To establish a base line against which future pollution may be measured, eight common commercial species of New Zealand sea fish were analysed for cadmium, chromium, copper, iron, lead, manganese, nickel, and zinc. One sample of edible muscle tissue was analysed for each of 70 samples of each species. The internal organs of up to five specimens of each species were also analysed. The fish studied were: kahawai, Arripis trutta, trevally, Caranx lutescens, tarakihi, Cheilodactylis macropterus, snapper, Chrysophrys auratus, moki, Latridopsis ciliaris, hapuku, Polyprion oxygeneios, kingfish, Seriola grandis and gurnard, Trigla kumu. Although, none of the edible parts of the fish appeared to have trace element levels likely to be a public health problem (cadmium 0.002–0.02 ppm, chromium 0.01–0.04 ppm, copper 0.04–0.95 ppm, iron 0.9–13.5 ppm, lead ‘ 0.14–0.95 ppm, manganese 0.04–2.00 ppm, nickel 0.01–0.08 ppm, zinc 2.0–36.0 ppm), some of the organs (particularly the liver) had relatively high concentrations of elements such as cadmium (up to 54 ppm). Only if some industry were to seek to exploit internal organs of fish for human consumption would such levels become important. There was some evidence for a relationship between trace element concentrations and fish size for copper in kingfish and snapper, iron in hapuku, manganese in gurnard, and for zinc in kingfish and tarakihi. Some element pairs such as copper and zinc, iron and manganese, appeared to have concentrations which were mutually related. It was assumed that the elemental concentrations reported represent natural levels and are not the result of significant man‐made pollution because there are no major industries or large urban centres adjacent to the fishing grounds. 相似文献
A new off-axis integrated cavity output spectroscopy(ICOS) is coupled to Weiss equilibrator for continuous highresolution dissolved methane measurement in the surface ocean. The time constant for the equilibrator in freshwater at room temperature is determined via dis-equilibration and re-equilibration experiments. The constant for methane is about 40 min. The system is calibrated using a standard gas of 3.980×10–6, and the precision of the ICOS for methane is 0.07%. This system is equipped onboard to measure the spatial distribution in methane concentrations of South Yellow Sea(SYS) along the cruise track from Shanghai to Qingdao. Result shows that the methane concentration varies from 2.79 to 36.36 nmol/L, reveals a significant pattern of methane source in SYS, and a distinct decreasing trend from south to north. The peak value occurs at the coast area outside mouth of the Changjiang River, likely to be affected by the Changjiang diluted water mass dissolving a large amount of rich in methane. Moreover, all the surface waters are oversaturated, air-to-sea fluxes range from 98.59 to 5 485.35 μmol/(m2·d)(average value(1 169.74±1 398.46) μmol/(m2·d)), indicating a source region for methane to the atmosphere. Key words: methane, equilibrator, off-axis integrated cavity output spectroscopy(ICOS), South Yellow Sea 相似文献
We estimated metamorphic conditions for the 6 Ma Taitao ophiolite, associated with the Chile triple junction. The metamorphic grade of the ophiolite, estimated from secondary matrix minerals, changes stratigraphically downwards from the zeolite facies, through the prehnite–actinolite facies, greenschist facies and the greenschist–amphibolite transition, to the amphibolite facies. The metamorphic facies series corresponds to the low-pressure type. The metamorphic zone boundaries are subparallel to the internal lithological boundaries of the ophiolite, indicating that the metamorphism was due to axial hydrothermal alteration at a mid-ocean ridge.
Mineral assemblages and the compositions of veins systematically change from quartz-dominated, through epidote-dominated, to prehnite-dominated with increasing depth. Temperatures estimated from the vein assemblages range from 230 °C in the volcanic unit to 380 °C at the bottom of the gabbro unit, systematically 200 °C lower than estimates from the adjoining matrix minerals. The late development of veins and the systematically lower temperatures suggest that the vein-forming alteration was due to off-axis hydrothermal alteration.
Comparison between the Taitao ophiolite with its mid-ocean ridge (MOR) affinity, and other ophiolites and MOR crusts, suggests that the Taitao ophiolite has many hydrothermal alteration features similar to those of MOR crusts. This is consistent with the tectonic history that the Taitao ophiolite was formed at the South Chile ridge system near the South American continent (Anma, R., Armstrong, R., Danhara, T., Orihashi, Y. and Iwano, H., 2006. Zircon sensitive high mass-resolution ion microprobe U–Pb and fission-track ages for gabbros and sheeted dykes of the Taitao ophiolite, Southern Chile, and their tectonic implications. The Island Arc, 15(1): 130–142). 相似文献
ABSTRACTNew analysis of the geophysical data of the ultraslow-spreading Mohns Ridge and its off-axis structure reveals a distinctive asymmetric structure. We calculate residual bathymetry (RB) and residual mantle Bouguer gravity anomaly (RMBA) and decompose the anomalies into symmetric and asymmetric components between the ridge conjugates. The western flank of the Mohns Ridge at crustal age of ~50–15 Ma is characterized by a broad zone of elevated RB and more negative RMBA, which we term the Vesteris Plateau (VP). The VP anomaly has a surface area of ~1.12 × 105 km2 and an excess crust volume of ~2.33 × 105 km3, making it a significant anomaly comparable to other anomalies such as the Bermuda Rise. Extending north of the Kolbeinsey Ridge for more than 500 km, the VP lies above an anomalous upper mantle region of low shear-wave seismic velocity, indicating that the VP might represent the northernmost reach of the Iceland-Jan Mayen mantle anomaly. In addition, the western ridge flank of the Mohns Ridge at crustal age of 6–0 Ma is associated with higher RB and more positive RMBA relative to the eastern conjugate, indicating tectonic uplift and associated exposure of lower crust and upper mantle near the ridge axis. 相似文献