金活动态提取剂提取-电感耦合等离子体质谱法测定深穿透地球化学样品中的金     

王冀艳  胡家祯  丁汉铎  曹立峰  张明炜  张帆  黄杰  姚文生 《岩矿测试》2020,39(4):525-534

金的地球化学勘查基于金的准确测定,地球化学样品中金含量通常处于ng/g水平,需先进行分离富集,再采用电感耦合等离子体质谱法(ICP-MS)或石墨炉原子吸收光谱法(GFAAS)进行测定。当前,隐伏矿床勘查是地球化学探测技术的发展前沿,金活动态提取技术是寻找隐伏金矿的有效手段之一。相比于全量分析,金的活动态含量更低,需要解决选择性提取、高效预富集与准确测定等一系列难题。本文采用柠檬酸铵与土壤中黏土矿物及次生矿物作用促使吸附和可交换组分的金进入提取液,以硫脲和硫代硫酸钠络合金使活动态金向提取液中扩散,达到选择性提取的目的,建立了提取液中金的预富集及ICP-MS测定方法。实验确定的分析条件为:采用5g/L柠檬酸铵-2g/L硫脲-5g/L硫代硫酸钠为提取剂,提取时间24h,在酸性硫脲介质下用活性炭富集金,金吸附率可达89.6%～109.2%,灰化解吸温度为650～700℃。本方法检出限为0.05ng/g,相对标准偏差(RSD)为9.4%～10.2%,加标回收率为91.2%～93.4%。与已报道的硫酸铁-硫脲-硫代硫酸钠溶液提取再GFAAS测定的方法相比,本方法具有检出限低、测试线性范围宽、测试速度快的优势;应用于森林覆盖区黑龙江东安金矿区地球化学探测试验,金活动态异常与隐伏金矿位置一致。  相似文献   

Classification of inorganic natural fine-grained soils in Korea based on modified plasticity chart     

Juhyun Kim 《Marine Georesources & Geotechnology》2018,36(5):579-588

Classification of fine-grained soils is typically conducted using plasticity charts. The typically used plasticity chart proposed by Casagrande was questioned by Polidori proposing different classification criterion in separating clayey and silty soils. Using natural clayey and silty soils sampled from four different coastal sites in Korea, applicability of both Casagrande’s and Polidori’s plasticity charts was evaluated. Classification results of Korean natural soils based on the Casagrande’s and Polidori’s plasticity charts did not match well with those based on the soils’ behavior reported in the previous publication. The disagreement in classification of Korean natural fine-grained soils may result from disregard of considerable silt fraction effect on plastic and liquid limits for Polidori’s chart. Consequently, revised proposal of Polidori’s plasticity chart was tentatively made for further classification of fine-grained soils suitable for Korean natural soils by accounting the effect of silt fraction on soil classification.  相似文献   

Lidar-aided analysis of boreal forest backscatter at Ku band     

《International Journal of Applied Earth Observation and Geoinformation》2020

This paper analyzes the backscatter of the microwave signal in a boreal forest environment based on a Ku -band airborne Frequency-Modulated Continuous Waveform (FMCW) profiling radar—Tomoradar. We selected a half-managed boreal forest in the southern part of Finland for a field test. By decomposing the waveform collected by the Tomoradar, the vertical canopy structure was achieved. Based on the amplitude of the waveform, the Backscattered Energy Ratio of Canopy-to-Total (BERCT) was calculated. Meanwhile, the canopy fraction was derived from the corresponding point cloud recorded by a Velodyne VLP-16 LiDAR mounted on the same platform. Lidar-derived canopy fraction was obtained by counting the number of the first/ the strongest returns versus the total amount of returns. Qualitative and quantitative analysis of radar-derived BERCT on lidar-derived canopy fraction and canopy height are investigated. A fitted model is derived to describe the Ku-band microwave backscatter in the boreal forest to numerically analyze the proportion contributed by four factors: lidar-derived canopy fraction, radar-derived canopy height, the radar-derived distance between trees and radar sensor and other factors, from co-polarization Tomoradar measurements. The Root Mean Squared Error (RMSE) of the proposed model was 0.0958, and the coefficient of determination R2 was 0.912. The fitted model reveals that the correlation coefficient between radar-derived BERCT and lidar-derived canopy fraction is 0.84, which illustrates that lidar surface reflection explains the majority of the profiling /waveform radar response. Thus, vertical canopy structure derived from lidar can be used for the benefit of radar analysis.  相似文献   

2017年九寨沟7.0级地震前不同级别地震空区的演化过程分析     

张博  张辉  冯建刚  王朋涛 《中国地震》2018,34(4):765-771

结合传统地震学方法与数字地震学方法，回顾总结了日常分析预报中针对九寨沟7.0级地震开展的相关工作，梳理总结了地震前提出的甘东南地震异常信息，进一步讨论了九寨沟地震前中期、短期及临震异常特征。通过分析九寨沟7.0级地震之前区域范围内不同震级活动图像，发现甘青川交界地区5级空区在震前向震中一侧收缩、4级地震超长平静458天、3级空区在震前4天被打破的现象，同时发现，震中附近区域震源机制一致性较高，反映了震源区的高应力水平。  相似文献   

基于两种无人机航拍影像的林窗和林冠提取分析     

王悦  练琚愉  张昭臣  胡健波  杨骥  李勇  叶万辉 《热带地理》2019,39(4):553-561

森林冠层和林窗的结构及其时空变化是理解森林生态系统格局、动态变化过程的重要基础。在当前生物多样性监测倍受关注的契机下，如何以合适的手段准确描述林窗面积、分布等特征，并与森林固定样地监测数据有效地结合，更好地回答群落构建的理论问题，使森林群落物种多样性维持机制得到更全面的认识，是目前亟待解决的问题。以鼎湖山南亚热带常绿阔叶林20 hm2固定监测样地为研究对象，基于不同遥感影像提取方法对其林窗和林冠表层数据进行提取分析。结果表明：基于监督分类的提取方法适合RGB波段航片林窗的提取，在林窗分类中，应首先确定林窗高度、边界木与最小面积，不同分类方法差异主要表现在林冠分类中，林窗分类生产者精度和用户精度表现都较为一致。无人机航拍识别率受地形因素影响较大，在地形复杂林地应按坡度分区域进行飞行以降低误差。相对于地面调查，MD4-1000无人机航片的林窗识别率为98.7%；大疆Phantom4无人机航片的林窗识别率为72.3%，影像后期处理数据量小，同样适用于森林林窗定量研究，符合生态学、林业等从业人员对大型样地林窗长期监测的要求。无人机航拍南亚热带森林物种识别难度较大，基于MD4-1000无人机搭载的高分辨率相机，在地势平缓区域优选的4 hm2样地中可识别林冠表层物种数17种，共2 706个个体。搭载高分辨率无人机在降低飞行高度的基础上可进行部分物种识别。应用无人机近地面遥感对森林固定样地进行林冠监测，可为后期群落构建研究提供数据基础，有望从新的研究角度探讨森林群落物种多样性维持机制。  相似文献   

How forest gaps shaped plant diversity along an elevational gradient in Wolong National Nature Reserve?     

Chen  Li  Han  Wangya  Liu  Dan  Liu  Guohua 《地理学报(英文版)》2019,29(7):1081-1097

Journal of Geographical Sciences - Understanding the underlying ecological processes that control plant diversity within (α-diversity) and among (β-diversity) forest gaps is important for...  相似文献   

Assessing basin storage: Comparison of hydrometric- and tracer-based indices of dynamic and total storage     

Ciara D. Cooke  James M. Buttle 《水文研究》2020,34(9):2012-2031

Storage is a fundamental but elusive component of drainage basin function, influencing synchronization between precipitation input and streamflow output and mediating basin sensitivity to climate and land use/land cover (LULC) change. We compare hydrometric and isotopic approaches to estimate indices of dynamic and total basin storage, respectively, and assess inter-basin differences in these indices across the Oak Ridges Moraine (ORM) region of southern Ontario, Canada. Dynamic storage indices for the 20 study basins included the ratio of baseflow to total streamflow (baseflow index BFI), Q ₉₉ flow and flow duration curve (FDC) slope. Ratios of the standard deviation of the streamflow stable isotope signal relative to that of precipitation were determined for each basin from a 1 year bi-weekly sampling program and used as indicators of total storage. Smaller ratios imply longer water travel times, smaller young water fractions (F _yw, < ~2–3 months in age) in streamflow and greater basin storage. Ratios were inversely related to BFI and Q ₉₉, and positively related to FDC slope, suggesting longer travel times and smaller F _yw for basins with stable baseflow-dominated streamflow regimes. Inter-basin differences in all indices reflected topographic, hydrogeologic and LULC controls on storage, which was greatest in steep, forest-covered headwaters underlain by permeable deposits with thick and relatively uniform unsaturated zones. Nevertheless, differential sensitivity of indices to controls on storage indicates the value of using several indices to capture more completely how basin characteristics influence storage. Regression relationships between storage indices and basin characteristics provided reasonable predictions of aspects of the streamflow regime of test basins in the ORM region. Such relationships and the underlying knowledge of controls on basin storage in this landscape provide the foundation for initial predictions of relative differences in streamflow response to regional changes in climate and LULC.  相似文献   

Snowpack disrupts relationship between young water fraction and isotope amplitude ratio; approximately one fifth of mountain streamflow less than one year old     

Éowyn M. S. Campbell  Igor Pavlovskii  M. Cathryn Ryan 《水文研究》2020,34(25):4762-4775

Previous “fraction of young water” (F_yw) estimates based on relative annual isotopic amplitudes in precipitation (A_p) and streamflow (A_s) produced low F_yw values in mountain catchments, which is contrary to extensive research that reports rapid water transmission in mountains. This study investigated this discrepancy by testing the effect of snow accumulation on the model that underpins the F_yw method. A Monte-Carlo analysis of simulations for 20,000 randomly-generated catchment model configurations used 10 years of precipitation inputs for the Upper Elbow River catchment in the Rocky Mountains (Alberta, Canada) to model discharge with and without snowpack storage of winter precipitation. Neither direct nor modified precipitation input produced a 1:1 relationship between A_s/A_p and F_yw, undermining the applicability of the original F_yw method in mountain watersheds with large seasonal snow accumulation. With snowpack-modified input a given A_s/A_p ratio corresponds to a range of F_yw values, which can still provide semi-quantitative information. In the small (435 km²) Elbow River catchment a F_yw range of 7–23% supports previous findings of rapid transmission in mountain catchments. Further analysis showed that the improved discharge prediction (Nash–Sutcliffe efficiency > 0.9) correlates with higher F_yw values and demonstrated that the interannual shifts in δ¹⁸O can be used to estimate of new water (<1 year) fraction in winter streamflow, and the estimate of 20% for the Elbow River further supports rapid transmission in mountain catchments.  相似文献   

Application of S-SEBI model for crop evapotranspiration using Landsat-8 data over parts of North India     

Abhishek Danodia  N. R. Patel  Choe Won Chol  B. R. Nikam  V. K. Sehgal 《国际地球制图》2019,34(1):114-131

Estimation and monitoring of crop evapotranspiration (ET_c) or consumptive water use over large-area holds the key to irrigation management plans and regional drought preparedness. The objective of this study was to estimate ET_c by applying the simplified-surface energy balance index (S-SEBI) model to Landsat-8 data for the 2014–2015 period in parts of North India. An average ET_c was estimated 2.72 and 2.47 in mm day^?1 with 0.22, 0.18 standard deviation and 0.11, 0.07 standard error for Kharif and Rabi crops, respectively. On validation part, a close relationship was observed between S-SEBI derived and scintillometer observed evaporative fraction with 0.85 correlation coefficient and 0.86 agreement index. The statistical analysis also endorses the results accuracy and reliability with 0.026 and 0.602, relative root-mean square errors and model efficiency for wheat crop, respectively. The study showed that normalized difference vegetation index and LST are closely related and serve as a proxy for qualitative representation of ET_c.  相似文献   

黔西南泥堡金矿床容矿火山岩系中“粉砂岩”夹层的岩石类型归属研究          下载免费PDF全文

祁连素 《贵州地质》2021,38(1):22-28, 64

原先认为泥堡金矿床容矿火山岩系中间的"粉砂岩夹层",研究发现其具有与火山碎屑岩的成分与结构构造特征,包括熔蚀石英晶屑和长石板状晶假象,局部还出现大量生物化石碎片,应归属为蚀变凝灰岩。火山岩系的原"粉砂岩夹层"并不存在,只是短暂的火山喷发间隙,整个容矿火山岩系形成从偏基性火山碎屑岩到中基性火山角砾岩的晚二叠世火山喷发旋回。火山岩旋回的早期到晚期,金矿成矿作用强度逐渐增强,印证金成矿作用与火山岩的密切成因联系。  相似文献