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1.
High quality marine source rock (HQMSR) is the key prerequisite for medium to large hydrocarbon accumulations. However, the forming mechanism remains unclear. On the basis of the in-vestigation for the geodynamic setting of the Middle-Upper Yangtze during the Early Cambrian in dif-ferent spatial scales and the analysis of trace elements, the main controlling factors of the development of high quality marine source rock are discussed, with specific consideration of the burial rate of the organic matter. The ... 相似文献
2.
WenHui Liu Tenger ZhongNing Zhang HouYong Luo DianWei Zhang Jie Wang LiWu Li Bo Gao LongFei Lu Heng Zhao 《中国科学:地球科学(英文版)》2016,59(11):2142-2154
The mechanism of hydrogen sulfide (H2S) generation plays a key role in the exploration and development of marine high-sulfur natural gas, of which the major targets are the composition and isotope characteristics of sulfur-containing compounds. Hydrocarbon source rocks, reservoir rocks, natural gases and water-soluble gases from Sichuan Basin have been analyzed with an online method for the content of H2S and isotopic composition of different sulfur-containing compounds. The results of comparative analysis show that the sulfur-containing compounds in the source rocks are mainly formed by bacterial sulfate reduction (BSR), and the sulfur compounds in natural gas, water and reservoir are mainly formed by thermal sulfate reduction (TSR). Moreover, it has been shown that the isotopically reversion for methane and ethane in high sulfur content gas is caused by TSR. The sulfur isotopic composition of H2S in natural gas is inherited from the gypsum or brine of the same or adjacent layer, indicating that the generation and accumulation of H2S have the characteristics of either a self-generated source or a near-source. 相似文献
3.
无机地球化学参数与有效烃源岩发育环境的相关研究 总被引：7，自引：0，他引：7
探索海相有效烃源岩判识指标仍是我国油气勘探中尚待解决的重要科研任务之一。古生产力及氧化还原条件是研究全球变化和海洋环境的重要内容,也是重塑有效烃源岩发育环境的主要参数。Si、Ba是古生产力的替代指标,Cd对古营养盐的反演具良好前景。过渡金属及其相关比值是缺氧环境的有效判识指标,可用其推断有机质保存条件。δ13Ccarb正偏移指示有机质埋藏量增加,是底部水体缺氧的响应。过渡金属同位素（δ65Cu、δ66Zn、δ97Mo）受生物活动及氧化还原条件的影响发生较大分馏,示踪环境变化具灵敏、高效性。将这些无机参数对古环境的示踪意义引入油气地质研究,从环境角度分析某一套地层能否发育有效烃源岩,进而探讨高演化海相有效烃源岩的判识,就更具特殊意义。 相似文献
4.
通过扫描电镜精细观测,在贵州遵义松林地区早寒武世黑色岩系剖面,于其底部的硅质页岩中发现了可能的细菌状化石,直径200～500 nm,形态不一,具有细菌的大小和形状,有机碳含量丰富,大部分细菌含磷.通过与已有报道中具相似形态生物体的对比,认为其可能是原生的、具有细菌生物结构的微生物小球体(Microbioids),本文称之为细菌状化石.这类细菌状化石可以赋存于石英颗粒表面、石英颗粒间,甚至嵌入石英颗粒中.据前人的模拟实验推测,细菌在石英颗粒沉淀过程中可能起到过重要促进作用,这从微观上为硅质岩的形成提供了新信息. 相似文献
5.
对黔南坳陷典型古油藏、残余油气藏的精细解剖对南方海相碳酸盐岩层系油气勘探研究具有重要意义。本文运用碳同位素、饱和烃色谱、饱和烃色质及芳烃色质等技术,对黔东南地区二叠系—寒武系油苗与固体沥青进行了地球化学特征研究和油源分析。研究表明,凯里地区虎庄47井原油、洛棉志留系砂岩油苗和麻江地区奥陶系红花园组固体沥青三者同源,主要来自下寒武统牛蹄塘组的优质烃源岩。而麻江地区早二叠世茅口组油苗与虎庄47井原油明显不同,主要源于下二叠统栖霞组的优质烃源岩。 相似文献
6.
Since the discovery of the Tahe oilfield, it has been controversial on whether the main source rock is in the Cambrian or Middle-Upper Ordovician strata. In this paper, it is assumed that the crude oil from the Wells YM 2 and TD 2 was derived from the Middle-Upper Ordovician and Cambrian source rocks, respectively. We analyzed the biomarkers of the crude oil, asphalt-adsorbed hydrocarbon and saturated hydrocarbon in bitumen inclusions from the Lunnan and Hade areas in the North Uplift of the Tarim Basin. Results show that the ratios of tricyclic terpane C21/C23 in the crude oil, asphalt-adsorbed hydrocarbon and saturated hydrocarbon in bitumen inclusions are less than 1.0, indicating that they might be from Upper Ordovician source rocks; the ratios of C28/(C27+C28+C29) steranes in the saturated hydrocarbon from reservoir bitumen and bitumen inclusions are higher than 25, suggesting that they might come from the Cambrian source rocks, however, the ratios of C28/(C27+C28+C29) steranes in oil from the North Uplift are less than 25, suggesting that they might be sourced from the Upper Ordovician source rocks. These findings demonstrate that the sources of crude oil in the Tarim Basin are complicated. The chemical composition and carbon isotopes of Ordovician reservoired oil in the Tarim Basin indicated that the crude oil in the North Uplift (including the Tahe oilfield) and Tazhong Depression was within mixture areas of crude oil from the Wells YM 2 and TD 2 as the end members of the Cambrian and Middle-Upper Ordovician sourced oils, respectively. This observation suggests that the crude oil in the Ordovician strata is a mixture of oils from the Cambrian and Ordovician source rocks, with increasing contribution from the Cambrian source rocks from the southern slope of the North Uplift to northern slope of the Central Uplift of the Tarim Basin. Considering the lithology and sedimentary facies data, the spatial distribution of the Cambrian, Middle-Lower Ordovician and Upper Ordovician source rocks was reconstructed on the basis of seismic reflection characteristics, and high-quality source rocks were revealed to be mainly located in the slope belt of the basin and were longitudinally developed over the maximum flooding surface during the progressive-regressive cycle. Affected by the transformation of the tectonic framework in the basin, the overlays of source rocks in different regions are different and the distribution of oil and gas was determined by the initial basin sedimentary structure and later reformation process. The northern slope of the Central Uplift-Shuntuo-Gucheng areas would be a recent important target for oil and gas exploration, since they have been near the slope area for a long time. 相似文献
7.
On the basis of the results of hydropyrolysis simulations for about 90 different types of immature to mature source rocks
selected from about 5 000 marine source rocks in China, along with the natural thermal evolution profiles, the following conclusions
were obtained. (1) Total organic carbon (TOC) content of excellent marine source rocks does not change obviously when Ro < 0.8% or Ro > 1.3%, and the residual TOC content is decreasing gradually with the maturity increase at 0.8% < Ro < 1.3%. (2) At the high-post mature stage (Ro > 1.3%), the decreased maximums of residual TOC content for the kerogen of sapropel (I), II1, and II are usually 40%, 32% and 24%, respectively, and their TOC restitution coefficient is, respectively, 1.68, 1.48 and
1.32. (3) Both the TOC decreasing amplitude and the restitution coefficient decrease gradually with the decrease of TOC content
for the source rocks with low organic matter abundance (usually 0.3% < TOC < 1.0%). The TOC restitution coefficients are,
respectively, 1.20 and 1.0, when 0.3% < TOC < 0.5% and TOC < 0.3%. (4) TOCres of solid bitumen and shale with high organic matter abundance (TOC > 30%) also require no restitution at the high mature
stage. Such kind of TOC restitution is further supported by the coincidence of the decrease of residual TOC with the decreasing
of S1 + S2 and the increasing of hydrocarbon quantity during the experimental simulation of hydrocarbon generation and expulsion for
marine source rocks (0.3% < TOC < 30%) in natural thermal evolution profiles.
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Translated from Earth Science—Journal of China University of Geosciences, 2007, 32(6): 853–860 [译自: 地球科学—中国地质大学学报] 相似文献
8.
贵州凯里寒武系底部硅质岩系生物组成、沉积环境与烃源岩发育关系研究 总被引：1，自引：0，他引：1
贵州凯里麻江地区羊跳剖面寒武系牛蹄塘组底部发育了一套3.2m厚的硅质岩系。通过对其进行高频逐层采样68件,根据沉积环境-生物组成-烃源岩形成的思路,精细分析了生物组成及有机碳TOC含量,进而讨论了沉积环境与烃源岩发育的关系。结果表明,该剖面生物组成多样,包括有浮游藻、底栖宏观藻、疑源类、海绵骨针、须腕动物蠕虫等,并可归纳为三大类生物微相:浮游藻类、底栖藻类、其它生物类型。不同藻类体和不同疑源类所反映的水体深度特征显示,该套烃源岩沉积经历了先水进后水退的过程,水体深度最深时期,底栖红藻和Heliosphaeridium longum-Asteridium tornatum疑源类组合发育,烃源岩有机碳含量也较高(TOC平均值为4.73%,最高可达13.97%),说明利于烃源岩发育。总体而言,不同生物微相烃源岩TOC含量不同,底栖藻类(平均值3.50%)浮游藻类(平均值1.46%)其它生物类(平均值1.0%)。而须腕动物蠕虫和海绵动物的发现反映了热液环境,受热水事件影响强烈的样品TOC最低(TOC含量为0.90%和0.94%),说明热液活动强烈对烃源岩发育可能具有一定的不利影响。 相似文献
9.
10.
Baojian Shen Jianzhong Qin Borjigin Tenger Anyang Pan Yunfeng Yang Lizeng Bian 《中国地球化学学报》2018,37(1):68-79
Based on the results of conventional geochemistry analysis including thin sections and SEM observations, different shapes of bacterial fossils, with size ranging from dozens of nanometers to several microns, were discovered in the low-mature marine source rocks and coal seams in South China, of which the Permian source rocks were dominated by the bacterial fossils derived from symbiotic sulphur bacteria with gypsum, and the Chengkou section in the Cambrian strata were occupied by abundant nanoscale bacterial fossils with rod and bar shapes. In contrast, a large quantity of possible bacterial fossils found in the high-mature Permian, Silurian, and Cambrian source rocks using SEM need to be further explored. Despite this, this study has indicated that bacterial fossils were prevalent in the source rocks, such as mudstone, siliceous rock and gypsum-bearing coal seams in South China, which has been ignored before. It also suggests that the bacterial fossils may play an important role in the formation and accumulation of shale gas in the geological history. 相似文献