溴素的有机化学──I．2，4，6－三溴苯甲酸溴代和非溴代芳酯的合成     

蔡月琴  钱佐国  孙明昆 《中国海洋大学学报(自然科学版)》1994,(3)

用ｍ－氨基苯甲酸作原料，经溴代、重氮化、还原脱氨、酰氯化和酯化反应等步骤，合成了六种新型的三溴苯甲酸的溴代和非溴代芳酯，即；双（２，４，６－三溴苯甲酸）－２＇，３＇，５＇，６＇－四溴－１＇，４＇－苯二酯，２，４，６－三溴苯甲酸－２＇，３＇，４＇，５＇，６＇－五溴苯酯，２，４，６－三溴苯甲酸－２＇，４＇，６＇－三溴苯酯，２，４，６－三溴苯甲酸－４＇－溴苯酯，２，４，６－三溴苯甲酸－４＇－甲基苯酯和２，４，６－三溴苯甲酸苯酯．通过对产物中碳、氢、溴元素的定量分析以及红外吸收光谱和氢核磁共振谱的研究，验证了合成产物的结构。  相似文献   

深水资料浮标中温度传感器电路的设计     

唐原广 《海洋科学》1991,15(2):68-71

本文对深水资料浮标中温度传感器的电路原理作了介绍。传感器中的感温元件,采用两端单片集成温度传感器AD590;整个测温电路仅用一片高精度4×1/2位A/D转换器7135;为了能方便地检验和标定温度值,在电路上还设计了温度显示部分,并设计了闭显的功能,以达到省电的目的。  相似文献   

一种动态P2P网络监测系统     

姜永玲  李江涛 《中国海洋大学学报(自然科学版)》2007,37(6):1023-1026,1050

重点研究P2P监测子网的动态自组织方法，通过对等点资源度量，优选汇聚节点，以适应P2P网络环境的动态变化。该方法有助于提高P2P监测系统的可靠性，降低网络监测成本。  相似文献   

Reducing the short-term mortality of juvenile school prawns (Metapenaeus macleayi) discarded during trawling     

Macbeth  William G.; Broadhurst  Matt K.; Paterson  Brian D.; Wooden  Michael E.L. 《ICES Journal of Marine Science》2006,63(5):831-839

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4-溴苯甲酸-2,3,4,5,6-五溴苯酯的合成(英文)     

钱佐国  王燕君  孙明昆 《中国海洋大学学报(自然科学版)》1992,(3)

以苯酚和4—溴苯甲酸为原料,合成一种尚未见文献记载的新化合物——4—溴苯甲酸—2,3,4,5,6—五溴苯酯,用无水三氯化铝催化苯酚的全溴化。此产物可望在阻燃剂方面得到应用。  相似文献   

四种重金属对刺参幼参的急性致毒效应   总被引：1，自引：0，他引：1  

孙振兴  陈书秀  陈静  高洪梅  李丹 《海洋通报》2007,26(5):80-85

采用静水试验法,在水温18.5℃~20℃的条件下,用Cu2 ,Zn2 ,Cd2 和Cr6 四种重金属对刺参幼参进行了单一急性毒性试验。结果表明:Cu2 对刺参幼参的24h,48h,72h和96hLC50分别为0.299,0.176,0.133和0.120mg/L;Zn2 的24h,48h,72h和96hLC50分别为6.700,3.624,2.577和1.951mg/L;Cd2 的24h,48h和72hLC50分别为4.246,2.588和2.137mg/L;Cr6 的24h,48h和72hLC50分别为31.974,7.499和3.808mg/L;Cu2 ,Zn2 ,Cd2 和Cr6 对刺参幼参的安全浓度分别为0.018,0.362,0.259和0.750mg/L。四种重金属对刺参幼参的毒性大小依次为Cu2 >Cd2 >Zn2 >Cr6 。  相似文献   

Spectrophotometric determination of pH in seawater off Taiaroa Head,Otago, New Zealand: Full-spectrum modelling and prediction of pCO₂ levels     

Shane M. Ohline  Malcolm R. Reid  Shamus L.G. Husheer  Kim I. Currie  Keith A. Hunter 《Marine Chemistry》2007

Accurate measurement of seawater pH has long been sought by marine chemists (for example: [Dickson, A.G. 1993a. The measurement of sea water pH. Marine Chemistry, 44, 131–142, Dickson, A.G. 1993b. pH buffers for sea water media based on the total hydrogen ion concentration scale. Deep-Sea Research, 40, 107–118; Zhang, 1996; Tapp, M., Hunter, K.A., Currie, K. and Macaskill, B. 2000. Apparatus of continuous-flow underway spectrophotometric measurement of surface water pH. Marine Chemistry 72(2–4), 193–202; Friis, K., Koetzinger, A., Wallace, D.W.R. 2004. Spectrophotometric pH measurement in the ocean: Requirements, design and testing of an autonomous charge-coupled device detector system. Limnology and Oceanography: Methods 2, 126–136]. Recently, such attempts have taken on greater significance as anthropogenic carbon dioxide emissions may create rapidly changing oceanic pH. Spectrophotometric techniques have been accepted generally as the best for determination of seawater pH. Here we report a new technique using thymol blue as the indicator dye and fitting the entire spectrum from 400 to 900 nm rather than measuring the absorbance values at only two or three points in the spectrum. This full-spectrum modelling enables a reduction in signal to noise over other techniques. In the laboratory, we find with seawater samples a pH precision increase of five-fold “within” a sample and seven-fold “between” samples when comparing the full spectrum to the three-point method of analysis [Zhang, H., Byrne, R.H. 1996. Spectrophotometric pH measurements of surface seawater at in-situ conditions: absorbance and protonation behaviour of thymol blue. Marine Chemistry 52, 17–25].  相似文献   

往复流中双向导向叶冲动透平模型性能试验研究     

梁贤光  孙培亚  王伟  蒋念东 《海洋工程》2001,19(4):84-93

研制了 30 0双向自调导叶透平试验机组 ,安装在 10 0 0活塞式往复流透平试验台上 ,对两种叶轮方案和 6种不同喷咀、扩压器进行了不同活塞行程、不同周期和不同恒定输出电压下性能试验。试验结果表明在喷咀出口角α1=2 1 5°、扩压器入口角α2 =6 5 5°和α1=2 4°、α2 =6 3°组合最佳 ,最高效率达 5 3 3% ,而且在宽广流量系数范围内 ,特别是大流量系数范围内都有较高效率。大大优于常用对称翼透平。将上下游导叶固定 ,变成双向固定导叶透平。用No 1叶轮和 6种导叶出口角组合进行试验。表明最佳导叶出口角为 2 4°～ 30°,最高效率仍达 38 5 % ,比对称翼透平仍高许多  相似文献   

Responses of CO₂ in surface water in subtropical West Pacific to El Niño event     

Xing Runan  Ma Liming  Qiao Ran  Wang Zhanggui 《海洋学报(英文版)》2001,20(1):39-50

In order to investigate the relationships between the change of TCO2, △PCO2 and SST, current, upwelling and biological activities during El Nin(～)o event in the subtropical Pacific, the responses of TCO2 and △PCO2 in surface water in the subtropical Pacific during El Nin(～)o and La Nina have been simulated using a three-dimension carbon cycle model with biota pump. The results of numerical simulations show that TCO2 in sea water increases with reducing of SST during mature phase of El Nin(～)o in the subtropical West Pacific . At the same period , the Kuroshio in this region was weakened , the zonal currents were divergence , the upwelling carried the water with high concentrations of CO2 to the sea surface , so both of TCO2 and △PCO2 in surface water were increased . But TCO2 and △pCO2 were decreased during La Nina period. These simulated results confirmed the observations in 1982/1983 , 1986/1987 ,1991/1995 and 1997/1998 El Nin(～)o events .  相似文献   

Algorithm for Harmonic Tidal Analysis along T/P Tracks： Taking Differences of Observed Sea Surface Heights at Adjacent Points as Observations     

Xu  Jun  Bao  Jingyang  Liu  Yanchun  Yu  Caixia 《地球空间信息科学学报》2008,11(1):17-20

An algorithm （differential mode） is presented for the improvement of harmonic tidal analysis along T/P tracks, in which the differences between the observed sea surface heights at adjacent points are taken as observations. Also, the observation equations are constrained with the results of the crossover analysis; the parameter estimations are performed at 0.1° latitude intervals by the least squares. Cycle 10 to 330 T/P altimeter data covering the China Sea and the Northwest Pacific Ocean （2°-50° N,105°-150° E） are adopted for a refined along-track harmonic tidal analysis, and harmonic constants of 12 constituents in 8 474 points are obtained, which indicates that the algorithm can efficiently remove non-tidal effects in the altimeter observations, and improve the precision of tide parameters. Moreover, parameters along altimetry tracks represent a smoother distribution than those obtained by traditional algorithms. The root mean squares of the fitting errors between the tidal height model and the observations reduce from 11 cm to 1.3 cm.  相似文献