排序方式: 共有40条查询结果,搜索用时 216 毫秒
1.
报道了大兴安岭东部博克图地区二支沟岩体的岩相学、岩石地球化学以及地质年代学特征,探讨了它们的形成时代、岩石成因以及成岩构造背景。根据LA-ICP-MS U-Pb定年结果,二支沟岩体的侵位年龄为(317.2±2.2) Ma与(319.2±2.3) Ma。二支沟岩体岩性为花岗闪长岩,具高硅、富碱,低MgO、CaO的特征,属于准铝质-过铝质,高钾钙碱性I型花岗岩。二支沟岩体的Ba/Nb=70.44~98.20,Ba/La=17.85~28.12,δEu具负异常,暗示源区可能为壳源,存在少量地幔物质与强氧化流体混入。此外,二支沟岩体具有高Sr和低Y、Yb的特征(Sr含量>400×10-6,Y含量<18×10-6,Yb含量<1.9×10-6),与埃达克岩类似,但其更为富钾,表明二支沟岩体具有C型埃达克岩特征。二支沟岩体富集大离子亲石元素(LILE) Rb、K、Ba、Th,相对亏损Ta、Nb、P、Hf、Zr等高强场元素(HFSE),其 (La/Yb)N=12.05~18.03,轻稀土元素(LREE)富集,重稀土元素(HREE)亏损。其Rb、Ba含量和Rb/Yb(51.49~148.93)、Ba/Yb(430.17~698.83)比值明显高于MORB,与海拉尔盆地和西藏冈底斯埃达克岩相似,表明其成因为底侵作用新生的增厚的玄武质下地壳的熔融。研究区晚石炭世岩浆形成于造山阶段挤压环境。额尔古纳-兴安地块与松嫩地块于晚石炭世((317.2±2.2) Ma之后)构造背景由碰撞造山晚期的挤压、地壳加厚向造山后期的伸展、垮塌的环境转换,并向更加稳定的板内构造环境演变。 相似文献
2.
吡啶偶氮类试剂在光度分析中的应用进展 总被引:1,自引:1,他引:0
吡啶偶氮类试剂是一类性能优良的络合滴定指示剂和光度显色剂,迄今已合成了200余种,在分光光度分析测定各种金属离子方面得到了广泛的应用。为了进一步改善这类试剂的灵敏度和选择性等分析性能,近年深入研究了吡啶偶氮类试剂的结构与性能的关系,进而相继开发出一系列性能优异的吡啶偶氮类试剂。文章综述了1990—2010年以来常见的吡啶偶氮类试剂及其在分光光度分析测定金属离子方面的进展。从反应体系、最大吸收波长、灵敏度、线性范围等方面归纳了吡啶偶氮类试剂在实际样品中的应用情况,为此类试剂的开发和应用提供一些理论依据。 相似文献
3.
The size effect of copper wire radius (0.04–0.82 mm) on the diffusion-limited current density of an oxygen reduction reaction in stagnant simulated seawater (naturally aerated 0.5 mol/L NaCl) is investigated by potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) and compared with the results obtained in 0.5 mol/L H2SO4. In the oxygen diffusion-limited range, size effect is found to occur independent of electrolytes, which is attributed to non-linear diffusion. Additionally, to sati... 相似文献
4.
《Geography and Natural Resources》2008,29(3):297-300
We examine the history of the establishment and evolution of the Institute of Geography RAS. We provide an overview of the major geographical investigations carried out by the Institute on the territory of Asian Russia during 1920–2000. The most significant scientific works published on the basis of research results are pointed out. 相似文献
5.
含油废水污染范围广,对人类和生态环境危害大。采用常规方法(如浮选法、絮凝法、电化学法、膜分离法和生物法)处理的除油率不高于91%,成本较高,因此急需开发一种高效低廉的吸附剂。膨润土是一种优良的吸附剂,但用其直接处理含油废水的效果较低。本文选用壳聚糖和PDMDAAC两种有机物作为改性剂,对钠基膨润土改性,使膨润土能有效地处理含油废水。通过实验比较了两种有机改性膨润土处理含油废水的最佳去除条件,探讨了表征对其吸附性能的影响。去油效果结果表明:壳聚糖改性膨润土的除油率可达87.8%,PDMDAAC改性膨润土的除油率可达89.3%,处理所需时间少于15 min;除油效率和处理时间都优于常规方法。吸附性能表征结果显示,两种改性剂均以负载的方式和钠基膨润土颗粒结合,吸附性能良好;相比而言,PDMDAAC改性膨润土的处理效果比壳聚糖改性膨润土更好。PDMDAAC应用于含油废水的处理,具有成本低、效率高、操作简单的特点,在含油废水处理领域具有较好的应用前景。 相似文献
6.
7.
8.
《Applied Geochemistry》2005,20(1):123-133
The use of the organoarsenical roxarsone, added to poultry feed to increase weight gain, results in elevated As concentrations (10–50 mg/kg) in poultry litter. This litter is used extensively as fertilizer in agricultural regions. The authors investigated the sources and sinks of As within the vadose zone of an agricultural watershed in the Shenandoah Valley of Virginia, USA, an area of intense poultry production. Batch experiments were constructed to examine adsorption and biotransformation characteristics of roxarsone within the Ap and Bt soil horizons of Frederick series soils, common in the Shenandoah Valley. Roxarsone exhibits weak adsorption to the Ap soils; however, it is rapidly biotransformed to As(V) in this soil horizon. Although the Bt horizon demonstrated strong adsorption of roxarsone and thus may act as a sink for As species, soil water data collected from lysimeters at an agricultural field site suggest that As, as As(V), is mobile in the Bt soil water. It is unclear if this mobilization is due to competitive reactions with phosphate or organic acids, also present in litter. These results have implications for As cycling within poultry-dominated watersheds. For watersheds that have experienced years of litter application, As and other litter-associated species will be attenuated in soils through adsorption to mineral surfaces, but a variety of geochemical processes, such as competitive adsorption, may allow for enhanced transport of As through the vadose zone and into aquifer systems. 相似文献
9.
稀土作为一种重要的不可再生资源,在各行业的应用正逐渐被人们所重视。色谱技术以其快速、高效、自动化程度高等优势已成为稀土元素分离分析的主要方法。文章总结了纸色谱法、薄层色谱法、气相色谱法、超临界色谱法、高效液相色谱法、毛细管电泳法等色谱法在稀土元素分离分析中的应用及研究概况。其中,纸色谱法因展开时间过长,分离效果不理想已很少应用;薄层色谱法因其操作方便、设备简单、显色容易等优点,可用于稀土元素分离分析的初步检测;气相色谱法由于对样品热稳定性的限制,以及因常用的β-二酮类稀土螯合物配体存在分辨率差和吸附等问题也很少应用;超临界色谱法在分离稀土元素络合物中分离效果较好,但是仪器难以普及,限制了技术的发展;高效液相色谱法因分离效率高、重复性好、自动化操作等优点已成为目前稀土元素分离分析的主要方法;毛细管电泳法具有高效、样品及试剂用量少、操作模式灵活等优点,在稀土元素分离分析方面更具有广阔的发展空间。 相似文献
10.
Better understanding of plant community structure in relationship to land use history and nitrogen (N) will facilitate grassland conservation and projections of community succession under future N deposition. We conducted a field experiment in northern China to examine the influence of 2-year N addition on species composition and community structure in three temperate grasslands with different land use history: steppe fenced for two years (ST), steppe fenced for five years (SF), and old field grassland fenced for five years (OF). The results showed previous farming reduced species diversity and plant cover, which is mainly caused by decrease in perennial grasses (PG) and forbs (PF). Nitrogen addition increased plant cover, especially the PG cover, but had little effects on species diversity. Nitrogen enrichment also has a tendency to alter community composition by decreasing proportional cover of PF but increasing that of PG and annuals and biennials (AB), suggesting enhanced dominance of PG under increasing N deposition. Irrespective of the short-term (2 years) experimental periods, our findings highlight the dominant role of land use history in structuring plant community, and have valuable implications for grassland conservation and model projections of ecosystem succession under global scenarios of N deposition in the semi-arid grasslands. 相似文献