A new interpretation of measured ionic diffusion coefficient in compacted bentonite-based materials   总被引：1，自引：0，他引：1  

Steven C.H. Cheung 《Engineering Geology》1990,28(3-4):369-378

Previous model based on free-water properties to interpret the measured diffusion coefficient in compacted bentonite-based materials is demonstrated to be inadequate. A model considering ionic diffusion in clay surface (bound) and interstitial (free) water is presented to interpret the measured diffusion coefficients and to explain the possible reasons for the discrepancies in the data. The measured diffusion coefficient is determined by the predominant diffusion pathway, which depends on the charge of diffusing species, soil fabric, diffusion time and by the starting concentration condition of the method used.  相似文献   

Erosion rates in the southern oregon coast range: Evidence for an equilibrium between hillslope erosion and sediment yield     

Steven L. Reneau  William E. Dietrich 《地球表面变化过程与地形》1991,16(4):307-322

The relationship of hillslope erosion rates and sediment yield is often poorly defined because of short periods of measurement and inherent spatial and temporal variability in erosion processes. In landscapes containing hillslopes crenulated by alternating topographic noses and hollows, estimates of local hillslope erosion rates averaged over long time periods can be obtained by analysing colluvial deposits in the hollows. Hollows act as local traps for a portion of the colluvium transported down hillslopes, and erosion rates can be calculated using the age and size of the deposits and the size of the contributing source area. Analysis of colluvial deposits in nine Oregon Coast Range hollows has yielded average colluvial transport rates into the hollows of about 35cm³cm^?1yr^?1 and average bedrock lowering rates of about 0.07 mm yr^?1 for the last 4000 to 15000 yr. These rates are consistent with maximum bedrock exfoliation rates of about 0.09 mm yr^?1 calculated from six of the hollows, supporting the interpretation that exfoliation rates limit erosion rates on these slopes. Sediment yield measurements from nine Coast Range streams provide similar basin-wide denudation rates of between 0.05 and 0.08mm yr^?1, suggesting an approximate steady-state between sediment production on hillslopes and sediment yield. In addition, modern sediment yields are similar in basins varying in size from 1 to 1500 km², suggesting that erosion rates are spatially uniform and providing additional evidence for an approximate equilibrium in the landscape.  相似文献   

Planktonic dimethylsulfide and cloud albedo: An estimate of the feedback response     

Jonathan A. Foley  Karl E. Taylor  Steven J. Ghan 《Climatic change》1991,18(1):1-15

Partial control of climate by the biosphere may be possible through a chain of processes that ultimately links marine plankton production of dimethylsulfide (DMS) with changes in cloud albedo (Charlson et al., 1987). Changes in cloud optical properties can have profound impacts on atmospheric radiation transfer and, hence, the surface environment. In this study, we have developed a simple model that incorporates empirically based parameterizations to account for the biological control of cloud droplet concentration in a first attempt to estimate the strength of the DMS-cloud albedo feedback mechanism. We find that the feedback reduces the global climatic response to imposed perturbations in solar insolation by less than 7%. Likewise, it modifies the strength of other feedbacks affecting surface insolation over oceans by roughly the same amount. This suggests that the DMS-cloud albedo mechanism will be unable to substantially reduce climate sensitivity, although these results should be confirmed with less idealized models when more is known about the net production of DMS by the marine biosphere and its relation to aerosol/cloud microphysics and climate.  相似文献   

Seafloor hydrothermal activity and spreading rates: the eocene carbon dioxide greenhouse revisited     

James F. Kasting  Steven M. Richardson 《Geochimica et cosmochimica acta》1985,49(12):2541-2544

A suggestion has been made that enhanced rates of hydrothermal activity during the Eocene could have caused a global warming by adding calcium to the ocean and pumping CO₂ into the atmosphere (Owen and Rea, 1984). This phenomenon was purported to be consistent with the predictions of the CO₂ geochemical cycle model of Berner, Lasaga and Garrels (1983) (henceforth BLAG). In fact, however, the BLAG model predicts only a weak connection between hydrothermal activity and atmospheric CO₂ levels. By contrast, it predicts a strong correlation between seafloor spreading rates and pCO₂, since the release rate of CO₂ from carbonate metamorphism is assumed to be proportional to the mean spreading rate. The Eocene warming can be conveniently explained if the BLAG model is extended by assuming that the rate of carbonate metamorphism is also proportional to the total length of the midocean ridges from which the spreading originates.  相似文献   

Fluid ascent through the solid lithosphere and its relation to earthquakes   总被引：1，自引：0，他引：1  

Thomas Gold  Steven Soter 《Pure and Applied Geophysics》1984,122(2-4):492-530

The Earth is continuously expelling gases and liquids from great depths—juvenile volatiles from the mantle and recycled metamorphic products. Some of these fluids ascend through liquid rock in volcanic processes, but others utilize fractures and faults as conduits through the solid lithosphere. The latter process may have a major influence on earthquakes, since fluids at near lithostatic pressures appear to be required to activate deep faults that would otherwise remain locked.Fluids can be driven upward through solid rock by buoyancy, but only if present in sufficient concentration to form large-scale domains occupying interconnected fracture porosity. A growing fluid domain becomes so mobilized only when it attains the critical vertical dimension required for hydrostatic instability. This dimension, depending on the ultimate compressive yield strength of the rock, may be as much as several kilometers.Any column of fluid ascending through fractures in the solid lithosphere from a prolific deep source must become organized into a vertical sequence of discrete domains, separated by fluid-pressure discontinuities. This is required because a continuous hydrostatic-fluid-pressure profile extending from an arbitrarily deep source to the surface cannot be permitted by the finite strength of rock. A vertically stacked sequence of domains allows the internal fluid-pressure profile to approximate the external rock-stress profile in a stepwise fashion. The pressure discontinuity below the base of the uppermost hydrostatic domain may be responsible for some occurrences of so-called anomalous geopressures. An ascending stream of fluid that percolates upward from a deep source through a column of domains must encounter a sequence of abrupt pressure decreases at the transitions between successive domains. If supercritical gases act as solvents, the dissolved substances may drop out of solution at such pressure discontinuities, resulting in a local concentration of minerals and other substances.At great depths, brittle fracture would normally be prevented by high pressure and temperature, with all excessive stress discharged by ductile flow. Rock strata invaded by an ascending fluid domain are weakened, however, because cracks generated or reactivated by the high-pressure fluid can support the overburden, greatly reducing internal friction. This reduction of strength may cause a previously stressed rock to fail, resulting in hydraulic shear fracture. Thus, earthquakes may be triggered by the buoyant migration of deep-source fluids.The actual timing of the failure that leads to such an earthquake may be determined by the relatively rapid inflation of a fluid domain and not by any significant increase in the probably much slower rate of regional tectonic strain. Many earthquake precursory phenomena may be secondary symptoms of an increase in pore-fluid pressure, and certain coseismic phenomena may result from the venting of high-pressure fluids when faults break the surface. Instabilities in the migration of such fluid domains may also contribute to or cause the eruption of mud volcanoes, magma volcanoes, and kimberlite pipes.  相似文献   

The mid-ocean ridge axial valley as a steady-state neck     

Steven H. Emerman  D.L. Turcotte 《Earth and Planetary Science Letters》1984,71(1):141-146

In this paper the mid-ocean ridge axial valley is modelled as a steady-state lithospheric neck in which lithospheric stretching balances lithospheric accretion. Conversely, the axial high is a steady-state lithospheric bulge. The lithosphere is modelled as a thin plate with a Newtonian rheology. It is shown that an axial valley will occur if the rate of viscosity increase away from the ridge axis is faster than the rate at which accretion decreases. An axial high will occur if the opposite condition holds. This is consistent with the observation that axial valleys occur at low spreading rates and axial highs at high spreading rates. By fitting our model to profiles across the Mid-Atlantic Ridge and the East Pacific Rise and assuming the lithospheric thickness at the ridge axis to be 5 km, we find accretion widths of 6–8 km. We find the width over which there is a significant increase in lithospheric viscosity to be also 6–8 km.  相似文献   

The 1982 eruptions of El Chichon volcano,Mexico (2): Observations and numerical modelling of tephra-fall distribution     

Steven Carey  Haraldur Sigurdsson 《Bulletin of Volcanology》1986,48(2-3):127-141

Tephra fallout from the A-1 (March 29, 0532 UT), B (April 4, 0135 UT), and C (April 4, 1122 UT) 1982 explosive eruptions of El Chichon produced three tephra fall deposits over southeastern Mexico. Bidirectional spreading of eruption plumes, as documented by satellite images, was due to a combination of tropospheric and stratospheric transport, with heaviest deposition of tephra from the ENE tropospheric lobes. Maximum column heights for the eruptions of 27, 32, and 29 km, respectively, have been determined by comparing maximum lithic-clast dispersal in the deposits with predicted lithic isopleths based on a theoretical model of pyroclast fallout from eruption columns. These column heights suggest peak mass eruption rates of 1.1 × 10⁸, 1.9 × 10⁸, and 1.3 × 10⁸ kg/s. Maximum column heights and mass eruption rates occured early in each event based on the normal size grading of the fall deposits. Sequential satellite images of plume transport and the production of a large stratospheric aerosol plume indicate that the eruption columns were sustained at stratospheric altitudes for a significant portion of their duration. New estimates of tephra fall volume based on integration of isopach area and thickness yield a total volume of 2.19 km³ (1.09 km³ DRE, dense rock equivalent) or roughly twice the amount of the deposit mapped on the ground. Up to one-half of the erupted mass was therefore deposited elsewhere as highly dispersed tephra.  相似文献   

Ground-Water Problems in the Mesozoic Pax Mountain Fault Zone     

David S. Snipes  Peter R. Manoogian  Michael W. Davis  Laura L. Burnett  Jerry A. Wylie  Steven B. Heaton 《Ground water》1986,24(3):375-381

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Petrochemistry of the silicic-mafic complexes at Vesturhorn and Austurhorn, Iceland: evidence for zoned/stratified magma     

Steven R. Mattson  Thomas A. Vogel  John T. Wilband 《Journal of Volcanology and Geothermal Research》1986,28(3-4)

Within the Austurhorn and Vesturhorn silicic intrusions of southeastern Iceland are composite complexes that consist of pillow-like bodies of mafic and intermediate rock entirely surrounded by silicic rock. The pillows with cuspate and chilled boundaries are interpreted to indicate a liquid-liquid relationship with a silicic magma. Some pillow-like bodies have a chilled and sharp cuspate boundary, whereas others have a distinct chemical and visible gradational contact with the silicic rock. The visible scale of mixing is of the same order of magnitude as the size of the pillows enclosed in the silicic rock (mm to meters).Two important types of chemical variation in the pillows are recognized. The first type of variation occurs from mafic pillow interiors to margins and into the surrounding silicic rock. These variations are due to mechanical mixing between mafic magma and the silicic magma. The second type of chemical variation occurs between individual pillows. Large variations occur between pillows in P and Ti at nearly constant silica. These variations cannot have resulted from in situ simple magma mixing or crystal fractionation, and must have originated at depth below the present level of exposure. These compositions could have been derived from separate mafic (or intermediate) magma bodies or from a single zoned and/or stratified magma body. Because the Austurhorn, Vesturhorn, and Ardnamurchan composite complexes all exhibit similar variations in P and Ti and because these occurrences are separated in space and time, they are thought to have had similar processes occur during their evolution. The chemical variations are interpreted to have resulted from mafic magma that has underplated silicic magma and become zoned/stratified due to the effects of magma mixing and cooling-crystallization.  相似文献   

A chemical survey of the Mississippi estuary     

Lewis E. Fox  Frederick Lipschultz  Lee Kerkhof  Steven C. Wofsy 《Estuaries and Coasts》1987,10(1):1-12

A “snap shot” survey of the Mississippi estuary was made during a period of low river discharge, when the estuarine mixing zone was within the deltaic channels. Concentrations of H⁺, Ca²⁺, inorganic phosphorus and inorganic carbon suggest that the waters of the river and the low salinity (<5‰) portion of the estuary are near saturation with respect to calcite and sedimentary calcium phosphate. An input of oxidized nitrogen species and N₂O was observed in the estuary between 0 and 4‰ salinity. The concentrations of dissolved NH₄ ⁺ and O₂, over most of the estuary, appeared to be influenced by decomposition of terrestrial organic matter in bottom sediments. The estuarine bottom also appears to be a source of CH₄ which has been suggested to originate from petroleum shipping and refining operations. Estuarine mixing with offshore Gulf waters was the dominant influence on distributions of dissolved species over most of the estuary (i.e., from salinities >5‰). The phytoplankton abundance (measured as chlorophylla) increased as the depth of the mixed layer decreased in a manner consistent with that expected for a light-limited ecosystem. Fluxes of NO₃ ^?+NO₂ ^? and soluble inorganic phosphorus to the Gulf of Mexico were estimated to be 3.4±0.2×10³ g N s^?1 and 1.9±0.2 g P s^?1 respectively, at the time of this study.  相似文献