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High resolution(939 samples)total organic carbon content(TOC)analyses were conducted on the Shuanghe Section of^152.6 m in the Changning area,Sichuan Basin.The sampling section was divided into two units considering the distinct-different deposit environment and sediments accumulation rate.The lower part(Unit 1)and the peer part(Unit 2)with high resolution sample spacing(0.08–0.4 m)enables the identification of the precession cycle in two sedimentary sequences with distinct different sedimentary accumulation rate.MTM Power spectral analyses on untuned TOC series reveals significant peaks exceeding above the 95%confidence level and shows that both Unit 1 and Unit 2 have recorded Milankovitch cycles of 405 kyr long eccentricity,short eccentricity,obliquity and precession.The floating astronomical time scale(ATS)was constructed on the Shuanghe Section in the Early Silurian(~439.673–444.681 Ma),and which was calibrated by 405 kyr long eccentricity cycles.The total duration of the Wufeng and Longmaxi shales is 5.01 Myr.The floating ATS used for estimating the duration of the graptolite zones and each stage in the study interval.Finally,we postulated two models that could verify the linkage between orbital cycle and organic accumulation.To make sure whether productivity or preservation is the main factor that under long eccentricity control,the phase correlation between the obtained filtered signal and the theoretical orbital solution should be made clear in the further research. 相似文献
3.
刘家峡水库西南部水域表层沉积物重金属污染评价 总被引:1,自引:0,他引:1
为了研究刘家峡水库西南部水域表层沉积物中重金属的污染状况,对采集的55个表层沉积物样品中的6种重金属元素Cr、Cd、Ni、Cu、Zn和Pb的含量进行测试,其平均含量分别为77.03μg/g、0.16μg/g、33.53μg/g、32.09μg/g、291.77μg/g、22.44μg/g。在研究表层沉积物重金属含量空间分布的基础上,运用单因子污染指数法、内梅罗综合污染指数法、地累积指数法、潜在生态风险指数法,综合判断水库的受污染程度并对其潜在生态风险进行评估。6种元素的地累积指数排序依次为:Zn > Cu > Cd > Ni > Pb > Cr;潜在生态风险系数排序依次为:Cd > Cu > Pb > Zn > Ni > Cr;各区域重金属污染程度或潜在生态风险水平依次为黄河主河道 > 大夏河河口 > 黄河横剖面。综合4种方法的评价结果,认为对刘家峡水库西南部表层沉积物重金属污染及潜在生态风险评价贡献率较高的重金属污染因子是Zn、Cu和Cd;综合相关性分析与主成分分析,认为研究区沉积物重金属污染主要来源于两个方面:(1) Zn、Cu主要来源于生活污染或工业污染;(2) Cd主要来源于工农业活动产生的污染。 相似文献
4.
2012-2018年巢湖水质变化趋势分析和蓝藻防控建议 总被引:4,自引:3,他引:1
巢湖自1990s中期至2012年间水质明显改善,但是近年来水质改善效果变缓,2018年蓝藻水华面积显著增加,为有效评估巢湖水体环境的变化,通过对20122018年巢湖17个点位的逐月调查数据分析阐述了近年来巢湖水质和藻情的变化特征,并在流域空间尺度上分析了巢湖流域水污染治理的进展和不足,为后续治理方向的调整和确定提供支撑.20122018年湖区调查数据显示:巢湖湖体总磷和总氮浓度显著升高,铵态氮浓度显著下降,水华蓝藻总量显著升高.在空间上,各污染指标水平呈现由西向东呈逐渐降低的趋势,但是各指标在不同湖区随时间的变化趋势差异明显,西部湖区的总磷、总氮和水华蓝藻指标近年来略有下降或持平,中部和东部湖区则显著升高,所以巢湖湖体总氮和总磷浓度的升高主要源于中、东部湖区的升高,这也是这两个湖区水华蓝藻变动的主要驱动因素.主要入湖河口数据显示:西部4条主要入湖污染河流(南淝河、十五里河、塘西河和派河)水质明显改善,但仍处于较高污染水平,中东部入湖河流(兆河、双桥河和柘皋河)总磷浓度明显升高,是中东部湖区水体营养盐升高的主要原因.中东部河流入湖污染的增加加剧了该区域湖体的富营养化水平,尤其是总磷浓度明显提升,导致中东部湖区夏季水华蓝藻的优势种从鱼腥藻种类演替为微囊藻种类.夏季微囊藻的大量繁殖,使得2018年巢湖中东部湖区部分月份水华面积异常增高.因此,巢湖流域的治理应该在持续强化流域西部合肥市污染治理的同时,增加对流域中部和东部治理的关注和投入. 相似文献
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6.
Lipid biomarkers widely dotted in marine sediments, as their distribution characteristics accurately record huge information on the metabolism of the original organisms and migration and transformation of these organic components, are often used to reconstruct the paleoclimatic and paleoenvironmental conditions. This paper reviewed the progress in the study of paleoclimatic-environmental changes during the late Quaternary using abundant core lipids Glycerol Dialkyl Glyceryl Tetraethers (GDGTs) and long-chain alkyl diols in marginal sea sediments. It is pointed out that clarifying the “source-sink” process of lipid biomarkers buried in marine sediments is a prerequisite for paleoclimatic-environmental reconstruction. It is believed that the use of multiple indicators that are less affected by early diagenesis can increase the accuracy of reconstructing paleoclimatic changes. In the large-river dominated marginal seas, the mechanism of land-sea climate coupling evolution stimulated by the paleoclimatic-environmental changes can be elucidated based on paleoclimatic records reconstructed from core lipids GDGTs and long-chain alkyl diols in marine sediments. It is hoped that this paper can provide reliable technical means and a solid theoretical basis for predicting future temperature and rainfall changes. 相似文献
7.
Effects of heavy metal pollution on farmland soils and crops: A case study of the Xiaoqinling Gold Belt,China 总被引:1,自引:0,他引:1
《China Geology》2020,3(3):402-410
This paper focuses on the heavy metal enrichment and heavy metal pollution degree associated with mining activities in some crops and the soils of different parent materials in the Xiaoqinling Gold Belt. According to the geochemical analysis results of the soils observed in the gold belt, the soils are most highly enriched in Pb, followed by Cr, Cu, and Zn. Furthermore, they are relatively poor in Hg, Cd, and As. It is also shown that the heavy metals in all kinds of soils have the same geochemical characteristics in the gold belt. As for the crops (such as corn and wheat) in the gold belt, Zn and Cu are the most abundant elements, followed by Pb and Cr. Meanwhile, Hg, Cd, and As were found to have relatively low concentrations in the crops. The heavy metals in wheat and corn have the same geochemical characteristics in the gold belt in general. Compared to the aeolian loess soils and the crops therein, heavy metals are more enriched in diluvial and alluvial soils and the crops therein. As shown by relevant studies, the Hg, Pb, Cd, Cu, and Zn pollution are mainly caused by mining activities. Corn and wheat in the gold belt have a high tendency of risk exposure to heavy metal pollution since they are mostly affected by mining activities and feature high background values of heavy metal concentrations. Furthermore, wheat is more liable to be enriched in heavy metals than corn is grown in all types of soils. The Hg pollution in soils leads to Hg accumulation, increasing the risk of Hg uptake in crops, and further affecting human health. This study will provide a scientific basis for the control and management of heavy metals in farmland soils of mining areas. 相似文献
8.
《Chemie der Erde / Geochemistry》2019,79(3):434-445
Human activities in cities affect properties of urban soils. In particular, urban soils often contain high contents of harmful metals even in deeper horizons added to them from diverse sources over centuries of the city development. This is reflected in complex distribution of metals in bulk soils with depth and the complex metal fractionation, but the exact sources of the metals are difficult to identify. This is also the situation in soils from Wroclaw, one of the largest cities in Poland. Potentially harmful elements Pb, Cd and Hg were examined in six profiles located along the major communication route and compared to two non-urban soils profiles located close to the same route. In all of the urban profiles, Pb and Cd exceeded the element contents observed in non-urban profiles and showed an erratic distribution compared to the more predictable one in non-urban soils. The differences between urban and non-urban profiles were explained as the result of contamination coming from more pollution sources in the case of urban soils, the conclusion supported by Pb isotope analyses. In fact, Pb isotopes showed that the contamination sources in urban soils included leaded petrol, coal combustion, smelting and possibly old pre-industrial ore processing, whereas leaded petrol and pre-industrial lead were the only possible anthropogenic sources in non-urban soils. The comparison of Wrocöaw soils with those from cities of comparable size Kraków and Poznań show similar ranges of metal contents with implication that urban pollution oversteps diverse geogenic chemical background. On the other hand, the comparison with other European cities show large variability in metal contents and suggest that urban soils contamination is time integrated and reflects long-term industrial evolution of each country. 相似文献
9.
随着化肥、农膜等在农业生产中的过量投入,耕地面源污染的程度随之加重。文章选取塔里木河流域上游和田地区为研究区域,依据P-S-R框架理论,构建和田地区耕地面源污染生态风险评价指标体系,加入土壤理化数据,使用生态风险评价模型对和田地区1980 年及2016 年耕地面源污染状况进行生态风险评价,运用耕地生态风险模型、生态风险转移矩阵、Arcgis分析和田地区耕地面源污染时空分异状况。研究结论如下:和田地区1980 年耕地生态风险等级均为II级或III级,呈“中间高,两侧低”分布;2016 年耕地生态风险等级上升至IV级或V级,呈“倒W型”分布,各县耕地面源污染程度较1980 年均有较大幅度的上升,其中墨玉县和于田县在2016 年耕地生态风险等级达到最高的V级,而民丰县因自身生态环境的强脆弱性,同样需要提高关注。根据面源污染“从源头治理”的原则,应切实推进和田地区耕地生态环境保护与治理,提高政府重视程度,增强技术指导,开展试点工作,改善和田地区耕地面源污染现状。 相似文献
10.
针对区域大气污染物排放量与空气质量在时空分布上存在不完全协同、匹配的现象,论文选择SO2、NOX、PM2.5、CO和VOCs作为大气污染物指标,选择气溶胶光学厚度(Aerosol Optical Depth, AOD)表征颗粒物环境空气质量,以武汉市为例,综合应用耦合模型和空间错位指数模型研究2类指标之间的空间非协同耦合规律。主要结论如下:① 武汉市大气污染物排放量与颗粒物空气质量具有不同空间分布特征,大气污染物排放量呈现由城市中心城区向远城区递减的趋势,其中SO2、PM2.5和VOCs的排放具有明显的中心聚集现象,而NOX和CO聚集现象不显著,且与道路分布明显相关;AOD分布具有明显的空间差异性,总体上呈由西北向东南依次递减的趋势。② 武汉市大气污染物排放与颗粒物空气质量的空间非协同耦合规律:越靠近城市中心城区,空间协同耦合现象越显著,空间错位现象越弱;越远离主城区,空间非协同耦合现象越显著,空间错位现象越显著;SO2排放量与AOD在武汉市远城区的空间错位指数均大于0.7,且耦合度指数小于0.3,呈现较强的非协同耦合特征,NOX、VOCs、PM2.5的排放量与AOD在武汉中心城区的空间错位指数均小于0.5,且耦合度指数大于0.5,协同耦合现象较为显著。③ 基于时空非协同耦合分析城市大气环境污染治理建议:针对污染物与AOD空间错位不显著的城市中心城区,以本地减排治理为主;针对污染物与AOD空间错位显著的远城区,应在污染溯源分析的基础上进行区域协调综合治理。 相似文献