Oil-generation kinetics for organic facies with Type-II and -IIS kerogen in the Menilite Shales of the Polish Carpathians     

M.D. Lewan  M.J. Kotarba  D. Wi?c?aw 《Geochimica et cosmochimica acta》2006,70(13):3351-3368

The Menilite Shales (Oligocene) of the Polish Carpathians are the source of low-sulfur oils in the thrust belt and some high-sulfur oils in the Carpathian Foredeep. These oil occurrences indicate that the high-sulfur oils in the Foredeep were generated and expelled before major thrusting and the low-sulfur oils in the thrust belt were generated and expelled during or after major thrusting. Two distinct organic facies have been observed in the Menilite Shales. One organic facies has a high clastic sediment input and contains Type-II kerogen. The other organic facies has a lower clastic sediment input and contains Type-IIS kerogen. Representative samples of both organic facies were used to determine kinetic parameters for immiscible oil generation by isothermal hydrous pyrolysis and S₂ generation by non-isothermal open-system pyrolysis. The derived kinetic parameters showed that timing of S₂ generation was not as different between the Type-IIS and -II kerogen based on open-system pyrolysis as compared with immiscible oil generation based on hydrous pyrolysis. Applying these kinetic parameters to a burial history in the Skole unit showed that some expelled oil would have been generated from the organic facies with Type-IIS kerogen before major thrusting with the hydrous-pyrolysis kinetic parameters but not with the open-system pyrolysis kinetic parameters. The inability of open-system pyrolysis to determine earlier petroleum generation from Type-IIS kerogen is attributed to the large polar-rich bitumen component in S₂ generation, rapid loss of sulfur free-radical initiators in the open system, and diminished radical selectivity and rate constant differences at higher temperatures. Hydrous-pyrolysis kinetic parameters are determined in the presence of water at lower temperatures in a closed system, which allows differentiation of bitumen and oil generation, interaction of free-radical initiators, greater radical selectivity, and more distinguishable rate constants as would occur during natural maturation. Kinetic parameters derived from hydrous pyrolysis show good correlations with one another (compensation effect) and kerogen organic-sulfur contents. These correlations allow for indirect determination of hydrous-pyrolysis kinetic parameters on the basis of the organic-sulfur mole fraction of an immature Type-II or -IIS kerogen.  相似文献   

Soil quality changes in land degradation as indicated by soil chemical, biochemical and microbiological properties in a karst area of southwest Guizhou, China   总被引：7，自引：0，他引：7  

Pingjiu Zhang  Lianqing Li  Genxing Pan  Jingchen Ren 《Environmental Geology》2006,51(4):609-619

Not only the nutritional status and biological activity but also the soil ecological functioning or soil health has been impacted profoundly by land degradation in the karst area of southwest China where the karst ecosystems are generally considered as extremely vulnerable to land degradation under intensified land-use changes. The objectives of this study are to elucidate the changes in overall soil quality by a holistic approach of soil nutritional, biological activity, and soil health indicators in the karst area as impacted by intense cultivation and vegetation degradation. Topsoil samples were collected on selected eco-tesserae in a sequence of land degradation in a karst area of southwest Guizhou in 2004. The soil nutrient pools of organic carbon (C_org), extractable extracellular carbon (C_ext), total soil nitrogen (N_t), alkali-hydrolyzable nitrogen (N_ah), total phosphorus (P_t), available phosphorus (P_a) were analyzed by wet soil chemistry. The soil biological properties were studied by means of measurements of microbial biomass carbon (both by fumigation–extraction, FE-C_mic, and by calculation from substrate-incubation respiration, SIR-C_mic) of respiration [respiration without addition of substrates, basal respiration (BR), and potential respiration (PR) with substrate-incubation] and of soil enzyme activities (invertase, urease, and alkaline phosphatase). Soil health status was assessed by simple indices of C_mic/C_org and BR/C_mic in conjunction with bacterial community structures determined by polymerase chain reaction and denaturing gradient gel electrophoresis. While the nutritional pool parameters, such as C_org and C_ext, described basically the changes in soil life-supporting capacity with cultivation interference and vegetation declined, those parameters of biological activity such as FE-C_mic, SIR, and SIR-C_mic as well as bacterial community structures measured by molecular method evidenced well the changes in soil functioning for ecosystem health with the land degradation.  相似文献   

T -distributed Random Fields: A Parametric Model for Heavy-tailedWell-log Data1     

Jo R?islien  Henning Omre 《Mathematical Geology》2006,38(7):821-849

Histograms of observations from spatial phenomena are often found to be more heavy-tailed than Gaussian distributions, which makes the Gaussian random field model unsuited. A T-distributed random field model with heavy-tailed marginal probability density functions is defined. The model is a generalization of the familiar Student-T distribution, and it may be given a Bayesian interpretation. The increased variability appears cross-realizations, contrary to in-realizations, since all realizations are Gaussian-like with varying variance between realizations. The T-distributed random field model is analytically tractable and the conditional model is developed, which provides algorithms for conditional simulation and prediction, so-called T-kriging. The model compares favourably with most previously defined random field models. The Gaussian random field model appears as a special, limiting case of the T-distributed random field model. The model is particularly useful whenever multiple, sparsely sampled realizations of the random field are available, and is clearly favourable to the Gaussian model in this case. The properties of the T-distributed random field model is demonstrated on well log observations from the Gullfaks field in the North Sea. The predictions correspond to traditional kriging predictions, while the associated prediction variances are more representative, as they are layer specific and include uncertainty caused by using variance estimates.  相似文献   

基于夜间灯光数据的环渤海地区城市化空间模式和过程研究     

何春阳  李景刚  陈婧  SHI Peijun  CHEN Jin  PAN Yaozhong  LI Jing  ZHUO Li 《地理学报(英文版)》2006,16(2):174-182

1 Introduction Urban agglomeration is a system of cities, supporting by the modern transportation and information network in the system, these cities, with different characteristics, types, sizes and hierarchies, interact with each other, and one or two …  相似文献   

Late Early Miocene lake deposits near Mauensee, central Switzerland: Fish fauna (otoliths, teeth), accompanying biota and palaeoecology     

Jürg Jost  Daniel K?lin  Tanja Schulz-Mirbach  Bettina Reichenbacher 《Eclogae Geologicae Helvetiae》2006,99(3):309-326

  相似文献   

低温分解钾长石的热力学研究   总被引：2，自引：0，他引：2  

薛彦辉  潘兆科  张桂斋 《化工矿产地质》2006,28(3):167-170

通过不同温度、浓度、分压下ΔrGm的计算和不同条件下对平衡常数K的影响,作出ΔrGm～—T、ΔrGm—C、ΔrGm—P图,把热力学的一些规律应用于钾长石低温分解中,对参与低温分解钾长石的各物质能量转换进行分析判断反应进行的方向和限度,对钾长石的分解有指导作用。从热力学角度分析,在低温条件下分解钾长石的反应是可能的。  相似文献   

论信息时代的城市发展     

金江军  潘懋  承继成 《国土资源信息化》2005,20(2):2-5,41

城市信息化是中国城市发展的新主题与新动力,是解决目前我国城市发展中诸多难题的重要途径。本文首先对比了数字城市和信息城市,然后指出了建设信息城市的迫切性和重要性,最后提出了城市信息科学的学科范畴。  相似文献   

韧性剪切变形对岩石地球化学行为的制约——以北阿尔金巴什考供韧性剪切带为例   总被引：6，自引：0，他引：6  

戚学祥李海兵  吴才来陈松永 《地质通报》2005,24(3):252-257

韧性剪切变形对岩石地球化学行为的制约一直是地质学家们探讨的课题。本文以构成北阿尔金红柳沟——拉配泉俯冲碰撞杂岩带与北阿尔金地块边界的巴什考供斜向逆冲型韧性剪切带为例，通过对韧性剪切带内花岗岩变形前后不同变形强度构造岩的地球化学组成进行对比，确定等比线斜率，探讨韧性变形对岩石体积和成分变异的影响。计算结果表明，在糜棱岩化过程中，糜棱岩化花岗岩体积亏损21％，花岗质糜棱岩体积亏损31％。质量平衡计算结果和等比线图表明，韧；陛剪切作用导致SiO2，流失量最大，A12O3、K2O及Ba、Rb、Sr等都有不同程度的丢失，显示出较强的活动性，MnO、P2O5、Sc位于等比线上或附近，表现出相对的稳定性。岩石中活动组分的变异是流体渗滤作用引起的，不活动组分的变异是体．积亏损造成的。  相似文献   

地下导线随盾构推进逐段接测中的可靠性检验     

高俊强  潘庆林 《现代测绘》2005,28(1):17-19

盾构法施工的要点是需要在井下布设高精度的控制支导线，当我们根据盾构推进进度对导线接测时，由于观测条件、观测方法、观测仪器基本相同，但观测、的成果往往会存在一定的差异，有时我们无法直接判断成果的正确与否，此时，采用测量平差中的统计检验的方法来分析这些观测数据，可以取得比较满意的结果。  相似文献   

利用DXF文件进行测量数据辅助处理   总被引：1，自引：0，他引：1  

吴敬文  潘苏成 《现代测绘》2005,28(6):45-46,48

DXF文件是AUTOCAD与高级语言程序设计之间的接口文件,在测量工作中,充分利用DXF文件对测量数据进行辅助处理计算,可以达到事半功倍的效果.  相似文献