夏季洪水对长江口及邻近海域颗粒有机碳分布与来源的影响          下载免费PDF全文

罗颖  金海燕  李德望  季仲强  王斌  杨志  张扬  庄燕培  李杨杰  陈建芳  郑侦明 《海洋学研究》2021,39(4):73-81

基于2020年7月洪水期间采集的长江口及邻近海域的温度、盐度、总悬浮物(Total Suspended Matter,TSM)质量浓度、颗粒有机碳(Particulate Organic Carbon,POC)质量浓度和颗粒有机碳稳定同位素(δ13CPOC)等数据,分析了洪水事件对该区域POC分布与来源的影响。结果显示,研究区域内POC和盐度呈显著负相关(r2=0.41,p＜0.01),与TSM呈显著正相关(r2=0.92,p＜0.01),表明咸淡水的混合是影响POC分布的重要因素。研究区域东北部表层海水POC质量浓度局部升高,并且δ13CPOC值显示为海源信号,表明浮游植物生产是影响该海域POC分布的另一重要因素。此外,由于高径流量形成的稀释效应,洪水事件会降低陆源输入的POC质量浓度,研究区域东南侧偏轻的δ13CPOC也表明,洪水事件会扩大陆源POC在东海的影响范围。  相似文献   

重庆市青木关地下河水化学及其δ¹³C DIC变化特征   总被引：1，自引：0，他引：1  

邱述兰  蒋勇军  张兴波  曹敏  胡毅军  廖文娥 《中国岩溶》2012,31(3):279-288

为了确定地下水中溶解无机碳和地下水中物质的来源,于2010年4月至2011年1月对重庆市青木关地下河流域系统进行了连续监测,分析其常规水化学组成、溶解无机碳含量及其同位素(δ13CDIC)组成变化特征及影响因素,2010年农耕期间(5-6月)又对部分观测点进行了加密取样分析.分析结果表明:(1)地下河水为HCO3-Ca型,其变化受水岩作用和降水作用的影响;(2)地下水中(Ca2++ Mg2+)/HCO3-的摩尔比值为0.6～0.72,平均为0.67,表明碳酸盐岩溶解受C3植被下土壤CO2、HNO3和H2SO4的共同作用的影响;(3)地下河水中由碳酸溶解碳酸盐岩产生的[HCO3-]的贡献率为56.16％～81.25％,平均为66.96％,硝酸和硫酸溶解碳酸盐岩产生的[HCO3-]的贡献率为18.75 ％～43.84％,平均为33.04％;(4)青木关地下河出口地下水的δ13 CDIC变化范围为-8.17‰～-13.68‰,平均值为-10.53 ‰.农耕期和枯水期地下河水的δ13 CDIC平均值分别为-9.25‰ 和-12.29‰,农耕期较枯水期偏正,偏正幅度达3‰,表明人类农业活动物质输入对地下河水δ13 CDIC有较大的影响.  相似文献   

Changes to depositional palaeoenvironments within the Qikou depression (Bohaiwan Basin,China): carbon and oxygen isotopes in lacustrine carbonates of the Palaeogene Shahejie Formation     

《International Geology Review》2012,54(15):1909-1921

This paper reports the carbon and oxygen isotope compositions of lacustrine carbonate sediments from the Palaeogene Shahejie Formation, Qikou depression, Bohaiwan Basin, with the aim of determining the palaeoenvironmental conditions in the region. Results from Es₂, the second member of the Shahejie Formation, showed values of δ¹³C and δ¹⁸O from –1.2‰ to +2.4‰ (average +0.6‰) and from –6.8‰ to –4.7‰ (average –5.7‰), respectively, suggesting a relatively hot climate attending deposition. The slightly closed nature of the lake, which contains brackish water, resulted in higher carbonate δ¹³C and δ¹⁸O values than in a meteoric environment. The values of δ¹³C and δ¹⁸O preserved within the carbonates of the overlying lower Shahejie I (Es₁) varied between +1.3‰ and +4.9‰ (average +3.2‰) and from ?4.4‰ to ?1.8‰ (average ?3.1‰), respectively, indicating that the climate became colder at that time. Subsequently, a marine transgression caused the salinity of the lake water to increase. The values of δ¹³C and δ¹⁸O were controlled by salinity. The high δ¹³C values were also influenced by the rapid burial of the lake organisms and by algal photosynthesis. Values of δ¹³C and δ¹⁸O from carbonates in upper Es₁ ranged from ?8.0‰ to +11.0‰ (average +10.1‰) and from ?5.0‰ to ?1.5‰ (average ?3.4‰), respectively, indicating a slight increase in the temperature over time. In the closed and reducing environment, extremes in δ¹³C values resulted from biochemical fermentation. The positive δ¹³C excursion recorded in the carbonates of the Shahejie Formation in the Qikou depression indicates that the palaeoclimate underwent a significant transformation during the Eocene and the Oligocene.  相似文献   

重庆北温泉地热水碳硫同位素特征研究   总被引：3，自引：1，他引：2       下载免费PDF全文

肖琼  沈立成  杨雷  伍坤宇  王鹏 《水文地质工程地质》2013,40(4):127-133

重庆市北碚区北温泉景区分布有多处自然出露温泉点,选取其中流量大于2000m3/d的北温泉(BWQ)和水文站(SWZ)两处泉点进行监测,结果显示:泉水水化学类型为SO4-Ca型,pH呈中性,其阳离子主要为Ca2+和Mg2+,阴离子主要为SO42-和HCO3-,阳离子当量变化范围为31.74～40.12 meq/L,阴离子当量变化范围为29.05 ～35.08meq/L.温泉水中δ13CHCO3-的值为-4.84‰ ～-9.73‰,计算得出CO2的δ13CCO2值集中在-11.91‰～-16.81‰之间,其参与水-岩反应的CO2为幔源和土壤混合成因.δ34SSO42-值为30.29‰～32.19‰,与四川盆地下三叠统嘉陵江组石膏中的δ34SSO2-值(28.3‰ ～ 35.4‰)一致.联系温泉水中阴阳离子含量、δ34SSO42-值与δ13CHCO3-的值认为地表雨水补给进入的是下三叠统嘉陵江组碳酸盐岩地层,发生水-岩反应且水-岩反应主要为石膏的溶解,其次是CO2进入储水层与围岩发生水化学作用生成HCO3-.  相似文献   

琼东南盆地崖13-1气田陵三段沉积微相对储层非均质性及流动单元划分的影响   总被引：6，自引：2，他引：4       下载免费PDF全文

李胜利  于兴河  姜平  李茂  李茂文  晋剑利  黄国政  黄月银 《地学前缘》2010,17(4):160

崖13-1气田陵三段是河控与潮控的辫状三角洲,主要储层沉积微相为分流河道、水下分流河道、河口坝、远砂坝及席状砂,其中河口坝的储层物性比分流河道和水下分流河道微相好,席状砂与远砂坝的物性相对较差,而各类正韵律河道与反韵律的砂坝决定了各垂向流动单元储层韵律特征。气田内的隔夹层与不同规模的海泛面相关,隔层以前三角洲泥为主,分布稳定,而夹层以分流间湾与水下分流间湾泥为主,分布较局限。结合沉积微相分布、储层非均质性及断层的分布,可以把气田区分为两个大区及6个流动单元,而南II、南III区仍可有较好的储层,但由于构造上处于低部位,含气前景还需进一步论证。  相似文献   

四川宁南银厂沟震旦-寒武纪交变期碳、氧同位素地球化学特征     

李雁龙  钟长洪  马比阿伟  刘炳璋 《四川地质学报》2010,30(1):82-85

扬子地台西缘攀西地区,晚震旦世-早寒武世为一套连续沉积碳酸盐岩,众多科研文献中时代地层、岩性地层和生物地层的划分各异。在此交变期及其近前后,随之发生诸多地质事件,成为地学研究的热点之一。于宁南等四幅1：5万区调工作中,实测灯影组麦地坪段地层剖面,采集新鲜岩样,测试碳、氧同位素,试从稳定同位素地球化学角度阐述其指示意义,提供研究震旦一寒武纪交变期的地球化学资料。  相似文献   

Latitudinal and downcore (0–750 ka) changes in n-alkane chain lengths in the eastern equatorial Pacific     

Keiji Horikawa  Masafumi Murayama  Masao Minagawa  Yoshihisa Kato  Takuya Sagawa 《Quaternary Research》2010,73(3):573-582

The n-alkane C₃₁/(C₂₉ + C₃₁) ratios from surface sediments in the eastern equatorial Pacific (EEP) exhibit higher values to the north and lower values to the south across the southern edge (2–4°N) of the Intertropical Convergence Zone (ITCZ). Since plants tend to synthesize longer chain length n-alkanes in response to elevated temperature and/or aridity, the higher C₃₁/(C₂₉ + C₃₁) ratios at northern sites suggest a higher contribution of vegetation under hot and/or dry conditions. This is consistent with the observation that northern sites receive higher levels of plant waxes transported by northeasterly trade winds from northern South America, where hot and dry conditions prevail. Furthermore, from a sediment core covering the past 750 ka (core HY04; 4°N, 95°W) we found that C₃₁/(C₂₉ + C₃₁) ratios exhibit a long-term decrease from MIS (marine oxygen isotope stage) 17 to 13. During this period, the zonal SST (sea-surface temperature) gradient in the equatorial Pacific increased, suggesting an increase in Walker circulation. Such intensified Walker circulation may have enhanced moisture advection from the equatorial Atlantic warm pool to the adjacent northern South America, causing arid regions in northern South America to contract, which may explain long-term decrease in n-alkane chain lengths.  相似文献   

Origins and maturity of organic matter in mid-Cretaceous black shales from ODP Site 1138 on the Kerguelen Plateau     

Philip A. Meyers  Jong-Gwon Yum  Sherwood W. Wise 《Marine and Petroleum Geology》2009

We have conducted elemental, isotopic, and Rock-Eval analyses of Cenomanian–Santonian sediment samples from ODP Site 1138 in the southern Indian Ocean to assess the origin and thermal maturity of organic matter in mid-Cretaceous black shales found at this high-latitude location. Total organic carbon (TOC) concentrations range between 1 and 20 wt% in black to medium-gray sediments deposited around the Cenomanian–Turonian boundary. Results of Rock-Eval pyrolysis indicate that the organic matter is algal Type II material that has experienced modest alteration. Important contributions of nitrogen-fixing bacteria to the amplified production of organic matter implied by the high TOC concentrations is recorded in δ¹⁵N values between −5 and 1‰, and the existence of a near-surface intensified oxygen minimum zone that favored organic carbon preservation is implied by TOC/TN ratios between 20 and 40. In contrast to the marine nature of the organic matter in the Cenomanian–Turonian boundary section, deeper sediments at Site 1138 contain evidence of contributions land-derived organic matter that implies the former presence of forests on the Kerguelen Plateau until the earliest Cenomanian.  相似文献   

GPS-RTK技术在抢险测量中的应用     

谢长淮 《测绘与空间地理信息》2008,31(2):55-56

GPS动态技术以其测量精度高、速度快等优势在地形测量中获得了广泛的应用。介绍了GPS实时动态测量系统的工作原理及其在长江抢险测量中的应用情况。实践证明,GPS技术大大地提高了水下地形测量的自动化程度和工作效率,降低了劳动成本,创造了良好的经济效益和社会效益。  相似文献   

用¹³C-NMR光谱法研究几种红藻含硫半乳聚糖的结构特征   总被引：1，自引：1，他引：1  

纪明侯  高洪峰  曹文达  范晓 《海洋与湖沼》1996,27(3):330-335

于１９８９年８月对采自青岛地区的５种红藻用冷水和热水分步提取或直接加热提取方法制备含硫半乳聚糖，对其多糖进行的＾１３Ｃ－光谱分析结果表明，扁江蓠多糖主要由琼胶糖和６－硫酸基－琼胶糖组分构成，海萝和多管藻多糖主要由６－硫酸基－琼胶糖组成，并含微量琼胶糖前体，６－ＯＣＨ３－琼胶糖组分，此两种藻的热水提取物中还含有微量２－ＯＣＨ３－琼胶糖，三叉仙菜的热水提取多糖主要由琼胶糖的前体组成；从海膜多糖谱图的信  相似文献