然气水合物和地热资源组合评价提出了相关的方法研究,并通过实例应用,丰富了该开采方法的可行性的论证,并对于2种资源的综合利用的靶区优选有一定的指导作用。  相似文献