Adsorption Mechanism and Kinetic Characterization of Bituminous Coal under High Temperatures and Pressures in the Linxing-Shenfu Area     

TAO Chuanqi  WANG Yanbin  LI Yong  NI Xiaoming  GAO Xiangdong 《《地质学报》英文版》2020,94(2):399-408

The majority of coalbed methane(CBM) in coal reservoirs is in adsorption states in coal matrix pores. To reveal the adsorption behavior of bituminous coal under high-temperature and high-pressure conditions and to discuss the microscopic control mechanism affecting the adsorption characteristics, isothermal adsorption experiments under hightemperature and high-pressure conditions, low-temperature liquid nitrogen adsorption-desorption experiments and CO2 adsorption experiments were performed on coal samples. Results show that the adsorption capacity of coal is comprehensively controlled by the maximum vitrinite reflectance(Ro, max), as well as temperature and pressure conditions. As the vitrinite reflectance increases, the adsorption capacity of coal increases. At low pressures, the pressure has a significant effect on the positive effect of adsorption, but the effect of temperature is relatively weak. As the pressure increases, the effect of temperature on the negative effect of adsorption gradually becomes apparent, and the influence of pressure gradually decreases. Considering pore volumes of pores with diameters of 1.7-100 nm, the peak volume of pores with diameters 10-100 nm is higher than that from pores with diameters 1.7-10 nm, especially for pores with diameters of 40-60 nm, indicating that pores with diameters of 10-100 nm are the main contributors to the pore volume. The pore specific surface area shows multiple peaks, and the peak value appears for pore diameters of 2-3 nm, indicating that this pore diameter is the main contributor to the specific surface area. For pore diameters of 0.489-1.083 nm, the pore size distribution is bimodal, with peak values at 0.56-0.62 nm and 0.82-0.88 nm. The adsorption capability of the coal reservoir depends on the development degree of the supermicroporous specific surface area, because the supermicroporous pores are the main contributors to the specific pore area. Additionally, the adsorption space increases as the adsorption equilibrium pressure increases. Under the same pressure, as the maximum vitrinite reflectance increases, the adsorption space increases. In addition, the cumulative reduction in the surface free energy increases as the maximum vitrinite reflectance increases. Furthermore, as the pressure increases, the surface free energy of each pressure point gradually decreases, indicating that as the pressure increases, it is increasingly difficult to adsorb methane molecules.  相似文献   

The effects of simulated inundation duration and frequency on litter decomposition: A one-year experiment     

《Limnologica》2019

There is major uncertainty in the responses of litter decomposition to the inundation regimes in field studies, mainly because of the difficulties in identification of the individual effect of duration and frequency using field studies alone. The interactive role of inundation regime and litter quality also remains unclear. The responses of mass loss to simulated inundation regime (duration and frequency) and litter quality were investigated in leaves of Carex brevicuspis and leaves and stems of Miscanthus sacchariflorus from Dongting Lake, China. Three litter types differing in litter quality were incubated under seven different inundations over 360 days (three single inundations of 90, 180, and 360 days; three repeated 180-day inundations of 2, 3, and 6 times; and no inundations) in a pond near Dongting Lake. Initial N and P contents were highest in C. brevicuspis leaves, intermediate in M. sacchariflorus leaves, and lowest in M. sacchariflorus stems, whereas the organic C, cellulose, and lignin contents were ranked in the opposite order among the three litter types. Decomposition rate was highest in M. sacchariflorus leaves (0.00222–0.00900 day⁻¹), intermediate in C. brevicuspis leaves (0.00135–0.00500 day⁻¹), and lowest in M. sacchariflorus stems (0.00080–0.00100 day⁻¹). The decomposition rate of both C. brevicuspis and M. sacchariflorus leaves increased with increasing inundation duration or decreasing frequency. However, both duration and frequency of inundation had no effect on decomposition of M. sacchariflorus stems. At the end of the incubation, N mineralization was complete in leaf litters with increasing rates with increasing inundation duration or decreasing inundation frequency, but accumulation was found in M. sacchariflorus stems. Organic C decayed quickly in both leaf litters compared with the stem litter. These data indicate that inundation regime has no effect on the decomposition of refractory stem litter while prolonged and stable inundation stimulates the degradation of labile leaf litter.  相似文献   

由下扬子区海陆对比分析南黄海盆地下志留统烃源岩特征及其主控因素     

蔡来星  肖国林  郭兴伟  王蛟  吴志强  李宝刚 《吉林大学学报(地球科学版)》2019,49(1):39-52

针对南黄海盆地海相油气勘探的重大需求，在收集、整理下扬子苏、浙、皖地区地质和地化资料的基础上，依托科学钻探CSDP-2井岩心，系统对比了南黄海盆地与下扬子陆区早志留世古地理背景和沉积充填特征，进而利用一系列地化测试数据总结了南黄海盆地下志留统烃源岩特征并探讨其主控因素。研究结果表明：南黄海盆地大陆架科学钻探CSDP-2井目前已钻遇了坟头组和高家边组上部两套丰度很低的厚层、暗色（粉砂质）泥岩，其有机质类型主要为Ⅱ₂型，热演化程度已整体进入过成熟阶段；受控于全球海侵事件和扬子板块构造活动的发展阶段，早志留世初期深水陆棚环境逐渐向后期的浅水陆棚环境演变，加之早期较高的初级生产力和良好的保存条件，使得下扬子区高家边组下部烃源岩的品质明显高于上部，并以底部黑色笔石页岩段有机质丰度最高。因此，南黄海盆地高家边组底部理应存在一套优质烃源岩层，可作为下一步页岩气勘探的重点层位。  相似文献   

兰坪金顶超大型铅锌矿床含矿岩石沉积特征     

朱志军  张治波  郭福生 《沉积学报》2019,37(2):292-300

云南兰坪金顶超大型铅锌矿含矿岩石的成因一直存在正常沉积和非正常沉积两种对立的观点。为了查明其成因，从矿区开采露头和岩芯观察描述出发，以矿区填图为基础，通过对含矿岩石的岩石学特征、粒度和沉积构造等相标志分析，确定了金顶超大型铅锌矿含矿岩石属于湖底扇深水重力流沉积，并识别出非沟道体系的液化流和沟道体系的砂质碎屑流、浊流等类型，进一步划分出内扇、中扇和外扇三个亚相。该湖底扇平面展布为自矿区东部至西部粒度明显由粗变细，岩性由厚层-块状灰岩岩块构成的角砾岩相逐渐过渡到交错层理发育的中细粒砂岩相，其中砂质碎屑流沉积体具有良好的储集层物性特征，亦是重要的含矿岩石，具有广阔的勘探前景。  相似文献   

贵州赤水地区晚白垩世古流向特征及构造意义          下载免费PDF全文

曹锐  颜照坤  王智勇  强坤  陈修风 《沉积与特提斯地质》2019,39(2):78-83

贵州赤水地区位于四川盆地西南缘,晚白垩世时期该地区沉积了一套厚达1300m的陆相地层。本文通过地表露头的古流向野外观测和室内分析,详细研究赤水地区晚白垩世沉积充填过程及构造意义。赤水地区晚白垩世早期辫状河的古流向为自北东向南西,表明碎屑物源主要来自盆地北侧和东侧。根据物源、地层分布及区域地质背景推断,赤水地区晚白垩世的陆相沉积盆地属于陆内前陆盆地,陆内造山带位于盆地东侧。晚白垩世陆内前陆盆地的形成,可能受控于此阶段华南的构造挤压事件形成的陆内造山作用。  相似文献   

轨道交通沿线土地溢价归公的政策与实践——以东莞市为例     

林雄斌  余筱琪  陈伟劲 《热带地理》2019,39(5):732-741

轨道交通周边土地开发和溢价归公有助于缓解城市财政压力,推动公交都市建设。结合国外实施溢价归公的政策和实践模式,以东莞市为例,在资料收集、政策分析、文本和案例解读的基础上,探讨了中国城市政府在规划和建设轨道交通中,以土地溢价归公反哺轨道交通融资的政策安排和实施效果。结果表明：1）溢价归公的本质是以特定方式实现正外部效应的内部化,由于土地制度和税收体系的差异,欧美地区溢价归公主要依赖多样化的土地税收体系,而中国城市的实践主要借鉴了“轨道+物业”的联合开发模式;2）东莞市溢价归公策略的形成是综合开发规划编制和审批、沿线土地控制和储备、土地发展权转移、土地增值分配等核心环节有效协调的结果;3）东莞轨道交通沿线土地开发能形成可观的财政收益,潜在土地收益占轨道资金总需求的比例超过20%,但在实施过程中仍面临较大困难。东莞市案例能为其他城市轨道交通融资、土地开发和溢价归公的政策体系编制和有效实施提供一定的参考。  相似文献   

Geochemical characteristics of a pre-Middle Jurassic oceanic crust fragment from the Central Pontides in northern Turkey: Geodynamic implications on intra-oceanic subduction initiation     

《Chemie der Erde / Geochemistry》2020,80(1):125535

The Central Pontides (northern Turkey) is one of the key localities to understand the geodynamic evolution of the Palaeo- and Neotethyan oceans. It consists of the pre-Jurassic basement units, the Early Jurassic and the Early Cretaceous accretionary complexes, the widespread Middle Jurassic continental arc magmatics and the Late Jurassic to Tertiary cover units. The Early Cretaceous accretionary complex is represented by the Central Pontide Structural Complex and includes the Middle Jurassic oceanic units, which were metamorphosed during the Early Cretaceous. Apart from these oceanic units, a few metaophiolite and serpentinite fragments have been recognized within the basement units, which may represent the remnants of an older ocean. The pre-Middle Jurassic Devrekani Metaophiolite is the largest oceanic fragment and tectonically intercalated within/between the Devrekani Metamorphics and the Çangaldağ Metamorphic Complex. It is mainly composed of harzburgites, dunites with chromite veins and metagabbros, and cut by metabasaltic andesites and metadacites. Petrographically, the gabbro consists mainly of plagioclase and clinopyroxene, and displays phaneritic/porphyritic texture. In contrast, the metabasaltic andesite includes plagioclase and mica phenocrysts within a fine-grained groundmass. Also, the metadacite is composed predominantly of quartz, plagioclase, and mica minerals. Two different magmatic groups belonging to completely different tectono-magmatic settings have been geochemically determined based on the immobile trace element systematics. The metadacites and metabasaltic andesites are akin to continental arc magmatics and characterized by negative Nb and Ta anomalies and depleted HFSE relative to Th and La contents. However, the metagabbro samples display the geochemical signatures of boninitic rocks and characterized by highly depletion in HFSEs and REEs relative to N-MORB. The Devrekani Metaophiolite in the Central Pontides may represent another remnant of pre-Middle Jurassic oceanic crust generation and can be north-eastward continuation of the Permian-aged Almacık complex and the Boğazköy Metaophiolite fragment in the western Sakarya Composite Terrane. It may have been cut by intrusions of the extensive Middle Jurassic continental arc magmatism after its imbrication within the basement unit. The presence of pre-Middle Jurassic oceanic units may indicate that the Paleozoic ocean may have survived as the Jurassic Intra-Pontide Ocean between the Scythian Platform and Sakarya Composite Terrane during the Mesozoic time. Thus, the Intra-Pontide Suture may normally include the Palaeozoic and Mesozoic remnants of the long-lived northward subducting Tethyan ocean.  相似文献   

甘肃红石泉地区伟晶状白岗岩LA-ICP-MS锆石U-Pb年龄与铀成矿关系     

戚佳伟  张树明  杨春四  蓝德初  王利玲 《地质通报》2019,38(4):562-572

白岗岩是大陆碰撞过程中陆壳低比例熔融的产物,与铀及多金属矿床在成因上密切关联。甘肃红石泉铀矿床含矿主岩为伟晶状白岗岩,前人对伟晶状白岗岩的成岩年龄研究较少且精度有限,影响了对铀矿床成因和构造背景的深入认识。对甘肃红石泉铀矿床含矿主岩——伟晶状白岗岩开展了高精度LA-ICP-MS锆石U-Pb同位素测年,获得伟晶状白岗岩成岩平均年龄值为2493.5Ma,形成时代为新太古代晚期—古元古代早期。认为伟晶状白岗岩应属于新太古代晚期-古元古代早期华北克拉通微陆块拼合作用后期的产物,同时也是华北克拉通约2.5Ga岩浆构造热事件在西部地块的响应。伟晶状白岗岩与红石泉铀矿床铀成矿没有直接成因关系,只是作为铀矿的含矿主岩。  相似文献   

Feedback control system for blow-out preventer positioning     

《Applied Ocean Research》2019

During the drilling of ultra-deep-water subsea petroleum wells, a blow-out preventer (BOP), a piece of safety equipment, must be assembled on the wellhead. The BOP is suspended using the drilling riser during the wellhead approach operation, and the riser's top end is connected to the floating platform rig. This article presents a feedback control system for the automatic approach of the BOP to the wellhead. Compared to state-of-the-art controls, ours does not require ancillary thrusters installed alongside the riser nor inclination sensors atop of the drilling riser. Additionally, our proposed control embeds a closed-loop dynamic positioning system, thus retaining the characteristics of the original control system and adding an extra closed-loop. This eases implementation of the BOP approach control to an existing platform. To calculate the optimal gains for the BOP controller, we assume a linear system for the riser, including only the pendulum-shape. The simulation is carried out using nonlinear models for both riser and floating platform. We assume an International Towing Tank Conference standard semi-submersible platform, coupled with a 3000-m free-hanging vertical riser for the time-domain simulation. The results show the BOP tracking to be a step-shaped input signal under current and wave loads. A discussion of the performance of feedback control under different environmental loads is also included.  相似文献   

基于ARIO模型的震后重建施工现场安全管理方法          下载免费PDF全文

顾连胜 《地震工程学报》2018,40(6):1350-1355

为提高受灾地区重建安全性，提出基于ARIO模型的震后重建施工现场安全管理方法。在将建筑设计影响因素划分为直接因素与间接因素的基础上，将ARIO模型引入震后重建施工现场安全管理中，利用其分析施工过程中各产业技术与该地区经济的联系，在考虑经济因素的基础上实现震后施工现场安全管理。设计并构建施工初期数据采集系统、施工前安全管理系统、施工过程中安全管理系统，将ARIO与VR结合，使各系统运行时施工人员能够在虚拟漫游中以第一视角完成虚拟施工，掌握整个工期、流程、所用设备等有关信息，并由辅助专家作出相应指导，实现震后重建施工现场安全系统化管理。提出施工安全辅助建议，以完善灾后重建安全管理方法。实验结果表明，该方法运行后安全系数大于当前方法，其科学性和鲁棒性较强。  相似文献