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81.
Polychlorodibenzo-p-dioxins (PCDDs) and polychlorodibenzofurans (PCDFs) are among the more toxic anthropogenic contaminants. They are fat-soluble and accumulate in animal tissues. Exposure to PCDD/Fs can cause several endocrine, reproductive and developmental problems in animals, including human beings. Several studies have demonstrated that fish and invertebrates living in association with sediments are exposed to and accumulate contaminants, but to date there have been no studies of PCDD/Fs contamination in deep-sea regions. Specimens of Aristeus antennatus (Risso, 1816) were collected from depths of 600–2500 m at different points in the Mediterranean Sea, from the western basin off the coast of Barcelona to the central basin off the Peloponnesian Peninsula, with otter trawl gear. Amounts of PCDD/Fs were measured in different animal tissues by high resolution gas chromatography coupled to high resolution mass spectrometry (HRGC–HRMS). This is the first study to report the presence of PCDD/Fs in deep-sea organisms dwelling at depths below 600 m. A. antennatus presented levels of PCDD/Fs of the same order of magnitude, or slightly higher, as those found in shallow-water species (Melicertus kerathurus) with respect to land-generated contamination. This highlights the widespread distribution of these pollutants and the potential threat posed to the biodiversity of fragile and vulnerable ecosystems such as the deep-sea. PCDD/F levels detected in the edible parts (muscle) of the commercial shrimp A. antennatus were clearly below the toxic limit value established by European legislation. Levels followed the trend muscle<ovary<hepatopancreas, according to the lipid content of the organs in question. The specific profile of toxic PCDD/F congeners in the studied Penaeid shrimp specimens was characterized mainly by octachlorodibenzo-p-dioxin (OCDD), 2,3,7,8-tetrachlorodibenzofuran (TCDF) and 2,3,4,7,8-pentachlorodibenzofuran (PeCDF) congeners. Moreover, non 2,3,7,8-substituted congeners bioaccumulated in this species, as observed in shallow-water crustaceans. PCDD/Fs were found in the shrimp A. antennatus throughout the Mediterranean Sea. Total PCDD/Fs burdens were higher in shrimps caught in the western Mediterranean than in those caught at eastern Mediterranean sites. There was a tendency for higher levels of PCDD/F contamination in samples obtained from deeper (2500 m) than from shallower sites (600 m).  相似文献   
82.
Inverse modeling studies employing data collected from the classic Henry seawater intrusion problem give insight into several important aspects of inverse modeling of seawater intrusion problems and effective measurement strategies for estimation of parameters for seawater intrusion. Despite the simplicity of the Henry problem, it embodies the behavior of a typical seawater intrusion situation in a single aquifer. Data collected from the numerical problem solution are employed without added noise in order to focus on the aspects of inverse modeling strategies dictated by the physics of variable-density flow and solute transport during seawater intrusion. Covariances of model parameters that can be estimated are strongly dependent on the physics. The insights gained from this type of analysis may be directly applied to field problems in the presence of data errors, using standard inverse modeling approaches to deal with uncertainty in data.  相似文献   
83.
ABSTRACT

In this research, we survey soil erosion processes using an index of connectivity and a non-invasive and long-term assessment in situ technique: the improved stock unearthing method (ISUM), for which the vineyard of Castilla La Mancha under tillage management was selected. Our results show, that in 10 years, the total average soil surface level decreased by – 1.6 cm and the total soil mobilization was up to 17.7 Mg ha?1 year?1. The surrounding lands of the survey plot showed meagre connectivity; however, smaller linear features with higher values were found as possible locations for potential rill generation. The survey plot is traversed by one of these linear features. In this inter-row survey, we found relatively low connectivity values. As a conclusion, we confirm that both methods can be useful to assess soil erosion processes in vineyards and detect areas that could increase the desertification as a consequence of non-sustainable soil erosion rates.  相似文献   
84.
ABSTRACT

Surface runoff generation capacity can be modified by land-use and climate changes. Annual runoff volumes have been evaluated in a small watershed of tropical forest (Brazil), using the Soil and Water Assessment Tool (SWAT) model. Firstly, the accuracy of SWAT in runoff predictions has been assessed by default input parameters and improved by automatic calibration, using 20-year observations. Then, the hydrological response under land uses (cropland, pasture and deforested soil) alternative to tropical forest and climate change scenarios has been simulated. SWAT application has showed that, if forest was replaced by crops or pasture, the watershed’s hydrological response would not significantly be affected. Conversely, a complete deforestation would slightly increase its runoff generation capacity. Under forecasted climate scenarios, the runoff generation capacity of the watershed will tend to decrease and will not be noticeably different among the representative concentration pathways. Pasture and bare soil will give the lowest and highest runoff coefficients, respectively.  相似文献   
85.
Sea level rise could bring about an event that has not previously been seen in modern history, that of the physical disappearance of some low-lying Island States. The objective of this paper is to examine what are the likely scenarios for some of these islands in the course of the next century, and analyse for each scenario if these Island States could continue to claim an Exclusive Economic Zone or not. Also, it will analyse the possibility that Island States could continue having some sort of status analogous to statehood even if it was to lose all territory. Finally, the idea of a “government-in-exile” will be discussed, where the State could retain its identity waiting for a future re-emergence of the island.  相似文献   
86.
87.
This paper presents a methodology for tsunami risk assessment, which was applied to a case study in Kamakura, Japan. This methodology was developed in order to evaluate the effectiveness of a risk-reducing system against such hazards, also aiming to demonstrate that a risk assessment is possible for these episodic events. The tsunami risk assessment follows these general steps: (1) determination of the probability of flooding, (2) calculation of flood scenarios, (3) assessment of the consequences and (4) integration into a risk number or graph. The probability of flooding was approximated based on the data provided by local institutes, and the flood scenarios were modeled in 1D using the Simulating WAves till SHore model. Results showed that a tsunami in Kamakura can result in thousands of casualties. Interventions such as improvements in evacuation systems, which would directly reduce the number of casualties, would have a large influence in risk reduction. Although this method has its limits and constraints, it illustrates the value it can add to existing tsunami risk management in Japan.  相似文献   
88.
Mineralogy and Petrology - We provide here an open version of Igpet software, called t-Igpet to emphasize its application for teaching and research in forward modeling of igneous geochemistry....  相似文献   
89.
We present echelle spectrophotometry of the Galactic H  ii region S 311. The data have been taken with the Very Large Telescope Ultraviolet-Visual Echelle Spectrograph in the 3100–10 400 Å range. We have measured the intensities of 263 emission lines; 178 are permitted lines of H0, D0 (deuterium), He0, C0, C+, N0, N+, O0, O+, S+, Si0, Si+, Ar0 and Fe0; some of them are produced by recombination and others mainly by fluorescence. Physical conditions have been derived using different continuum- and line-intensity ratios. We have derived He+, C++ and O++ ionic abundances from pure recombination lines as well as abundances from collisionally excited lines for a large number of ions of different elements. We have obtained consistent estimations of t 2 applying different methods. We have found that the temperature fluctuations paradigm is consistent with the T e(He  i ) versus T e(H  i ) relation for H  ii regions, in contrast with what has been found for planetary nebulae. We report the detection of deuterium Balmer lines up to Dδ in the blue wings of the hydrogen lines, whose excitation mechanism seems to be continuum fluorescence.  相似文献   
90.
Gisser and Sánchez (Water Resour Res 16(4):638–642, 1980) compared two different strategies to manage aquifers: “free market” and policy regulation. They stated that the outcome of both is practically the same, and that policy regulation could not improve social welfare. This study challenges this argument by analyzing the management strategies in two large aquifers located in southern Spain, the Eastern La Mancha and the Western La Mancha aquifers. The appeal of this case stems from the fact that management of the Eastern La Mancha aquifer is almost sustainable. In stark contrast, its neighboring Western La Mancha aquifer is being grossly mismanaged. The results engage two major questions from previous groundwater literature. The first question is whether or not aquifer management requires policy intervention. The answer depends upon the consideration and magnitude of environmental damages in the model. The second question addresses the nature of groundwater policies. The contrast in management outcomes between the Western and the Eastern La Mancha aquifers is related to the different types of policy instruments implemented for each aquifer. The results of these policies underline the importance of nurturing the stakeholders’ collective action under the appropriate institutional setting.  相似文献   
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