Treatment of arsenic rich waters by the HDS process     

Matthew Dey  Keith Williams  Richard Coulton 《Journal of Geochemical Exploration》2009,100(2-3):160-162

Arsenic contaminated waters are not uncommon; indeed from naturally occurring contaminated waters through to those that are a direct consequence of human activities such as mining, all are affecting the quality of water resources worldwide. The ever increasing demands on natural water resources mean that the effective control of this toxic contaminant is paramount and this is reflected in the ever increasing global legislation.There are currently three mechanisms by which arsenic is commercially treated in effluents. These are physical separation processes such as reverse osmosis, precipitation/adsorption processes, some of which are bacterially assisted, and a whole variety of ion exchange processes, again with some bacterial enhancement. The choice of treatment is not only driven by cost but by the chemistry of the water and the water quality standard to be met.In this study a very high arsenic enriched groundwater, containing in excess of 25,000 µg/L arsenic, was treated by a typical treatment method through a continuously operated pilot plant. In the treatment, iron III salts were added to the influent in order to form precipitates with the arsenic and to form an adsorptive surface that would assist with treatment of the enriched water. This addition of iron III salts for the removal of arsenic is common practice in the water treatment industry as the resulting iron III arsenates are highly stable.However, results from the pilot plant show that the process was further enhanced by the addition of small amounts of hydrogen peroxide. Hydrogen peroxide is a powerful oxidising reagent and assists in ensuring the complete conversion of any arsenic III to arsenic V that was then effectively removed in the pilot plant. After treatment residual arsenic levels of 10 µg/L were obtained compared to 68 µg/L without oxidation reagent addition.  相似文献   

Spatial-temporal Variations of H2 Concentration in Soil Gas in the Seismic Fault Zone Produced by the Wenchuan MS 8.0 Earthquake     

Zhou Xiaocheng  Shi Hongyu  Chen Chao  Zeng Linghua  Sun Fengxia  Li Jing  Chen Zhi  Lü  Chaojia  Huang Dan  Du Jianguo 《地球科学进展》2017,32(8):818-827

Degassing of Hydrogen (H₂) from fault may be a good indicator of fault activity. The concentration of H₂ in soil gas in the seismic surface rupture zone produced by the Wenchuan M_S 8.0 earthquake was investigated in twenty three measuring regions in order to explore the relationship between the spatio-temporal variations of H₂ concentration in soil gas along the seismic rupture zone and the vertical displacements and aftershocks activities. The results indicated: ① the sources of H₂ were directly related to from the release of natural gas reservoirs; ②the average concentration of H₂ in soil gas spatially decreased from Yingxiu to Nanba; ③the magnitudes of the H₂ concentration anomalies declined significantly with time. It is very significant to study the variation tendency of atmospheric environment with further research of degassing of H₂ from faults.  相似文献   

Changes of Paleo-precipitation on the Sunda Shelf Since the Last Glacial Maximum Revealed by Hydrogen and Oxygen Isotopes     

Juan He 《地球科学进展》2017,32(11):1137-1146

The Sunda Shelf, owing to its unique geographical location and roles, has attracted much attention on its changes during the glacial cycle. At present, there is a consensus about the change of temperature in the region, but the reconstruction of paleo precipitation has been disputed. The hydrogen and oxygen isotope records since the last glacial in the Sunda Shelf were collected, combining with other paleo climate record, we roughly divided the precipitation records in the region into the Northern and Southern areas. During the glacial, the precipitation changed little and climate remained moist in the northern area, while precipitation decreased greatly,and the climate became dry in the southern. Difference in the precipitation isotopes between the northern and southern areas might be related to the different controlling factors of the precipitation isotopes in the two areas and large-scale atmospheric circulation in the region. Limited by the collected hydrogen and oxygen records, the precise mechanism of division in regional hydrological changes of the region still needs more work to confirm.  相似文献   

鞍山-海城地区地震地下水地球化学研究     

仵柯田  崔月菊  孙凤霞  杜建国 《中国地震》2019,35(4):629-642

通过测量辽宁省鞍山-海城地区地震重点监测区地下水离子浓度和氢、氧同位素组成,讨论了该区地下水化学类型的时空变化及其成因。测量结果表明,取样点水温变化范围为11.0～97.0℃,水样的总固溶物（TDS）在197.89～829.99mg/L之间,水样分为8种化学类型。大部分水样的δD、δ¹⁸O值均沿中国东北地区大气降水线分布,少数有所偏离,表明该区的地下水主要接受大气降水的补给,并可能有深部水的供给。研究区Ca-HCO₃和Ca·Mg-HCO₃型水主要是岩石风化溶解和阳离子交换作用的结果;Ca-HCO₃·Cl和Ca·Na-Cl·SO₄型水主要受岩石风化溶解、阳离子交换作用、深部卤水混入或人类活动影响;Ca-HCO₃·SO₄和Ca-SO₄·HCO₃型水与岩石风化溶解以及深部流体混入有关;Na-SO₄·HCO₃和Na-HCO₃·SO₄型水主要是深部来源水体的混入造成的。采样期间研究区发生2次M_L≥3.0地震,采样点在地震发生月份出现了明显的离子浓度异常变化;Na⁺、Mg²⁺、Ca²⁺、Cl^-和SO₄^2-浓度变化明显,对地震活动响应较灵敏。  相似文献   

The Impact of Human Activities on Freshwater Aquatic Systems     

Yu. I. Skurlatov  L. S. Ernestova 《洁净——土壤、空气、水》1998,26(1):5-12

The roles of oxygen and its activated species (superoxide radicals, hydrogen peroxide, hydroxyl radicals), as well as that of sulfur compounds, are considered in relation to biological quality and the self-cleaning capacity of freshwater aquatic systems. The effects on the aquatic redox-processes are discussed in terms of atmospheric fallout of sulfur compounds, bottom sediment composition, and input of wastewaters containing reducing substances. It is shown that the totality of anthropogenic influences, and/or unfavourable natural geochemical conditions, as well as climatic effects in a region can increase the significance of one-electron transfer processes in bio-geochemical cycles of oxygen, sulfur and manganese, compared with the significance of two-electron transfer processes. The resulting, reactive intermediate products of one-electron transfer processes are very important with respect to the composition and properties of aquatic systems. Examples are given of practical applications of wastewater treatment, using hydrogen peroxide and UV-irradiation, and of regulation of consumers’ activities which affect natural waters.  相似文献   

Origin and distribution of hydrogen sulfide in the Yuanba gas field,Sichuan Basin,Southwest China     

《Marine and Petroleum Geology》2016

The Yuanba gas field in the Permian Changxing Formation (P₂c), which exhibits wide variations in its hydrogen sulfide (H₂S) concentration (1.20–12.16%), is a typical sour gas field in the northern Sichuan Basin. The sulfur-rich reservoir's solid bitumen (atomic S/C ratios are 0.032–0.142), and late calcite cement δ¹³C values, which are smaller than the δ¹³C values of the host dolostone, indicate that the H₂S originated from thermal sulfate reduction (TSR) and oil was involved in TSR. The gas souring index (GSI) of P₂c's gases is generally lower than 0.1. The ethane δ¹³C values increase as the GSI increases, although no obvious increase was observed in the methane δ¹³C values. The calcite cements' δ¹³C values (−15.36 to +4.56‰) in dolostone are heavier than the typical reported values, which implies that only limited heavy hydrocarbon gases were involved in TSR. No anhydrites developed in P₂c's reservoirs, and dissolved sulfate anions (SO₄²⁻) were mainly enriched during dolomitization. Insufficient dissolved SO₄²⁻ most likely caused the lower H₂S concentrations in the Permian to Triassic reservoirs in the northeastern Sichuan Basin compared to the Permian Khuff Formation in Saudi Arabia and the Jurassic Smackover Formation in Mississippi. Except for the SO₄²⁻ in residual water in paleo-oil zones, SO₄²⁻ from bottom water may also be involved in TSR; therefore, oil reservoirs with bottom water have more SO₄²⁻ and can produce more H₂S than pure oil reservoirs. This phenomenon may be the main cause of the great difference in the H₂S concentrations between reservoirs, while gravitational differentiation during late uplift most likely creates differences in H₂S concentrations in a single reservoir. Carbon dioxide (CO₂), which has a relatively heavy δ¹³C value (−3.9 to −0.3‰), may be the combined result of TSR, the balance between CO₂ and inorganic fluid systems, and carbonate decomposition.  相似文献   

Supernova Relic Neutrino search with neutron tagging at Super-Kamiokande-IV     

《Astroparticle Physics》2015

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盐场卤水氧化-吸附联合脱色工艺的研究          下载免费PDF全文

刘建超  张永刚  刘立平 《盐湖研究》2011,19(1):53-58

以天津汉沽盐场高镁卤水为研究对象,分析其成色原因,建立了过氧化氢氧化-氢氧化锆吸附联合脱色工艺,分别考察了脱色剂用量、温度、pH值等因素对卤水色度、CODCr及镁离子损失率的影响,确定了最佳的脱色工艺条件:用卤水处理量1%(体积比)的过氧化氢于室温下将卤水氧化2 h后,在pH值为2～3的条件下经氢氧化锆吸附脱色40 min,氢氧化锆用量为60 g/L。在此条件下,卤水色度及CODCr去除率分别可达99%和85%,镁离子的损失率可控制在1%以下,均高于目前使用的工艺方法。吸附剂氢氧化锆经脱附后可循环使用,大大降低了工艺运行成本。  相似文献   

Spectral Diagnostics of the Magnetic Field Orientation in a Prominence Observed with SOHO/SUMER     

B. Schmieder  S. Gunár  P. Heinzel  U. Anzer 《Solar physics》2007,241(1):53-66

During several campaigns focused on prominences we have obtained coordinated spectral observations from the ground and from space. The SOHO/SUMER spectrometer allows us to observe, among others, the whole Lyman series of hydrogen, while the Hα line was observed by the MSDP spectrograph at the VTT. For the Lyman lines, non-LTE radiative-transfer computations have shown the importance of the optical thickness of the prominence – corona transition region (PCTR) and its relation to the magnetic field orientation for the explanation of the observed line profiles. Moreover, Heinzel, Anzer, and Gunár (2005, Astron. Astrophys. 442, 331) developed a 2D magnetostatic model of prominence fine structures that demonstrates how the shapes of Lyman lines vary, depending on the orientation of the magnetic field with respect to the line of sight. To support this result observationally, we focus here on a round-shaped filament observed during three days as it was crossing the limb. The Lyman profiles observed on the limb are different from day to day. We interpret these differences as being due to the change of orientation of the prominence axis (and therefore the magnetic field direction) with respect to the line of sight. The Lyman lines are more reversed if the line of sight is across the prominence axis as compared to the case when it is aligned along its axis.  相似文献   

过氧化氢对全铁测定的影响     

张成恕  李智  孙秋萍 《国土资源》1996,(1)

由过氧化钠分解试样的熔融物，经水提取后，会产生大量的过氧化氢。它对重铬酸钾测定全铁的结果，会产生偏高的影响。如果加热煮沸或以饿驱除它，则所得结果将令人满意。  相似文献