Oil-generation kinetics for organic facies with Type-II and -IIS kerogen in the Menilite Shales of the Polish Carpathians     

M.D. Lewan  M.J. Kotarba  D. Wi?c?aw 《Geochimica et cosmochimica acta》2006,70(13):3351-3368

The Menilite Shales (Oligocene) of the Polish Carpathians are the source of low-sulfur oils in the thrust belt and some high-sulfur oils in the Carpathian Foredeep. These oil occurrences indicate that the high-sulfur oils in the Foredeep were generated and expelled before major thrusting and the low-sulfur oils in the thrust belt were generated and expelled during or after major thrusting. Two distinct organic facies have been observed in the Menilite Shales. One organic facies has a high clastic sediment input and contains Type-II kerogen. The other organic facies has a lower clastic sediment input and contains Type-IIS kerogen. Representative samples of both organic facies were used to determine kinetic parameters for immiscible oil generation by isothermal hydrous pyrolysis and S₂ generation by non-isothermal open-system pyrolysis. The derived kinetic parameters showed that timing of S₂ generation was not as different between the Type-IIS and -II kerogen based on open-system pyrolysis as compared with immiscible oil generation based on hydrous pyrolysis. Applying these kinetic parameters to a burial history in the Skole unit showed that some expelled oil would have been generated from the organic facies with Type-IIS kerogen before major thrusting with the hydrous-pyrolysis kinetic parameters but not with the open-system pyrolysis kinetic parameters. The inability of open-system pyrolysis to determine earlier petroleum generation from Type-IIS kerogen is attributed to the large polar-rich bitumen component in S₂ generation, rapid loss of sulfur free-radical initiators in the open system, and diminished radical selectivity and rate constant differences at higher temperatures. Hydrous-pyrolysis kinetic parameters are determined in the presence of water at lower temperatures in a closed system, which allows differentiation of bitumen and oil generation, interaction of free-radical initiators, greater radical selectivity, and more distinguishable rate constants as would occur during natural maturation. Kinetic parameters derived from hydrous pyrolysis show good correlations with one another (compensation effect) and kerogen organic-sulfur contents. These correlations allow for indirect determination of hydrous-pyrolysis kinetic parameters on the basis of the organic-sulfur mole fraction of an immature Type-II or -IIS kerogen.  相似文献   

Elucidation of different forms of organic carbon in marine sediments from the Atlantic coast of Spain using thermal analysis coupled to isotope ratio and quadrupole mass spectrometry     

Elisa Lopez Capel  Jos Maria de la Rosa Arranz  Francisco J. Gonzlez-Vila  Jos Antonio Gonzlez-Perez  David A.C. Manning 《Organic Geochemistry》2006,37(12):1983

Analysis of river, estuary and marine sediments from the Atlantic coast of Spain using thermogravimetry–differential scanning calorimetry–quadrupole mass spectrometry–isotope ratio mass spectrometry (TG–DSC–QMS–IRMS) was used to (a) distinguish bulk chemical hosts for C within a sediment and humic acid fraction, (b) track C pools with differing natural C isotope ratios and (c) observe variation with distance from the coast. This is the first application of such a novel method to the characterisation of organic matter from marine sediments and their corresponding humic acid fractions. Using thermal analysis, a labile, a recalcitrant and a refractory carbon pool can be distinguished. Extracted humic fractions are mainly of recalcitrant nature. The proportion of refractory carbon is greatest in marine sediments and humic acid fractions. Quadrupole mass spectrometry confirmed that the greatest proportion of m/z 44 (CO₂) and m/z 18 (H₂O) were detected at temperatures associated with recalcitrant carbon (510–540 °C). Isotope analysis detected progressive enrichment in δ¹³C for the sediment samples with an increase in marine influence. Isotopic heterogeneity in the refractory organic matter in marine sediments could be due to products of anthropogenic origin or natural combustion products. Isotope homogeneity of humic acids confirms the presence of terrigenous C in marine sediments, allowing the terrestrial input to be characterised.  相似文献   

Editorial     

Francisco J. Gonzlez-Vila  Jos A. Gonzlez-Prez 《Organic Geochemistry》2006,37(12):1641-1642

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HP–LT Variscan metamorphism in the Cubito-Moura schists (Ossa-Morena Zone, southern Iberia)     

Guillermo Booth-Rea  Jos Fernando Simancas  Antonio Azor  Jos Miguel Azan  Francisco Gonzlez-Lodeiro  Paulo Fonseca 《Comptes Rendus Geoscience》2006,338(16):1260-1267

Multi-equilibrium thermobarometry shows that low-grade metapelites (Cubito-Moura schists) from the Ossa–Morena Zone underwent HP–LT metamorphism from 340–370 °C at 1.0–0.9 GPa to 400–450 °C at 0.8–0.7 GPa. These HP–LT equilibriums were reached by parageneses including white K mica, chlorite and chloritoid, which define the earliest schistosity (S₁) in these rocks. The main foliation in the schists is a crenulation cleavage (S₂), which developed during decompression from 0.8–0.7 to 0.4–0.3 GPa at increasing temperatures from 400–450 °C to 440–465 °C. Fe³⁺ in chlorite decreased greatly during prograde metamorphism from molar fractions of 0.4 determined in syn-S₁ chlorites down to 0.1 in syn-S₂ chlorites. These new data add to previous findings of eclogites in the Moura schists indicating that a pile of allochtonous rocks situated next to the Beja-Acebuches oceanic amphibolites underwent HP–LT metamorphism during the Variscan orogeny. To cite this article: G. Booth-Rea et al., C. R. Geoscience 338 (2006).  相似文献   

Enregistrement de la variabilité hydroclimatique au cours des 6500 dernières années sur le littoral de Cabo Frio (Rio de Janeiro,Brésil)     

Bérengère Laslandes  Florence Sylvestre  Abdelfettah Sifeddine  Bruno Turcq  Ana Luiza S. Albuquerque  Jorge Abrão 《Comptes Rendus Geoscience》2006,338(10):667-675

This study concerns a core collected in Brejo do Espinho's lagoon from Cabo Frio littoral (Brazil) submitted to dry influence of local upwelling controlled by north-east trade winds from the South Atlantic and particularly strengthened during El Niño events. Diatoms study supported by sedimentological and isotopic analyses shows dry phases infrequent before 4000 yr, a highly variable climatic phase between 3600 and 2900 yr and from 2400 yr onward a dryness enhancement. To cite this article: B. Laslandes et al., C. R. Geoscience 338 (2006).  相似文献   

Late Pleistocene highstand and recession of a small, high-altitude pluvial lake, Jakes Valley, central Great Basin, USA     

Antonio Francisco García  Martin Stokes 《Quaternary Research》2006,65(1):179-186

Models of factors controlling late Pleistocene pluvial lake-level fluctuations in the Great Basin are evaluated by dating lake levels in Jakes Valley. “Jakes Lake” rose to a highstand at 13,870 ± 50 ¹⁴C Yr B.P., receded to a stillstand at 12,440 ± 50 ¹⁴C yr B.P., and receded steadily to desiccation thereafter. The Jakes Lake highstand is roughly coincident with highstands of lakes Bonneville, Lahontan and Russell. The rise to highstand and recession of Jakes Lake were most likely controlled by a storm track steered by the polar jet stream. The final stillstand of Jakes Lake helps constrain timing of northward retreat of the polar jet stream during the Pleistocene-Holocene transition.  相似文献   

T -distributed Random Fields: A Parametric Model for Heavy-tailedWell-log Data1     

Jo R?islien  Henning Omre 《Mathematical Geology》2006,38(7):821-849

Histograms of observations from spatial phenomena are often found to be more heavy-tailed than Gaussian distributions, which makes the Gaussian random field model unsuited. A T-distributed random field model with heavy-tailed marginal probability density functions is defined. The model is a generalization of the familiar Student-T distribution, and it may be given a Bayesian interpretation. The increased variability appears cross-realizations, contrary to in-realizations, since all realizations are Gaussian-like with varying variance between realizations. The T-distributed random field model is analytically tractable and the conditional model is developed, which provides algorithms for conditional simulation and prediction, so-called T-kriging. The model compares favourably with most previously defined random field models. The Gaussian random field model appears as a special, limiting case of the T-distributed random field model. The model is particularly useful whenever multiple, sparsely sampled realizations of the random field are available, and is clearly favourable to the Gaussian model in this case. The properties of the T-distributed random field model is demonstrated on well log observations from the Gullfaks field in the North Sea. The predictions correspond to traditional kriging predictions, while the associated prediction variances are more representative, as they are layer specific and include uncertainty caused by using variance estimates.  相似文献   

Inversion for rheological parameters from post-seismic surface deformation associated with the 1960 Valdivia earthquake, Chile   总被引：3，自引：0，他引：3  

Francisco Lorenzo-Martín  Frank Roth  Rongjiang Wang 《Geophysical Journal International》2006,164(1):75-87

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Late Early Miocene lake deposits near Mauensee, central Switzerland: Fish fauna (otoliths, teeth), accompanying biota and palaeoecology     

Jürg Jost  Daniel K?lin  Tanja Schulz-Mirbach  Bettina Reichenbacher 《Eclogae Geologicae Helvetiae》2006,99(3):309-326

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韧性剪切变形对岩石地球化学行为的制约——以北阿尔金巴什考供韧性剪切带为例   总被引：6，自引：0，他引：6  

戚学祥李海兵  吴才来陈松永 《地质通报》2005,24(3):252-257

韧性剪切变形对岩石地球化学行为的制约一直是地质学家们探讨的课题。本文以构成北阿尔金红柳沟——拉配泉俯冲碰撞杂岩带与北阿尔金地块边界的巴什考供斜向逆冲型韧性剪切带为例，通过对韧性剪切带内花岗岩变形前后不同变形强度构造岩的地球化学组成进行对比，确定等比线斜率，探讨韧性变形对岩石体积和成分变异的影响。计算结果表明，在糜棱岩化过程中，糜棱岩化花岗岩体积亏损21％，花岗质糜棱岩体积亏损31％。质量平衡计算结果和等比线图表明，韧；陛剪切作用导致SiO2，流失量最大，A12O3、K2O及Ba、Rb、Sr等都有不同程度的丢失，显示出较强的活动性，MnO、P2O5、Sc位于等比线上或附近，表现出相对的稳定性。岩石中活动组分的变异是流体渗滤作用引起的，不活动组分的变异是体．积亏损造成的。  相似文献