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81.
INTRODUCTIONThetoxicityofheavymetalsreleasedintotheenvironmenthasrecentlytriggeredanumberofstudiesaimingattheremovalofmetalionsfromaqueoussolutions (FourestandVolesky ,1 997;FehrmannandPohl,1 993 ;KuyucakandVolesky,1 989) .Itwasfoundthattheaccumulationofheavymeta… 相似文献
82.
The sorption of AuCl4
−,AuCl2
− and Au(S2O3)3- on δ-MnO2 was investigated at pH2–11.6, 0.01 mol/L and 0.1 mol/L NaNO3 solutions. At pH 4 in two electrolyte strength solutions, Au sorption densities on δ-MnO2 are 0.18–0.21 and 0.28μmoL/m2 for AuCl4
− and Au(S2O3)2
3-, respectively, and the Au surface coverage is approximate to or lower than 1%. This adsorption of the two Au complexes decreases
as the solution pH increases, which conforms to the sorption regularity of the anion on δ-MnO2. The Au sorption decreases in the sequence of Au(S2O3)2
3- >AuCl4
− >AuC12
−. The intrinsic equilibrium constants (logK
int) of the three Au complexes are 1.17–2.7, much higher than those of Cu and Cd. The hydrolysis products of AuCl4
- are preferentially adsorbed by δ-MnO2 and the inner-sphere Au-surface complexes are formed on the surface.
Project supported by the National Studying-abroad Foundation, the National Natural Science Foundation of China (Grant No.
49573200) and the Australian Mining Industry. 相似文献
83.
Role of coal type and rank on methane sorption characteristics of Bowen Basin, Australia coals 总被引:5,自引:0,他引:5
The effect of coal composition, particularly the organic fraction, upon gas sorption has been investigated for Bowen Basin and Sydney Basin, Australia coals. Maceral composition influences on gas retention and release were investigated using isorank pairs of hand-picked bright and dull coal in the rank range of high volatile bituminous (0.78% Ro max) to anthracite (3.01% Ro max). Adsorption isotherm results of dry coals indicated that Langmuir volume (VL) for bright and dull coal types followed discrete, second-order polynomial trends with increasing rank. Bright coals had a minimum VL at 1.72% Ro max and dull coals had a minimum VL at 1.17% Ro max. At low rank, VL was greater in bright coal by about 10 cm3/g, but as rank increased, the bright and dull trends converged and crossed at 1.65% Ro max. At ranks higher than 1.65% Ro max, both bright and dull coals followed similar trends. These competing trends mean that the importance of maceral composition on VL varies according to rank. In high volatile bituminous coals, increases in vitrinite content are associated with increases in adsorption capacity. At ranks higher than medium to low volatile bituminous, changes in maceral composition may exert relatively little influence on adsorption capacity. The Langmuir pressure (PL) showed a strong relationship of decreasing PL with increasing rank, which was not related to coal type. It is suggested that the observed trend is related to a decrease in the heterogeneity of the pore surfaces, and subsequent increased coverage by the adsorbate, as coal rank increases. Desorption rate studies on crushed samples show that dull coals desorb more rapidly than bright coals and that desorption rate is also a function of rank. Coals of lower rank have higher effective diffusivities. Mineral matter was found to have no influence on desorption rate of these finely crushed samples. The evolution of the coal pore structure with changing rank is implicated in diffusion rate differences. 相似文献
84.
活性炭从硫脲浸出液中回收金的工艺研究 总被引:6,自引:0,他引:6
本文研究了在酸性硫脲浸出液中活性炭回收金的工艺过程,实验表明,在该浸出液中活性炭对金具有较高的吸附速度、吸附率和吸附容量并易于解吸,为工业应用提供了可靠的技术依据。 相似文献
85.
研究了二异氰酸酯与壳聚糖的交联反应,其产物与壳聚糖相比,酸溶解度由82.04%降到58.08%。DSC曲线表明,交联产物的热稳定性明显提高,对低价重金属离子(Hg 相似文献
86.
Li Xuqian 《吉林大学学报(地球科学版)》1989,(4)
土壤对重金属离子的吸附容量严格受H~+浓度的控制。本文通过试验探讨了H~+ 对Cu~(2+)——Pb~(2+),Cn~(2+)——Zu~(2+),Cu~(2+)——Hg~(2+)系统中Cu~(2+)吸附量的影响规律。当pHpH时,Cu~(2+)吸附量随pH值增大而减小。对于酸性土,pH=6.5(初始值)或7.0(平衡值),对碱性土,pH=5.5(初始值)或7.8(平衡值)。在pHpH_(ZPC)时,吸附模式具有完全不同的形式。 相似文献
87.
Renaud Denoyel 《Comptes Rendus Geoscience》2002,334(9):689-702
The applications of calorimetric and ellipsometric methods to the understanding of adsorption phenomena occurring at the solid–liquid interface are presented with examples in the field of surfactant adsorption. The various experimental approaches are presented and compared, i.e., immersion calorimetry, titration calorimetry and liquid flow calorimetry. It is shown how they can be used to follow, in situ, the building steps of the surfactant adsorbed layer. On the other hand, ellipsometry allows the adsorption isotherm, the adsorption kinetics as well as the thickness of the adsorbed layer to be determined on well-defined flat surfaces. To cite this article: R. Denoyel, C. R. Geoscience 334 (2002) 689–702. 相似文献
88.
传统认为中国南方的离子吸附型稀土矿床可划分为以“足洞式”为代表的重稀土型和以“河岭式”(或“花山式”)为代表的轻稀土型两种矿化类型。然而,近年来发现的许多矿床(如清溪、寨背和馒头山等)的赋矿风化壳中出现了轻稀土矿与重稀土矿并存现象,表现出特殊的“上轻下重”双层矿体结构。这指示了除重稀土型和轻稀土型之外,还存在着轻重稀土共生型的过渡类型。本研究通过对三种不同成矿类型的若干典型矿床系统对比,指出成矿类型的多样性与母岩性质密切相关,尤其是母岩的稀土元素地球化学和稀土载体矿物属性是制约成矿类型变化的关键因素。统计数据表明,从重稀土型→轻重稀土共生型→轻稀土型,成矿母岩的全岩稀土总量变化不大(ΣREY: 200×10-6~450×10-6→200×10-6~500×10-6→200×10-6~800×10-6),但轻重稀土配分值出现较显著的区间性差异(ΣLREE/ΣHREY: 02~1→1~5→2~10)。与之同时,母岩中能为离子相稀土提供物源且具有重稀土配分属性的稀土副矿物类型和数量明显减少,这与全岩稀土元素地球化学特征中重稀土分量占比的降低趋势也互相匹配。该结果指示,以往认为重稀土配分母岩形成重稀土矿床、轻稀土配分母岩形成轻稀土矿床的传统观点需要外延,即一部分具有低度轻稀土配分属性(1<ΣLREE/ΣHREY<5)且含有丰富易风化稀土副矿物的母岩还可能形成轻重稀土共生型矿床,该认识可为今后离子吸附型稀土矿床勘查工作提供新的找矿依据。 相似文献
89.
90.