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1.
Understanding the hydrological processes of colloids within the karst vadose zone is vital to the security of karst groundwater and providing appropriate paleohydrological explanations of colloid-facilitated metals in speleothem. This study addresses the mobilization mechanisms driving colloidal organic matter (COM) transport in the karst vadose zone using a 15-year long monthly monitoring dataset from a cave drip point (HS4) in Heshang Cave, Qingjiang Valley, China. Variations in COM concentrations were reported as the fluorescence difference values of raw and filtered (<0.22 μm) samples at an excitation wavelength of 320 nm and emission wavelength of ~400 nm. A fluorescence humification index (HIX) lower than 0.8 and an autochthonous index (BIX) higher than 1.2 indicated that the origin of COM was mainly from the karst vadose zone, rather than the soil zone. The COM concentration varied from 0.001 to 0.038 Raman Unit (RU), with evident seasonal fluctuations. Rising limbs for COM values occurred prior to rising limbs within a dripwater hydrograph; moreover, the COM peak values corresponding to the beginning of the increasing hydrograph generally suggested that the mobilization of COM reflected the movement of the air–water interface (AWI) in the karst vadose zone rather than rainfall intensity or flow velocity. COM peak values were positively correlated with the antecedent drying duration and negatively correlated with HIX values. These phenomena may be explained by the increased amount of organic matter that was aggregated and absorbed on the surface of carbonate in the karst vadose zone during a longer drying duration. Moreover, the longer drying duration was also beneficial to autochthonous biological activity, which subsequently decreased the HIX value of the organic matter in the karst vadose zone. The movement of AWI and the drying duration are both controlled by the outside weather conditions. This study is therefore conducive to evaluating the security of karst groundwater in response to climate change, and challenges prevailing paleoclimate interpretations of colloid-facilitated metal abundance timeseries reported from speleothems.  相似文献   
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近年来煤矿奥灰治水注浆定向钻进技术发展迅速,多分支超深水平注浆孔数量激增。在水平注浆孔施工过程中,普遍存在地层漏失量大,泥浆突然失返,小径钻孔裸孔段长,水平段孔眼轨迹复杂,控制难度大,靶点技术误差要求严,定向仪器、工具等价格昂贵,施工风险相对较高,极易发生埋钻卡钻事故。一旦发生卡钻事故,就会面临着处理周期长、处理难度大等问题,传统的卡埋钻处理方法在水平注浆孔中应用效果不明显。通过采用空压机输送压缩空气,破坏水平孔着床的沉砂结构,将着床的沉砂吹出孔外或吹入地层裂隙,成功地实现了解卡。总结了水平注浆孔施工中卡埋钻事故的预防措施。  相似文献   
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2012-2018年巢湖水质变化趋势分析和蓝藻防控建议   总被引:4,自引:3,他引:1  
巢湖自1990s中期至2012年间水质明显改善,但是近年来水质改善效果变缓,2018年蓝藻水华面积显著增加,为有效评估巢湖水体环境的变化,通过对20122018年巢湖17个点位的逐月调查数据分析阐述了近年来巢湖水质和藻情的变化特征,并在流域空间尺度上分析了巢湖流域水污染治理的进展和不足,为后续治理方向的调整和确定提供支撑.20122018年湖区调查数据显示:巢湖湖体总磷和总氮浓度显著升高,铵态氮浓度显著下降,水华蓝藻总量显著升高.在空间上,各污染指标水平呈现由西向东呈逐渐降低的趋势,但是各指标在不同湖区随时间的变化趋势差异明显,西部湖区的总磷、总氮和水华蓝藻指标近年来略有下降或持平,中部和东部湖区则显著升高,所以巢湖湖体总氮和总磷浓度的升高主要源于中、东部湖区的升高,这也是这两个湖区水华蓝藻变动的主要驱动因素.主要入湖河口数据显示:西部4条主要入湖污染河流(南淝河、十五里河、塘西河和派河)水质明显改善,但仍处于较高污染水平,中东部入湖河流(兆河、双桥河和柘皋河)总磷浓度明显升高,是中东部湖区水体营养盐升高的主要原因.中东部河流入湖污染的增加加剧了该区域湖体的富营养化水平,尤其是总磷浓度明显提升,导致中东部湖区夏季水华蓝藻的优势种从鱼腥藻种类演替为微囊藻种类.夏季微囊藻的大量繁殖,使得2018年巢湖中东部湖区部分月份水华面积异常增高.因此,巢湖流域的治理应该在持续强化流域西部合肥市污染治理的同时,增加对流域中部和东部治理的关注和投入.  相似文献   
5.
《China Geology》2020,3(1):124-136
Utilization of urban underground space has become a vital approach to alleviate the strain on urban land resources, and to optimize the structure and pattem of the city. It is also very important to improve the city environment, build livable city and increase the capacity of the city. Based on the analysis of existing evaluation methods and their problems, a method for evaluating underground space resources based on a negative list of adverse factors affecting underground space development is proposed, to be primarily used in urban planning stages. A list of the adverse factors is established, including limiting factors, constraining factors and influencing factors. Taking Xi’an as an example, using a geographical information system platform, a negative list of adverse factors for the underground space resources in Xi’ an City are evaluated, and preventive measures are proposed. Natural resources, exploitable resources, and the potential growth of exploitable underground space resources are evaluated. Underground space assessment in the different development stages of the city, collaborative utilization and safety evaluation for multiple subsurface resources, environmental impact and assessment, as well as evaluation methods based on big data and intelligent optimization algorithms are all discussed with the aim of serving city planning and construction.  相似文献   
6.
Dust, as a source of trace metal elements, affects the health of society. The spatial and temporal concentrations of dust‐bound trace metals (Cd, Pb, Ni, Zn, Cu, and Mn) in Kuhdasht watershed (456 km2), Lorestan Province, Iran, is investigated. Dust is collected using glass traps placed in ten research stations in the region. The spatial and temporal distribution of dust trace metals are plotted using ARC‐GIS. The highest and the lowest concentrations of Zn (9751150 mg kg?1), Pb (46.352.9 mg kg?1), and Cd (2.443.30 mg kg?1) are obtained in winter, of Ni (98110 mg kg?1) and Cu in autumn (16.053.5 mg kg?1), and of Mn in summer (385505 mg kg?1). The spatial concentrations of dust‐bound trace metals indicate all, except Cu, show a decreasing trend from the mountains toward the plains, similar to that of soil and of dust, except for Zn, which shows higher concentrations in dust than in soil. The potential sources of dust‐bound trace metals and their rate of contamination are also investigated using the enrichment and contamination factors. The major sources of Cd and Zn in the dust of watershed are due to anthropogenic activities or from activities outside the borders.  相似文献   
7.
As a signatory to the Paris Climate Agreement, Australia committed to reduce emissions significantly by 2030. In a country highly urbanised and dependent on fossil fuels as its primary energy source, one key avenue for meeting these commitments is energy transition in the built environment. Australia has emerged as a leader in the design and construction of high-performance buildings in the premium commercial office sector. In this paper, we address a significant gap in understanding the diverse mechanisms through which building energy transition is being constituted in this sector, focusing on Sydney and Melbourne. In the absence of substantive publicly available data, we draw on mixed methods comprising a database developed around high-performing CBD office buildings and qualitative interviews with a range of sectoral stakeholders. We characterise the building stock in each city, and document five trends constituting energy transitions. We demonstrate that building energy transitions are not only shaped purposefully by dominant governance regimes but also by opportunistic responses to specific material and commercial conditions and legacies in each city. Thus the urban built environment affords significant opportunity for energy transitions, but pathways towards such transitions are necessarily multiple and ultimately shaped by material as well as institutional geographies.  相似文献   
8.
随着化肥、农膜等在农业生产中的过量投入,耕地面源污染的程度随之加重。文章选取塔里木河流域上游和田地区为研究区域,依据P-S-R框架理论,构建和田地区耕地面源污染生态风险评价指标体系,加入土壤理化数据,使用生态风险评价模型对和田地区1980 年及2016 年耕地面源污染状况进行生态风险评价,运用耕地生态风险模型、生态风险转移矩阵、Arcgis分析和田地区耕地面源污染时空分异状况。研究结论如下:和田地区1980 年耕地生态风险等级均为II级或III级,呈“中间高,两侧低”分布;2016 年耕地生态风险等级上升至IV级或V级,呈“倒W型”分布,各县耕地面源污染程度较1980 年均有较大幅度的上升,其中墨玉县和于田县在2016 年耕地生态风险等级达到最高的V级,而民丰县因自身生态环境的强脆弱性,同样需要提高关注。根据面源污染“从源头治理”的原则,应切实推进和田地区耕地生态环境保护与治理,提高政府重视程度,增强技术指导,开展试点工作,改善和田地区耕地面源污染现状。  相似文献   
9.
利用乌鲁木齐市4座10层100 m梯度气象塔2013年6月~2014年4月气象观测资料和7个环境监测站[WTBX]AQI[WTBZ]资料,计算并分析了大气混合层厚度和稳定度特征,探讨了大气混合层厚度和稳定度与污染的关系。结果表明:乌鲁木齐市混合层厚度夏季郊区高、城区低,冬季从南郊—城区—北郊随地势降低依次降低;夏季和冬季分别在1 559~1 772 m和526~1 156 m之间。地面至2 km以上每500 m高度间隔统计混合层厚度,500~1 000 m出现频率最多;月变化为6~9月基本在500 m以上,且每个高度区间其概率均超过10%,10月~次年2月1 500 m以上区间概率明显减小;日变化为中午13:00~16:00达到最高值,下午和傍晚迅速下降。白天较大的感热输送提供充足的热力条件,这也体现出白天以不稳定层结为主,夜间则以稳定层结为主。大气稳定度分类结果,夏季郊区和城区不稳定(A~C类)所占比例差不多,冬季北郊稳定(E、F类)所占比较最大、城区最弱。[WTBX]AQI指数冬季最大,从南郊—城区—北郊依次增大,这与采暖期污染物多、南郊比北郊地势高有利于扩散输送有关。总体来看,乌鲁木齐大气混合层厚度空间分布与气象要素、大气稳定度、地形等密切相关,对AQI[WTBZ]指数分布有重要影响,这对近地层大气污染状况预报有着重要的指导意义。  相似文献   
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总磷是长江流域水环境污染的首要超标因子,岷江作为长江上游流量最大的支流,总磷污染严重,对长江总磷污染贡献较大。为了解岷江流域总磷污染,采用排污系数法,计算得到2016年岷江流域污染源总磷入河量为1 154 t,以农村生活污染负荷占比最高(51.3%),其次为城镇生活源(28.7%)、农业非点源(8.24%)、工业源(9.57%)、畜禽养殖源(1.21%),城市径流源(0.99%)最低;在空间上岷江流域总磷污染负荷呈中游(64.2%)>下游(32.6%)>上游(3.1%)的特点,与岷江干流总磷浓度变化趋势相符,其中成都市总磷污染负荷最高(51.2%),与区域人口密度高、生产和生活活动密集有关。结合资料收集和现场调查,岷江流域总磷污染成因主要包括农村生活污染治理缺口较大、城镇生活污染处理基础设施建设不足、工业企业密布、部分支流总磷污染严重、水污染治理导向不全面。针对岷江总磷污染负荷分布特征及成因,提出“上游保护优质水体、中游治理重污染水体、下游恢复不达标水体”的分区污染防治对策,统筹流域监管体制机制,强化岷江流域水环境保护和治理。  相似文献   
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