A clinoenstatite-bearing cumulate Olivine Pyroxenite from Howqua,Victoria     

Anthony J. Crawford 《Contributions to Mineralogy and Petrology》1981,75(4):353-367

The Howqua Olivine Pyroxenite of eastern Victoria, Australia, intrudes a metamorphosed sequence of Cambrian high-Mg lavas. It crystallized an unusual mineral assemblage: Cr-rich magnesiochromite, olivine (Fo₉₄), and protoenstatite (now inverted to polysynthetically-twinned clinoenstatite). Residual liquid crystallized strongly-zoned interstitial pyroxenes followed by pargasite. Pargasite, often showing quench habit, crystallized in interstitial glass which is now altered to serpentine.The extremely refractory nature of the cumulus phases indicates a very high temperature of crystallization for liquidus olivine and chromite from a high-MgO, low-Al₂O₃ parent liquid similar in some respects to Archaean peridotitic komatiites. The suggested origin by hydrous melting of depleted mantle peridotite, plus other compositional and mineralogical similarities (especially the olivine-liquid reaction producing protoenstatite) indicate that the parent magma of the Howqua Olivine Pyroxenite had many features in common with the high-SiO₂, high-MgO clinoenstatite-bearing boninitic lavas of the Western Pacific. It is interpreted as a more extreme melt with affinities to boninite and it demonstrates that ultramafic magmas existed in the Cambrian.  相似文献   

Subsolidus and melting relationships for calcite,magnesite and the join CaCO₃-MgCO₃ 36 kb     

Anthony J Irving  Peter J Wyllie 《Geochimica et cosmochimica acta》1975,39(1):35-53

Subsolidus and melting relations for the CaCO₃-MgCO₃ join at 30 kb have been determined using piston-cylinder apparatus. Data are also presented for the melting curve of CaCO₃ to 30 kb, the decomposition and melting curves of MgCO₃ to 36 kb, and the calcite-aragonite transition at 800°C, 950°C and 1100°C. At 30kb, the melting loop for the CaCO₃-MgCO₃ join extends from 1610°C (CaCO₃) to 1585°C (MgCO₃) through a liquidus minimum at 1290°C (near 42 mole% MgCO₃). The dolomite-magnesite solvus barely intersects the 30 kb melting loop to produce a peritectic reaction at 1385°C. Integration of the new experimental data with other published data permits construction of a complete P-T projection and a sequence of isobars for the CaCO₃-MgCO₃ join for pressures between 5 and 30 kb. The phase relations for this join provide part of the essential framework of the model peridotite system CaO-MgO-SiO₈-CO₂-H₂O, which has particular application to the origin of carbonatitic and kimberlitic magmas. In light of the accumulating evidence for CO₂ in various forms within the upper mantle and of its effect on magmatic processes, analysis of the melting relations in this system is of considerable importance.  相似文献   

Effect of freezing and thawing on the permeability and structure of soils   总被引：17，自引：0，他引：17  

Edwin J. Chamberlain  Anthony J. Gow 《Engineering Geology》1979,13(1-4):73-92

The permeability and structure of four fine-grained soils were observed to be changed by freezing and thawing. In all cases freezing and thawing caused a reduction in void ratio and an increase in vertical permeability. The increase in permeability is attributed to the formation of polygonal shrinkage cracks and/or to the reduction of the volume of fines in the pores of the coarse fraction, the mechanism controlling the process depending on material type. No definite relationships are established; however, it appears that the largest increase in permeability occurs for the soil of highest plasticity.  相似文献   

Characterization of the chemical structures of natural and synthetic aluminosilicate gels and sols by infrared spectroscopy     

Victor C. Farmer  Anthony R. Fraser  J.Mervyn Tait 《Geochimica et cosmochimica acta》1979,43(9):1417-1420

Infrared spectra in the 300–1400 cm^?1 region indicate that the non-crystalline products of interaction between hydroxyaluminium species and orthosilicic acid in dilute aqueous solutions of pH < 5 differ markedly in structure from those formed in near-neutral and alkaline solutions of pH > 6. The compound formed in acid solution has an infrared spectrum similar to imogolite, and is termed proto-imogolite; like imogolite, it contains orthosilicate groups and 6-coordinated aluminium, and has an ideal Si:Al ratio of around 0.5, but it can incorporate some excess alumina or silica and it does not have the regular tubular structure of imogolite. Compounds formed in alkaline solutions that are not too dilute have infrared spectra resembling the feldspathoid group of minerals and are termed hydrous feldspathoids. They incorporate a condensed tetrahedral framework with an Si:Al ratio greater than one, but can also contain 6-coordinated aluminium.Natural allophanes of the proto-imogolite and hydrous feldspathoid types exist. The allophane of weathered pumice, however, contains a condensed silicate anion that incorporates little tetrahedral aluminium. Proto-imogolite forms stable sols at pH < 5 and must play an important role in the transport of aluminium in acidic natural waters containing dissolved silica.  相似文献   

Seismic motion and response prediction alternatives     

C. Allin Cornell  Hooshang Banon  Anthony F. Shakal 《地震工程与结构动力学》1979,7(4):295-315

Statistical methods are available which predict the maximum response of simple oscillators given the peak acceleration (A_p), peak velocity (V_p) or peak displacement (D_p) of seismic ground motions. An alternative parameter, namely an ordinate (or ordinates) of the Fourier amplitude spectrum of ground motion acceleration, FS(f), may in fact be a preferred predictor of peak response, especially in a frequency range close to f. Other statistical methods (attenuation laws) use distance R and other parameters such as magnitude (M), Modified Mercalli epicentral Intensity (I_o) and Modified Mercalli site Intensity (MMI or I_s) to predict spectral velocity (S_v(f)), etc. In using such approaches, it is most desirable to know the total uncertainty in the predicted peak response of the system given the starting parameter values. An extensive strong motion data set is used to study these questions, The most direct prediction models are found to be preferable (have lower prediction dispersion) but data may not be available in all regions to permit their use.  相似文献   

Model Simulations on the Variability of Particulate MSA to Non-Sea-Salt Sulfate Ratio in the Marine Environment     

Veli-Matti Kerminen  Risto E. Hillamo  Anthony S. Wexler 《Journal of Atmospheric Chemistry》1998,30(3):345-370

A box model was constructed to investigate connections between the particulate MSA to non-sea-salt sulfate ratio, R, and DMS chemistry in a clean marine boundary layer. The simulations demonstrated that R varies widely with particle size, which must be taken into account when interpreting field measurements or comparing them with each other. In addition to DMS gas-phase chemistry, R in the submicron size range was shown to be sensitive to the factors dictating sulfate production via cloud processing, to the removal of SO₂ from the boundary layer by dry deposition and sea-salt oxidation, to the entrainment of SO₂ from the free troposphere, to the relative concentration of sub- and supermicron particles, and to meteorology. Three potential explanations for the increase of R toward high-latitudes during the summer were found: larger MSA yields from DMS oxidation at high latitudes, larger DMSO yields from DMS oxidation followed by the conversion of DMSO to MSA at high latitudes, or lower ambient H₂O₂ concentrations at high latitudes leading to less efficient sulfate production in clouds. Possible reasons for the large seasonal amplitude of R at mid and high latitudes include seasonal changes in the partitioning of DMS oxidation to the OH and NO₃ initiated pathways, seasonal changes in the concentration of species participating the DMS-OH reaction pathway, or the existence of a SO₂ source other than DMS oxidation in the marine boundary layer. Even small anthropogenic perturbations were shown to have a potential to alter the MSA to non-sea-salt sulfate ratio.  相似文献   

Second order elasticity theory: An improved formulation of the Grüneisen parameter at high pressure     

Anthony J. Falzone  Frank D. Stacey 《Physics of the Earth and Planetary Interiors》1981,24(4):284-290

The second order theory of elasticity, in which terms to second order in strain are retained in calculating atomic bond length changes and elastic moduli, is extended to describe thermal vibration of a face-centred cubic crystal. Coupled with equations relating the pressure dependences of elastic constants, this yields a new formulation of the thermal Grüneisen parameter γ in terms of pressure P, incompressibility K and rigidity, μ where f = 24 (3 K ? 2 P)/(3 K + 115 μ + 90 P). The factor f arises from bond interactions and the case f = 1, representing independent bonds (no interactions), yields the free-volume γ- Since we have shown earlier that the second order elasticity theory provides a convincing explanation of the elasticity of the inner core, we believe that the new formula is appropriate for the inner core. It is, however, inadequate to describe the lower mantle γ, in which atomic bond angle rigidity, not considered here, may be appreciable.  相似文献   

Mineralogy and petrogenesis of lunar magnesian granulitic meteorite Northwest Africa 5744          下载免费PDF全文

Jeremy J. Kent  Alan D. Brandon  Katherine H. Joy  Anne H. Peslier  Thomas J. Lapen  Anthony J. Irving  Daniel M. Coleff 《Meteoritics & planetary science》2017,52(9):1916-1940

Lunar meteorite Northwest Africa (NWA) 5744 is a granulitic breccia with an anorthositic troctolite composition that may represent a distinct crustal lithology not previously described. This meteorite is the namesake and first‐discovered stone of its pairing group. Bulk rock major element abundances show the greatest affinity to Mg‐suite rocks, yet trace element abundances are more consistent with those of ferroan anorthosites. The relatively low abundances of incompatible trace elements (including K, P, Th, U, and rare earth elements) in NWA 5744 could indicate derivation from a highlands crustal lithology or mixture of lithologies that are distinct from the Procellarum KREEP terrane on the lunar nearside. Impact‐related thermal and shock metamorphism of NWA 5744 was intense enough to recrystallize mafic minerals in the matrix, but not intense enough to chemically equilibrate the constituent minerals. Thus, we infer that NWA 5744 was likely metamorphosed near the lunar surface, either as a lithic component within an impact melt sheet or from impact‐induced shock.  相似文献   

Environmental limitations on recruitment from seed in invasive Spartina densiflora on a southern European salt marsh     

Enrique Mateos-Naranjo  Susana Redondo-Gmez  Carlos J. Luque  Eloy M. Castellanos  Anthony J. Davy  M. Enrique Figueroa 《Estuarine, Coastal and Shelf Science》2008,79(4):727-732

The South American cordgrass, Spartina densiflora, has invaded a range of different habitats that can support different native species assemblages on salt marshes in the Gulf of Cadiz, Spain. Little is known about the mechanisms of invasion. We examined the potential for seed germination and recruitment in a field transplant experiment, representing a wide range of environments, on elevational gradients across marshes with muddy and sandy sediments. The biotic resistance of native, perennial vegetation (where present) to recruitment of the alien was also investigated. Spartina densiflora seeds were able to germinate over a greater than 2-m range of elevation in the tidal frame. Germination success on unvegetated muddy sediments was related to sediment redox potential, with poor germination at strongly negative redox potentials on the lower sites. On sandy, well-drained sediments, germination was apparently constrained by water availability at the highest elevations. Comparison of vegetated and cleared plots on the upper marsh showed that there was a negative relationship between the presence of Atriplex portulacoides and germination on the muddy sediments. Recruitment (survival of seedlings for 12 weeks) was seen only on unvegetated muddy sediments at the highest elevation. Hence the invasive success and wide elevational tolerance of S. densiflora on the marshes of the Gulf of Cadiz are not reflected in its short-term ability to become established from its prolific seed production. Colonization of sub-optimal habitats may be largely by vegetative propagules and clonal growth.  相似文献   

OPA 90's impact at reducing oil spills     

Anthony C. Homan  Todd Steiner   《Marine Policy》2008,32(4):711-718

OPA 90 set out stringent requirements and liabilities for tankers operating in US national waters. OPA 90 was in response to the public concern caused by the grounding of the Exxon Valdez in 1989. It made ship owners responsible for the cost of pollution incidents and required all tank ships/barges operating in US waters have double hulls by 2015. We model factors influencing oil spills and test whether OPA 90 helped reduce the number of those spills. After accounting for causal factors, both increased liability and double hulls were statistically significant factors in reducing the number of spills.  相似文献