黔西北地区龙马溪组页岩有机质和脆性矿物的控缝机制     

袁余洋  刘永林  王瑛 《岩石矿物学杂志》2020,39(6):808-818

页岩"甜点"层段中有机质和脆性矿物对裂缝的发育具有极为重要的控制作用，揭示并把握裂缝萌生、发育和演化的机理与规律，对于压裂目标层段的优选以及页岩气增产和稳产具有极为重要的工程实践价值。以黔西北地区龙马溪组页岩为例，通过地化测试、岩石力学实验以及扫描电镜，深入剖析和揭示了"甜点"层段中与有机质和脆性矿物相关的控缝机制，并结合数值模拟实验展现了"甜点"层段中裂缝的形成和演化的完整过程。研究结果表明，有机质和脆性矿物的同步富集为裂缝的发育和演化提供了重要的物质基础，其中裂缝趋向于沿着有机质形成的结构面传播，有机质的孔隙结构对裂缝具有较为明显的诱导机制。在外力作用下，内在积累的能量转化为脆性矿物的变形和变位，脆性矿物含量越高者裂缝发育能力越强，裂缝发育程度越高。数值模拟实验呈现了一种由于有机孔隙和脆性矿物所导致的应力集中从而诱发裂缝萌生和演化的整个过程。该研究成果可为深化认识裂缝的成因机理以及压裂施工过程中相关压裂参数的调整提供一定的借鉴与参考。  相似文献   

Migration and dispersion of trace elements in the rock–soil–plant system in areas underlain by black shales and slates of the Okchon Zone, Korea     

Jin-Soo Lee  Hyo-Taek Chon  Kyoung-Woong Kim 《Journal of Geochemical Exploration》1998,65(1):61-78

The Okchon black shale in Korea provides a typical example of natural geological materials enriched with potentially toxic elements. The Chung-Joo, Duk-Pyung, Geum-Kwan, I-Won, Bo-Eun and Chu-Bu areas are underlain by these black shales and slates of the Guryongsan Formation or the Changri Formation, which are parts of the Okchon Group in the central part of the southern Korean Peninsula. In order to investigate the enrichment levels and dispersion patterns of potentially toxic elements in the rock–soil–plant system, environmental geochemical surveys were undertaken in the above six study areas in the Okchon Zone. After appropriate preparation, rock and soil samples were analyzed for potentially toxic elements by instrumental neutron activation analysis (INAA) and inductively coupled plasma atomic emission spectrometry (ICP-AES), and plant samples by atomic absorption spectrometry (AAS). In particular, Ba, Cd, Mo, V and U in Okchon black shales are highly enriched, and their mean concentrations are significantly higher than those in black slates. These elements are geochemically associated, and might be enriched simultaneously. The highest mean concentrations of 42.0 μg g⁻¹ As, 2100 μg g⁻¹ Ba, 10.9 μg g⁻¹ Cd, 213 μg g⁻¹ Mo, 83 μg g⁻¹ U, 938 μg g⁻¹ V and 394 μg g⁻¹ Zn are found in black shales from the Duk-Pyung area. Mean concentrations of As, Mo and U in soils overlying black shales occurring in the Duk-Pyung area (30 μg g⁻¹ As, 24 μg g⁻¹ Mo and 50 μg g⁻¹ U) and Chu-Bu area (39 μg g⁻¹ As, 15 μg g⁻¹ Mo and 27 μg g⁻¹ U) are higher than the permissible level. Enrichment index values of the six study areas decrease in the order of Duk-Pyung > Chu-Bu > Bo-Eun > Chung-Joo > Geum-Kwan = I-Won areas. Relationships between trace element concentrations in soils and plants are significantly correlated, and the biological absorption coefficients (BAC) in plants are in the order of Cd > Zn = Cu > Pb, which suggests that Cd is more bioavailable to plants than the other elements. Cadmium concentrations in plant species decrease in the order of chinese cabbage > red pepper > soybean = sesame > rice stalk > corn > rice grain. From the result of sequential extraction analysis of soils, relatively high proportions of Cu, Pb and Zn are present as residual fractions, and that of Cd as non-residual fractions. Cadmium occurs predominantly as exchangeable/water-acid soluble phase in soils, and this is in agreement with the findings of high Cd concentrations in plants.  相似文献   

湘黔地区中奥陶世海平面上升的沉积响应   总被引：2，自引：0，他引：2       下载免费PDF全文

江茂生 《地质科学》1998,33(1):93-101

中奥陶世克拉道克阶(Caradocian)在全球范围内为海侵期,体现在全球范围广泛的黑色页岩沉积及笔石动物的大规模繁盛,湘黔地区这一时期地层发育完全,从碳酸盐台地-斜坡-外陆架盆地均有不同程度的响应。在台地区表现为碳酸盐台地的淹没,斜坡区表现为碳酸盐重力流及黑色页岩、粉砂岩沉积,形成碳酸盐与陆源碎屑的混合沉积,而在外陆架盆地区表现为黑色岩系大规模发育及笔石的大量繁盛。  相似文献   

Swelling Behaviour of Expansive Shales from the Middle Region of Saudi Arabia     

Abdullah I. Al-Mhaidib 《Geotechnical and Geological Engineering》1998,16(4):291-307

Severe and widespread damage in residential buildings, sidewalks and pavements in various parts of the middle region of Saudi Arabia is caused by the development of heave and swelling pressure in the expansive shales in the region. This paper presents the problems and the geotechnical and physicochemical properties of the tested shales. The swelling potential was determined using various methods. Swell tests were conducted under different loading conditions and following different procedures to quantify the amount of vertical swell and swelling pressure. The conventional one-dimensional oedometer swell tests were performed using three different procedures, namely, free swell, constant volume swell and swell overburden. In addition, swell tests were performed in the stress path triaxial apparatus. Tests under different vertical stresses and confinements were conducted. Vertical swell and swelling pressure obtained from the various methods were compared. The reliability of the different methods for estimation of swelling potential is discussed.  相似文献   

Oil migration driven by exhumation of the Canol Formation oil shale: A new conceptual model for the Norman Wells oil field,northwestern Canada     

《Marine and Petroleum Geology》2015

Thermal history, petroleum system, structural, and tectonic constraints are reviewed and integrated in order to derive a new conceptual model for the Norman Wells oil field, and a new play type for tectonically active foreland regions. The thermal history recorded by Devonian rocks suggests that source rocks experienced peak thermal conditions in the Triassic–Jurassic, during which time oil was likely generated. After initial oil generation and expulsion, the Canol Formation oil shale retained a certain fraction of hydrocarbons. The shallow reservoir (650–350 m) is a Devonian carbonate bank overlain by the Canol Formation and resides within a hanging wall block of the Norman Range thrust fault. Both reservoir and source rocks are naturally fractured and have produced high API non-biodegraded oil. Thrust faults in the region formed after the Paleocene, and a structural cross-section of the field shows that the source and reservoir rocks at Norman Wells have been exhumed by over 1 km since then.The key proposition of the exhumation model is that as Canol Formation rocks underwent thrust-driven exhumation, they crossed a ductile–brittle transition zone and dip-oriented fractures formed sympathetic to the thrust fault. The combination of pore overpressure and new dip-directed subvertical fractures liberated oil from the Canol Formation and allowed for up-dip oil migration. Reservoir rocks were similarly fractured and improved permeability enhanced charging and pooling of oil. GPS and seismicity data indicate that strain transfer across the northern Cordillera is a response to accretion of the Yakutat terrane along the northern Pacific margin of North America, which is also the probable driving force for foreland shortening and rock exhumation at Norman Wells.  相似文献   

The origin,type and preservation of organic matter of the Barremian–Aptian organic-rich shales in the Muglad Basin,Southern Sudan,and their relation to paleoenvironmental and paleoclimate conditions     

《Marine and Petroleum Geology》2015

Barremian–Aptian organic-rich shales from Abu Gabra Formation in the Muglad Basin were analysed using geochemical and petrographic analyses. These analyses were used to define the origin, type of organic matters and the influencing factors of diagenesis, including organic matter input and preservation, and their relation to paleoenvironmental and paleoclimate conditions. The bulk geochemical characteristics indicated that the organic-rich shales were deposited in a lacustrine environment with seawater influence under suboxic conditions. Their pyrolysis hydrogen index (HI) data provide evidence for a major contribution by Type I/II kerogen with HI values of >400 mg HC/g TOC and a minor Type II/III contribution with HI values <400 mg HC/g TOC. This is confirmed by kerogen microscopy, whereby the kerogen is characterized by large amounts of structured algae (Botryococcus) and structureless (amorphous) with a minor terrigenous organic matter input. An enhanced biological productivity within the photic zone of the water columns is also detected. The increased biological productivity in the organic-rich shales may be related to enhanced semi-arid/humid to humid-warm climate conditions. Therefore, a high bio-productivity in combination with good organic matter preservation favoured by enhanced algae sizes are suggested as the OM enrichment mechanisms within the studied basin.  相似文献   

陕西铜川—黄陵地区油页岩地质特征及利用前景   总被引：6，自引：1，他引：5  

白云来  赵应成  徐东  马玉虎 《现代地质》2010,24(1)

位于鄂尔多斯盆地东南部的陕西铜川、宜君和黄陵一带赋存着丰富的油页岩资源。主要的含油页岩层位是中—晚三叠世延长组下段上部,具体形成时间为中三叠世晚期。野外观察发现,油页岩露头主要分布于铜川—宜君—黄陵一带,主矿层厚度一般为2~36 m。测得含油率为1.8%~13.7%,发热量为1.66~11.45 M J/kg,推测干酪根类型为I-II1,产烃率为400 kg/t,中等偏好,页岩油(相当于原油)资源量约100×108t,储量近亿吨。宏观和微观资料表明,该区油页岩是在淡水、近岸、强还原、富含有机质的沉积环境下形成的,属于大型内陆湖盆的半深—深湖相,埋藏浅,储量较大,交通条件好,如果在适当时机开发,不仅可获得初步经济效益,也可为鄂尔多斯油页岩的开发利用获取开拓性的经验。该区油页岩矿位于西部最大城市西安市附近,开发利用的意义重大。  相似文献   

油页岩灰渣提取氧化铝制备铝酸盐发光材料     

季桂娟  李晓军  郝磊  李广环 《世界地质》2010,29(4):668-682

利用干馏后的油页岩灰渣,湿法提取氧化铝作为发光材料基质,经采用高温固相法合成 CaAl2O4 : Eu3 + ,R + ( R = Li,Na,K,Rb) 荧光粉。最佳合成条件为: 烧结温度1 200 ℃,烧结时间3 h,助熔剂加入量3 wt%,激活离子配比3 mol%; 实验发现辅助激活离子为Li + 时,CaAl2O4 : Eu3 + , Li + 的发光强度最强。样品荧光光谱分析结果表明,发射光谱在615 nm 处出现强谱峰,归属为Eu3 + 的5D0→7F2 跃迁辐射。  相似文献   

世界页岩气勘探开发现状及对中国的启示   总被引：16，自引：3，他引：13  

李世臻  乔德武  冯志刚 《地质通报》2010,29(6):918-924

页岩气是一种潜在资源量巨大的非常规天然气资源,具有开采技术要求高、开采寿命长、稳产周期长的特点。近些年来,严峻的能源紧张形势和能源价格的快速增长,使页岩气资源在全世界受到了广泛的重视。回顾了美国页岩气勘探开发的历史,总结了美国的页岩气发育情况,跟踪了世界其他地区(加拿大、欧洲)包括中国页岩气研究的最新进展情况。根据前人的资料,认为中国南方海相页岩和北方盆地的湖相页岩具有巨大的页岩气资源潜力。鉴于页岩气是一种非常规能源,对其研究具有重大的现实意义,建议中国相关部门加大研究投入力度,尽快开展页岩气资源战略调查和选区研究工作,加强技术攻关创新、引进和国际合作,探讨中国现实国情下的页岩气相关政策,以早日实现页岩气在中国的商业性开发,促进经济快速发展。  相似文献   

山东省油页岩资源特征及开发利用前景          下载免费PDF全文

薛成  邢楠  赵赫  杨栋栋  曹治国 《山东国土资源》2014,30(6)

随着石油资源可用量的不断减少,页岩气、油页岩、油砂与稠油作为一种新能源,近年来备受人们的重视。山东省存在着丰富的油页岩资源。近年来笔者通过收集前人相关资料、野外地质填图、钻探编录、典型矿区考察、关键样品化验分析等手段对其进行了初步研究,初步认识了山东地区油页岩的资源特征及其形成环境,对未来山东地区油页岩矿的预测及潜力的评价具有一定的指导与借鉴作用。  相似文献