白钨矿晶体结构及微量元素替代机理     

吴锟言  刘飚 《地质学报》2023,97(10):3314-3325

白钨矿是钨矿床中主要的载钨矿物,其独特的晶体结构使其富含微量元素,被广泛用于示踪钨成矿过程与流体源区。本文对南岭地区氧化型矽卡岩、还原型矽卡岩、黑钨矿-石英脉型、白钨矿-石英脉型、(矽卡岩-)云英岩型、(石英脉-)云英岩型钨矿床中白钨矿开展矿物组合和X-射线单晶衍射分析,实验结果显示：(1)白钨矿晶体结构存在一定差异,矽卡岩型钨矿中白钨矿Ca-O键长变化较大(0.0043 nm),石英脉型钨矿中白钨矿次之(0.0035 nm),云英岩型钨矿中白钨矿最小(0.0034 nm);(2) Ca-O键长的差异对最优替代稀土元素影响较大,氧化型矽卡岩钨矿中白钨矿从成矿早期到晚期,最优替代稀土元素从Pr-Nd(进变质阶段)、Pr-Sm(退变质阶段)转变为Nd-Sm(石英-方解石-萤石阶段),而(石英脉-)云英岩型钨矿中白钨矿呈现以Sm³⁺为中心(Nd-Gd)的最优替代元素;(3)矽卡岩型和云英岩型钨矿中白钨矿,稀土元素主要通过Nb⁵⁺耦合替代和空位替代进入白钨矿晶格,石英脉型钨矿的白钨矿中,稀土元素主要通过空位替代和Na⁺耦合替代进...  相似文献   

http://www.sciencedirect.com/science/article/pii/S1674987111000545     

Chongwen Yu 《地学前缘(英文版)》2011,2(3):323-347

By applying the ’theory of synchronization’ from the science of complexity to studying the regional regularity of ore formation within the Nanling region of southern China,a characteristic target-pattern regional ore zonality has been discovered.During the early and late Yanshanian epoch(corresponding respectively to the Jurassic and Cretaceous periods),two centers of ore formation emerged successively in the Nanling region;the former is mainly for rare metals(W,Sn,Mo,Bi,Nb) and one rare-earth element (La) and was generated in the Jurassic period;whereas the latter is mainly for base metals(Cu,Pb,Zn,Sb, Hg),noble metals(Au,Ag),and one radioactive element(U) and was generated in the Cretaceous period. Centers of ore formation were brought about by interface dynamics respectively at the Qitianling and Jiuyishan districts in southern Hunan Province.The characteristic giant nonlinear target-pattern regional ore zonality was generated by spatio-temporal synchronization process of the Nanling complex metallo-genic system.It induced the collective dynamics and cooperative behavior of the system and displayed the configuration of the regional ore zonality.Then dynamical clustering transformed the configuration into rudimentary ordered coherent structures.Phase dynamics eventually defined the spatio-temporal structures of the target-pattern regional ore zonality and determined their localization and distribution.A new methodology for revealing regional ore zonality is developed,which will encourage further investigation of the formation of deep-seated ore resources and the onset of large-scale mineralization.  相似文献   

锡田印支-燕山期复式花岗质岩浆-热液活动时限和物质来源   总被引：2，自引：0，他引：2  

苏红中  郭春丽  伍式崇  侯可军  张彦 《地质学报》2015,89(10):1853-1872

锡田钨锡多金属矿田位于湘赣两省交界,南岭成矿带的北部。锡田花岗岩体是一个复式岩体。本文利用LA-MC-ICP MS技术对8个样品的锆石进行了原位微区U-Pb定年和Lu-Hf同位素测试,结果显示其中有4个为印支期(226~225Ma)、另外4个为燕山期(166~158Ma)。印支期花岗岩锆石的εHf(t)值为-4.6~-10.8,两阶段模式年龄TDM2值为2011~1534Ma,根据是否呈正态分布可分为7组;燕山期花岗岩锆石的εHf(t)值为-4.3~-10,TDM2值为1896~1429Ma,可分为5组。相似的Hf同位素组成表明两期花岗岩具有同源性,均源自古元古代晚期至中元古代早期地壳物质的部分熔融。而εHf(t)值变化范围较大且分成很多组可能更主要受控于源区Hf同位素的不均一性。此外,本文利用40 Ar-39 Ar定年方法测得花岗岩顶部石英脉和云英岩中4个白(金)云母的年龄为150~148Ma,这期与成矿有关的热液作用应该与最晚一期岩浆活动有关。通过本次获得的定年数据和对已有的成岩成矿定年数据的总结,本文认为锡田岩体可以分为三个期次,印支期(226~225Ma),燕山期第一阶段(166~158Ma)和燕山期第二阶段(151~141Ma)。  相似文献   

基于元素组合特征的相似性系数法圈定异常——以南岭地区为例     

龚晶晶 《地质与勘探》2015,51(2):312-322

强调了统计域的正确选择对区域地球化学数据分析的重要性。本文以南岭研究区的W元素原始异常作为统计域,分析得出了研究区内不同成矿类型钨矿一种量化的简单元素组合特征。以此量化的元素组合特征,并结合相似度分析方法,统计了研究区内样点与各典型钨矿元素组合特征的相似性系数,其成图结果非常准确地圈定了已知的各类型钨矿,相比W元素原始异常其准确率得到了明显提升。该方法亦可认为是对地球化学场的一种成因分解,能够准确提取其中与成矿有关的异常信息。该研究可作为区域异常结构模式研究的重要补充,也可以为扩大南岭地区钨矿找矿远景提供线索。  相似文献   

南岭成矿带前寒武纪地层区划与岩石地层的厘定     

牛志军  杨文强  刘浩  宋芳 《华南地质与矿产》2014,(4):308-318

南岭成矿带前寒武系为金、铁、锰、磷及铅锌的赋矿层位,近年来由于高精度测年数据的应用,建立了较为清晰的年代地层格架,然而由于历史原因,前寒武系岩石地层序列在湘黔桂赣粤交界地区存在同物异名现象,不利于地质矿产图的编制,需要重新厘定完善。本文以武陵运动构造面为界,将南岭成矿带大地构造演化分为两个阶段,按中元古代至青白口纪早期、青白口纪晚期至震旦纪划分出不同地层区。早期划分出两个地层区—扬子与华夏地层区,晚期同属于华南地层区,依据处于盆地不同位置,再划分为六个地层分区。本文重点对湘黔桂交界地区的青白口系上部层位、赣湘桂地区南华系和震旦系进行了梳理,初步形成前寒武纪岩石地层序列,不再采用部分岩石地层单位,以便于编制该地区地质矿产图。  相似文献   

南岭地区中生代两种成矿花岗质岩的岩石学和矿物学特征探讨   总被引：1，自引：0，他引：1  

郭娜欣  吕晓强  赵正  陈振宇 《地质学报》2014,88(12):2423-2436

南岭地区是我国重要的有色金属矿产资源集中区,中生代多金属成矿与本区广泛分布的花岗质岩石具有密切的成因关系.本文在总结南岭地区与花岗质岩石有关的钨锡钼铋和铜(钼)铅锌金银两类多金属矿床时空分布规律、岩体特征的基础上,探讨并对比了这两种成矿花岗质岩的岩石学和矿物学特征,指出:①与钨锡钼铋成矿有关的岩浆岩以壳源物质重熔形成的黑云母花岗岩为主,但不少岩体也带有幔源物质信息.造岩矿物组合为石英+钾长石+斜长石+黑云母+白云母±角闪石,石英、长石、黑云母包含结构十分发育.斜长石以钠长石为主,An平均值为8;黑云母为富铁黑云母—铁叶云母—铝铁叶云母,MF值为0.001～0.5311;个别岩体中含角闪石,Mg# =0.21～0.53.②与铜(钼)铅锌金银成矿有关的岩浆岩以壳幔混源的花岗闪长岩为主.造岩矿物组合为石英+斜长石+钾长石+黑云母+角闪石±白云母,包含结构不发育.斜长石以更长石为主,An平均值为22;黑云母为富镁黑云母,MF值为0.5120～0.7216;普遍见有角闪石,Mg# =0.48～1.00.两类成矿岩浆岩的岩石学和矿物学差异可以为南岭花岗质岩石地区找矿提供初步的指示意义.  相似文献   

南岭山地高速公路雾区能见度预报系统   总被引：9，自引：4，他引：9  

吴兑  邓雪娇  游积平  黄健  赵博  毕雪岩  万齐林  梁建茵  闫敬华  彭涛涌 《热带气象学报》2006,22(5):417-422

在研究南岭山地浓雾的气候规律，开展了2次多学科综合野外观测，对典型个例进行了天气学分析、雾的宏观结构特征分析、雾的微物理特征分析，在利用数值试验分析了雾生成的物理机制等研究的基础上，研制开发了4种南岭山地京珠高速公路云岩雾区的能见度预报方法，包括：中尺度数值模式产品释用方法、结构预测方法、天气学指标预报方法和动态统计预报方法；并研制了相应的自动化程度高的预测预报系统，与京珠高速公路粤境北段通车同步投入准业务运行，使用雾区路段的5套自动气象站和能见度仪资料，制作的集成预报结果为高速公路行车安全提供服务，经过各种方法的独立预报检验和准业务运行服务的预报结果检验，预报准确率比较高，提供服务的集成预报准确率可达83．3％。  相似文献   

南岭东段岩前钨矿床地质特征及成岩成矿时代     

赵正  陈毓川  曾载淋  陈郑辉  王登红  赵斌  张家菁 《吉林大学学报(地球科学版)》2013,43(6):1828

岩前钨矿位于南岭东西向构造与滨太平洋北北东向构造带的交汇复合部位,南岭成矿带东段北部。主要矿床类型有矽卡岩型白钨矿和石英脉型黑钨矿,矿体产于燕山早期花岗岩内外接触带内。在区域地质和矿床地质研究的基础上,采用LA-ICP-MS 锆石U-Pb 法和辉钼矿Re-Os等时线方法,对与成矿关系密切的岩前花岗岩和含矿石英脉中辉钼矿进行精确定年,获得花岗岩的单颗粒锆石U-Pb谐和年龄加权平均值为(160.6±0.72) Ma,黑钨矿化石英脉中的辉钼矿为(159.2 ±2.3) Ma。这一成果揭示,花岗岩的就位年龄与含矿石英脉的形成几乎在相同热过程完成。结合前人研究,进一步得出南岭地区160~150 Ma成岩成矿作用主要分布于南岭中东段,成岩成矿作用与华南地区东部岩石圈大规模伸展的构造运动力学背景有关。岩前钨矿与区内盘古山、画眉坳、柿竹园等著名矿床具有相同的成矿时代、成矿背景和相似的成矿条件,属同一个成矿亚系列,预测岩前钨矿具有较大的找矿潜力,重点突破对象为内接触带石英脉型和接触交代矽卡岩型钨多金属矿体。  相似文献   

Variation in δ15N of a lacustrine sedimentary sequence in the Nanling Mountains and its potential implication for climatic conditions over the past ∼16 000 years     

钟巍  曹家元  薛积彬  欧阳军 《中国海洋湖沼学报》2013,31(5):1098-1106

Although extensive studies have been performed on nitrogen isotopes in lake sediments,understanding the complexity of the δ~15N variation related to past environmental and climatic conditions still remains unclear.Supported by multi-proxy records including litho-units,organic carbon isotopes,ration of total organic carbon and total nitrogen,organic matter content,bulk dry density,the accumulation rate of organic matter,median grain size,magnetic susceptibility,and Rb/Sr and Ca/Mg ratios obtained from a sedimentary sequence in a small lake(i.e.,Dahu Swamp) in the eastern Nanling Mountains in South China,we deduce that variation in the δ15N values results primarily from the sources of organic matter,which are significantly influenced by climatic conditions over the past ~16 000 years.A low(or high) lake level resulting from dry(or wet) conditions would lead to more(or fewer) vascular plant remains in the sediments and stronger(or weaker) denitrification associated with hypolimnetic anoxia,resulting in lower(or higher) δ15N values.In addition,dry(or wet) conditions would favor weakened(or strengthened) biogeochemical activity in the catchment,which could result in less(or more) external input of15N-enriched OM,thus leading to decreased(or increased) δ15N values.Our results indicate that the lake sediment δ15N record in the Nanling Mountains has the potential to provide valuable insight into past East Asian monsoon climatedriven environmental changes.  相似文献   

Mineralogical feature and geological significance of muscovites from the Longyuanba Indosinian and Yanshannian two-mica granites in the eastern Nanling Range     

TAO JiHua  LI WuXian  CAI YuanFeng  CEN Tao 《中国科学:地球科学(英文版)》2014,57(6):1150-1157

Emplacement P-T condition estimations using granites are important for understanding metamorphic and erosional processes of orogenic belt.Granites are widespread in South China and a majority of them are peraluminous.Particularly,over 91%of the Indosinian granites exposed in the region are peraluminous in composition.It is extremely hard to determine the pressure of intrusion of these peraluminous granites due to the absence of amphibole,a good mineral barometer commonly identified in metaluminous granites.Muscovite is a common mineral in peraluminous granites,certain kind of it could be used as a mineral barometer to constrain the emplacement pressure of peraluminous granites.In this paper,results of petrographic and geochemical studies of muscovites from the Indosinian and early Yanshanian two-mica granites at the Longyuanba in the eastern Nanling Range are reported.Based on petrographic studies,the primary muscovite can be discriminated from the secondary muscovites.Muscovites from the Indosinian two-mica granites are enriched in Ti,Al,Mg,and Na,and depleted in Fe and Mn.Geochemically,these muscovites were considered as primary,whereas those from the Yanshanian two-mica granites fall into the area of secondary muscovite on discrimination diagrams.Barometer estimations show that pressures calculated for primary muscovites are accurate,but those calculated for secondary muscovites are overestimated.The average pressure of emplacement of the Longyuanba Indosinian two-mica granites is 5.9 kbar,corresponding to~19 km in depth,suggesting that the Indosinian granitic magmas were probably generated by partial melting of a thickened crust root in a compressional tectonic setting.  相似文献