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1.
摘要:目的 探讨菌株Salinivibrio sp.YH4分泌的丝氨酸蛋白酶EYHS的耐盐性及结构特征。方法 明胶底物酶谱法分析EYHS的耐盐性。应用生物信息学手段对EYHS及6种耐盐的S8家族丝氨酸蛋白酶结构特征进行分析。结果 EYHS在4 mol/L的NaCl溶液中仍具有活性,属于耐盐蛋白酶。EYHS及6种S8家族丝氨酸蛋白酶分子表面的loop区等无规则卷曲所占比例较高,α-螺旋与β-片层则主要位于酶分子内部。EYHS分子表面酸性氨基酸含量较高,且具有弱疏水内核。多序列比对发现蛋白酶的催化三联体两侧存在高度保守的基序和保守的极性氨基酸及芳香族氨基酸,并存在多个保守的Gly与Ala。同源模建和表面电荷分布显示,α螺旋和β片层围成了蛋白酶的催化腔,EYHS活性中心包含由Asp32、His65与Ser215组成的催化三联体,且催化位点区域表面静电势为负。结论 上述结构特征可能有助于耐盐丝氨酸蛋白酶EYHS在高盐环境下维持其稳定性和适度柔性,并有助于其催化功能的发挥,为深入研究耐盐丝氨酸蛋白酶的高盐环境适应性提供了一定的理论依据。 相似文献
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ENSO is an interannual mode which may be affected by external forcing, such as volcanic eruptions. Based on the reconstructed volcanic eruptions chronology and ENSO sequences, both 195 large volcanic eruptions(VEI≥4) and 398 ENSO(El Ni?o and La Ni?a) events were extracted from 1525 to 2000. An analysis of the correspondence between the large volcanic eruptions and ENSO events was performed by matching the large volcanic eruptions with the types and magnitudes of ENSO events present in the 0–2 years after the eruptions. The results show the following:(1) The percentages of ENSO events within the 3 years after the large eruptions had increased to 68.3% from 31.7% compared with those with no-eruptions in the previous 0–2 years. In addition, the ratio of El Ni?o to La Ni?a events turned from 2:3 to 1:1, and more El Ni?o events occurred in the 0 year after eruptions in the low-latitudes of the Northern Hemisphere and in the tropics but more La Ni?a events occurred in the 0 year after in the high-latitudes of the Northern Hemisphere and the Southern Hemisphere.(2) After the eruptions, the weak(W) El Ni?o events had increased by 8 percentage points and the very strong(VS) El Ni?o events had decreased by 10 percentage points; conversely, there was a decrease by 15 percentage points of the weak La Ni?a events and an increase by 11.4 percentage points of the very strong La Ni?a events. Specifically, the percentages of strong La Ni?a events increased to a peak at 1(+1) year after the eruptions.(3) The percentage of eruptions followed by single-year ENSO was the greatest. The percentage of ENSO events that occurred in the consecutive 2 years following an eruption was approximately equal to the percentage of events that occurred consecutively 3 years following an eruption, and both sets of ENSO magnitudes showed a decreasing trend. 相似文献
3.
敞开酸溶和偏硼酸锂碱熔ICP-MS法测定多金属矿中的稀土元素及铌钽锆铪 总被引:2,自引:2,他引:0
用电感耦合等离子体质谱法(ICP-MS)测定地质样品中的稀土及难熔元素,混合酸敞开酸溶法和碱熔融法是两种主要的溶样方法。但地质样品组分复杂,元素之间存在相互共生的现象,对于特殊元素、特殊样品用传统酸溶法会造成部分元素消解不完全,使测定结果不准确;而碱熔法的操作过程繁琐,且溶液盐度高,易产生基体干扰和堵塞仪器进样系统。本文改进了传统四酸和五酸体系,采用氢氟酸-硝酸-硫酸敞开酸溶体系,用国家一级标准物质制作标准曲线测定15种稀土元素,方法准确度(ΔlgC)为0.001~0.027。同时改进了偏硼酸锂碱熔法,样品用偏硼酸锂碱熔提取,加入氢氧化钠调节溶液至碱性条件,所测元素与偏硼酸锂共沉淀后过滤分离熔剂,再用硝酸复溶测定15种稀土元素及铌钽锆铪。两种溶样方法的测定值与认定值的相对误差为1.09%~9.30%。将混合酸敞开酸溶法测定稀土元素、偏硼酸锂碱熔法测定铌钽锆铪的结果与其他实验室密闭酸溶法相比,两组数据的相对偏差为0.13%~15.32%。本实验表明,混合酸敞开酸溶法适用于测定地质样品中的稀土元素,偏硼酸锂碱熔法不仅适用于测定地质样品中的稀土元素及铌钽锆铪,也适用于测定如古老高压变质岩石及铝含量高的样品中的铌钽锆铪。 相似文献
4.
冰川作为地表特殊的下垫面,冰川区内气温明显低于同高度非冰川区大气温度。如何利用低海拔非冰川区观测资料精确估算高海拔冰川区气温,直接关系着青藏高原冰川消融估算及其水文效应的评估。利用架设在藏东南帕隆藏布4号冰川不同高度带的四台自动气象站资料,分析了冰川区与非冰川区气温的波动特征,评估了迄今为止通用的线性递推模型(DT模型)、分段拟合模型(SM模型)和简化热力学模型(GB模型)三种方法在藏东南冰川区气温估算方面的应用效果。对比研究发现:SM模型在帕隆4号冰川上的模拟效果最为理想且操作相对简单;传统DT模型在消融区存在严重的高估,帕隆4号冰川表面夏季(6-8月)正积温的高估比例接近39%;GB模型由于受到诸如冰川风边界层厚度等不确定性的影响,降低了大范围温度估算的可操作性。 相似文献
5.
Weihan Li Jian‐Ming Zhu Decan Tan Guilin Han Zhouqiao Zhao Guangliang Wu 《Geostandards and Geoanalytical Research》2020,44(3):523-535
The high‐precision δ60/58Ni values of twenty‐six geological reference materials, including igneous rocks, sedimentary rocks, stream sediments, soils and plants are reported. The δ60/58Ni values of all samples were determined by double‐spike MC‐ICP‐MS (Nu Plasma III). Isotope standard solution (NIST SRM 986) and geological reference materials (BHVO‐2, BCR‐2, JP‐1, PCC‐1, etc.) were used to evaluate the measurement bias and intermediate precision over a period of six months. Our results show that the intermediate precision of Ni isotope determination was 0.05‰ (2s, n = 69) for spiked NIST SRM 986 and typically 0.06‰ for actual samples, and the δ60/58Ni NIST SRM 986 values were in excellent agreement with previous studies. Eighteen high‐precision Ni isotope ratios of geological reference materials are first reported here, and their δ60/58Ni values varied from ?0.27‰ to 0.52‰, with a mean of 0.13 ± 0.34‰ (2s, n = 18). Additionally, SGR‐1b (0.56 ± 0.04‰, 2s), GSS‐1 (?0.27 ± 0.06‰, 2s), GSS‐7 (?0.11 ± 0.01‰, 2s), GSD‐10 (0.46 ± 0.06‰, 2s) and GSB‐12 (0.52 ± 0.06‰, 2s) could potentially serve as candidate reference materials for Ni isotope fractionation and comparison of Ni isotopic compositions among different laboratories. 相似文献
6.
DO4事件(Dansgaard-Oeschger event 4,简称DO4事件)是发生在MIS3阶段后期的1次明显升温事件。根据福建仙云洞石笋(编号XYⅢ-28)300~500 mm层段6个高精度230Th年龄和188个氧同位素数据,获得了29.13~27.94 kyrB.P.时期平均分辨率达7 yr的东亚夏季风强度的演变过程数据。该石笋 δ18O 记录的DO4事件起止时间为28.83±0.06~28.46±0.06 kyr B.P.,持续时间为0.37±0.06 kyr。相对基于GICC05年层计数时标NGRIP冰芯 δ18O 记录在DO4开始阶段的突变特征,仙云洞石笋记录的DO4事件开始阶段 δ18O 值在145±60 yr内偏负0.4‰,表现为相对缓慢的变化特征,这说明仙云洞所处的中国东南沿海地区有可能受到热带低纬海气耦合的影响。此外,仙云洞石笋 δ18O 记录揭示了在DO4事件内部及附近存在一系列的百年至十年际尺度夏季风增强事件,与格陵兰冰芯 δ18O 记录、阿拉伯海海盆反照率记录的DO4事件亚旋回结构在定年误差范围内相对应,表明东亚夏季风强度与北高纬温度变化和ITCZ(赤道辐合带)位置移动在百年至十年际尺度上存在紧密的联系。 相似文献
7.
基于ROMS和4DVAR的沿轨与网格化SSH数据同化效果评价 总被引:1,自引:1,他引:0
Remote sensing products are significant in the data assimilation of an ocean model. Considering the resolution and space coverage of different remote sensing data, two types of sea surface height(SSH) product are employed in the assimilation, including the gridded products from AVISO and the original along-track observations used in the generation. To explore their impact on the assimilation results, an experiment focus on the South China Sea(SCS) is conducted based on the Regional Ocean Modeling System(ROMS) and the four-dimensional variational data assimilation(4 DVAR) technology. The comparison with EN4 data set and Argo profile indicates that, the along-track SSH assimilation result presents to be more accurate than the gridded SSH assimilation, because some noises may have been introduced in the merging process. Moreover, the mesoscale eddy detection capability of the assimilation results is analyzed by a vector geometry–based algorithm. It is verified that, the assimilation of the gridded SSH shows superiority in describing the eddy's characteristics, since the complete structure of the ocean surface has been reconstructed by the original data merging. 相似文献
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