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1.
The source and hydrochemical makeup of a stream reflects the connectivity between rainfall, groundwater, the stream, and is reflected to water quantity and quality of the catchment. However, in a semi-arid, thick, loess covered catchment, temporal variation of stream source and event associated behaviours are lesser known. Thus, the isotopic and chemical hydrographs in a widely distributed, deep loess, semi-arid catchment of the northern Chinese Loess Plateau were characterized to determine the source and hydrochemical behaviours of the stream during intra-rainfall events. Rainfall and streamflow were sampled during six hydrologic events coupled with measurements of stream baseflow and groundwater. The deuterium isotope (2H), major ions (Cl−, SO42−, NO3−, Ca2+, K+, Mg2+, and Na+) were evaluated in water samples obtained during rainfall events. Temporal variation of 2H and Cl− measured in the groundwater and stream baseflow prior to rainfall was similar; however, the isotope compositions of the streamflow fluctuated significantly and responded quickly to rainfall events, likely due to an infiltration excess, overland dominated surface runoff during torrential rainfall events. Time source separation using 2H demonstrated greater than 72% on average, the stream composition was event water during torrential rainfall events, with the proportion increasing with rainfall intensity. Solutes concentrations in the stream had loglinear relationships with stream discharge, with an outling anomaly with an example of an intra-rainfall event on Oct. 24, 2015. Stream Cl− behaved nonconservative during rainfall events, temporal variation of Cl− indicated a flush and washout at the onset of small rainfall events, a dilution but still high concentration pattern in high discharge and old water dominated in regression flow period. This study indicates rainfall intensity affects runoff responses in a semi-arid catchment, and the stored water in the thick, loess covered areas was less connected with stream runoff. Solute transport may threaten water quality in the area, requiring further analysis of the performance of the eco-restoration project. 相似文献
2.
Sam J. Leuthold Stephanie A. Ewing Robert A. Payn Florence R. Miller Stephan G. Custer 《水文研究》2021,35(2):e14029
In snowmelt-driven mountain watersheds, the hydrologic connectivity between meteoric waters and stream flow generation varies strongly with the season, reflecting variable connection to soil and groundwater storage within the watershed. This variable connectivity regulates how streamflow generation mechanisms transform the seasonal and elevational variation in oxygen and hydrogen isotopic composition (δ18O and δD) of meteoric precipitation. Thus, water isotopes in stream flow can signal immediate connectivity or more prolonged mixing, especially in high-relief mountainous catchments. We characterized δ18O and δD values in stream water along an elevational gradient in a mountain headwater catchment in southwestern Montana. Stream water isotopic compositions related most strongly to elevation between February and March, exhibiting higher δ18O and δD values with decreasing elevation. These elevational isotopic lapse rates likely reflect increased connection between stream flow and proximal snow-derived water sources heavily subject to elevational isotopic effects. These patterns disappeared during summer sampling, when consistently lower δ18O and δD values of stream water reflected contributions from snowmelt or colder rainfall, despite much higher δ18O and δD values expected in warmer seasonal rainfall. The consistently low isotopic values and absence of a trend with elevation during summer suggest lower connectivity between summer precipitation and stream flow generation as a consequence of drier soils and greater transpiration. As further evidence of intermittent seasonal connectivity between the stream and adjacent groundwaters, we observed a late-winter flush of nitrate into the stream at higher elevations, consistent with increased connection to accumulating mineralized nitrogen in riparian wetlands. This pattern was distinct from mid-summer patterns of nitrate loading at lower elevations that suggested heightened human recreational activity along the stream corridor. These observations provide insights linking stream flow generation and seasonal water storage in high elevation mountainous watersheds. Greater understanding of the connections between surface water, soil water and groundwater in these environments will help predict how the quality and quantity of mountain runoff will respond to changing climate and allow better informed water management decisions. 相似文献
3.
Aubry Vanderstraeten Steeve Bonneville Stefania Gili Jeroen de Jong Wendy Debouge Philippe Claeys Nadine Mattielli 《Geostandards and Geoanalytical Research》2020,44(2):307-329
Atmospheric dust is an integral component of the Earth system with major implications for the climate, biosphere and public health. In this context, identifying and quantifying the provenance and the processes generating the various types of dust found in the atmosphere is paramount. Isotopic signatures of Pb, Nd, Sr, Zn, Cu and Fe are commonly used as sensitive geochemical tracers. However, their combined use is limited by the lack of (a) a dedicated chromatographic protocol to separate the six elements of interest for low‐mass samples and (b) specific reference materials for dust. Indeed, our work shows that USGS rock reference materials BHVO‐2, AGV‐2 and G‐2 are not applicable as substitute reference materials for dust. We characterised the isotopic signatures of these six elements in dust reference materials ATD and BCR‐723, representatives of natural and urban environments, respectively. To achieve this, we developed a specific procedure for dust, applicable in the 4–25 mg mass range, to separate the six elements using a multi‐column ion‐exchange chromatographic method and MC‐ICP‐MS measurements. 相似文献
4.
南海北部西沙海槽S1站位的岩心柱沉积物中广泛发育自生矿物黄铁矿,其形态以管状为主,且具有内部中空的圈层结构。使用扫描电镜、电子探针、LA-ICP-MS、SIMS等测试方法研究了管状黄铁矿的形态及圈层结构,结果显示: (1)管状黄铁矿发育内部中空的圈层结构,其中内圈层(Ipy)由莓球状黄铁矿呈五角十二面体紧密堆积组成,外圈层(Opy)由晶形较好晶粒较大的八面体黄铁矿组成,并混有沉积碎屑及钙质生物壳体;(2)内圈层和外圈层分别呈现出贫S富Fe和富S贫Fe的特征,其成因是甲烷渗漏造成的局部还原环境使得As进入黄铁矿中导致晶格空缺或被扭曲,从而促进Ni、Co、Cu、Zn、Pb等微量元素的掺入;(3)内圈层、外圈层发生了明显的硫同位素分馏现象,内圈层中 δ34S 平均为-37.8‰,外圈层中 δ34S 平均为-29.3‰。研究认为,管状黄铁矿作为曾经甲烷渗漏的通道,其生长机制可分为3个阶段: (1)气水通道形成阶段: 向上运移的甲烷流体在沉积物孔隙中逐渐形成气水通道;(2)外圈层形成阶段: 当向上运移的甲烷与硫酸盐发生甲烷厌氧氧化时,逐渐形成晶体较大、晶形较好的八面体黄铁矿外圈层;(3)内圈层形成阶段: 随着甲烷浓度逐渐降低,在气水通道中的微生物作用下,剩余甲烷与向下运移的硫酸盐继续反应形成莓球状黄铁矿内圈层。因此,南海北部的泥岩中大量发育的管状黄铁矿常常与地层中甲烷水合物的存在有关。 相似文献
5.
东昆仑夏日哈木地区首次发现了早泥盆世二长花岗岩,对其开展年代学和地球化学特征研究,进一步探讨其岩石成因和构造地质背景。二长花岗岩锆石U-Pb年龄为(412.1±5.7) Ma(MSWD=0.95),形成于早泥盆世早期; 岩石为过弱铝质亚碱性花岗岩,富SiO2(含量为71.41%~72.46%)、K2O(含量为5.27%~6.16%),贫Fe2O3(含量为1.86%~2.05%)、P2O5(含量为0.08%~0.12%),富集轻稀土元素,具明显的负Eu异常; 在原始地幔标准化微量元素蛛网图上可以看出,岩石明显富集Rb、Th、Zr、Hf,强烈亏损Nb、Sr、P、Ti、Ba。夏日哈木地区二长花岗岩属于I型花岗岩,其源岩可能由幔源岩浆底侵加热下地壳岩石致其部分熔融而形成,处于由同碰撞向后碰撞转换的构造环境,说明东昆仑夏日哈木地区在早泥盆世早期已进入伸展阶段。 相似文献
6.
莱州市三山岛北部海域金矿区是世界上第一个查明的海域岩金矿。它通过追索延伸至海域的三山岛断裂,圈定破金找矿靶区。利用海域高精度磁测和浅地层剖面测量配合海上钻探,找到了海域大型金矿。以三山岛海域金矿普查为依托,研究出来的这套海域金矿找矿方法和海上钻探平台,可为今后开展海域金及其它与断裂有关的矿产资源找矿,提供指导和借鉴。 相似文献
7.
基于地缘政治视角,分析本世纪初发生在原苏联地区“颜色革命”的诱发因素,认为美国根据其地缘战略格局对“颜色革命”发生地存在一定程度的主观选择性,国家内部经济、政治、社会等层面的矛盾也同样作为发生背景。在中亚地缘格局动态分析的基础上,结合中亚五国形势,从时间和空间双重维度对中亚地区未来发生“颜色革命”的可能性进行识别与评判,得出1) 整体来看,中亚近期内爆发“颜色革命”可能性较小,但从长远来看不能掉以轻心。2)土、乌未来稳定可期,塔、吉、哈需谨防“颜色革命”卷土重来。 相似文献
8.
首先利用ALOS PALSAR数据,通过D-InSAR技术获取2007-06-03云南宁洱MS6.4地震的同震形变场,然后基于Okada弹性半空间位错模型反演该地震的断层几何以及精细滑动分布,最后计算宁洱地震后周边断层的静态库仑应力变化。结果表明,形变主要集中在西盘,最大视线向形变量为51.6 cm;反演得到的震源位置为23.05°N、101.02°E,深度3 km,断层走向145°,倾向49.5°,平均滑动角153°,发震断层为NNW向普洱断裂,断层活动以右旋走滑为主,兼具逆冲分量;断层面最大滑动量为1.2 m,反演得到的震级为MW619。基于库仑应力场发现,磨黑断裂处于库仑应力增加区域,而2014年景谷地震位于负值区域。结合实地考察资料和反演结果表明,宁洱地震为浅源地震,但断层并未出露地表。 相似文献
9.
刘杰 《大地测量与地球动力学》2019,39(9):906-909
将微粒群算法与位错理论模型相结合,采用中国地壳运动观测网络提供的青藏高原地区2001~2004年GPS测量数据和2000~2006年水准测量数据,通过常规定权和附有相对权比的方法对祁连山北缘断裂的三维滑动速率进行联合反演,并与蚁群算法反演结果进行对比。结果表明,微粒群算法收敛速度快、稳定性高,结合经典位错理论模型,是一种可以有效求解断层三维滑动速率反演问题的优化算法,在大地测量反演领域极具应用潜力。 相似文献
10.
通过滑坡防治格构锚固大型物理模型试验,分析了土质滑坡格构锚杆体系在坡顶荷载下的变形和位移,揭示了格构锚杆的抗滑机制,探讨了锚固力与坡体位移及锚杆变形的关系,提出了极限锚固力的计算方法。结果表明:滑坡滑动时,格构梁与坡体整体发生旋转滑移,锚杆在滑面处发生了弯曲变形,处于弯曲和轴向拉伸组合变形状态;格构锚杆的抗滑作用表现为锚杆在滑面处的抗剪抗滑和锚杆格构梁的挡土阻滑;格构锚杆的极限锚固力由初始预应力、锚杆弯曲变形引起锚拉力、坡体位移引起锚拉力三部分组成,可通过公式 计算。该研究结果可为格构锚固体系的优化设计提供一定的参考。 相似文献