Evaluation of riverbed magnetic susceptibility for mapping biogeochemical hot spots in groundwater-impacted rivers     

Chen Wang  Martin A. Briggs  Frederick D. Day-Lewis  Lee D. Slater 《水文研究》2021,35(5):e14184

Redox hot spots occurring as metal-rich anoxic groundwater discharges through oxic wetland and river sediments commonly result in the formation of iron (Fe) oxide precipitates. These redox-sensitive precipitates influence the release of nutrients and metals to surface water and can act as ‘contaminant sponges’ by absorbing toxic compounds. We explore the feasibility of a non-invasive, high-resolution magnetic susceptibility (MS) technique to efficiently map the spatial variations of magnetic Fe oxide precipitates in the shallow bed of three rivers impacted by anoxic groundwater discharge. Laboratory analyses on Mashpee River (MA, USA) sediments demonstrate the sensitivity of MS to sediment Fe concentrations. Field surveys in the Mashpee and Quashnet rivers (MA, USA) reveal several discrete high MS zones, which are associated with likely anoxic groundwater discharge as evaluated by riverbed temperature, vertical head gradient, and groundwater chemistry measurements. In the East River (CO, USA), widespread cobbles/rocks exhibit high background MS from geological ferrimagnetic minerals, thereby obscuring the relatively small enhancement of MS from groundwater induced Fe oxide precipitates. Our study suggests that, in settings with low geological sources of magnetic minerals such as lowland rivers and wetlands, MS may serve as a complementary tool to temperature methods for efficiently mapping Fe oxide accumulation zones due to anoxic groundwater discharges that may function as biogeochemical hot spots and water quality control points in gaining systems.  相似文献   

Exploring the stemflow dynamics and driving factors at both inter- and intra-event scales in a typical subtropical deciduous forest     

Haixia Zhang  Congsheng Fu  Aimin Liao  Can Zhang  Jiufu Liu  Niu Wang  Bin He 《水文研究》2021,35(3):e14091

Numerous efforts have been made to understand stemflow dynamics under different types of vegetation at the inter-event scale, but few studies have explored the stemflow characteristics and corresponding influencing factors at the intra-event scale. An in-depth investigation of the inter- and intra-event dynamics of stemflow is important for understanding the ecohydrological processes in forest ecosystems. In this study, stemflow volume (F_V), stemflow funnelling ratio (F_R), and stemflow ratio (F_%) from Quercus acutissima and Broussonetia papyrifera trees were measured at both inter- and intra-event scales in a subtropical deciduous forest, and the driving factors, including tree species and meteorological factors were further explored. Specifically, the F_V, F_R and F_% of Q. acutissima (52.3 L, 47.2, 9.6%) were lower than those of B. papyrifera (85.1 L, 91.2, 12.4%). The effect of tree species on F_V and F_% was more obvious under low intensity rainfall types. At the inter-event scale, F_V had a strong positive linear correlation with rainfall amount (G_P) and event duration (D_E) for both tree species, whereas F_R and F_% had a positive logarithmic correlation with G_P and D_E only under high-intensity, short-duration rainfall type. F_R and F_% were mainly affected by wind speed and the maximum 30-min rainfall intensity under low-intensity, long-duration rainfall type. At the intra-event scale, for both tree species, the mean lag time between the start of rainfall and stemflow was the shortest under high-intensity, short-duration rainfall type, while the mean duration and amount of stemflow after rain cessation were the greatest under high-amount, long-duration rainfall type. The relationship between stemflow intensity and rainfall intensity at the 5-min interval scale also depended greatly on rainfall type. These findings can help clarify stemflow dynamics and driving factors at both inter- and intra-event scales, and also provide abundant data and parameters for ecohydrological simulations in subtropical forests.  相似文献   

A two-layer model for studying 2D dissolved pollutant runoff over impermeable surfaces     

Taotao Zhang  Yang Xiao  Dongfang Liang  Hongwu Tang  Junzeng Xu  Saiyu Yuan  Nairu Wang  Bin Luan 《水文研究》2021,35(5):e14152

Dissolved pollutants in stormwater are a main contributor to water pollution in urban environments. However, many existing transport models are semi-empirical and only consider one-dimensional flows, which limit their predictive capacity. Combining the shallow water and the advection–diffusion equations, a two-dimensional physically based model is developed for dissolved pollutant transport by adopting the concept of a ‘control layer’. A series of laboratory experiments has been conducted to validate the proposed model, taking into account the effects of buildings and intermittent rainfalls. The predictions are found to be in good agreement with experimental observations, which supports the assumption that the depth of the control layer is constant. Based on the validated model, a parametric study is conducted, focusing on the characteristics of the pollutant distribution and transport rate over the depth. The hyetograph, including the intensity, duration and intermittency, of rainfall event has a significant influence on the pollutant transport rates. The depth of the control layer, rainfall intensity, surface roughness and area length are dominant factors that affect the dissolved pollutant transport. Finally, several perspectives of the new pollutant transport model are discussed. This study contributes to an in-depth understanding of the dissolved pollutant transport processes on impermeable surfaces and urban stormwater management.  相似文献   

Analytical investigation of the exact groundwater divide between rivers beyond the Dupuit–Forchheimer approximation     

Ruoyi Li  Xu-Sheng Wang 《水文研究》2021,35(2):e14036

The groundwater divide is a key feature of river basins and significantly influenced by subsurface hydrological processes. For an unconfined aquifer between two parallel rivers or ditches, it has long been defined as the top of the water table based on the Dupuit–Forchheimer approximation. However, the exact groundwater divide is subject to the interface between two local flow systems transporting groundwater to rivers from the infiltration recharge. This study contributes a new analytical model for two-dimensional groundwater flow between rivers of different water levels. The flownet is delineated in the model to identify groundwater flow systems and the exact groundwater divide. Formulas with two dimensionless parameters are derived to determine the distributed hydraulic head, the top of the water table and the groundwater divide. The locations of the groundwater divide and the top of the water table are not the same. The distance between them in horizontal can reach up to 8.9% of the distance between rivers. Numerical verifications indicate that simplifications in the analytical model do not significantly cause misestimates in the location of the groundwater divide. In contrast, the Dupuit–Forchheimer approximation yields an incorrect water table shape. The new analytical model is applied to investigate groundwater divides in the Loess Plateau, China, with a Monte Carlo simulation process taking into account the uncertainties in the parameters.  相似文献   

Origin of sulphate in the unsaturated zone and groundwater of a loess aquifer     

Yin Long  Tianming Huang  Fen Zhang  Zhenbin Li  Baoqiang Ma  Yiman Li  Zhonghe Pang 《水文研究》2021,35(4):e14166

The use of the sulphate mass balance (SMB) between precipitation and soil water as a supplementary method to estimate the diffuse recharge rate assumes that the sulphate in soil water originated entirely from atmospheric deposition; however, the origin of sulphate in soil and groundwater is often unclear, especially in loess aquifers. This study analysed the sulphur (δ³⁴S-SO₄) and oxygen (δ¹⁸O-SO₄) isotopes of sulphate in precipitation, water-extractable soil water, and shallow groundwater samples and used these data along with hydrochemical data to determine the sources of sulphate in the thick unsaturated zone and groundwater of a loess aquifer. The results suggest that sulphate in groundwater mainly originated from old precipitation. When precipitation percolates through the unsaturated zone to recharge groundwater, sulphates were rarely dissolved due to the formation of CaCO₃ film on the surface of sulphate minerals. The water-extractable sulphate in the deep unsaturated zone (>10 m) was mainly derived from the dissolution of evaporite minerals and there was no oxidation of sulphide minerals during the extraction of soil water by elutriating soil samples with deionized water. The water-extractable concentration of SO₄ was not representative of the actual SO₄ concentration in mobile soil water. Therefore, the recharge rate cannot be estimated by the SMB method using the water-extractable concentration of SO₄ in the loess areas. This study is important for identifying sulphate sources and clarifying the proper method for estimating the recharge rate in loess aquifers.  相似文献   

黄土洞室掘进深度与围岩位移变化规律研究     

时卫民  王鹏  赵尚毅 《岩土工程技术》2020,(2):70-75

应用PLAXIS 2D/3D有限元分析软件,对某黄土洞室进行了二维、三维分步掘进、三维一次掘进等工况的弹塑性有限元分析,研究分析了不同工况下洞室围岩位移的变化规律,并对掌子面的空间效应进行了分析。分析结果表明,二维与三维分步计算的最终位移基本一致,可以用二维的计算结果来估算洞室开挖的最终位移。三维分步掘进的分析表明,不同埋深的洞室其位移比的变化规律基本一致,当L/B<1时(L为掘进深度,B为洞室跨度),位移比呈线性增加;当L/B>1时,位移比呈非线性增加;当L/B>3时,其最大位移接近最终位移。掌子面的空间效应分析表明,在掌子面处的位移约为最终位移的1/3,距掌子面0.5倍跨度处的位移约为最终位移的2/3,距掌子面2.5倍跨度处的位移基本达到了最终位移。  相似文献   

南海北部西沙海槽沉积物管状黄铁矿特征及其形成机理^*          下载免费PDF全文

石思思  吴朝东  梁金强  王熠哲  叶云涛  方允鑫  马健  翟俪娜 《古地理学报》2020,22(1):175-192

南海北部西沙海槽S1站位的岩心柱沉积物中广泛发育自生矿物黄铁矿,其形态以管状为主,且具有内部中空的圈层结构。使用扫描电镜、电子探针、LA-ICP-MS、SIMS等测试方法研究了管状黄铁矿的形态及圈层结构,结果显示: (1)管状黄铁矿发育内部中空的圈层结构,其中内圈层(I_py)由莓球状黄铁矿呈五角十二面体紧密堆积组成,外圈层(O_py)由晶形较好晶粒较大的八面体黄铁矿组成,并混有沉积碎屑及钙质生物壳体;(2)内圈层和外圈层分别呈现出贫S富Fe和富S贫Fe的特征,其成因是甲烷渗漏造成的局部还原环境使得As进入黄铁矿中导致晶格空缺或被扭曲,从而促进Ni、Co、Cu、Zn、Pb等微量元素的掺入;(3)内圈层、外圈层发生了明显的硫同位素分馏现象,内圈层中 δ³⁴S 平均为-37.8‰,外圈层中 δ³⁴S 平均为-29.3‰。研究认为,管状黄铁矿作为曾经甲烷渗漏的通道,其生长机制可分为3个阶段: (1)气水通道形成阶段: 向上运移的甲烷流体在沉积物孔隙中逐渐形成气水通道;(2)外圈层形成阶段: 当向上运移的甲烷与硫酸盐发生甲烷厌氧氧化时,逐渐形成晶体较大、晶形较好的八面体黄铁矿外圈层;(3)内圈层形成阶段: 随着甲烷浓度逐渐降低,在气水通道中的微生物作用下,剩余甲烷与向下运移的硫酸盐继续反应形成莓球状黄铁矿内圈层。因此,南海北部的泥岩中大量发育的管状黄铁矿常常与地层中甲烷水合物的存在有关。  相似文献   

内蒙古碾子沟钼矿床成矿流体来源、演化及成矿机理     

孙丰月  王睿  王一存  李顺达  王可勇  石开拓  孙清飞  王文元 《吉林大学学报(地球科学版)》2020,50(3):768-780

内蒙古自治区碾子沟钼矿床地处华北地台北缘西拉木伦钼成矿带西段，为一典型的中型石英脉型钼矿床。该钼矿床矿脉（体）主要产于燕山早期二长花岗岩-钾长花岗岩内NNW、NW向断裂构造体系之中，成矿作用过程经历了黄铁矿±辉钼矿＋石英（Ⅰ）、辉钼矿＋黄铁矿±黄铜矿＋石英（Ⅱ）、黄铜矿＋黄铁矿±闪锌矿＋石英（Ⅲ）及石英±方解石（Ⅳ）4个阶段。系统的流体包裹体岩相学、包裹体组分析、包裹体显微测温研究表明，矿床初始成矿流体为高温、中低盐度（490~550℃，盐度（w（NaC1））2%~10%，50~62 MPa）均匀的NaCl-H₂O体系热液，δ¹⁸O_H2O-SMOW（2.21‰）及δD_H2O-SMOW（-68.9‰）表明其主要来源于岩浆热液；成矿流体上升并不断汇聚于容矿断裂空间，伴随温度、压力降低（380~460℃，26~40 MPa→360~420℃，25~30 MPa）而进入两相不混溶区，流体开始发生沸腾→强烈沸腾作用，导致成矿元素Mo大量沉淀富集成矿，成矿晚期残余流体与大气降水混合（δ¹⁸O_H2O-SMOW为-2.41‰~2.51‰，δD_H2O-SMOW为-110.1‰~-105.5‰），矿床属燕山早期中高温岩浆热液型钼矿床。  相似文献   

2007-2017年中国沙尘气溶胶的三维分布特征及输送过程     

贾瑞  刘玉芝  吴楚樵  祝清哲  汪兵 《中国沙漠》2019,39(6):108-117

利用最新发布的CALIPSO产品，构建了2007-2017年中国沙尘气溶胶的三维分布，并结合HYSPLIT-4模式和再分析数据，探讨了沙尘的三维输送过程。结果表明：中国的沙尘排放源区主要是塔克拉玛干沙漠和巴丹吉林沙漠，沙尘气溶胶出现频率分别为60%和35%。塔克拉玛干沙漠排放的沙尘主要（50%~70%）停留在源地0~6 000 m高度，少部分向东输送至甘肃和内蒙古；巴丹吉林沙漠排放的沙尘则主要向东输送。中国沙尘排放量在春季最大，向东输送最强；夏季，东亚夏季风限制了沙尘向东输送；秋季，沙尘排放减弱，输送强度和夏季相当；沙尘排放量在冬季最小，输送最弱。夏季，沙尘在输送过程中可被抬升至高度5 000 m以上，春季次之，秋、冬季的沙尘主要在低层大气输送。沙尘在向东输送的过程中被抬升并和当地人为污染物混合变为污染性沙尘，华北地区污染性沙尘出现频率高达30%；输送到海洋的沙尘也会与洋面上（0~3 000 m高度）的海盐气溶胶混合，出现频率约为10%。  相似文献   

辽河盆地西部凹陷古近系沙四上亚段沉积相及演化     

王夏斌  姜在兴  胡光义  范廷恩  王俊辉  卢欢 《吉林大学学报(地球科学版)》2019,49(5):1222-1234

薄互层砂体研究是湖盆沉积学的研究难点。本文针对辽河西部凹陷沙四上亚段（Es^4上）薄互层砂体，以层序地层学、沉积学、测井地质学等理论为指导，综合岩心、测录井和地震等多种资料，对西部凹陷的薄互层砂体进行精细描述和深入剖析。结果表明，研究区主要发育辫状河三角洲和湖泊沉积相，其中，滩坝砂体是湖泊相的主力砂体。通过考虑不同沉积背景下滩坝在岩相组合、发育位置和成因机理的差异性，将滩坝划分成侧缘改造型滩坝、前缘改造型滩坝、基岩改造型滩坝、淹没改造型滩坝和风暴改造型滩坝5种沉积模式；对薄层滩坝砂体的控制因素进行分析，认为其受到"风场-物源-盆地"三端元的控制。  相似文献