稀有金属矿物溶解度对花岗伟晶岩成矿作用的制约     

唐勇  覃山县  赵景宇  吕正航  刘喜强  王宏  陈剑争  张辉 《地学前缘》2022,29(1):81-92

花岗伟晶岩型矿床是稀有金属矿床重要的类型之一。在花岗伟晶岩中,稀有金属元素Li、Be、Nb和Ta主要以独立矿物的形式存在,前人对稀有金属独立矿物在硅酸盐熔体中的溶解度及其影响因素展开了系统研究。本文综合分析了已有的实验数据,其结果表明,影响稀有金属独立矿物溶解度最为重要的2个参数是温度(T)和铝饱和指数(ASI)。因此本文建立了稀有金属独立矿物,尤其是铌锰矿和钽锰矿溶解度,与温度(T)和铝饱和指数(ASI)之间的定量关系: lg [w(Li)/10^-6]=-0.37×[1 000/(T/K)]+4.56,R²=0.44 lg [w(BeO)/10^-6]=-4.21×[1 000/(T/K)]+6.86,R²=0.91 lg [K_sp(Nb)/(mg²·kg^-2)]=-(2.86±0.14)×ASI_(Mn+Li)-(4.95±0.31)×[1 000/(T/K)]+(4.20+0.28),R²=0.86 lg [K_sp(Ta)/(mg²·kg^-2)]=-(2.46±0.11)×ASI_(Mn+Li)-(4.86±0.30)×[1 000/(T/K)]+(4.00+0.30),R²=0.80 式中,温度T为热力学温度,ASI_(Mn+Li)(ASI=Al₂O₃/(CaO+Na₂O+K₂O+Li₂O+MnO),摩尔分数比)和T的适用范围分别为0.6~1.2和1 073~1 373 K的范围内。上述公式为估算硅酸盐熔体中稀有金属含量提供了便利,为量化花岗伟晶岩成矿模型提供了基础。 稀有金属独立矿物溶解度随温度降低和铝饱和指数的增加而急剧降低,因此,在岩浆演化过程中,由岩浆侵位、分离结晶以及流体作用等因素引起的岩浆温度降低和铝饱和指数的增加,是导致稀有金属独立矿物结晶的主要机制。  相似文献   

贵州都匀下泥盆统蟒山群Zosterophyllum australianum(澳大利亚工蕨)新材料及其古地理意义^*          下载免费PDF全文

周志强  赵景宇  王嘉树  吴成洋  肖彪  黄璞 《古地理学报》2022,24(3):479-492

Zosterophyllum(工蕨属)是早期陆生植物的代表性类群之一,全球广泛分布。Z.australianum(澳大利亚工蕨)产自华南和澳大利亚,是东北冈瓦纳古植物地理区系的典型分子。文中描述了产自贵州都匀包阳剖面蟒山群中的Z.australianum新材料。该标本的孢子囊具短柄,呈椭圆形或扇形,宽2.6~4.1 mm,高可达3.9 mm,加厚带宽约0.6 mm,紧密螺旋排列形成孢子囊穗,与云南文山早泥盆世坡松冲植物群中的Z. australiaunum极为相似。依据目前对Z. australianum时代延限的认识,并结合蟒山群其他植物属种的发现(如Adoketophyton subverticillatum),推断该群下段的时代为早泥盆世布拉格期。Z. australianum在蟒山群中的发现,扩展了该植物的地理分布范围,反映出蟒山群中的植物组合与坡松冲植物群存在一定联系。  相似文献   

Reaction between basaltic melt and orthopyroxene at 3.0–4.5 GPa:Implications for the evolution of ocean island basalts in the mantle     

Chunjuan Zang  Mingliang Wang  Hongfeng Tang  Hanqi He 《地学前缘(英文版)》2021,12(2)

Interactions between basaltic melt and orthopyroxenite(Opx)were investigated to gain a better understanding of the consequences of the residence and transport of ocean island basalts(OIBs)within the mantle.The experiments were conducted using a DS-3600 six-anvil apparatus at 3.0–4.5 GPa and 1300–1450℃.The basaltic melt and Opx coexisted at local equilibrium at these pressures and temperatures;the initial melts dissolved Opx,which modified their chemical composition,and clinopyroxene(Cpx)precipitated with or without garnet(Grt).The trace-element contents of Grt,Cpx,and melt were measured and the mineral–melt distribution coefficients(D)of Cpx–melt and Grt–melt were calculated,which can be used to assess the distribution of trace elements between basalt and minerals in the mantle.Two types of reaction rim were found in the experimental products,Cpx,and Cpx+Grt;this result indicates that residual rocks within the mantle should be pyroxenite or garnet pyroxenite.Both rock types are found in mantle xenoliths from Hawaii,and the rare-earth-element(REE)pattern of Cpx in these mantle pyroxenites matches those of Cpx in the experimental reaction rims.Furthermore,residual melts in the experimental products plot in similar positions to Hawaiian high-SiO₂OIBs on major-element Harker diagrams,and their trace-element patterns show the signature of residual Grt,particularly in runs at1350℃ and 4.0–4.5 GPa.Trace-element concentrations of the experimental residual melts plot in similar positions to the Hawaiian OIBs on commonly used discrimination diagrams(Ti vs.Zr,Cr vs.Y,Cr vs.V,Zr/Y vs.Zr,and Ti/Y vs.Nb/Y).These results indicate that reaction between basaltic melt and pyroxenite might contribute to the generation of Hawaiian high-SiO2 OIBs and account for their chemical variability.  相似文献   

Contrasting water–rock interaction behaviors of antimony and arsenic in contaminated rivers around an antimony mine,Hunan Province,China     

《Chemie der Erde / Geochemistry》2021,81(2):125748

Although antimony (Sb) and arsenic (As) exhibit similar geochemical behavior and toxicity in the environment, growing evidence suggests that their water–rock interaction behavior in contaminated rivers is quite different. Twenty-nine river water samples were collected between September and November 2018 from contaminated rivers around an antimony mine in Hunan Province, China. The concentrations of As and Sb were inversely proportional to the water flow distance. The rates and magnitudes of Sb decrease were more prominent than those of As. Silicate mineral dissolution from rocks such as silicified limestone increased the As and Sb concentration of in-mine-district (IMD) water. Dissolution of carbonate minerals, ion exchange, and competitive adsorption were the major water–rock interactions, resulting in rapidly decreasing As and Sb concentration in IMD direct impacted water and IMD indirect impacted water. The behaviors of As and Sb during water–rock interaction were dissimilar for areas dominated by carbonate and silicate minerals.  相似文献   

常德青峰煤矿地面钻孔注浆堵水实践   总被引：1，自引：0，他引：1       下载免费PDF全文

王强 《探矿工程》2011,38(10):63-65

简要分析了湖南常德青峰煤矿突水矿井的水文地质条件、突水因素,编制了注浆堵水方案,阐述了注浆堵水过程中注浆段的划分、浆液的配置、注浆结束的标准等工艺流程及所取得的成果。  相似文献   

淮南市朱集东矿井新生界松散层地下水开采保证程度评价     

王海波  李磊 《中国煤炭地质》2011,(9):42-44,51

利用淮南市朱集东矿井新生界松散层供水水文地质勘探成果和抽水试验资料,查明了区内新生界松散层供水含水层的供水水文地质条件,认为第一含水层埋藏浅,易受污染,水量随季节变化大,不宜作为生活饮用水供水水源,第三含水层水质较差,亦不作为生活饮用水供水水源,确定了第二含水层为矿区主要供水层位。采用解析法对第二含水层的水量进行了计算,并设计了布井方案,计算了井群水量;水位预报结果表明,开采50a后,3#、4#井中的水位最大降深为35.229m,小于其顶板埋深,说明拟建井群布置是合适的。评价结果为矿井供水设计提供了依据。  相似文献   

Variations of annual and seasonal runoff in Guangdong Province,south China: spatiotemporal patterns and possible causes   总被引：1，自引：0，他引：1  

Qiang Zhang  Mingzhong Xiao  Vijay P. Singh  Chong-Yu Xu  Jianfeng Li 《Meteorology and Atmospheric Physics》2015,127(3):273-288

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煤田三维地震叠前深度偏移技术及其应用     

高远  王琦  董守华  于鹏飞 《煤田地质与勘探》2011,39(3):71-73

三维地震叠前深度偏移可实现反射点的正确空间归位和真正的共反射点叠加,减小菲涅尔带的影响范围,大大提高地震资料的分辨率。论述了三维地震叠前深度偏移的成像原理和关键技术,并应用于实际地震资料的处理中。结果显示,小断点显示较叠前时间偏移剖面更为清晰,提高了煤田三维地震探测细微构造的能力,取得了较好的地质效果。   相似文献   

CSAMT法和TEM法在铜陵龙虎山地区隐伏矿勘探中的应用   总被引：3，自引：0，他引：3  

王大勇  李桐林  高远  方含珍  赵广茂 《吉林大学学报(地球科学版)》2009,39(6):1134-1140

CSAMT法是深部隐伏矿勘探工作的重要手段之一。将CSAMT法用于铜陵龙虎山地区隐伏矿勘察,在深入认识研究区的成矿规律和控矿因素的基础上,对该区的CSAMT数据进行了预处理和反演,对比TEM法反演结果,电性特征的统一性验证了CSAMT法反演结果的可靠性。联合CSAMT和TEM反演结果成功地分辨出侵入岩体和岩浆热液的运移通道,为该区寻找隐伏矿提供了有效的勘探手段。  相似文献   

淮北平原气象观测场与农田土壤湿度对比分析     

张学贤  李德  杨太明  祁宦  戚尚恩 《气象科技》2012,40(1):114-120

为研究在同一气候背景下气象观测场与农田两地土壤湿度之间的互可代替使用关系,对2006—2008年在宿州市气象观测场和农田内开展的3年土壤湿度平行对比监测试验所获取的每旬一次两地土壤湿度监测数据,采用对比差值率、相关性分析等数理统计手段,研究分析了两地不同季节不同深度的土壤湿度之间的关系。结果表明：春、夏、秋、冬4季气象观测场地与农田的土壤湿度具有一致性,均为统计正相关。春季,取土日前有降水时,气象观测场地与农田的土壤湿度的差异高于取土日前无降水时的差异。夏季,气象观测场地与农田0～30 cm土层之间的  相似文献