Atmospheric Reactive Nitrogen Cycle and Stable Nitrogen Isotope Processes: Progresses and Perspectives   总被引：1，自引：1，他引：0  

Tao Zhou  Zhuang Jiang  Lei Geng 《地球科学进展》2019,34(9):922-935

Oxidized reactive nitrogen in the atmosphere mainly consists of nitrogen oxides (NO _X =NO+NO₂, NO₃) and nitric acid. The atmospheric cycling of NO _X influences the formation of ozone and hydroxyl radicals that are important for atmospheric oxidation capacity. Nitric acid, the final product of NO _X oxidation, not only is an important component of particulate pollutants, but also has a direct impact on the ecosystem through dry and wet deposition. The stable nitrogen isotope (δ¹⁵N) shows the potential to study reactive nitrogen cycle, and to trace the emission, transport and deposition of reactive nitrogen from local to global scales. Here, we reviewed previous studies using δ¹⁵N to investigate NO _X emission and atmospheric reactive nitrogen cycle, and discuss the uncertainties of δ¹⁵N signatures of different NO _X sources from two aspects: NO _X generation mechanism and NO _X collection methods. We also discussed the nitrogen isotope fractionation and the consequences during the conversions of NO _y molecules. We ended up with discussions on the possibility of using δ¹⁵N to trace NO _X emissions. Although there are still large uncertainties in quantifying and tracing NO _X emissions using nitrogen stable isotopes, such isotope tool is efficient enough to trace reactive nitrogen cycles in the atmosphere. On the basis of this, we proposed that we can combine atmospheric chemistry transmission models with isotope tracers to improve our understanding of regional and global atmospheric reactive nitrogen cycle regarding the fluxes of different emission sources, their atmospheric transformation, etc.  相似文献   

Volatile element chemistry during accretion of the earth     

《Chemie der Erde / Geochemistry》2020,80(1):125594

We review some issues relevant to volatile element chemistry during accretion of the Earth with an emphasis on historical development of ideas during the past century and on issues we think are important. These ideas and issues include the following: (1) whether or not the Earth accreted hot and the geochemical evidence for high temperatures during its formation, (2) some chemical consequences of the Earth’s formation before dissipation of solar nebular gas, (3) the building blocks of the Earth, (4) the composition of the Earth and its lithophile volatility trend, (5) chemistry of silicate vapor and steam atmospheres during Earth’s formation, (6) vapor - melt partitioning and possible loss of volatile elements, (7) insights from hot rocky extrasolar planets. We include tabulated chemical kinetic data for high-temperature elementary reactions in silicate vapor and steam atmospheres. We finish with a summary of the known and unknown issues along with suggestions for future work.  相似文献   

Detection of coffee berry necrosis by digital image processing of landsat 8 oli satellite imagery     

《International Journal of Applied Earth Observation and Geoinformation》2020

Coffee berry necrosis is a fungal disease that, at a high level, significantly affects coffee productivity. With the advent of surface mapping satellites, it was possible to obtain information about the spectral signature of the crop on a time scale pertinent to the monitoring and detection of plant phenological changes. The objective of this paper was to define the best machine learning algorithm that is able to classify the incidence CBN as a function of Landsat 8 OLI images in different atmospheric correction methods. Landsat 8 OLI images were acquired at the dates closest to sampling anthracnose field data at three times corresponding to grain filling period and were submitted to atmospheric corrections by DOS, ATCOR, and 6SV methods. The images classified by the algorithms of machine learning, Random Forest, Multilayer Perceptron and Naive Bayes were tested 30 times in random sampling. Given the overall accuracy of each test, the algorithms were evaluated using the Friedman and Nemenyi tests to identify the statistical difference in the treatments. The obtained results indicated that the overall accuracy and the balanced accuracy index were on an average around 0.55 and 0.45, respectively, for the Naive Bayes and Multilayer Perceptron algorithms in the ATCOR atmospheric correction. According to the Friedman and Nemenyi tests, both algorithms were defined as the best classifiers. These results demonstrate that Landsat 8 OLI images were able to identify an incidence of the coffee berry necrosis by means of machine learning techniques, a fact that cannot be observed by the Pearson correlation.  相似文献   

1951—2018年衢州市椪柑采摘期连阴雨天气变化特征     

汪晨  毛程燕  龚理卿  王健疆 《气象与环境学报》2021,37(2):71-76

基于1951—2018年衢州市椪柑采摘期降水量、雨日、日照时数、相对湿度等逐日气象资料,应用统计分析和小波分析方法,分析椪柑采摘期连阴雨天气变化特征及其大气环流背景。结果表明：1951—2018年衢州椪柑采摘期连阴雨日数、次数和强度呈略微增加趋势、滑动3 d无雨次数呈减少趋势;滑动3 d无雨次数存在明显的5 a、7 a和15 a左右的年际和年代际周期变化规律,并且均呈现缩短趋势;椪柑采摘期连阴雨较强年亚欧地区呈两高一低的径向型环流,强冷空气南下活动较频繁、东移缓慢,偏南暖湿气流活跃,致使冷暖空气在中国长江中下游地区长时间交汇,导致连阴雨天气。  相似文献   

大连地区雷暴时空变化特征及其严重年大气环流背景分析     

王秀萍  金巍  王岩  侯彦泽  高磊 《气象与环境学报》2019,35(2):61-68

利用1961—2013年大连地区3测站逐日地面雷暴观测资料及1948—2016年NCEP/NCAR再分析月平均资料,采用线性趋势估计和合成分析方法分析了大连地区雷暴日数的时间和空间分布规律,并进一步探讨雷暴严重年5—9月平均大气环流背景特征。结果表明:大连地区雷暴具有明显的地域特征,空间分布主要呈现北部内陆地区多,南部沿海地区少的特点;除2月外,各地其余月份均可发生雷暴,7月和8月达到高峰值,雷暴集中发生在5—9月,雷暴具有较强的季节性,夏季6—8月最多,冬季很少出现雷暴;年平均雷暴日数总体呈减少趋势,其中北部的减少趋势尤为显著;雷暴初日多出现在4月,终日多出现在10月,初日较终日稳定,无论初日和终日均以北部地区较南部地区稳定,各地雷暴初日显著提前,终日推迟不显著,但仅有大连终日推迟趋势显著;雷暴初日和终日北部地区对应的候平均气温阈值分别为-1℃和10℃,南部(东部)地区对应的候平均气温阈值分别为6℃(-1℃)和3℃(8℃);多雷暴年,高层500 hPa蒙古低涡异常偏强,副热带高压偏西偏北,低层850 hPa偏南风水汽输送和大连上空整层垂直上升运动均异常偏强,这些有利于雷暴日数的增多,而少雷暴年与多雷暴年特征基本相反。  相似文献   

宁波地区空气质量及大气自净能力海陆差异对比     

杨栋  朱佳敏  姚日升  涂小萍 《气象与环境学报》2019,35(3):52-59

以镇海、奉化分别作为宁波沿海和内陆空气质量代表站。基于代表站2013-2017年污染物资料和2015年12月至2017年2月冬季激光雷达资料,对比分析宁波地区沿海和内陆站点的空气质量差异;利用NCEP的GDAS(Global Data Assimilation System)资料和ERA-Interim高分辨率再分析资料评估两地气溶胶来源及大气自净能力差异。结果表明:宁波沿海和内陆地区中度及以上污染主要集中于冬季,冬季首要污染物以PM2.5为主;镇海NO2浓度较奉化显著偏高,而两地PM2.5 和PM10 浓度差异较小。冬季镇海和奉化3km以下都存在消光系数大的气溶胶集中层,镇海3km内消光系数平均值较奉化偏高约40%。两地中度及以上污染时,镇海和奉化的气溶胶粒子主要来自宁波西北方向的内陆地区,比例分别为90%和63%,镇海地区其余10%左右来自近距离低空偏东气流的输送,而奉化地区有37%来自浙江西南部的短距离输送。冬季当宁波地区出现区域性优和中度以上污染时,浙江北部沿海分别盛行东北风和西北风,空气质量优时混合层内平均风速大于中度以上污染时。浙江省大气自净能力比值呈自西北向东南减小,宁波地区优等空气质量大气自净能力约为中度以上污染的 1.5倍。大气自净能力在不同空气质量等级下差异显著,可作为大气污染发生、发展和消退判定的参考依据。  相似文献   

六盘山区夏秋季大气水汽和液态水特征初步分析     

田磊  桑建人  姚展予  常倬林  单新兰  曹宁  孙艳桥 《气象与环境学报》2019,35(6):28-37

六盘山区是中国典型的农牧交错带和生态脆弱带,也是黄土高原重要的水源涵养地、生态保护区及国家级扶贫开发区。利用2017年6-11月隆德气象站地基多通道微波辐射计资料,结合同期平凉探空站及隆德地面降水等观测资料,分析了六盘山区夏秋季大气水汽、液态水变化特征。结果表明：六盘山区夏秋季在降水天气背景下,大气水汽含量和液态水含量均较高,分别为无降水天气背景下的1.4倍和7.0倍;降水天气背景下水汽在5000 m以下有明显的增加,且在此高度范围内的水汽密度随高度的递减率比无降水天气背景下明显偏小;各高度层的液态水相比无降水天气背景下均有明显增大,除6月外,主峰值均出现在0℃层高度层以下。六盘山区夏秋季各月中,6-9月。大气水汽含量高值区均出现在正午到傍晚时段,低值区均出现在日出前后;液态水含量在日出前、午后及傍晚分别出现峰值,最明显的峰值出现在午后。对一次对流性降水天气过程分析后发现,降水发生前40 min大气水汽含量和液态水含量出现两次明显的跃增,水汽向上输送不断加强,2500-7500 m高度的相对湿度明显增大。  相似文献   

Advances and Trends in Atmospheric Measurement by Smartphones*     

Xichuan Liu  Taichang Gao  Binsheng He  Lei Liu  Min Yin  Kun Song 《地球科学进展》2018,33(12):1223-1236

With the development and popularization of smartphones and embedded sensors, a non-professional atmospheric measurement method by using smartphones carried by the public has been proposed recently. Without extra dedicated instrument, this method has many advantages, such as low hardware cost, high spatio-temporal resolution, and wide coverage, and it can supplement the professional atmospheric measurement methods, which has broad applications in the meteorological operation, scientific research, public service, and other fields. At present, the research on the non-professional atmospheric measurement in China is limited. In order to make full use of this method, this paper briefly outlined the states of existing smartphones and embedded sensors, highlighted the measurement of precipitation, air temperature, pressure, aerosols, and radiation by smartphones. To promote the development of smartphones for atmospheric measurement, future research should focus on mechanism study, available sources exploration, data quality control, big data processing, joining and matching with operation, research and service, etc.  相似文献   

Objective Analysis on Large-scale Circulation Type and Its Links to Precipitation over China     

Liang Chen  Jianping Duan  Zhuguo Ma 《地球科学进展》2018,33(4):396-403

Atmospheric circulation anomaly is a direct cause of weather and climate change. In the past, most researches for the relationship between Weather Type (WT) and precipitation have mainly focused on the subjective classification and diagnosis. Compared to the subjective analysis, objective classification uses more consistent index and standard unification, thus, we can get more WTs, and it has been widely used in many areas. By using daily 12UTC Sea Level Pressure (SLP), Precipitable Water (PW), and 700 hPa wind speed (UV700) data from ECMWF’s Interim Reanalysis, the classification of WTs over China was performed with the method of obliquely rotated T-mode principle component analysis. WT and its link to precipitation over China were further analyzed. The results show that the influence of different WTs on precipitation is not uniform over China, and also show distinctly difference in different seasons. A common feature is that WTs great impact on the regions and months with large precipitation, while less impact on regions and months have with less precipitation. In addition, precipitation trends originating from WT intensity changes are much more deterministic, significant, and predictable than trends from WT frequency changes.  相似文献   

1961-2020年郑州主城区大气自净能力变化特征分析     

刘美  姬兴杰  田力  丁亚磊  左璇 《气象与环境学报》2022,38(3):93-100

利用郑州市主城区1961—2020年气象观测资料和2014—2018年空气质量监测数据,分析了郑州主城区大气自净能力指数的长期变化趋势与影响因子以及2014—2018年主城区大气自净能力与PM_(2.5)的关系。结果表明:郑州主城区大气自净能力指数30 a气候均值为4.42 t·(d·km^(2))^(-1),春季大气自净能力最强,为5.20 t·(d·km^(2))^(-1);秋季大气自净能力最弱,为3.88 t·(d·km^(2))^(-1),不利于对大气污染物的清除。1961—2020年郑州主城区大气自净能力呈显著的减弱趋势,其中1969年最强为6.85 t·(d·km^(2))^(-1),2020年最弱为3.06 t·(d·km^(2))^(-1)。影响因子中,1961—1980年混合层厚度与大气自净能力指数呈正相关;日平均风速≥2.5 m·s^(-1)的日数和小风日数与大气自净能力分别呈正、负显著相关;大气自净能力指数与降水日数显著相关,2015年后偏强降水日数的增加对大气自净能力在同时期的增强有一定影响。此外,研究还表明主城区大气自净能力和PM_(2.5)浓度存在显著的负相关,说明大气自净能力强时,对应的PM_(2.5)浓度低,环境空气质量趋好。  相似文献