Study on the fate of petroleum-derived polycyclic aromatic hydrocarbons (PAHs) and the effect of chemical dispersant using an enclosed ecosystem,mesocosm     

Yamada M  Takada H  Toyoda K  Yoshida A  Shibata A  Nomura H  Wada M  Nishimura M  Okamoto K  Ohwada K 《Marine pollution bulletin》2003,47(1-6):105-113

Polycyclic Aromatic Hydrocarbons (PAHs) are one of the components found in oil and are of interest because some are toxic. We studied the environmental fate of PAHs and the effects of chemical dispersants using experimental 500 l mesocosm tanks that mimic natural ecosystems. The tanks were filled with seawater spiked with the water-soluble fraction of heavy residual oil. Water samples and settling particles in the tanks were collected periodically and 38 PAH compounds were analyzed by gas chromatography-mass spectrometry (GC-MS). Low molecular weight (LMW) PAHs with less than three benzene rings disappeared rapidly, mostly within 2 days. On the other hand, high molecular weight (HMW) PAHs with more than four benzene rings remained in the water column for a longer time, up to 9 days. Also, significant portions (10-94%) of HMW PAHs settled to the bottom and were caught in the sediment trap. The addition of chemical dispersant accelerated dissolution and biodegradation of PAHs, especially HMW PAHs. The dispersant amplified the amounts of PAHs found in the water column. The amplification was the greater for the more hydrophobic PAHs, with an enrichment factor of up to six times. The increased PAHs resulting from dispersant use overwhelmed the normal degradation and, as a result, higher concentrations of PAHs were observed in water column throughout the experimental period. We conclude that the addition of the dispersant could increase the concentration of water column PAHs and thus increase the exposure and potential toxicity for organisms in the natural environment. By making more hydrocarbon material available to the water column, the application of dispersant reduced the settling of PAHs. For the tank with dispersant, only 6% of chrysene initially introduced was detected in the sediment trap whereas 70% was found in the trap in the tank without dispersant.  相似文献   

Topography of the Seismic Velocity Discontinuities beneath the Chugoku and Shikoku Districts,Southwest Japan     

Hitoshi?OdaEmail author  Michiro?Okamoto  Motoko?Ishise 《Pure and Applied Geophysics》2005,162(12):2389-2407

The first P-arrival-time data from 513 local earthquakes were analyzed to study lateral variation of the depth to the Conrad and Moho discontinuities beneath the Chugoku and Shikoku districts, southwest Japan, as well as to determine earthquake hypocenters and P-wave station corrections. The depth to the discontinuity was estimated by minimizing the travel-time residuals of more than 8700 first P arrivals observed at 55 seismic stations. The Conrad and Moho discontinuities are located within depth ranges of 15–25 km and 30–40 km, respectively. The Moho is deeper under the mountain area than under the Seto Inland Sea area, and especially deep under the Pacific Coast of the Shikoku district and the mountain area in the Chugoku district. The depth variation of the Moho is quite similar to the Bouguer gravity anomaly distribution and the lateral variations of the P-wave velocity. The deep Moho under the southern Shikoku is located at the portion in which the continental Moho under the island arc meets the oceanic Moho that is the boundary interface between the oceanic crust and the Philippine Sea (PHS) plate dipping toward the back arc. Although there are high mountains in the northern and middle Shikoku, the Moho is not so deep because subduction of the PHS plate prevents the Moho from getting deep, while the Moho is deep due to isostatic balance under the mountain area in the Chugoku district. In addition, we indicated the possibility that the upper boundary of the oceanic crust just above the high-velocity PHS plate is in contact with the deep Moho under the western Chugoku. The contact of the Moho with the oceanic crust can explain the markedly negative gravity anomaly observed in the western Chugoku and the later phase that appears just after the first P arrival from local earthquakes.  相似文献   

Variable microstructure of peridotite samples from the southern Mariana Trench: Evidence of a complex tectonic evolution   总被引：2，自引：0，他引：2  

Katsuyoshi Michibayashi  Miki Tasaka  Yasuhiko Ohara  Teruaki Ishii  Atsushi Okamoto  Patricia Fryer 《Tectonophysics》2007,444(1-4):111-118

We retrieved samples of peridotite from a dredge haul (KH92-1-D2) collected during Cruise KH92-1 undertaken by the research vessel (R/V) Hakuho in 1992 at the landward trench slope of the southern Mariana Trench (11°41.16′N, 143°29.62′E; depth 6594–7431 m), which is the deepest ocean in the world. Ten of 30 retrieved samples possessed both a foliation and lineation, as assessed from 46 thin sections of various orientations and observations of hand samples. The samples showed marked variation in microstructure, ranging from coarse (> 5 mm) equigranular and intensely elongated textures to finer (< 1 mm) porphyroclastic and fine-grained equigranular textures. Olivine fabrics also varied among the different samples, with (010)[100] and (010)[001] patterns (termed A- and B-type, respectively) observed in samples with coarse textures and no clear patterns observed in samples with fine textures. Even though the peridotite samples were retrieved from a single dredge site, some contain primary tectonic microstructures and some contain secondary microstructures. Recent bathymetric and topographic analyses indicate that the lithosphere in this region is as thin as 20 km. Such a thin lithosphere may have been intensely deformed, even perhaps in the ductile regime, during fore-arc extension; consequently, the observed variations in microstructure within the peridotite samples probably reflect the complex tectonic evolution of the southern Mariana region.  相似文献   

A Low-Power High-Resolution Broad-Band Radar Using a Pulse Compression Technique for Meteorological Application     

Mega  T. Monden  K. Ushio  T. Okamoto  K. Kawasaki  Z.-I. Morimoto  T. 《Geoscience and Remote Sensing Letters, IEEE》2007,4(3):392-396

A new high-resolution Ku-band Doppler radar for meteorological applications has been developed. With the new system design, the radar can accurately measure the radar reflectivity factor with 4-m resolution over a range from 40 m to several kilometers for 100-mW power using a pulse compression technique. Details of the system design, signal processing algorithm, and data acquisition procedures are described. To demonstrate the accuracy of the system, the radar reflectivity measurements are compared with the Joss-Waldvogel disdrometer measurements, and fairly good agreement is shown. The ability of the system to capture the backscattered signal and Doppler spectrum from rain volume at low altitude with high resolution is demonstrated for both convective- and stratiform-type rain events.  相似文献   

Anomalously large seismic amplifications in the seafloor area off the Kii peninsula     

Takeshi Nakamura  Masaru Nakano  Naoki Hayashimoto  Narumi Takahashi  Hiroshi Takenaka  Taro Okamoto  Eiichiro Araki  Yoshiyuki Kaneda 《Marine Geophysical Researches》2014,35(3):255-270

Seismic wave amplifications were investigated using strong-motion data obtained from the ground’s surface (K-net) on the Kii peninsula (southwestern Japan) and from the network of twenty seismic stations on the seafloor (DONET) located off the peninsula near the Nankai trough. Observed seismograms show that seismic signals at DONET stations are significantly larger than those at K-net stations, independent of epicentral distances. In order to investigate the cause of such amplifications, seismic wavefields for local events were simulated using the finite-difference method, in which a realistic 3D velocity structure in and around the peninsula was incorporated. Our simulation results demonstrate that seismic waves are significantly amplified at DONET stations in relation to the presence of underlying low-velocity sediment layers with a total thickness of up to 10 km. Our simulations also show considerable variations in the degree of amplification among DONET stations, which is attributed to differences in the thickness of the sediment layers. The degree of amplification is relatively low at stations above thin sediment layers near the trough axis, but seismic signals are much more amplified at stations closer to the Kii peninsula, where sediment layers are thicker than those at the trough axis. Simulation results are consistent with observations. This study, based on seafloor observations and simulations, indicates that because seismic signals are amplified due to the ocean-specific structures, the magnitude of earthquakes would be overestimated if procedures applied to data observed at land stations are used without corrections.  相似文献   

Petrology of the diamond-grade eclogite in the Kokchetav Massif, northern Kazakhstan   总被引：2，自引：0，他引：2  

K. Okamoto  J. G. Liou and  Y. Ogasawara 《Island Arc》2000,9(3):379-399

Abstract The Kokchetav Massif of northern Kazakhstan is unique because of the abundant occurrence of microdiamond inclusions in garnet, zircon and clinopyroxene of metasediments. In order to determine precise pressure–temperature (P–T) conditions, we have systematically investigated mineral inclusions and the compositions of major silicates in Ti–clinohumite–garnet peridotite and diamond-grade eclogite from Kumdy–Kol. It was found that garnet peridotites from Kumdy–Kol contain assemblages of garnet, olivine, Ti–clinohumite and ilmenite. The garnet contains inclusions that are indicative of both ultrahigh pressure (UHP) and retrograde conditions. Inclusions of hydrous phases such as chlorite, amphibole and zoisite were formed at the post-UHP stage. The study also found that eclogite from Kumdy–Kol contains albite–augite symplectites after omphacitic pyroxene. The core of pyroxene (sodic augite) contains high K₂O (up to 1wt%; average 0.24wt%). Phengite is included in the core. Applying the K₂O-in-augite geobarometry, which is based on recent experiments, and the garnet–clinopyroxene (Grt–Cpx) geothermometer for peak metamorphism, the eclogites yield P–T estimates of > 6 GPa and > 1000 °C, and the diamond-grade eclogites yield lower temperature estimates at 900–1000 °C and 5 GPa.  相似文献   

Three‐dimensional texture of natural pseudotachylyte: Pseudotachylyte formation mechanism in hydrous accretionary complex          下载免费PDF全文

Yohei Hamada  Gaku Kimura  Jun Kameda  Asuka Yamaguchi  Mari Hamahashi  Rina Fukuchi  Yujin Kitamura  Shin'ya Okamoto 《Island Arc》2018,27(2)

Melt‐origin pseudotachylyte is the most reliable seismogenic fault rock. It is commonly believed that pseudotachylyte generation is rare in the plate subduction zone where interstitial fluids are abundant and can trigger dynamic fault‐weakening mechanisms such as thermal pressurization. Some recent studies, however, have discovered pseudotachylyte‐bearing faults in exhumed ancient accretionary complexes, indicating that frictional melting also occurrs during earthquakes in subduction zones. To clarify the pseudotachylyte generation mechanism and the variation of slip behavior in the plate subduction zone, a pseudotachylyte found in the exhumed fossil accretionary complex (the Shimanto Belt, Nobeoka, Japan) was re‐focused and microscopic and three‐dimensional observations of the pseudotachylyte‐bearing fault were performed based on optical, electron, and X‐ray microscope images. Based on the patterns contained in the fragment, the pseudotachylyte is divided into four domains, although no clear domain boundaries or layering structures are not found. Three‐dimensional observation also suggests that the pseudotachylyte were fragmented or isolated by cataclasite or carbonate breccia. The pseudotachylyte was rather injected into the surrounding carbonate breccia, which is composed of angular fragments of the host rock and a matrix of tiny crystalline carbonate. The pseudotachylyte volume was extracted from the X‐ray microscope image and the heat abundance consumed by the pseudotachylyte generation was estimated at 2.18 MJ/m², which can be supplied during a slip of approximately 0.5 m. These observations and calculations, together with the results of the previous investigations, suggest hydrofracturing and rapid carbonate precipitation that preceded or accompanied the frictional melting. Dynamic hydrofracturing during a slip can be caused by rapid fluid pressurization, and can induce abrupt decrease in fluid pressure while drastically enhancing the shear strength of the shear zone. Consequently, frictional heating would be reactivated and generate the pseudotachylyte. These deformation processes can explain pseudotachylyte generation in hydrous faults with the impermeable wall rock.  相似文献