Spatial variability of soil nutrients in disturbed riverine mangrove forests at different stages of regeneration in the San Juan River estuary,Venezuela     

Victor?H.?Rivera-MonroyEmail author  Robert?R.?Twilley  Ernesto?Medina  E.?Barry?Moser  Leonor?Botero  Ana?Marta?Francisco  Evelyn?Bullard 《Estuaries and Coasts》2004,27(1):44-57

Geostatistical analysis of selected soil properties were performed in two mangrove sites (B7 and B9) dominated by the mangrove speciesRhizophora mangle along the San Juan River, Venezuela, to evaluate the effect of forest disturbance on nutrient spatial distributions. Plots within area B7 were clear-cut in 1972–1973 and in area B9 in 1982–1983. Four plots within each area were systematically selected and represented natural (2) and regenerated (2) forests. Individual plots were 1.5 ha in B7 and 1.25 ha in B9 and sampled at a resolution of 25 m. Soil samples were obtained at the intersection of an aligned grid with 90 points in B7 and 78 points in B9. Measured soil properties included salinity, total nitrogen, total carbon, total phosphorus, osmolality, and pore water cation concentrations (potassium, calcium, magnesium, and sodium). Sites were sampled in May 1996 and 1997, although spatial analysis was performed only for the data obtained in May 1997. Geostatistical analysis showed that most of the variables tested were spatially auto-correlated within each area and that there were no differences between regenerated and natural plots. Structural variance as a proportion of sample variance ranged from 55–99% for most of the properties. The significant spatial dependence observed for most of the variables in natural and regenerated plots, despite management schedules, indicates that clear-cutting did not have an effect on modifying the distribution of nutrient concentrations. These results suggest that after 15 and 25 yr following forest disturbance nutrient distributions were reestablished either there was not a net effect on patterns of element loss or tidal input was stronger than plant modifications of soils.  相似文献   

The usefulness of UV–visible and fluorescence spectroscopies to study the chemical nature of humic substances from soils and composts   总被引：1，自引：1，他引：1  

Marta Fuentes  Gustavo Gonzlez-Gaitano  Jos Ma García-Mina 《Organic Geochemistry》2006,37(12):1949

The aim of this work is to study the suitability of the use of fluorescence and UV–visible spectroscopies to evaluate the humification degree of different organic alkaline extracts obtained from diverse materials (humic substances, composted and non-composted materials). Our results indicate that the complementary utilization of the fluorescence index proposed by Milori et al. [Milori, D., Martin-Neto, L., Bayer, C., Mielniczuk, J., Vagnato, V., 2002. Humification degree of soil humic acids determined by fluorescence spectroscopy. Soil Science, 167, 739–749] (the total area of the emission spectra collected over a range of 460–650 nm using an excitation wavelength of 465 nm), the ratio between the electron-transfer band and benzenoid band of benzene UV light absorption, and the molar absorption coefficients at 600 nm and 280 nm proved capable of discriminating between extracts obtained from non-humified, partially humified and very humified materials.Likewise, our results suggest that humification is related to increments in the aromatic character of the molecules, which may be reflected in the presence of more aromatic rings and/or more condensed polyaromatic structures, and the degree of substitution in aromatic rings with polar functional groups, as well as to the possible increase in the conjugation degree in unsaturated aliphatic chains.  相似文献   

Field-scale Variations in Plant and Grasshopper Communities: A GIS-based Assessment   总被引：1，自引：0，他引：1  

William P. Kemp  Kevin M. O'Neill  Maria Marta Cigliano  & Sandra Torrusio 《Transactions in GIS》2002,6(2):115-133

GIS technology allowed us to examine species-specific occurrence and abundance patterns of important grassland herbivore species through the use of appropriate statistical methods and the superior spatial representation commonly available in existing GIS packages. The study was conducted on a 254 ha grassland area located 10 km south of Three Forks, Gallatin County, Montana, in the Agropyron spicatum province of the western steppe region of the U.S.A. From an ecological perspective, grasshopper species distribution and abundance patterns observed on a local, non-uniform landscape (2.6 km 2) were consistent with results found in other studies at the valley (≈1,400 km 2) and state-level (≈237,000 km 2) scales. Our observations at the local scale further demonstrate the importance of vegetation type and specific local stand physiognomies in structuring grasshopper populations. The application of results from studies conducted at various scales to the development of decision support tools for resource managers is also discussed.  相似文献   

Fluid seepage along the San Clemente Fault scarp: basin-wide impact on barium cycling     

Marta E. Torres  James McManus  Chih-An Huh 《Earth and Planetary Science Letters》2002,203(1):181-194

Material fluxes associated with fluid expulsion at cold seeps and their contribution to oceanographic budgets have not been accurately constrained. Here we present evidence that the barium released at cold seeps along the San Clemente Fault zone may significantly impact the geochemical budget of barium within the basin. Barium fluxes at seep localities on the fault scarp, measured with benthic chambers, reach values as high as 5 mmol m⁻² day⁻¹. This is the largest dissolved barium flux measured to date at a cold seep. The discharge of barium-rich fluids results in formation of massive barite deposits along the escarpment wall. The deposits are young (approximately 8 yr) and appear to grow at a minimum rate of 0.2 cm yr⁻¹. This rapid growth rate requires a barium efflux rate that is about two orders of magnitude higher than the measured dissolved flux. We believe that the discrepancy reflects a highly localized seepage system and that chambers positioned as close as possible to the growing chimneys did not sample the foci of fluid discharge. Transport of fine barite particles from the seeps may be responsible for excess rates of barium accumulation throughout the San Clemente Basin, relative to other basins in the California Margin. Based on a preliminary budget, we estimate that cold-seep barite is accumulating at the basin floor in San Clemente at a rate of 2 μmol m⁻² day⁻¹, a value that is comparable to the total barium accumulation rates driven by detrital and biogenic components in neighboring basins. Remobilization of cold-seep barite on the basin floor adds to that driven by the biogenic barium flux and results in benthic barium recycling rates (effluxes) within the San Clemente Basin that are as much as seven times higher than the effluxes from surrounding borderland basins. Our estimates imply that processes associated with fluid seepage along the San Clemente Fault significantly contribute to the basin’s barium cycle. The strontium isotopic composition of the seep barite is significantly different from marine ‘biogenic’ barite, which is known to accurately record seawater composition. In addition, the seep deposits are depleted in ²²⁶Ra relative to their modern biogenic counterparts, and are likely to be a source of radium-depleted particulate barium to the basin. Thus the impact of barite transport from seeps on the San Clemente escarpment to the basin floor might also have implications for the geochemistry of elements other than barium.  相似文献   

<Emphasis Type="Italic">P</Emphasis>–<Emphasis Type="Italic">T</Emphasis> and fluid evolution of barren and lithium pegmatites from Vlastějovice,Bohemian Massif,Czech Republic     

Lukáš Ackerman  Jiří Zachariáš  Marta Pudilová 《International Journal of Earth Sciences》2007,96(4):623-638

Fluid inclusions, mineral thermometry and stable isotope data from two types of mineralogically and texturally contrasting pegmatites, barren ones and lithium ones, from the Moldanubian Zone of the Bohemian Massif were studied in order to constrain P–T conditions of their emplacement, subsolidus hydrothermal evolution and to estimate composition of the early exsolved fluid and that of the parental melt. Despite the fact that the lithium pegmatites are abundant throughout the crystalline units of the Bohemian Massif, data similar to this paper have not been published yet. The studied pegmatites are hosted by iron-rich calcic skarn bodies. This specific setting allowed scavenging of calcium, fluorine and some other elements from the host rocks into the pegmatitic melts and post-magmatic fluids. Such contamination process was important namely in the case of barren pegmatites, as can be deduced from the variation in anorthite contents in plagioclase and from the presence of fluorite, hornblende (with F content) or garnet in the contact zones of pegmatite dykes. Fluid inclusions were studied mostly in quartz, but also in fluorite, titanite and apatite. Early aqueous–carbonic and late aqueous fluids were identified in both pegmatite types. The P–T conditions of crystallization as well as the detailed composition of exsolved magmatic fluid, however, particularly differ. The magmatic fluids associated with barren pegmatites correspond to H₂O–CO₂ low salinity fluids, composition of which evolved from 20 to 23 to <5 mol% CO₂, and from 2 to 4–6 mol% NaCl eq. Sudden decrease in the CO₂ content of the post-magmatic fluids (<5 mol% CO₂) seems to coincide with the enrichment of the fluid in calcium (from the contamination process) and resulted in precipitation of calcites (frequently found as trapped solid phases in fluid inclusions). The fluids associated with lithium pegmatites are more complex (H₂O–CO₂/N₂–H₃BO₃–NaCl). The CO₂ content of early exsolved fluid is 26–20 mol% CO₂ and remains the same in the next fluid generation. The main difference between the magmatic and the first post-magmatic fluids is the presence of 7–9 wt% of H₃BO₃ (identified as daughter mineral sassolite) in the former. The second post-magmatic fluids are again CO₂-poor (∼4 mol%) and more saline (∼4 mol% NaCl eq.). The composition of exsolved fluid was further used to constrain volatile composition and content of the parental melts. Finally, P–T conditions of pegmatite crystallization are constrained: 600–640°C and 420–580 MPa for the barren pegmatites and 500–570°C and 310–430 MPa for the lithium pegmatite. While the emplacement of the former occurred in thermal equilibrium with the Moldanubian host rock environment, the emplacement of the later suggests substantial thermal disequilibrium.  相似文献   

A Matrix Approach Coupled with Monte Carlo Techniques for Solving the Net Radiative Balance of the Urban Block   总被引：2，自引：0，他引：2  

Marta J. N. Oliveira Panão  Helder J. P. Gonçalves  Paulo M. C. Ferrão 《Boundary-Layer Meteorology》2007,122(1):217-241

A new method is developed for solving the shortwave and longwave net radiative balance of a three-dimensional urban structure, represented by parallelepiped blocks uniformly distributed in each direction. The method is based on a novel approach to determine the shape factors among surfaces, which are estimated by Monte Carlo techniques due to the complex geometry associated with the three-dimensional urban structure. Then, a set of linear equations is solved to quantify the radiative balance, in order to obtain their exact solution, considering all the inter-reflections among surfaces. The comparison between the new and the ray-tracing tracking methods resulted in a Pearson correlation coefficient of 0.996. However, by integrating the linear equations’ exact solution with Monte Carlo techniques, the new method reduces by a factor of 36 the central processing unit (CPU) time used to perform the calculations of the ray-tracing tracking method. The use of the model for a sensitivity study allows us to verify the effective absorptance and emittance increases with the canyon aspect ratio of the urban layout. An urban structure formed by square cross-sectional blocks absorbs more solar radiation than an urban structure formed by rectangular cross-sectional blocks. The approximation of a specific geometry for an equivalent bi-dimensional infinite street can be applied for rectangular cross-sectional blocks, where the width is 11 times or more greater than the depth dimension.  相似文献   

On the individual calibration of hailpads     

Covadonga Palencia  Claude Berthet  Marta Massot  Amaya Castro  Jean Dessens  Roberto Fraile   《Atmospheric Research》2007,83(2-4):493-504

This paper is a comparative study between the two most common hailpad calibration systems: one annual calibration of a whole consignment of material, and the individual calibration of each plate after a hailfall. Individual calibration attempts to minimize errors due to differences in sensitivity to the impact of hailstones between plates from the same consignment, or due to differences in the inking process before the actual measurement.The comparison was carried out using calibration data from the past few years in the hailpad network in south-western France, and data from an individual calibration process on material provided by the hailpad network in Lleida (Spain). The same type of material was used in the two cases.The results confirm that the error in measuring hailstone sizes is smaller in the case of an individual calibration of hailpads than when one single calibration process was carried out for a whole consignment. The former is approximately 80% of the latter. However, this error could have been higher if it had not been the same person carrying out the single calibration process and the measuring of the dents: it has been found that differences in the inking process may account for up to 20% of the error in the case of small hailstones. Calibration errors affecting other variables, e.g. energy or parameter λ of the exponential size distribution are generally higher (5% and 18%, respectively) than errors due to the spatial variability of the hailstones. However, the calibration method does not influence the maximum size, since the relative error attributed to the spatial variability is about 8 times the calibration error.In conclusion, if errors in determining energy or parameter λ are to be reduced to a minimum, it is highly advisable to be consistent in applying the measuring procedure (if possible with the same person carrying out the measurements all the time), and even to use individual calibration on each plate, always bearing in mind that technicians have to be trained appropriately in order to achieve the highest possible degree of uniformity.  相似文献   

Areal versus linear evaluation of relationship between drainage basin lithology and geochemistry of stream and overbank sediments in low-order mountainous drainage basins     

Zoran Peh  Slobodan Miko  Marta Mileusnic 《Environmental Geology》2006,49(8):1102-1115

The comparison of two multiple regression models is based on the assumption that geochemical composition of the drainage basin alluvial sediments is derived primarily from the underlying bedrock lithology. The parent material is integrated with both stream sediment and overbank sediment geochemistry via the two essentially different approaches as regards the drainage basin geomorphological data: (1) as the relative area of influence representing a portion of the catchment basin occupied by a specific rock type and (2) as the relative “line” of influence representing a narrow zone of the underlying bedrock traversed by the perennial streams which form the active stream network. The model comparison is established on the goodness-of-fit test for both experimental designs and for the same set of data. Both experiments converge on the linear approach as the more appropriate model in evaluating the lithologic influence on the analysed sample media in small mountainous watersheds.  相似文献   

Determination of the apparent copper complexing capacity of seawater by anodic stripping voltammetry     

Marta Plavšić  Damir Krznarić  Marko Branica 《Marine Chemistry》1982,11(1):17-31

A new experimental technique using differential pulse anodic stripping voltammetry with a thin-film mercury electrode and efficient mixing of the electrolyte for the apparent copper complexing capacity of seawater is proposed. The effects of some factors such as type of electrode and cell, pH of the solution, potential of deposition, time of equilibration, and influence of a non-ionic surface active agent on the measurements are examined. Experimental results for the apparent copper complexing capacity of seawater are calculated presuming 1:1 inert complex formation. By using EDTA as a model ligand, it is shown that the proposed procedure with efficient mixing of the solution excludes any appreciable kinetic influence upon the electroanalytical results.  相似文献   

Diffuse Component Spectra of Solar Active Regions at Submillimeter Wavelengths     

Adriana?V.?R.?SilvaEmail author  Tatiana?F.?Laganá  C.?Guillermo?Gimenez?De?Castro  Pierre?Kaufmann  Joaquim?E.?R.?Costa  Hugo?Levato  Marta?Rovira 《Solar physics》2005,227(2):265-281

Solar maps at 212 and 405 GHz obtained by the Solar Submillimetric Telescope (SST) show regions of enhanced brightness temperature, which coincide with the location of active regions. A statistical study of the radio emission from these active regions was performed for the first time at such high frequencies during 23 days on June and July 2002, when the atmospheric opacity was low. The brightest regions on the maps were chosen for this study, where the brightness excess observed varies from 3 to 20% above quiet Sun levels (i.e., 200–1000 K) at both wavelengths. Sizes of the regions of enhanced emission calculated at half the maximum value were estimated to be between 2′ and 7′. These sizes agree with observed sizes of active regions at other wavelengths such as Hα and ultraviolet. An important result is that the flux density spectra of all sources increase toward submillimeter frequencies, yielding flux density spectral index with an average value of 2.0. The flux density of the active region sources were complemented with that from maps at 17 and 34 GHz from the Nobeyama Radio Heliograph. The resulting spectra at all four frequencies were fit considering the flux density to be due to thermal bremsstrahlung from the active region. In the calculations, the source radius was assumed to be the mean of the measured values at 212 and 405 K. The effective temperatures of the radio emitting source, assumed homogeneous, obtained from this fit were 0.6–2.9 × 10⁴ K, for source diameters of 2′–7′.  相似文献