高精度ICP-MS 230Th测年新技术及其在贵州衙门洞Y1石笋测年研究中的应用   总被引：5，自引：0，他引：5  

杨琰  袁道先  程海 《中国岩溶》2006,25(2):89-94

在系统介绍洞穴石笋高精度ICP-M S铀系年代学原理与方法的基础上,对贵州荔波县衙门洞Y1石笋进行了IC P-M S 　230 Th测年研究。综合分析认为精确时标的建立对于利用石笋进行古气候重建具有重要的实际意义;采用ICP-M S　230 Th测年方法进行石笋样品定年准确可靠,并且比TIM S方法具有更高的效率,所需样品更微量。通过生长速率变化分析表明,石笋生长速率记录了过去冷暖突变事件,因此可以用它作为一个有意义的环境记录替代指标来研究古降水及古气候变化。   相似文献   

运用铀同位素研究砂岩型铀矿的几个问题     

刘金辉  孙占学  史维浚 《吉林大学学报(地球科学版)》2006,36(4):516-520

通过砂岩铀矿矿卷前锋铀同位素特征和512矿床含矿层铀同位素特征的研究,对砂岩型铀矿形成过程、铀同位素找矿标志进行了讨论。研究结果表明,砂岩铀矿的形成是一个多期次、滚动式、由氧化向还原环境推进的动态成矿过程,矿体主要定位于Ⅲ区段。根据铀同位素样品在不同氧化还原分带中的分布和矿体的滚动性特征,认为A区定名为地球化学矛盾区更为恰当。  相似文献   

砂岩铀矿成矿过程与氧化还原分带: 铀系不平衡证据   总被引：3，自引：0，他引：3  

孙占学刘金辉  朱永刚张文 《地球科学》2004,29(2):224-230

铀系不平衡技术被用来研究新疆伊犁盆地库捷尔太砂岩型铀矿床的氧化还原分带和成矿过程.取自该矿床的26个样品的铀、钍含量以及234 U/ 238U, 230 Th/ 234 U和230 Th/ 238U活度比值分别用ICP -MS和α能谱仪进行了测量.不同氧化还原带岩石的铀、钍含量和钍/铀比明显不同: 强氧化带岩石的U、Th含量和Th/U比分别为12.4 μg/g, 4.5 μg/g和0.48; 弱氧化带分别为20.4 μg/g, 5.0 μg/g和0.38; 过渡带(矿化带)分别为169.7μg/g, 4.7μg/g和0.07; 还原带(未蚀变带)分别为6.8μg/g, 3.7μg/g和0.87.其同位素特征亦有明显差异: 氧化带岩石234 U/ 238U大多大于1, 过渡带(矿化带)岩石部分大于或等于1, 部分小于1, 还原带(未蚀变带)岩石大多大于1; 氧化带岩石230 Th/ 234 U和230 Th/ 238U大多大于1, 过渡带(矿化带)岩石大多小于或等于1, 还原带(未蚀变带)岩石大多大于1.这可作为砂岩型铀矿床矿体定位的指示剂.铀系不平衡特征还示踪了该矿床的成矿作用过程.   相似文献   

宿亥图地区延安组第一岩段岩石地球化学特征及其与铀成矿关系     

杨胜富 《西部资源》2022,(1):132-134

宿亥图地区位于鄂尔多斯盆地北东部.中侏罗统延安组为新的铀找矿目的层,通过施工钻孔,发现了较好的铀矿化信息,且矿化(异常)位置位于灰色砂体与绿色砂体接触附近,表明该层铀成矿与层间氧化带具有密切联系.该区延安组第一岩段层间氧化带发育,铀矿化位置位于氧化砂体上翼,结合直罗组找矿模式,分析该地区岩石地球化学特征、层间氧化带展布...  相似文献   

溶剂萃取—电感耦合等离子体原子发射光谱测定铀,钍,钚基体中痕量杂质     

唐良保 《国外铀金地质》1998,15(2):179-184

  相似文献   

Size-fractionated uranium isotopes in surface waters in the Jiulong Estuary in China   总被引：1，自引：1，他引：0  

L&#; E  ZHANG Lei  CHEN Min  QIU Yusheng  XING N  YANG Weifeng  LI Yanping  HUANG Yipu 《海洋学报(英文版)》2008,27(1):29-41

Surface water was collected from the Jiulong Estuary for determination of activity concentrations of uranium isotopes in different size fractions, namely, greater than 53, 10 -53, 2 - 10, 0.4 -2 μm, 10 000 u -0.4 μm and less than 10 000 u fractions by microfihration and cross-flow uhrafiltration technologies. Results indicated that most of the dissolved uranium （ 〈 0.4 μm） exis- ted in the low molecular mass fraction （ 〈 10 000 u）, and the colloidal uranium-238 （10 000 u -0.4 μm） only contributed less than 1% of the dissolved uranium-238. The fractions of colloidal uranium in the dissolved phases decreased with the increasing sa- linity. A positive linear relationship between uranium-238 activities and salinities was observed for the dissolved, colloidal and low molecular mass fractions, indicating a conservative behavior of uranium in the Jiulong Estuary. In the particulate phases （ 〉 0.4 μm）, the partitioning of uranium isotopes among different size fractions was controlled by the partitioning of particle concentrations. In the regions with salinities below 20, the partitioning of uranium-238 among different size fractions was as follows： 10 - 53 μm 〉 2 - 10 μm 〉 0.4 - 2 μm greater than above 53 μm. However, the order at the offshore station with salinities above 30 changed as follows ： 0.4 - 2 μm 〉 10 - 53 μm 〉 2 - 10 μm greater than above 53 μm. The fraction of the 0.4 - 2 μm particles increased at the offshore station, suggesting the increased contribution of the authigenic uranium. The activity ratio of uranium-234 to uranium-238 in the dissolved phases, including the low molecular mass fraction and the colloidal fraction, was larger than unity, showing the occurrence of excess uranium-234. In contrast, the activity ratio of uranium-234 to uranium-238 in all size fractions of the particulate phase was close to the equilibrium value （1.0）. The observed different values of the activity ratio of uranium-234 to uranium-238 in the dissolved phase and the partic  相似文献   

太原地区地下水中铀含量和^235U／^238U比值研究     

林瑞芬卫克勤  王志祥 《地球化学》1986,(3):193-201

太原地区地下水中铀含量及铀同位素比值的测定结果表明，同一含水层有相近的铀含量及^235U／^238U比值。氧化为主的含水屡，地下水的^235U／^238U比值随径流方向逐渐增加。  相似文献   

德国铀矿册的退设和生态环境恢复     

赵凤民 《国外铀金地质》2000,17(1):61-64

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浅成磷钙土中的铀     

朱佛宏 《海洋地质前沿》2008,24(10):42-42

磷钙土被广泛用于生产肥料的原料或直接用作肥料。对它的研究非常深入，包括分析微量元素组分。发现沉积岩中微量元素的一般分面规律和从磷钙土的实际农业化学应用观点出发是很重要的，因为在其组分中的部分微量元素是微量肥料，而部分（例如铀）则在生态上是危险的。磷钙土是获得铀的重要矿石，美国大部分铀正是从磷钙土中获取的。  相似文献   

The investigation on particulate organic carbon fluxes with disequilibria between thorium-234 and uranium-238 in the Prydz Bay, the Southern Ocean   总被引：1，自引：0，他引：1  

HE Jianhu  MA Hao  CHEN Liqi  XIANG Baoqiang  ZENG Xianzhang  YIN Mingduan  ZENG Wenyi 《海洋学报(英文版)》2008,27(2):21-29

Dissolved and particulate thorium-234, particulate organic carbon in the upper 150 m of water columns from five stations in the Prydz Bay, the Southern Ocean were determined during the 22nd Chinese National Antarctic Research Expedition （from November 2005 to March 2006 ）. The disequilibria between thorium-234 and its parent uranium-238 in upper layer was used to derive the averaged residence time of thorium-234, which decreased along with the latitude to the south and a minimum value, 1 - 8 d for particulate thorium-234 and 29 - 48 d for dissolved thorium-234, appeared at the medium latitude station, and the export fluxes of thorium-234 were calculated too and ＇a maximum value, 0. 35 -0. 63 Bq/（m^3 · d） for the particulate thorium-234 and 0. 44 -0. 65 Bq/ （m^3 ·d） for the dissolved thorium-234, appeared at the same station. The export fluxes of particulate organic carbon at different water columns were derived by two methods with irreversible scavenging model, and the averaged values were 104. 7 mmol/ （ m2 · d ） （ E method） and 120. 6 mmol/（ m2·d ） （ B method ）, respectively, indicating that a relatively high new production would exist in summer in the Prydz Bay where it will play a potential significant role in sequestering the absorption CO2 to deeper ocean.  相似文献