Factors controlling the groundwater transport of U, Th, Ra, and Rn   总被引：1，自引：0，他引：1  

A. Tricca  D. Porcelli  G. J. Wasserburg 《Journal of Earth System Science》2000,109(1):95-108

A model for the groundwater transport of naturally occurring U, Th, Ra, and Rn nuclides in the²³⁸U and²³²Th decay series is discussed. The model developed here takes into account transport by advection and the physico-chemical processes of weathering, decay, α-recoil, and sorption at the water-rock interface. It describes the evolution along a flowline of the activities of the²³⁸U and²³²Th decay series nuclides in groundwater. Simple sets of relationships governing the activities of the various species in solution are derived, and these can be used both to calculate effective retardation factors and to interpret groundwater data. For the activities of each nuclide, a general solution to the transport equation has been obtained, which shows that the activities reach a constant value after a distance ϰ_i, characteristic of each nuclide. Where ϰ_i is much longer than the aquifer length, (for²³⁸U,²³⁴U, and²³²Th), the activities grow linearly with distance. Where gKⁱ is short compared to the aquifer length, (for²³⁴Th,²³⁰Th,²²⁸Th,²²⁸Ra, and²²⁴Ra), the activities rapidly reach a constant or quasi-constant activity value. For²²⁶Ra and²²²Rn, the limiting activity is reached after 1 km. High δ²³⁴U values (proportional to the ratio^ɛ234Th/^W238U) can be obtained through high recoil fraction and/or low weathering rates. The activity ratios²³⁰Th/²³²Th,²²⁸Ra/²²⁶Ra and²²⁴Ra/²²⁶Ra have been considered in the cases where either weathering or recoil is the predominant process of input from the mineral grain. Typical values for weathering rates and recoil fractions for a sandy aquifer indicate that recoil is the dominant process for Th isotopic ratios in the water. Measured data for Ra isotope activity ratios indicate that recoil is the process generally controlling the Ra isotopic composition in water. Higher isotopic ratios can be explained by different desorption kinetics of Ra. However, the model does not provide an explanation for²²⁸Ra/²²⁶Ra and²²⁴Ra/²²⁶Ra activity ratios less than unity. From the model, the highest²²²Rn emanation equals 2ɛ. This is in agreement with the hypothesis that²²²Rn activity can be used as a first approximation for input by recoil (Krishnaswamiet al 1982). However, high²²²Rn emanation cannot be explained by production from the surface layer as formulated in the model. Other possibilities involve models including surface precipitation, where the surface layer is not in steady-state.  相似文献   

粉煤灰中污染离子淋释试验及其运移模型   总被引：9，自引：0，他引：9  

许光泉  桂和荣  黄文辉  李禄荣 《煤田地质与勘探》1999,27(1):48-51

通过对不同介质条件下粉煤灰中污染离子的淋释实验,得出一些离子淋释规律,在此基础上,对粉煤灰中淋释污染离子在地下水中的浓度变化从理论上给出两种数学模型   相似文献   

Direct Conversion of Food Waste into 3D Porous Carbon Traps for Selective Adsorption of Cationic Dyes     

Anitha Senthamizhan  Brabu Balusamy  Doriana Debellis  Jose Alejandro Heredia-Guerrero  Giorgio Mancini  Riccardo Carzino  Luca Ceseracciu  Athanassia Athanassiou  Despina Fragouli 《洁净——土壤、空气、水》2023,51(1):2200284

Conversion of waste biomass into valuable functional materials accomplishes the concept of circular economy in the development of sustainable waste management, and also recovery of such resources possibly reduces the requirement of feedstocks. In this scenario, the development of methodologies toward the direct conversion of the raw biomass into solid adsorbent materials without the use of any templates is highly desirable, but exceptionally challenging due to the complexity of the process. Here the direct synthesis of 3D porous carbon traps by a simple, cost-effective, and template-free process starting from a kitchen-based recipe and fermented food waste is described. Precisely, a robust carbon trap is formed with a spongy structure and highly interconnected hierarchical pores after the pyrolysis of a rice-based foam in the air. The developed materials float on water and interact efficiently with cationic dyes at static conditions. Importantly, such performance of the 3D carbon traps is not affected in the presence of anionic dyes, indicating the excellent selectivity towards the adsorption of cationic dyes. The adsorbent can be easily recovered and reused for up to 3 cycles without releasing any byproducts, thus, without causing hazardous risk of any secondary pollution to the environment.  相似文献   

底泥就地稳定化中零价铁(Fe⁰)对有机污染物的作用及其对上覆水体水质的影响     

章萍  相明雪  马若男  刘强  葛刚  钱光人 《湖泊科学》2018,30(5):1218-1224

在实验室模拟静态湖泊体系条件下,通过向实际底泥中投加零价铁(Fe~0),考察反应前后底泥中有机物数量、种类、总有机质含量以及上覆水体溶解氧(DO)浓度、氧化还原电位(Eh)、pH和化学需氧量(CODCr)浓度等指标的变化,探讨Fe~0对底泥有机物的降解效果以及对上覆水体水质的影响.结果表明,投加Fe~0处理80 d后,(1)经GC-MS检测出底泥中易被降解的小分子有机物(分子量小于200)数量明显增多,底泥总有机去除率为44%.(2)上覆水体的DO浓度、Eh和pH都有不同程度的变化.DO浓度从6.6 mg/L迅速下降至0.2 mg/L,Eh从150 mV左右下降至74 mV,pH升高至8.4,此体系易形成厌氧环境;且上覆水体中CODCr低于纯底泥-水体系,上覆水中DO浓度、Eh及pH与CODCr浓度具有一定相关性.综上,底泥中投加Fe~0可有效降解有机物,且不会对上覆水体产生持久、较大的影响.  相似文献   

基于多指标综合评分法筛选地表水环境优先污染物——以湖北涨渡湖为例     

丁琪琪  龚雄虎  王兆德  金苗  卢少勇  张路  赵中华 《湖泊科学》2022,34(1):90-107

人类活动和社会经济迅速发展导致大量化学品排放进入地表水环境,对水生生态系统和人类健康产生诸多不利影响,如何从众多的化学品中筛选识别出具有潜在危害的优先污染物是水污染治理和管控的关键.本研究基于污染物环境暴露水平、持久性、生物累积性、生态风险和人体健康风险5个评价参数,构建多指标综合评分法定量筛选识别地表水环境优先污染物类别,并应用于涨渡湖水体中优先污染物清单的建立.污染物环境暴露水平基于靶向分析综合考虑了污染物环境实测浓度和检出频率.目标污染物持久性和生物累积性毒害性参数分别采用生物降解系数和正辛醇-水分配系数来表征.此外在物种敏感度分布法和评估因子法的基础上计算生态风险熵以定量表征生态风险,人体健康风险则由终生致癌风险指数或危害指数来表征.基于该多指标综合评分法可于涨渡湖水体7类151种特征污染物中筛查出41种优先污染物,主要包括11种多氯联苯、8种有机氯农药、6种多环芳烃、4种邻苯二甲酸酯、4种挥发性有机物和8种金属元素.鉴于不同地表水环境污染状况不同,通过多指标综合评分法可建立因地制宜的优先污染物清单,从而有利于形成以保护水生生物和人类健康为最终目标的优先污染物水质基准,为地表水环境污染物管控及治理提供方法学支撑和科学依据.  相似文献   

江苏省入太湖污染量分析(1998-2007年)   总被引：14，自引：8，他引：6  

马倩  刘俊杰  高明远 《湖泊科学》2010,22(1):29-34

近年来,太湖水体受到了严重污染,水环境质量逐年下降,太湖水环境的状况直接影响了地区的经济和社会发展,保护太湖已列为国家重点治理项目。本文根据1998-2007年环太湖水文巡测资料及主要入湖河道水质监测成果,分析入湖水量、入湖河道水质、入湖污染物量及其变化趋势,为太湖地区水环境综合整治提供技术支撑和决策依据。  相似文献   

Analysis of the Water Environmental Capacity of Zhongba-Nyingchi Section of the Yarlung Tsangpo River     

ZHAO Xiang  LIU Zhaofei  WANG Rui  YAO Zhijun 《资源与生态学报(英文版)》2018,9(6):690-699

The Yarlung Tsangpo River, the longest river in Tibet, houses most of the population and economy in Tibet Autonomous province. Under the rapid development of economy and society in Tibet, the pollution in the Yarlung Tsangpo River basin has rapidly increased. Evaluating water quality and water environmental capacity is needed for water resource management in Tibet. This study used a single factor evaluation method to evaluate water quality of the Zhongba-Nyingchi section of the Yarlung Tsangpo River based on measured data of COD_Cr, NH3-N and TP in the study area. Based on these data, determinations of ideal water environmental capacity, emissions of pollutants and remaining water environmental capacity of the study area were made by a one-dimensional steady water quality model under either section-head control or cross-section control. The data indicate that most of the monitoring sections in the study area experienced good water quality. The three pollutants all had large remaining water environmental capacity generally, but TP exceeded state levels in the two upstream functional areas, and levels above state standards of COD_Cr and TP were found in several calculation cells of the two downstream functional areas. Therefore, emissions of pollutants need to be reduced to protect the water environment quality of the Yarlung Tsangpo River.  相似文献   

Accumulation discrepancy of heavy metal and organic pollutants in three near-shore depositional environments, southeastern China     

Huan-Xin Weng  Yang-Ming Zhu  Ya-Chao Qin  Jian-Yu Chen  Xun-Hong Chen   《Journal of Asian Earth Sciences》2008,31(4-6):522-532

Heavy metal and organic pollutants in sediments along the coastal zone of southeastern China have been investigated. Sediment samples are retrieved from three depositional environments: coast, estuary, and tide-affected river mouth. The relative abundance of heavy metal and organic pollutants is related to their geochemical properties as well as depositional environments and anthropogenic discharge. Based on a sequential extraction method, it is revealed that anthropogenic Pb, Cr, Cu, and Cd are mainly bound to Fe–Mn oxides, suggesting that adsorption and co-precipitation of Fe–Mn oxides are in the control of their transfer processes from water column to sediment. Heavy metal bound to carbonates is also an important pool especially for Cd, Mn, and Pb. The main organic pollutants found in the study area include petroleum-related alkanes, phthalic acid ester, organic silicon, chlorophenol, phenyl ether, and amine. The accumulation of heavy metals and organics in surficial sediments has a decrease tendency from estuarine environment to coastal environment and to tide-affected river mouth.  相似文献   

基于粮食安全的村镇区域农用地质量综合评价系统设计及其应用     

刘以  张扬  方乐道 《测绘与空间地理信息》2017,(2):24-26

基于ArcGIS Obejects,设计并开发了基于粮食安全的村镇区域农用地质量综合评价系统,该系统能够对不同尺度的农用地进行评价,特别是村镇区域,充分考虑了污染物对农用地质量的影响,融合了多种指标获取、指标量化、权重确定、分值计算等技术,并能够对评价的成果进行专题图的制作,适用于不同目的的农用地质量评价。  相似文献   

厦门近岸定点降水的化学组成及来源分析——2006年7月14日热带风暴“碧利斯”影响厦门期间   总被引：2，自引：0，他引：2       下载免费PDF全文

杜俊民  陈立奇  张远辉  林奇  杨绪林  孙霞  李伟 《海洋学报》2007,29(6):147-154

随着工农业生产的快速发展,大量污染物通过各种途经进入大气层,而降雨的冲刷则是大气中污染物和其他营养物输入海洋的重要途经[1~8].因此研究台风降雨的化学特征对近海养殖、渔业、环境保护等具有特别重要的意义.  相似文献