重庆及其周缘地区下古生界页岩气成藏条件及有利区预测   总被引：4，自引：1，他引：3       下载免费PDF全文

龙鹏宇  张金川  李玉喜  唐玄  程礼军  刘珠江  韩双彪 《地学前缘》2012,19(2):221-233

从野外地表露头、井下岩心及典型剖面等基础资料出发,以富有机质页岩形成地质背景及其展布特征-页岩气成藏条件-有利区预测为主线,对重庆及周缘地区下古生界页岩气成藏条件进行分析,并采用综合信息叠合法对该区有利区进行预测。指出研究区下寒武统筇竹寺组和上奥陶统五峰组—下志留统龙马溪组两套富有机质页岩普遍发育,分布广,厚度大,埋藏适中,有机质类型好,有机质含量高,具有充足的储集空间和运移通道,并且等温吸附模拟和现场解析实验也表明,这两套页岩均具有较强的气体吸附、较好的含气性能;多口井钻遇黑色页岩段气显异常普遍,也为页岩气的存在提供证据。总之,该区与美国东部典型页岩气盆地有诸多地质可比性,具有形成页岩气藏的有利地质条件,是页岩气勘探研究值得关注的重要领域。  相似文献   

静电场轨道阱质谱在水中溶解性有机质表征中的应用进展     

王书越  何洪源  饶竹  石喆元  孟建卫  王立平  李开开 《地球学报》2022,43(1):101-109

溶解性有机质(Dissolved Organic Matter,DOM)在水生生态环境中广泛存在,影响着水环境中多种物质的生物地球化学性质.分析其组成与含量具有重要的生态环境意义,是生态环境科学领域研究的热点.溶解性有机质组成非常复杂,其分子组成的解析一直是难题.近年来,具有高分辨率、高灵敏度、高通量、高扫描速率等特性...  相似文献   

四川盆地西南缘金坷村剖面五峰组-龙马溪组生物地层划分及区域对比     

王万能  张耀堂  袁永盛  陈庆松  于一帆 《地质与资源》2023,(4):394-405

为了探究上扬子海盆在奥陶纪-志留纪之交的沉积环境、明确四川盆地西南缘金坷村筠连地区有机质页岩沉积层位，通过对金坷村剖面五峰组-龙马溪组岩石地层及生物地层的研究，识别出自晚奥陶世凯迪阶WF2带至早志留世埃隆阶LM6带的9个连续生物带及组合.认为金坷村地区是上扬子海盆最早进入前陆期的地区，时间为鲁丹阶LM1期.金坷村剖面与其北部的新地2井、宁211井、威202井生物地层对比发现，自南向北黑色页岩笔石带上限自LM6延伸至LM9，呈逐渐增高的趋势.金坷村剖面富有机质页岩层位于WF2-LM4带，厚度20.6 m，为该地区页岩气勘探开发提供了一定的基础资料.  相似文献   

富含有机质的化探样品中多元素的X射线荧光光谱测定     

宋云阔  于清池 《地质实验室》1990,6(2):81-81

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Water, organic matter, nitrogen and phosphorus contents in sediment of a large-scale mariculture area in the Zhelin Bay of eastern Guangdong Province, China     

DONG Qiaoxiang  LIN Jun  SHANG Xu  LI Jin  HUANG Changjiang 《海洋学报(英文版)》2008,27(2):133-148

The Zhelin Bay is one of the most important bays for large-scale mariculture in Guangdong Province, China. Owing to the increasing human population and the expanding mariculture in the last two decades, the ecological environment has greatly changed with frequent harmful algal blooms. A monthly survey of water content, organic matter （TOM）, and various forms of nitrogen and phosphorous in sediment from July 2002 to July 2003 in the bay was conducted. The results showed that the water content was correlated significantly with TOM and various forms of nitrogen and phosphorus and can be used as proxy for quick and rough estimate of these factors in the future surveys. TOM was also correlated significantly with various forms of nitrogen and phosphorus, indicating that it was one of the key factors affecting the concentrations and distributions of nitrogen and phosphorus in the investigated waters. Average total Kjeldhal nitrogen （TkN） content was（ 1 113.1 ± 382.5）μg/g and average total phosphorus （TP） content was（567.2± 223.3）μg/g, and both were much higher than those of similar estuaries in China and elsewhere. Average nitrogen and phosphorus tended to be higher inside than outside the bay, higher at aquaculture than non-aquaculture areas, and higher at fish-cage culture than oyster culture areas, suggesting that large-scale mariculture inside the bay played an important role in the eutrophication of the Zhelin Bay. Various forms of nitrogen and phosphorus concentrations were higher during the warm season （July--September）, which was due to the increased decomposition and concentration of organic matter resulted from the fast growth and high mortality of the cultured species. Compared with July 2002, TkN and TP contents were much higher in July 2003, in consonance with the eutrophication of the Zhelin Bay. Because exchangeable phosphorus （Ex-P）, iron-bounded phos- phorus （Fe-P） and organic phosphorus （OP） combined accounted for 34.3% of the TP and authigenic phosphorus （Au-P  相似文献   

Multivariate analysis of fluorescence and source identification of dissolved organic matter in Jiaozhou Bay, China   总被引：1，自引：0，他引：1  

JIANG Fenghu  YANG Baijuan  LEE Frank Sen-Chun  WANG Xiaoru  CAO Xuan 《海洋学报(英文版)》2009,28(2):60-72

Hierarchical clustering analysis and principal component analysis (PCA) methods were used to assess the similarities and dissimilarities of the entire Excitation-emission matrix spectroscopy (EEMs) data sets of samples collected from Jiaozhou Bay, China. The results demonstrate that multivariate analysis facilitates the complex data treatment and spectral sorting processes, and also enhances the probability to reveal otherwise hidden information concerning the chemical characteristics of the dissolved organic matter (DOM). The distribution of different water samples as revealed by multivariate results has been used to track the movement of DOM material in the study area, and the interpretation is supported by the results obtained from the numerical simulation model of substance tracing technique, which show that the substance discharged by Haibo River can be distributed in Jiaozhou Bay.  相似文献   

黏粒和有机质对黄河口潮间带沉积物微团聚体的影响     

陈友媛  赵文娟  贾永刚  许国辉 《海洋地质与第四纪地质》2009,(1)

微团聚体是形成沉积物结构的基本单元,沉积物的结构性影响了土体的稳定性、渗透性和强度等工程地质性质。对废弃黄河口刁口流路潮间带沉积物微团聚体受黏粒含量、有机质和生物黏液等胶结作用进行分析,结果表明,研究区沉积物多团聚成粉粒级微团聚体(0.05～0.01 mm),含量在85.3%～95.8%之间,与黄土高原土相比,0.05～0.01 mm微团聚体增加,而0.1～0.05 mm微团聚体减少,团聚性差,易于侵蚀;黏粒含量与团聚度表现出显著正相关性,说明黏粒含量增加了沉积物微团聚体的稳定性;沉积物中有机质含量在0.27%～0.61%之间,有机质含量较少,对沉积物微团聚体贡献少;生物扰动的螃蟹洞壁土、螃蟹掘出物的团聚度明显大于表层未受生物扰动土的团聚度,说明螃蟹分泌的黏液能加大微团聚体的稳定性。  相似文献   

应用MODIS影像监测海州湾无机氮浓度的研究   总被引：1，自引：0，他引：1  

许勇  张鹰  刘吉堂  张东 《海洋科学》2008,32(9):76-81

利用连云港海州湾2004年至2006年的水质监测资料，选取时间上完全同步的空间分辨率为500m的MODIS Terra 1B数据，对反射率的单波段因子和波段组合因子与可溶无机氮（DIN）质量浓度之间进行相关分析。从总体上看，单波段因子与DIN质量浓度的相关性较低，但在含氮基团倍频和合频吸收带附近的波段（波段2、7）反射率与DIN质量浓度呈负相关，显示了含氮基团对水体光谱特征的影响；在波段组合因子中，因子F11（3.4）和F13（3.4）与DIN质量浓度呈显著正相关，用这两个因子建立DIN质量浓度的回归模型，R^2都达到0．7以上，相对精度达70％左右，最终选择因子F11（3.4）的线性模型反演该海域的DIN质量浓度，其结果与实际情况非常吻合。  相似文献   

腐植烟煤还原性质成因初探     

赵师庆 《地球化学》1985,(4):363-370

腐植煤不同的还原性质，不仅在我国华北聚煤区晚古生代含煤建造的煤层中有明显表现，而且在我国各聚煤区、各成煤时代不同含煤建造的煤层中也均有不同程度的显示。  相似文献   

腐殖酸三维荧光光谱特性研究   总被引：53，自引：3，他引：50  

傅平青  刘丛强  尹祚莹  吴丰昌 《地球化学》2004,33(3):301-308

腐殖质的荧光特性被广泛用来解析其在各种天然环境中的来源及分布.由于荧光光谱分析具有灵敏度高,选择性好,且不破坏样品结构的优点,非常适合用来研究腐殖质的结构和官能团等特征.利用三维荧光激发-发射光谱研究了 Fluka腐殖酸的荧光光谱特性,结果显示,离子强度(0～0.05 mol/L KClO4)对 Fluka腐殖酸的三维荧光光谱特性影响非常小,而腐殖酸的浓度(5～100 mg/L)和溶液 pH(2～12)对其三维荧光光谱特性影响显著.当腐殖酸浓度增大时,荧光峰出现明显红移现象.荧光强度一般随着 pH的升高而增大,当 pH大于 10后呈下降趋势,我们从垃圾渗滤液溶解有机质的实验结果中也得到相同结论;在浓度为 50 mg/L和 100 mg/L的 Fluka腐殖酸中,荧光峰 B(fulvic-like)的荧光强度却在 pH=5.0左右时达到最大值,与前人报道的土壤富里酸的行为一致,质子化常数 lgK′ HL分别为 3.57和 3.13,与二羧基化合物接近,说明荧光峰 B可能与 Fluka腐殖酸结构中的羧基有关;荧光峰 A与荧光峰 B的荧光强度比值 r(A/B)在 0.61～2.59之间,并且在 pH=2～11范围内, r(A/B)与 pH具有较好的线性相关关系,表明荧光峰 A和荧光峰 B随着 pH值的改变有着相同的变化趋势.  相似文献