Palaeoclimatic studies in South Shetland Islands,Antarctica, based on numerous stratigraphic variables in lake sediments     

Svante Björck  Hannelore Håkansson  Siv Olsson  Lena Barnekow  Jan Janssens 《Journal of Paleolimnology》1993,8(3):233-272

The hitherto longest found lake sediment sequence on Byers Peninsula, Livingston Island, South Shetland Islands, was analysed with respect to lithology, chronology, diatoms, Pediastrum, pollen and spores, mosses, mineralogy, and sediment chemistry. During the ca. 5000 year long development the sediments were influenced by frequent tephra fall-outs. This volcanic impact played a major role in the lake's history during two periods, 4700–4600 and 2800–2500 BP, but was of importance during the lake's entire history with considerable influence on many of the palaeoenvironmentally significant indicators. The large and complex data set was analysed and zonated with different types of multivariate analysis. This resulted in a subdivision of the sequence into 8 time periods and 21 variables. Redundancy analysis (RDA) of this data set, both without and with the tephra periods, and with 4–6 of the variables as explanatory environmental variables, reveal that climatic/environmental signals are detectable. The palaeoclimatic picture that emerged out of the tephra noise suggests that the first 100 years were characterized by mild, humid conditions. This was followed by a less mild and humid climate until ca. 4000 BP when a gradual warming seems to have started, coupled with increased humidity. These mild and humid conditions seem to have reached an optimum slightly after 3000 BP. At ca. 2500 BP a distinct climatic deterioration occurred with colder and drier conditions and long seasons with ice cover. This arid, cold phase probably reached its optimum conditions at ca. 1500 BP, when slightly warmer conditions might have prevailed for a while. Except for the modern sample with rather mild climate, the last 1400 years seem to have been fairly arid and cold, and the effects of the frequent volcanic activity during this period is only vaguely seen in the records.  相似文献   

Planar deformation features in quartz grains from the resurge deposit of the Lockne structure,Sweden     

A. M. Therriault  M. Lindstrm 《Meteoritics & planetary science》1995,30(6):700-703

Abstract— Microscopic planar deformation features (PDFs) in quartz grains are diagnostic of shock meta-morphism during hypervelocity impact cratering. Measurements of the poles of sets of PDFs and the optic axis of 25 quartz grains were carried out for a sample of the Loftarsten deposit from the Lockne area, Sweden. The most abundant PDFs observed in the sample from the Lockne area correspond to those found at known impact craters (i.e., ω (1013} and π (1012). This study confirms the previous suggestion that the Lockne structure is an impact crater. The Loftarsten is, therefore, interpreted as the final stage of resurge deposition after a marine impact at Lockne in the Middle Ordovician.  相似文献   

Investigation of the instability of graveyard orbits due to the earth's gravitational perturbations     

Jan Kostelecký  Jaroslav Klokočník 《Studia Geophysica et Geodaetica》1992,36(4):297-301

Summary The Banach theorem is applied to the Lagrange planetary equation for the semimajor axis of a geostationary satellite orbit to estimate the stability of near-geostationary satellite orbits. To achieve a graveyard (disposal) orbit, which will not interfere (=cross) the initial geostationary orbit, the geostationary semi-major axis a_g have to be increased at least by 50 km. Numerical results for a variety of graveyard orbits show that the increase of a_g by about 100 km will yield sufficiently stable orbits (accounting for the Earth's gravitational perturbations only) during the next 150 years.Dedicated to the 75th Birthday of Professor Academician Tibor Kolbenheyer  相似文献   

Magmatic evolution of the Karmøy Ophiolite Complex,SW Norway: relationships between MORB-IAT-boninitic-calc-alkaline and alkaline magmatism     

Rolf B. Pedersen  Jan Hertogen 《Contributions to Mineralogy and Petrology》1990,104(3):277-293

The polyphasal magmatic evolution of the Caledonian Karmøy Ophiolite Complex includes: (1) formation of an axis sequence from island-arc tholeiitic (IAT) and more MORB-like magmas (493+7/-4 Ma); (2) intrusion of magmas of boninitic affinity (485±2 Ma); (3) intrusion of MORB- and IAT-like magmas; (4) intrusion and extrusion of calc-alkaline magmas (470+9/-5 Ma); (5) intrusion and extrusion of basalts with alkaline trace-element affinity. Repeated intrusion of MORB and IAT-like magmas may be explained by intermittent magmatism involving magma-chamber solidification and remelting of a source characterized by initial _Nd of approximately +6.5. The boninitic rocks may have formed from two LREE-depleted sources: the primary source of the axis-sequence magmas and the residual source left after extraction of these magmas. These sources have been enriched in LREE, Th and Zr from subducted material exhibiting a continental Nd-isotope signature with initial _Nd less than-8. Covariation between _Nd and Th, Zr, Nd, Y and Yb may be explained by metasomatic enrichment of a LREE-depleted mantle source by a LREE-enriched subduction component, followed by partial melting during which the degree of melting of the metasomatized mantle source increased linearly with the amount of subduction component added to the mantle source. The calc-alkaline magmas may have formed by remelting of a highly depleted source, which became enriched in some trace elements derived from the source of the subsequent alkaline magmatism. The geology and geochemistry of the Karmøy Ophiolite Complex suggest growth of an island-arc upon newly-formed oceanic crust, followed by arc-splitting and the development of a new basin.  相似文献   

Type IV dm bursts: Onset and sudden reductions     

Arnold O. Benz  Jan Kuijpers 《Solar physics》1976,46(2):275-290

The effect of collisions of suprathermal electrons with a thermal background plasma is investigated and is shown to cause flattening of a monotonically descending velocity distribution of fast particles. As a result flare-produced energetic electrons that are trapped in a coronal magnetic arch and that are initially distributed in energy according to a power-law, can give rise to an instability of Langmuir waves in the background plasma and the subsequent emission of continuum radiation as observed in type IV dm bursts.To explain the appearance of sudden reductions observed in type IV dm outbursts the effects both of magnetic compressions of the source region and of renewed injections of fast particles on the continuum source are investigated. It is found that the latter process can explain the observed reductions.  相似文献   

Oil-generation kinetics for organic facies with Type-II and -IIS kerogen in the Menilite Shales of the Polish Carpathians     

M.D. Lewan  M.J. Kotarba  D. Wi?c?aw 《Geochimica et cosmochimica acta》2006,70(13):3351-3368

The Menilite Shales (Oligocene) of the Polish Carpathians are the source of low-sulfur oils in the thrust belt and some high-sulfur oils in the Carpathian Foredeep. These oil occurrences indicate that the high-sulfur oils in the Foredeep were generated and expelled before major thrusting and the low-sulfur oils in the thrust belt were generated and expelled during or after major thrusting. Two distinct organic facies have been observed in the Menilite Shales. One organic facies has a high clastic sediment input and contains Type-II kerogen. The other organic facies has a lower clastic sediment input and contains Type-IIS kerogen. Representative samples of both organic facies were used to determine kinetic parameters for immiscible oil generation by isothermal hydrous pyrolysis and S₂ generation by non-isothermal open-system pyrolysis. The derived kinetic parameters showed that timing of S₂ generation was not as different between the Type-IIS and -II kerogen based on open-system pyrolysis as compared with immiscible oil generation based on hydrous pyrolysis. Applying these kinetic parameters to a burial history in the Skole unit showed that some expelled oil would have been generated from the organic facies with Type-IIS kerogen before major thrusting with the hydrous-pyrolysis kinetic parameters but not with the open-system pyrolysis kinetic parameters. The inability of open-system pyrolysis to determine earlier petroleum generation from Type-IIS kerogen is attributed to the large polar-rich bitumen component in S₂ generation, rapid loss of sulfur free-radical initiators in the open system, and diminished radical selectivity and rate constant differences at higher temperatures. Hydrous-pyrolysis kinetic parameters are determined in the presence of water at lower temperatures in a closed system, which allows differentiation of bitumen and oil generation, interaction of free-radical initiators, greater radical selectivity, and more distinguishable rate constants as would occur during natural maturation. Kinetic parameters derived from hydrous pyrolysis show good correlations with one another (compensation effect) and kerogen organic-sulfur contents. These correlations allow for indirect determination of hydrous-pyrolysis kinetic parameters on the basis of the organic-sulfur mole fraction of an immature Type-II or -IIS kerogen.  相似文献   

Acid leaching of ash and coal: Time dependence and trace element occurrences     

Mehtap Paul  Meryem Seferinoğlu  Gul Asiye Ayçık  Åke Sandström  Michael L. Smith  Jan Paul 《International Journal of Mineral Processing》2006

The leaching of coal and coal/asphaltite/wood-ashes in sulfuric acid (pH 1.0, 25 °C, S/L, 1:10) was studied as a function of time; acid consumption and extracted metal concentrations are presented. Whole coals consumed acid rapidly during the first few minutes, followed by slow acid consumption. Wood-, lignite-, and asphaltite-ashes consumed acid in two stages, the rapid phase extending < 30 min and the slow phase extended up to 10 days. The rapid phase was dominated by the dissolution of Ca, K and Mg ions for wood-ash, by Ca, Al and Mg ions for lignite-ash and Ca and Mg ions for asphaltite-ash. The sulfur concentration in solution and the concentrations of Ca, Fe, K, Mg, Na, P, Al and Mn in the aqueous phase verified the neutralizing capacity of the untreated ashes as well as the formation of insoluble sulfates in the residues. The slow phase kinetics differed for different fuels and exhibited leaching of several abundant elements—Fe, Al, K, Na and Mn. Trace elements (Ba, Cd, Co, Cr, Cu, Mo, Ni, Pb, Th, U, V, Zn) sometimes required up to 32 h for maximal extraction from ashes. Suggestions are presented regarding the chemical nature of trace elements in the untreated coals and ashes and suitable residence times for economical industrial processes. We think it possible to combine bacteriological oxidation of sulfidic concentrates of acid leaching from ash of various qualities or even whole coals.  相似文献   

Ductile deformation of garnet in mylonitic gneisses from the Münchberg Massif (Germany)   总被引：1，自引：0，他引：1  

Axel Vollbrecht  Jan Pawlowski  Bernd Leiss  Till Heinrichs  Madlen Seidel  Andreas Kronz 《Tectonophysics》2006,427(1-4):153

Mylonitic gneisses from the Münchberg Massif contain single grains (type I) and polycrystalline aggregates (type II) of garnet displaying a distinct elongation parallel to a macroscopic lineation which is interpreted as the result of ductile deformation. Lattice-preferred orientations of quartz (textures) symmetrical to the macroscopic foliation and lineation and the lack of rotational microfabrics indicate that the bulk deformation was pure shear at least during the latest strain increments. Garnet textures measured by EBSD together with microprobe analyses demonstrate that these two structural types of garnet can be related to two different processes of ductile deformation: (1) For the single grains stretching can be attributed to diffusion creep along grain boundary zones (Coble creep). The related mass transfer is indicated by the fact that primary growth zones are cut off at the long faces of the grains while the related strain shadow domains do not show comparable chemical zoning. Pressure solution and precipitation suitable to produce similar structures can be largely ruled out because retrogressive reactions pointing to the presence of free hydrous fluids are missing. (2) For the polycrystalline garnet aggregates consisting of cores grading into fine-grained mantles, dislocation creep and associated rotation recrystallization can be assumed. Continuous lattice rotation from the core to the outer polycrystalline rim allow a determination of the related dominant slip systems which are {100}<010> and equivalent systems according to the cubic lattice symmetry. The same holds for garnets which appear to be completely recrystallized. For this type of fine-grained aggregates an alternative nucleation model is discussed. Due to penetrative dislocation glide in connection with short range diffusion and the resulting lattice rotation, primary growth zones are strongly disturbed.Since for the considered rock unit of the Münchberg Massif peak metamorphic temperatures between 630 and 670 °C can be assumed, this study clearly demonstrates that the inferred processes of ductile garnet deformation can occur not only in HT regimes as often suggested in the literature even if embedded within a matrix of “low-strength” minerals like quartz, feldspars and micas.  相似文献   

Comparison of soil solution chemistry sampled by centrifugation, two types of suction lysimeters and zero-tension lysimeters     

Christine E. Geibe  Rolf Danielsson  Patrick A.W. van Hees  Ulla S. Lundstrm 《Applied Geochemistry》2006,21(12):2096-2111

The choice of sampling method for soil solution is of great importance. In this paper soil solution chemistry sampled by centrifugation, two types of suction lysimeters and zero-tension lysimeters have been studied with the purpose of investigating systematic differences between them. The samples were taken at 4 depths from an acidified forest soil as well as from adjacent lime and ash treated soils. A centrifugation drainage method was compared with two types of suction lysimeters (‘Rhizon’ and ‘Prenart’) and zero-tension lysimeters. About half of the 27 variables measured showed a significant difference between the sampling methods used. Typically the centrifuged samples had lower pH (4.0 vs. 4.4), Ca (21 μM vs. 30 μM) and Mg (25 μM vs. 34 μM) concentrations and higher Cl (330 μM vs. 230 μM) and DOC (4.4 mM vs. 3.2 mM) concentrations than the Rhizon lysimeters. Also the other lysimeters showed significant differences compared to the centrifuged samples for about half the number of analytes. Centrifuged samples had higher concentrations of all analytes except NO₃ and PO₄ compared to zero-tension lysimeters and also for all analytes except NO₃ and Al compared to Prenart lysimeters. Among the environmental factors considered depth showed an influence to some extent, while sampling occasion had a great significant impact on the difference between the centrifugation method and the Rhizon lysimeters. Factors like individual pits or soil treatment did not show any influence on the difference between the methods.  相似文献   

The structure and dynamics of 2-dimensional fluids in swelling clays   总被引：3，自引：0，他引：3  

Neal T. Skipper  Peter A. Lock  James O. Titiloye  Jan Swenson  Zakaria A. Mirza  W. Spencer Howells  Felix Fernandez-Alonso 《Chemical Geology》2006,230(3-4):182-196

The interlayer pores of swelling 2:1 clays provide an ideal 2-dimensional environment in which to study confined fluids. In this paper we discuss our understanding of the structure and dynamics of interlayer fluid species in expanded clays, based primarily on the outcome of recent molecular modelling and neutron scattering studies. Counterion solvation is compared with that measured in bulk solutions, and at a local level the cation-oxygen coordination is found to be remarkably similar in these two environments. However, for the monovalent ions the contribution to the first coordination shell from the clay surfaces increases with counterion radius. This gives rise to inner-sphere (surface) complexes in the case of potassium and caesium. In this context, the location of the negative clay surface charge (i.e. arising from octahedral or tetrahedral substitution) is also found to be of major importance. Divalent cations, such as calcium, eagerly solvate to form outer-sphere complexes. These complexes are able to pin adjacent clay layers together, and thereby prevent colloidal swelling. Confined water molecules form hydrogen bonds to each other and to the clays' surfaces. In this way their local environment relaxes to close to the bulk water structure within two molecular layers of the clay surface. Finally, we discuss the way in which the simple organic molecules methane, methanol and ethylene glycol behave in the interlayer region of hydrated clays. Quasi-elastic neutron scattering of isotopically labelled interlayer CH₃OD and (CH₂OD)₂ in deuterated clay allows us to measure the diffusion of the CH₃- and CH₂-groups in both clay and liquid environments. We find that in both the one-layer methanol solvates and the two-layer glycol solvates the diffusion of the most mobile organic molecules is close to that in the bulk solution.  相似文献