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Hongcang ZHOU 《中国地球化学学报》2006,25(B08):54-55
Direct coal combustion not only has a low utilizing efficiency, but also produces a large amount of pollutants such as particulate, CO2, SO2, NOx, polycyclic aromatic hydrocarbons （PAHs）, PCDD/PCDFs, and so on. Coal gasification is a clean coal technology that presents good prospects for coal use, mainly for producing electricity with a high coal conversion efficiency and low environmental impact. However, there is a problem about the minimization of PAHs in coal gasification or direct coal combustion. PAHs are harmful to the environment and human health due to their high degree of mutagenicity and carcinogenicity when they enter human bodies through breathing, eating, and drinking. It is said that about 75%-90% cancers of human beings are mainly caused by PAHs. So the US EPA has prioritized 16 PAH compounds as hazardous air pollutants; these compounds are naphthalene （NAP）, acenaphthylene （AcPy）, acenaphthene （AcP）, fluorene （Flu）, phenanthrene （PhA）, anthracene （ANT）, fluoranthene （FluA）, pyrene （Pyr）, benzo （a） anthracene （BaA）, chrysene （Chr）, benzo （b） fluoranthene （BbF）, benzo （k） fluoranthene （BkF）, benzo （a） pyrene （BaP）, indeno（1,2,3,-cd） pyrene [In（1,2,3-cd） P], dibenzo （a,h） anthracene （DbA）, and benzo （ghi） perylene （BghiP）. The residual char is one of the main products during coal gasification, and then it is brought into the combustion chamber to combust. To investigate the distribution of PAHs in fly ash, the combustion of coal and residual char was tested in a pressurized spouted fluidized bed. After Soxhlet extraction and K-D concentration, the contents of 16 PAHs recommended by US EPA in coal, residual char, and fly ash, were analyzed by a HPLC coupled with fluorescence and diode-array detection. 相似文献
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Sanhita Majumdar Pijush Kanti Mandal Sudip Kumar Das Rabindranath Majumdar 《洁净——土壤、空气、水》2013,41(3):291-297
Carbon bearing materials derived from rice husk (RH) have long been recognized as sorbents for diverse chemicals – both organic and inorganic. This work presents an overview of studies demonstrating a single step process of carbonization of chemically pretreated RH to produce metal impregnated silica‐carbon char designated as silicarbon materials that can be utilized in sorbing out water‐borne organic and inorganic hazardous substances (such as phenol, hexavalent chromium, fluoride, and arsenic) and air‐borne volatile organic chemicals (such as acetone, chloroform, benzene, and pyridine). The metal‐impregnated silicarbon solids derived from RH appear to constitute renewable, low‐cost, user‐friendly, and efficient materials for control systems for indoor air contamination and for industrial as well as non‐industrial hazardous aqueous pollution. 相似文献
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钝化处理被广泛应用于含重金属尾矿的处理,可以从源头上防止酸矿废水(AMD)的产生,寻找一种价廉易得且对环境危害小的钝化剂十分必要。本文主要研究在骨炭作用下,用pH值为4的双氧水对黄铁矿进行氧化,探讨骨炭对黄铁矿氧化释放重金属的钝化作用。实验结果表明,添加不同含量的骨炭(分别为0.5、2.5和5 g)能将溶液的pH值分别提高到8.93、10.01和10.42,表明骨炭具有较强的中和能力,同时黄铁矿氧化释放的Pb、Zn和Cd等重金属离子浓度明显地降低。但当骨炭含量超过2.5 g时,对As有促进释放的趋势。红外光谱分析显示钝化后黄铁矿样品位于420、563、603、1 044、1 091 cm~(-1)处的特征峰主要来自PO_4~(3-)的振动,XRD进一步揭示了黄铁矿表面主要含磷次生矿物是磷铁矿和羟磷铁铅石,这些次生矿物对重金属钝化起着重要作用。因此,骨炭有望作为钝化含多重金属尾矿的钝化剂。 相似文献
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Christian Ruhlé 《Aquatic Sciences - Research Across Boundaries》1989,51(4):296-305
Within one decade the yield in arctic char fishery of Lake Walenstadt (Switzerland) has dropped from 1.7 kg · ha–1 to 0.7 kg · ha–1. In the same period growth decreased by about 15%. The fish considered as degenerated dwarfed chars by fishermen are supposed to mature in very young ages.The change of the growth pattern can be related to reoligotrophication of the lake and impoverishments of the food source. Compared to other arctic char populations in Switzerland maturation takes place at least one year later. 相似文献
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通过对已有多孔材料导热系数计算模型的总结和分析,提出了湿热老化后膨胀型钢结构防火涂层导热系数的计算模型。为考察该模型的计算精度,进行了湿热老化试验及隔热性能试验,测量涂层膨胀倍率、炭化层泡孔尺寸和钢板温度等数据。结果显示,湿热老化后炭化层泡孔尺寸增大导致涂层导热系数增大,隔热性能下降,钢板温度上升。利用本文试验测量数据（泡孔尺寸）计算炭化层导热系数,再根据炭化层导热系数的数值计算结果分析钢板温度,并将钢板温度的计算结果与试验结果进行对比,两者吻合良好,验证了膨胀型防火涂层导热系数计算模型的适用性。 相似文献
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黄河流域动力系统泥沙时序混沌特征分析——地理系统综合研究的一种尝试 总被引：2，自引：1，他引：2
选取黄河头道拐、潼关、花园口和利津断面19522000年的泥沙含量为时序,在G-P重构相空间的基础上,分别计算了各断面泥沙时序的关联维（D2）、K2熵和Hurst指数。结果表明,各断面的最小饱和镶嵌维（m）、D2和K2熵分别为5、3.24和0.13,说明黄河流域各级系统均具有混沌特征,并且从上游到下游混沌特性逐渐增强。随着混沌特性的增强其平均可预报时间下降,头道拐断面为8年,其余断面为3年。各断面Hurst指数均大于0.68,在可预报时间内,各断面泥沙时序具有持续性下降趋势,并用20012004年实际数据得到了验证。文章还给出了黄河流域动力系统的一般形式,该系统至少需要8个状态变量,2个控制变量。 相似文献
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《Limnologica》2021
Mountain lakes are the most affected by climate change; however, few of these lakes are regularly sampled because of their remoteness. We discussed limnological data (e.g. water temperature, light transparency, and plankton diversity) of Lake Campo (1944 m above sea level, Adamello Mountains, Italy) scattered over almost forty years in the light of climate change. Specifically, occasional samplings in 1980, 1988, 2016, 2017, and 2018 and more extensive surveys in 1997 and 2015 were carried out. Among the investigated years, 2015 was the warmest. Inter-year variability in water temperature was quite marked in Lake Campo. Water temperature profiles of July (1980, 1997, 2015) showed increased surface warming, while the deeper layers (> 15 m) were always isothermal at around 5 °C. Hypolimnetic dissolved oxygen never decreased below 50 % saturation. Secchi disk depth was not substantially different among years. Summer profiles of light transparency showed discontinuous light attenuation, which was tentatively attributed to algae located in deeper layers. In cluster analysis of phytoplankton and zooplankton data, differences between seasons but not years were found. The autumn decline of Bacillariophyta and the increase of mixotrophic Cryptophyta was linked to decreasing silica concentrations towards autumn. Apart from this general pattern, several observations (e.g. high abundance of Tovellia sanguinea, requiring warmer temperatures and thermal stratification to compete with Bacillariophyta; a spatially extended metalimnetic oxygen maximum in July 2015) showed the effects of particularly warm conditions of 2015 compared to 1997. The continuous presence of crustacean males and first generation of rotifers (Polyarthra f. aptera) hatching from sexual eggs indicated the importance of sexual reproduction in the lake. Length measurements of Daphnia gr. longispina before (1997) and after (2015) non-native fish removal and Arctic char introduction were similar and indicated no apparent change in predation pressure. Studies like this, despite scattered data, can provide valuable insights into the changes mountain lakes undergo through time. 相似文献