低压密闭消解-电感耦合等离子体发射光谱法测定地质样品中的硼     

杜宝华  盛迪波  罗志翔  王全 《岩矿测试》2020,39(5):690-698

采用酸溶-电感耦合等离子体发射光谱法(ICP-OES)测定地质样品中的全硼量,关键环节在于如何防止样品消解过程中硼元素的损失,降低测量过程中的基体干扰、光谱干扰和记忆效应。基于以上问题,本文采用氢氟酸-硝酸-高氯酸-磷酸在低压密闭溶样罐中消解样品,溶出的硼元素与少量磷酸充分络合,防止硼的挥发损失;以基体及主成分浓度与样品相类似的地质类固体标准物质绘制标准曲线做线性校准,有效匹配和降低样品的基体干扰;采用仪器自带的操作软件,观察分析谱线附近是否存在其他元素的干扰,来确定背景扣除最佳的位置及宽度,降低ICP-OES测量中的光谱干扰;以10%的王水作为进样系统的冲洗液,有效消减测量过程中的记忆效应。当稀释因子为200时,方法的检出限(3SD)为1.2μg/g,定量限(10SD)为4.0μg/g;用岩石、土壤及水系沉积物国家一级标准物质对精密度及准确度进行分析验证,11次测定相对标准偏差为1.8%～7.9%,相对误差为-3.6%～6.3%;以外检分析结果为参考,对硼含量在定量限以上的样品测定,相对误差为-9.3%～12.5%。  相似文献   

东北黑土区侵蚀沟遥感影像特征提取与识别   总被引：3，自引：0，他引：3  

于佩鑫  周询  刘素红  王西凯 《遥感学报》2018,22(4):611-620

东北黑土区是中国重要的粮食生产区,而长期的开垦造成了严重的水土流失现象,坡耕地表面出现大量的侵蚀沟。侵蚀沟的识别是土壤侵蚀监测的重要手段之一,目前遥感技术在侵蚀沟的识别中应用广泛,但自动化程度不高。针对特定地物影像的识别,如何选取最能够有效描述该地物的特征是解决问题的关键。本文构建了耕地和侵蚀沟遥感影像的训练样本集,基于样本集分别提取了由光谱特征和纹理特征组成的浅层特征、SIFT特征经编码后得到的中层特征,以及利用卷积神经网络提取的深层特征;再基于不同层次的特征选用合适的分类器对遥感影像进行分类,识别出含有侵蚀沟的遥感影像,形成了一套针对侵蚀沟的特征提取与识别方法,为东北黑土区的耕地保护提供有力支持。测试结果表明:基于中层特征的识别精度最高,为98.5%,但该特征需要人工设计,自动化程度有限;而利用卷积神经网络可自动提取深层特征,其识别精度达到了95.5%,同时大大提高了自动化程度,满足侵蚀沟影像的识别的需求。  相似文献   

Main technical innovations of Songke Well No.2 Drilling Project     

《China Geology》2018,1(2):187-201

Songke Well No.2, one of the main part of the scientific drilling project in Songliao Basin, which was drilled 7018 m and acquired the part of cores continuously from the Low Cretaceous to the Carboniferous and the Permian from the 2843 m deep, can be considered as the deepest continental drilling project in Asia. Aiming at the features of longer well sections, larger diameters and multiple spud-ins for coring of Songke Well No.2, this project broke through the “coring in small diameter and reaming in large diameter” spud-in drilling-completion procedures which are always used in large-diameter-well coring for continental scientific drilling projects in domestic and overseas and the drilling method of short-single-cylinder roundtrip footage. At the same time, “coring in the same diameter and completing drilling at one single diameter” was achieved at all φ311 mm and φ216 mm coring sections of more than one thousand meters long, high-efficient operation with “drilling long footage with drill tools combined in multi-cylinders” was achieved at deep coring section. Four world drilling records were created which include more than a thousand meters continuous coring at φ311 mm, and the footage per roundtrip footage at φ311 mm, φ216 mm and φ152 mm is all more than 30 m, all of these breakthroughs reduced at least 300 days for this project; moreover, considering the characteristics of formations that the geothermal gradient is high in the drilled sections and the inside-well temperature is over 240°C after drilling completion, a formate-polymer water-based mud system was developed by compounding attapulgite and sodium bentonite and by adding independently developed high-temperature stabilizer, which can provide critical technical support for successful well completion at 7018 m in the super-high-temperature environment It is the first time that the water-based mud is operated at the working temperature higher than 240°C in China; Besides, considering the high-quality requirement on cores imposed by the project, the method “mechanical cored is charge” to discharge core nondestructively on the ground was worked out, and more than 4000 m scatheless cores were discharged out of the drill pipes while maintaining original stratum structures.  相似文献   

京张地区区域地壳稳定性评价   总被引：3，自引：3，他引：0  

张树轩  杨为民  孟华君  张向营  李焕斌 《地质力学学报》2018,24(1):70-77

在野外调查和广泛收集资料的基础上,分析了控制和影响京张地区区域地壳稳定性的主要因素及内外动力地质的耦合作用。选取活动断裂、地震活动性和深部地球物理等因素,同时选取工程岩组、地形地貌与地表地质灾害等11个因素作为评价因子,并对评价因子进行了分类赋值。采用多因素加权叠加分析方法,建立了区域地壳稳定性评价模型,基于GIS平台对京张地区的区域地壳稳定性进行了定量化评价,将研究区划分为稳定区、次稳定区、次不稳定区和不稳定区4个等级。依据区域地壳稳定性评价结果,为京张高速铁路、云顶滑雪场、石京龙滑雪场的建设和运营提出相关建议,为京张地区国土规划提供了基础依据。  相似文献   

长短期记忆神经网络(LSTM)模型在低能见度预报中的应用     

方楠  谢国权  阮小建  任晨平  姜舒婕  张玮玮 《气象与环境学报》2022,38(5):34-41

利用浙江省义乌市2015—2019年逐小时气象观测数据(相对湿度、风速、地气温差、能见度)和空气质量指数(Air Quality Index, AQI)数据, 分析了义乌地区低能见度天气(观测能见度lt; 10 km)的分布特征和气象要素条件。利用长短期记忆神经网络(Long Short Term Memory Neural Network, LSTM)模型对逐小时能见度进行模拟, 分别对比了观测能见度作为输入变量与否的模拟效果; 根据义乌地区低能见度天气条件的特征, 将模拟时段分为三个时期(11月至翌年2月, 3—6月, 7—10月), 对比了分时期模拟的效果; 以及评估了模型的预报步长。结果表明: 高湿、高污染、气温高于地温和低风速是义乌地区低能见度天气的主要特征。LSTM模型对单站能见度有较好的模拟效果, 当输入参数中加入历史观测能见度时, 能大幅提高模拟准确度, 日均能见度模拟结果均方根误差RMSE=0.63 km, 平均绝对误差MAE=0.51 km, 拟合优度R²=0.99;分时期进行模拟能得到更精准的模拟结果。本研究中选用的输入要素在冬季(11月至翌年2月)模拟效果最好, RMSE=2.35 km, MAE=1.46 km, 低能见度均方根误差RMSE_10 km=1.81 km, 低能见度平均绝对误差MAE_10 km=1.13 km, R²=0.83; 3—6月的模拟中, 输入变量中不加AQI模拟效果更好, 这意味着3—6月义乌地区的低能见度天气以雾天气为主导, 加入过多变量并不一定能提高模型准确度; 随着预报步长增大, 模型预报效果变差, 预测步长等于3 h, R²=0.71, 预测结果已不具备实际应用意义。  相似文献   

长短时记忆神经网络在中期地震预报中的探索--以川滇地区为例     

李林芳  石耀霖  程术 《地球物理学报》2022,65(1):12-25

利用机器学习方法对地震活动大数据进行挖掘,识别出一些过去认识不到的异常,提高地震预测的准确性,是一个非常具有挑战性的科学问题.本文基于川滇部分地区(24°N—32°N,98°E—106°E)地震目录,采用滑动的时空窗口,选取16个反映地震时空强度分布特征的地震预测因子,建立了长短时记忆(LSTM)神经网络,对研究区域9个子区块未来一年的最大地震震级进行预测.通过设置训练集∶测试集=8∶2和训练集∶测试集=7∶3两个不同的训练测试模型,对过往发生的地震进行了回溯性预报.结果表明:训练集∶测试集=7∶3模型能够利用1970年1月至2004年9月的地震目录进行学习,成功回溯性预报2008年汶川地震;训练集∶测试集=8∶2模型利用1970年1月至2009年5月资料进行训练,回溯性预报2010—2019年间6级以上地震的R评分为0.407,回溯性7级地震预报时准确率高达92.31%.本文还探讨性给出预测意见:2022年2月前研究区西部、中部、东部、西南部存在发生5.1~5.3级地震的潜在危险性.  相似文献   

真三轴单面临空下煤岩组合体冲击破坏特征试验研究     

杨科  刘文杰  马衍坤  许日杰  池小楼 《岩土力学》2022,(1):15-27

煤岩复合承载结构所处的应力边界条件不同,冲击地压在巷道中的显现特征和前兆规律亦不相同。采用高频振动采集及孔内成像三轴动静载试验系统,开展了高静载和动静载耦合作用下煤岩组合体真三轴单面临空试验,分析了煤岩组合体界面处力学特征和强度条件,探究了不同应力边界下煤岩组合体的破坏形态、动力显现特征和声发射信号的演变规律。研究结果表明:(1)受煤岩变形相互制约的影响,交界面处砂岩强度被"弱化"。当界面处煤体裂隙尖端的应力大于"弱化"后砂岩强度时,裂隙将穿过煤岩界面发育至砂岩中,砂岩呈现出屈曲层裂、劈裂成板的破坏形态。(2)高静载作用下,煤岩组合体变形破坏特征和声发射信号具有明显的前兆规律,组合体发生承载失效前煤体局部颗粒弹射动能增大、弹射颗粒块度降低,声发射信号由"高频低能"向"高频高能"转变,组合体的破坏形态以剪切-张拉复合破坏为主。(3)受冲击动载影响,顶底板砂岩夹持作用减弱,煤体裂纹尖端应力得不到有效积聚,裂纹扩展到煤岩交界面时被阻隔,组合体以煤样的张拉破坏为主,声发射信号呈现出"高频高能"的特点,但大多集中在冲击破坏之后,导致组合体动力破坏难以预测。(4)与纯静载作用相比,虽然动静载耦合作...  相似文献   

Rapid screening of Zr-containing particles from Chang’e-5 lunar soil samples for isotope geochronology: Technical roadmap for future study     

《地学前缘(英文版)》2022,13(3):101367

New samples returned by China Chang’e-5 (CE-5) mission offer an opportunity for studying the lunar geologic longevity, space weathering, and regolith evolution. The age determination of the CE-5 samples was among the first scientific questions to be answered. However, the precious samples, most in the micrometer size range, challenge many traditional analyses on large single crystals of zircon developed for massive bulk samples. Here, we developed a non-destructive rapid screening of individual zirconium-containing particle for isotope geochronology based on a Micro X-ray fluorescence analysis (µXRF). The selected particles were verified via scanning electron microscopy (SEM), 3D X-ray microscopy (XRM), and focused ion beam scanning electron microscopy (FIB-SEM) techniques, which showed that zirconium-bearing minerals with several microns were precisely positioned and readily suitable for site-specific isotopic dating by second ion mass spectrometry (SIMS). Such protocol could be also applicable in non-destructively screening other types of particles for different scientific purposes. We therefore proposed a correlative workflow for comprehensively studying the CE-5 lunar samples from single particles on nanometer to atomic scales. Linking various microscopic and spectromicroscopic instruments together, this workflow consists of six steps: (1) single-particle selection with non-destructive µXRF technique, (2) 2D/3D morphological and structural characterization with a correlative submicron 3D XRM and nanoscale resolution FIB-SEM imaging methods, (3) SEM analysis of the surface morphology and chemistry of the selected particle, (4) a series of microscopic and microbeam analyses (e.g., SEM, electron probe microanalysis, and SIMS) on the cross-section of the selected particle to obtain structural, mineralogical, chemical, and isotopic features from the micron to nanometer scale, (5) advanced 2D/3D characterization and site-specific sample preparation of thin foil/tip specimens on a microregion of interest in the selected particle with FIB-SEM technique, and (6) comprehensive analyses on the FIB-milled specimens at nanometer to atomic scale with synchrotron-based scanning transmission X-ray microscopy, analytic transmission electron microscopy, and atom probe tomography. Following this technical roadmap, one can integrate multiple modalities into a uniform frame of multimodal and multiscale correlated datasets to acquire high-throughput information on the limited or precious terrestrial and extraterrestrial samples.  相似文献   

五酸溶样-电感耦合等离子体质谱法同时测定地质样品中的稀土等28种金属元素     

龚仓  丁洋  陆海川  卜道露  王立华  熊韬  张志翔 《岩矿测试》2021,(3):340-348

电感耦合等离子体质谱法(ICP-MS)测定大批量地质样品中的稀土和钴铪铟锰铌钽铊铬镉镓锗钒锡等金属元素,主要采用三酸或四酸溶解样品。由于地质样品组分复杂,稀土等金属元素含量低,各元素性质差异大,三酸或四酸溶样经常出现易挥发元素如钒铬镉镓锡的测定结果不稳定、镧铈镨钕等稀土元素溶解不完全的问题。本文在盐酸-硝酸-氢氟酸-高氯酸四酸基础上引入硫酸,形成盐酸-硝酸-氢氟酸-高氯酸-硫酸五酸溶样体系,用于水系沉积物、土壤和岩石等不同类型地质样品的一次敞口溶解,采用在线加入~(185)Re和~(103)Rh内标方式,建立了应用ICP-MS同时测定稀土等28种金属元素的方法。钒铬镉镓锡元素的准确度提高了1.4%～14.6%,镧和铈元素的准确度提高了0.2%～8.9%。该方法应用于分析水系沉积物、土壤、岩石标准物质(分别为GBW07301a、GBW07408、GBW07107),其测定值与认定值相一致,相对标准偏差(RSD)为1.14%～9.84%,准确度(△lgC)均≤0.1。该方法分析过程较简单,结果准确可靠,可满足测定大批量地质样品中稀土和钴铪铟锰铌钽等金属元素含量的要求。  相似文献   

Effect of the Dry Ashing Method on Cadmium Isotope Measurements in Soil and Plant Samples     

Wei‐Xin Lv  Hao‐Ming Yin  Meng‐Shu Liu  Fang Huang  Hui‐Min Yu 《Geostandards and Geoanalytical Research》2021,45(1):245-256

A dry ashing method is commonly used to remove organic material from samples prior to geochemical analysis. In the course of this study, the Cd isotope ratios of a series of soil and plant reference materials and samples were studied to evaluate the effect of the dry ashing method on measurement results of Cd isotope ratios. The samples were pre‐treated using the dry ashing method and high‐pressure bomb for comparison. The results show that the digestion using high‐pressure bombs did not lead to Cd loss, but using the dry ashing method would cause different proportions of Cd loss. The whole range of Cd isotope difference between two methods was from ?0.07‰ to 3.01‰. There was also an obvious difference in measured Cd isotope ratios from the same leaf sample pre‐treated independently by the dry ashing method, indicating that the amount of Cd loss and the effect on Cd isotope measurement during dry ashing is related to the properties of the samples. Therefore, dry ashing may not be appropriate for the removal of organic material in Cd isotope ratio measurement, especially for samples with high organic contents. The δ^114/110Cd values of reference materials NIST SRM 1573a and GSD‐30 are reported for the first time in this study.  相似文献