Pseudosection modelling for a selected eclogite body from the Koralpe (Hohl), Eastern Alps     

Emilie Bruand  Kurt Stüwe  Alexander Proyer 《Mineralogy and Petrology》2010,99(1-2):75-87

In the Kor-, Saualpe and Pohorje regions of the Eastern Alps eclogite bodies occur within metapelitic gneisses. The bodies are between 1 meter and several hundreds of meters in size and some of them were defined by Haüy (1822) as the type locality for the rock type “eclogite”. A growing body of petrological work has documented the metamorphic evolution of the metapelites surrounding the eclogites. However, few phase diagrams have been constructed for the eclogite bodies themselves. Here we use recently available activity models for amphiboles to present new thermodynamic pseudosections for the Hohl locality of the Koralpe eclogites. We show that this eclogite reached peak conditions in a narrow PT field obliquely oriented in PT space between 16.5 and 20.5 kbar and 620°C to 720°C and that its metamorphic evolution was likely to have occurred under water saturated conditions. We conclude that eclogite and the surrounding metapelites have certainly undergone the same metamorphic peak in Eo-alpine time. Comparison of our results with different PT estimates on the eclogite from Pohorje, suggest that a PT gradient from Koralpe to Pohorje is likely.  相似文献   

Geochemical effects of oxidation products and framboidal pyrite oxidation in acid mine drainage prediction techniques   总被引：1，自引：0，他引：1  

P. A. Weber  W. A. Stewart  W. M. Skinner  C. G. Weisener  J. E. Thomas  R. St. C. Smart   《Applied Geochemistry》2004,19(12):1953-1974

Acid mine drainage predictive testwork associated with the Australian Mineral Industries Research Association (AMIRA) P387A Project: Prediction and Kinetic Control of Acid Mine Drainage (AMD) has critically examined static acid assessment and kinetic information from acid–base accounting techniques, including net acid production potential (NAPP), net acid generation (NAG) and column leach tests. This paper compares results on two waste rock samples that were obtained from the Kaltim Prima Coal mine (KPC) containing significant quantities of fine-grained framboidal pyrite. In agreement with other research, the authors' results indicated that framboidal pyrite is more reactive than euhedral forms due to the greater specific surface area of framboidal pyrite. This is evidenced by optical microscopy of reacted samples. Importantly, the results showed that NAPP testing is biased by the rapid acid generating oxidation of framboidal pyrite prior to, and during the acid neutralisation capacity (ANC) test. This can result in negative ANC values for samples containing significant framboidal pyrite (often “corrected” to zero kg H₂SO₄/t) when significant ANC is actually present in the sample. NAG testing using H₂O₂ indicated that samples containing a significant quantity of framboidal pyrite can result in the catalytic decomposition of the H₂O₂ prior to complete oxidation of the sulfide minerals present, requiring sequential addition of H₂O₂ for completion. A benefit of the NAG test, however, is that it assesses the net acid generation capacity of the sample without bias towards acid generation as is observed using NAPP methods. The kinetic NAG test also gives information on the reaction sequence of framboidal and euhedral pyrite. Periodic (kinetic) analysis of sub-samples from column leach tests indicated rapid oxidation of the framboidal pyrite compared to the euhedral pyrite, which was correlated with the greater framboidal pyrite surface area.Calculations to determine the sulfide/sulfate acidity derived from the oxidation of framboidal pyrite prior to; and during the ANC test have been developed to provide a better indication of the actual ANC (ANC_Actual) of the sample. Paste pH values of <pH 4–5 may be one suitable trigger mechanism for the implementation of this new method. This has led to an improved NAPP estimation of total acid production. Together with NAG and column leach testing this improved methodology has resulted in accurate AMD characterisation of samples containing acidic oxidation products and framboidal pyrite.  相似文献   

Quantifying Barrovian metamorphism in the Danba Structural Culmination of eastern Tibet   总被引：3，自引：0，他引：3  

O. M. Weller  M. R. St‐Onge  D. J. Waters  N. Rayner  M. P. Searle  S.‐L. Chung  R. M. Palin  Y.‐H. Lee  X. Xu 《Journal of Metamorphic Geology》2013,31(9):909-935

The Danba Structural Culmination is a tectonic window into the late Triassic to early Jurassic Songpan‐Garzê Fold Belt of eastern Tibet, which exposes an oblique section through a complete Barrovian‐type metamorphic sequence. Systematic analysis of a suite of metapelites from this locality has enabled a general study of Barrovian metamorphism, and provided new insights into the early thermotectonic history of the Tibetan plateau. The suite was used to create a detailed petrographic framework, from which four samples ranging from staurolite to sillimanite grade were selected for thermobarometry and geochronology. Pseudosection analysis was applied to calculate P–T path segments and determine peak conditions between staurolite grade at ～5.2 kbar and 580 °C and sillimanite grade at ～6.0 kbar and 670 °C. In situ U–Pb monazite geochronology reveals that staurolite‐grade conditions were reached at 191.5 ± 2.4 Ma, kyanite‐grade conditions were attained at 184.2 ± 1.5 Ma, and sillimanite‐grade conditions continued until 179.4 ± 1.6 Ma. Integration of the results has provided constraints on the evolution of metamorphism in the region, including a partial reconstruction of the regional metamorphic field gradient. Several key features of Barrovian metamorphism are documented, including nested P–T paths and a polychronic field gradient. In addition, several atypical features are noted, such as P–T path segments having similar slopes to the metamorphic field gradient, and T_max and P_max being reached simultaneously in some samples. These features are attributed to the effects of slow tectonic burial, which allows for thermal relaxation during compression. While nested, clockwise P–T–t loops provide a useful framework for Barrovian metamorphism, this study shows that the effects of slow burial can telescope this model in P–T space. Finally, the study demonstrates that eastern Tibet experienced a significant phase of crustal thickening during the Mesozoic, reinforcing the notion that the plateau may have a long history of uplift and growth.  相似文献   

Ries crater and suevite revisited—Observations and modeling Part I: Observations     

Dieter Stöffler  Natalia A. Artemieva  Kai Wünnemann  W. Uwe Reimold  Juliane Jacob  Birgit K. Hansen  Iona A. T. Summerson 《Meteoritics & planetary science》2013,48(4):515-589

We report results of an interdisciplinary project devoted to the 26 km‐diameter Ries crater and to the genesis of suevite. Recent laboratory analyses of “crater suevite” occurring within the central crater basin and of “outer suevite” on top of the continuous ejecta blanket, as well as data accumulated during the past 50 years, are interpreted within the boundary conditions imposed by a comprehensive new effort to model the crater formation and its ejecta deposits by computer code calculations (Artemieva et al. 2013). The properties of suevite are considered on all scales from megascopic to submicroscopic in the context of its geological setting. In a new approach, we reconstruct the minimum/maximum volumes of all allochthonous impact formations (108/116 km³), of suevite (14/22 km³), and the total volume of impact melt (4.9/8.0 km³) produced by the Ries impact event prior to erosion. These volumes are reasonably compatible with corresponding values obtained by numerical modeling. Taking all data on modal composition, texture, chemistry, and shock metamorphism of suevite, and the results of modeling into account, we arrive at a new empirical model implying five main consecutive phases of crater formation and ejecta emplacement. Numerical modeling indicates that only a very small fraction of suevite can be derived from the “primary ejecta plume,” which is possibly represented by the fine‐grained basal layer of outer suevite. The main mass of suevite was deposited from a “secondary plume” induced by an explosive reaction (“fuel‐coolant interaction”) of impact melt with water and volatile‐rich sedimentary rocks within a clast‐laden temporary melt pool. Both melt pool and plume appear to be heterogeneous in space and time. Outer suevite appears to be derived from an early formed, melt‐rich and clast‐poor plume region rich in strongly shocked components (melt ? clasts) and originating from an upper, more marginal zone of the melt pool. Crater suevite is obviously deposited from later formed, clast‐rich and melt‐poor plumes dominated by unshocked and weakly shocked clasts and derived from a deeper, central zone of the melt pool. Genetically, we distinguish between “primary suevite” which includes dike suevite, the lower sublayer of crater suevite, and possibly a basal layer of outer suevite, and “secondary suevite” represented by the massive upper sublayer of crater suevite and the main mass of outer suevite.  相似文献   

Ambient pressure thermal desorption spectroscopy (AP-TDS) of NiO/SiO2 catalysts     

M. Städter  K. Müller  F. Rachow  M. Richter  D. Schmeißer 《Environmental Earth Sciences》2013,70(8):3779-3784

The Sabatier reaction is a key process in the “power-to-gas” application which is considered to contribute to future chemical energy storage systems. In this contribution we focus on the catalytic active sites of a NiO catalyst supported on SiO₂ (NiO/SiO₂) which is commonly used in the Sabatier reaction. A novel technique for the characterization of the active sites is presented and discussed using thermal desorption spectroscopy at ambient pressure. This analytical tool is operated under reaction conditions and allows element specific measurements during the catalytic process of CO₂ reforming towards methane. Beside the desorption experiments, XPS and XAS measurements of pristine and catalytically used samples are performed to determine the influence of the Sabatier reaction conditions on the surface structure of the catalyst.  相似文献   

Preface     

Eric R. Christian  Michael L. Kaiser  Therese A. Kucera  O. C. St. Cyr  Lidia van Driel-Gesztelyi  Cristina H. Mandrini 《Solar physics》2009,256(1-2):1-2

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Dust Detection by the Wave Instrument on STEREO: Nanoparticles Picked up by the Solar Wind?     

Meyer-Vernet  N.  Maksimovic  M.  Czechowski  A.  Mann  I.  Zouganelis  I.  Goetz  K.  Kaiser  M. L.  St. Cyr  O. C.  Bougeret  J.-L.  Bale  S. D. 《Solar physics》2009,256(1-2):463-474

Solar Physics - The STEREO wave instrument (S/WAVES) has detected a very large number of intense voltage pulses. We suggest that these events are produced by impact ionisation of nanoparticles...  相似文献   

STEREO SECCHI and S/WAVES Observations of Spacecraft Debris Caused by Micron-Size Interplanetary Dust Impacts     

St. Cyr  O. C.  Kaiser  M. L.  Meyer-Vernet  N.  Howard  R. A.  Harrison  R. A.  Bale  S. D.  Thompson  W. T.  Goetz  K.  Maksimovic  M.  Bougeret  J.-L.  Wang  D.  Crothers  S. 《Solar physics》2009,256(1-2):475-488

Early in the STEREO mission observers noted that the white-light instruments of the SECCHI suite were detecting significantly more spacecraft-related “debris” than any previously flown coronagraphic instruments. Comparison of SECCHI “debris storms” with S/WAVES indicates that almost all are coincident with the most intense transient emissions observed by the radio and plasma waves instrument. We believe the debris is endogenous (i.e., from the spacecraft thermal blanketing), and the storms appear to be caused by impacts of large interplanetary dust grains that are detected by S/WAVES. Here we report the observations, compare them to interplanetary dust distributions, and document a reminder for future spacebased coronagraphic instrument builders.

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A Multi-Wavelength Simultaneous Study of the Composition of the Halley Family Comet 8P/Tuttle     

E. Jehin  D. Bockelée-Morvan  N. Dello Russo  J. Manfroid  D. Hutsemékers  H. Kawakita  H. Kobayashi  R. Schulz  A. Smette  J. Stüwe  M. Weiler  C. Arpigny  N. Biver  A. Cochran  J. Crovisier  P. Magain  H. Rauer  H. Sana  R. J. Vervack  H. Weaver  J.-M. Zucconi 《Earth, Moon, and Planets》2009,105(2-4):343-349

We report on simultaneous optical and infrared observations of the Halley Family comet 8P/Tuttle performed with the ESO Very Large Telescope. Such multi-wavelength and coordinated observations are a good example of what can be done to support space missions. From high resolution optical spectroscopy of the CN (0,0) 388 nm and NH₂ (0,9,0) 610 nm bands using UVES at UT2 we determined ¹²C/¹³C = 90 ± 10 and ¹⁴N/¹⁵N = 150 ± 20 in CN and we derived a nuclear spin temperature of NH₃ of 29 ± 1 K. These values are similar to those found in Oort-Cloud and Jupiter Family comets. From low resolution long slit spectroscopy with FORS1 at UT2 we determined the CN, C₃ and C₂ production rates and the parent and daughter scale lengths up to 5.2 10⁵ km tailward. From high resolution IR spectroscopy with CRIRES at UT1 we measured simultaneously the production rates and mixing ratios of H₂O, HCN, C₂H₂, CH₄, C₂H₆, and CH₃OH.  相似文献   

Planetary transit observations at the University Observatory Jena: XO‐1b and TrES‐1     

St. Raetz  M. Mugrauer  T.O.B. Schmidt  T. Roell  T. Eisenbeiss  M.M. Hohle  N. Tetzlaff  M. Va&#x;ko  A. Seifahrt  Ch. Broeg  J. Koppenhoefer  R. Neuhuser 《Astronomische Nachrichten》2009,330(5):475-481

We report on observations of transit events of the transiting planets XO‐1b and TrES‐1 with a 25 cm telescope of the University Observatory Jena. With the transit timings for XO‐1b from all 50 available XO, SuperWASP, Transit Light Curve (TLC)‐Project‐ and Exoplanet Transit Database (ETD)‐data, including our own I ‐band photometry obtained in March 2007, we find that the orbital period is P = (3.941501 ± 0.000001) d, a slight change by ∼3 s compared to the previously published period. We present new ephemeris for this transiting planet. Furthermore, we present new R ‐band photometry of two transits of TrES‐1. With the help of all available transit times from literature this allows us to refine the estimate of the orbital period: P = (3.0300722 ± 0.0000002) d. Our observations will be useful for future investigations of timing variations caused by additional perturbing planets and/or stellar spots and/or moons (© 2009 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)  相似文献