Methodological comparison for quantitative analysis of fossil and recently derived carbon in mine soils with high content of aliphatic kerogen     

《Organic Geochemistry》2015

In mine soil, quantification of soil organic carbon (OC) derived recently from biomass decomposition is complicated by the presence of fossil (geogenic) C derived from coal, oil shale, or similar material in the overburden. The only reliable method for such measurement is ¹⁴C analysis (i.e. radiocarbon dating) using instrumentation such as accelerator mass spectrometry, which is too expensive for routine laboratory analysis. We tested two previously used and two new methods for recent C quantification and compared them with ¹⁴C AMS radiocarbon dating as a reference using a set of soil samples (n = 14) from Sokolov, Czech Republic: (i) ¹³C isotope ratio composition, (ii) cross polarization magic angle spinning ¹³C nuclear magnetic resonance (CPMAS ¹³C NMR) spectroscopy, (iii) near infrared spectroscopy (NIRS) coupled with partial least squares regression and (iv) Rock–Eval pyrolysis. Conventional methods for OC determination (dry combustion, wet dichromate oxidation, loss-on-ignition) were also compared to quantify any bias connected with their use. All the methods provided acceptable recent carbon estimates in the presence of mostly aliphatic fossil C from kerogen. However, the most accurate predictions were obtained with two approaches using Rock–Eval pyrolysis parameters as predictors, namely (i) S₂ curve components and (ii) oxygen index (OI). The S₂ curve approach is based on the lower thermal stability of recent vs. fossil organic matter. The OI approach corresponded well with ¹³C NMR spectra, which showed that samples rich in recent C were richer in carboxyl C and O-alkyl C. These two methods showed the greatest potential as routine methods for recent C quantification.  相似文献   

基于GlobeLand30的全球城乡建设用地空间分布与变化统计分析   总被引：3，自引：2，他引：1  

陈军  陈利军  李然  廖安平  彭舒  鲁楠  张宇硕 《测绘学报》2015,44(11):1181-1188

城乡建设用地分布与变化是人类活动的直观标志和生态足迹,在环境变化研究、地理国(世)情监测和可持续发展研究等方面发挥着重要作用。以往人们对一些城市、区域或国家的城乡建设用地分布与变化进行过较为深入系统的研究,但在全球尺度上,这方面研究尚为空白。本文是利用我国自主研制的世界上首套30m空间分辨率全球地表覆盖数据集GlobeLand30的人造地表数据层,首次开展了全球城乡建设用地的空间分布及变化的统计分析。它采用用地面积、构成占比和增量占比等主要指标,统计全球范围内城乡建设用地的空间分布及2000年至2010年10年间的变化,重点分析了2010年全球、各大洲及主要国家的城乡建设用地分布现状与地域差异,2000年至2010年全球、主要国家的建设用地变化以及其主要土地来源。研究结果表明,2010年全球城乡建设用地总面积为118.75×104km2,占全球陆表面积的0.88%;2000年至2010年全球城乡建设用地面积增加了5.74×104 km2,变化率为5.08%,其中,中国和美国新增城乡建设用地约占全球的一半;新增城乡建设用地占用最多的是耕地,占总量的50.26%。这些为研究全球陆表人类活动的空间分布特征与变化趋势提供了翔实的信息和知识。  相似文献   

Visualizing spatiotemporal trajectories of mobile social media users using space–time cube     

Chen Xu  Han Qin  Manzhu Yu 《制图学和地理信息科学》2015,42(4):75-83

The implementation of social network applications on mobile platforms has significantly elevated the activity of mobile social networking. Mobile social networking offers a channel for recording an individual’s spatiotemporal behaviors when location-detecting capabilities of devices are enabled. It also facilitates the study of time geography on an individual level, which has previously suffered from a scarcity of georeferenced movement data. In this paper, we report on the use of georeferenced tweets to display and analyze the spatiotemporal patterns of daily user trajectories. For georeferenced tweets having both location information in longitude and latitude values and recorded creation time, we apply a space–time cube approach for visualization. Compared to the traditional methodologies for time geography studies such as the travel diary-based approach, the analytics using social media data present challenges broadly associated with those of Big Data, including the characteristics of high velocity, large volume, and heterogeneity. For this study, a batch processing system has been developed for extracting spatiotemporal information from each tweet and then creating trajectories of each individual mobile Twitter user. Using social media data in time geographic research has the benefits of study area flexibility, continuous observation and non-involvement with contributors. For example, during every 30-minute cycle, we collected tweets created by about 50,000 Twitter users living in a geographic region covering New York City to Washington, DC. Each tweet can indicate the exact location of its creator when the tweet was posted. Thus, the linked tweets show a Twitter users’ movement trajectory in space and time. This study explores using data intensive computing for processing Twitter data to generate spatiotemporal information that can recreate the space–time trajectories of their creators.  相似文献   

Remote sensing and geophysical survey applications for delineating near-surface palaeochannels and shallow aquifer in the United Arab Emirates     

Samy Ismail Elmahdy  Mohamed Mostafa Mohamed 《国际地球制图》2015,30(7):723-736

This study integrates remote sensing data and geoelectrical dipole–dipole resistivity to delineate near-surface palaeochannels and shallow aquifer in the northern part of Abu Dhabi Emirate, United Arab Emirates. The shuttle imaging radar images and shuttle radar topographic mission DEM were used to delineate near-surface palaeochannels visually based on the contrast between bright and dark tone and automatically using the eight-direction flow model. The delineated palaeochannels were validated by comparing the textural features evident from advanced land observing satellite-phased array type L-band synthetic aperture radar images and determining whether these patterns were different. Field observation and geoelectrical dipole–dipole resistivity method was used to define the depth of palaeochannels and lithology of the shallow aquifer. The remote sensing and geophysical investigations in the UAE, including the study area, indicate the presence of buried palaeochannels with south-west and north-west flow directions from Oman Mountain. The study area can be of economic importance to the local population.  相似文献   

Innovation for sustainable energy from a pro-poor perspective     

Letha Tawney  Mackay Miller  Morgan Bazilian 《Climate Policy》2015,15(1):146-162

The development and transfer of clean energy technologies to achieve universal energy access is challenging due to the inherent complexities of the energy sector, and the energy governance and financial systems in developing economies. Innovation is an essential part of successfully addressing these difficulties. Duplicating the energy infrastructure models of developed countries will not be sufficient to meet the needs of poor consumers. To the extent that innovation can accelerate energy access, it is important to understand the specific types of innovations that are necessary and how they might be facilitated. The general features of existing international clean energy innovation systems, which are predominantly driven by the markets and emissions reduction mechanisms of developed and rapidly growing emerging economies, are reviewed and the alignment of these systems to the innovation processes required to extend energy access globally is evaluated. Drawing on the innovation policy literature, the attributes of effective international and domestic energy innovation systems that are pro-poor and the associated policy approaches are identified.  相似文献   

Scientists’ framing of the ocean science–policy interface     

《Global Environmental Change》2015

Scientists’ ideas, beliefs, and discourses form the frames that shape their choices about which research to pursue, their approaches to collaboration and communicating results, and how they evaluate research outputs and outcomes. To achieve ocean sustainability, there are increasing calls for new levels of engagement and collaboration between scientists and policy-makers; scientists’ willingness to engage depends on their current and evolving frames. Here, I present results about how scientists involved in diverse fields of ocean research perceived their role as scientists working at or near the ocean science–policy interface and how this related to their perceptions regarding ocean research priorities. The survey of 2187 physical, ecological and social scientists from 94 countries showed that scientists held different perspectives about their appropriate level of engagement at the ocean science–policy interface and the relative primacy of science versus politics in formulating ocean policy. Six clusters of scientists varied in their frames; three clusters accounted for 94% of the sample. Of 67 research questions identified from 22 research prioritization and horizon scanning exercises, the top eight were shared among all three clusters, showing consistency in research priorities across scientists with different framings of their role at the science–policy interface. Five focused on the mechanisms and effects of global change on oceans, two focused on data collection and management for long-term ocean monitoring, and one focused on the links between biodiversity and ecological function at different scales. The results from this survey demonstrated that scientists’ framings of the role of ocean science at the science–policy interface can be quantified in surveys, that framing varies among scientists, and that research priorities vary according to the framings.  相似文献   

2013年河北中南部PM_(10)和PM_(2.5)浓度时间变化特征及其影响气象条件分析     

吴雁  陈瑞敏  王颉 《气象与环境科学》2015,38(4):68-75

对2013年河北省中南部的石家庄、保定、沧州、衡水、邢台和邯郸6个地市市区各站点逐小时PM10和PM2.5监测资料及相应气象资料分析结果表明:6个地市中邢台年污染日数最多,对应其年平均风速最小;沧州的最少,年平均风速最大。各地市各个级别污染日数不同,五、六级重污染天气均集中在10月—次年3月。首要污染物主要是PM10和PM2.5,但比例不尽相同。特殊的地理位置、污染源差异和气象条件的差异造成各地市污染日数、级别的差异。6个地市污染天气过程时段大都相同,区域性污染明显。各地市PM10和PM2.5浓度平均最大值均出现在冬季,PM10浓度平均最小值均出现在夏季,各市PM2.5浓度平均最小值出现的季节不同。6个地市PM10和PM2.5浓度值的月变化趋势相似。不同季节各地市PM10和PM2.5浓度日变化趋势不同,极值出现的时间也各不相同,极值出现的时间与气象条件和人类活动关系密切。秋、冬季各地市PM10和PM2.5浓度日较差多大于春、夏季的。各地市PM10和PM2.5浓度日均值与当地的日均气温、风速、能见度呈负相关关系,与相对湿度呈正相关关系且相关性比较显著。  相似文献   

Application of an improved semi-Lagrangian procedure to fully-nonlinear simulation of sloshing in non-wall-sided tanks     

《Applied Ocean Research》2015

The semi-Lagrangian procedure is widely used for updating the fully-nonlinear free surface in the time domain. However, this procedure is only available to cases when the body surface is vertical near the waterline. Present study introduces an improved semi-Lagrangian procedure which removes this ‘vertical-wall’ limitation. Coupling with the boundary element method, the improved semi-Lagrangian procedure is applied to the simulation of fully-nonlinear sloshing waves in non-wall-sided tanks. From the result comparison with the open source CFD software OpenFOAM, it is confirmed that this numerical scheme could guarantee a sufficient accuracy. Further series studies on 2D and 3D fully-nonlinear sloshing waves in wedged tanks are performed. Featured phenomena are observed which are distinct from those in wall-sided tanks.  相似文献   

西北冰洋表-底层碳动力学耦合作用的同位素(¹³C,₂₃₄Th)指示     

张润  陈敏  马嫱  曹建平  邱雨生 《海洋学报(英文版)》2015,34(6):26-33

The coupling of upper ocean-benthic carbon dynamics in the ice-free western Arctic Ocean(the Chukchi Sea and the Canada Basin) was evaluated during the late July–early September 2003 using natural stable(13C) and radioactive(238U-234Th) isotope tracers. POC export flux estimated from 234Th/238 U disequilibria and dissolved CO2 concentration([CO2(aq)]) pointed out that the strengthened biological pump in the Chukchi Shelf have significantly lowered [CO2(aq)] and altered the magnitude of isotopic(12C/13C) fractionation during carbon fixation in the surface ocean. Further, d13 C signatures of surface sediments(d13Csed) are positively correlated to those of weighted d13 CPOC in upper ocean(d13Csed =13.64+1.56×d13CPOC, r2=0.73, p0.01), suggesting that the POC isotopic signals from upper ocean have been recorded in the sediments, partly due to the rapid export of particles as evidenced by low residence times of the highly particle-reactive 234 Th from the upper water column. It is suggested that there probably exists an upper ocean-benthic coupling of carbon dynamics, which likely assures the sedimentary d13 C record an indicator of paleo-CO2 in the western Arctic Ocean.  相似文献   

Diagenetic evolution of the upper Cretaceous limestone and sandstone exhumed reservoirs in the western Basque–Cantabrian Basin,North Spain     

《Marine and Petroleum Geology》2015

The Basque–Cantabrian Basin (NE Spain) has been considered one of the most interesting areas for hydrocarbon exploration in the Iberian Peninsula since the 60th to 70th of last century. This basin is characterized by the presence of numerous outcrops of tar sands closely associated with fractures and Triassic diapirs. The aims of this work is to establish the diagenetic evolution of the Upper Cretaceous reservoir rocks with special emphasis in the emplacement of oil and their impact on reservoir quality. The studied rocks are constituted of carbonates and sandstones that contain massive quantities of bitumen filling vugs and fractures.Petrographic results indicate that the carbonate rocks from Maestu outcrops are bioclastic grainstones and wackestones, whereas the tar sandstones from Atauri and Loza outcrops are dominated by quartzarenites and subordinated subarkoses. The paragenetic sequence of the main diagenetic phases and processes include, pyrite, bladed and drusy calcite cement, calcite overgrowths, silicification of bioclasts and microcrystalline rhombic dolomite cement, and first stage of oil emplacement, blocky calcite cement, coarse crystalline calcite cement, calcitized dolomite, calcite veins, saddle dolomite and stylolites filled by the second phase of oil entrance. Together with the above mentioned diagenetic alterations, the arenites are affected by early kaolinitization of feldspars and the scarce formation of clay rim and epimatrix of illite. All sandstones and dolomitized carbonate rocks show high intercrystalline and intergranular porosity which is full by biodegraded hydrocarbons (solid bitumen). The biodegradation affects alkanes, isoprenoids and partially hopanes and steranes saturated hydrocarbons. Aromatics hydrocarbons, like naphthalenes, phenanthrenes, dibenzothiophenes and triaromatics are also affected by biodegradation. Results indicate that the first HC emplacement corresponds to early stage of calcite and dolomite cementation, and the second and more important emplacement is related to fracturation processes resulting in the formation of excellent reservoirs.  相似文献