全球碳循环研究中的δ13C方法及其进展     

陈中笑  赵琦 《地球科学进展》2011,26(11):1225-1233

随着分析技术的进步,δ13C观测在全球碳循环研究中越来越受到重视。在讨论关于碳循环中δ13C的Suess效应、分布特征和同位素分馏等基本概念的基础上,结合现有的观测事实,介绍应用δ13C辨别碳的源汇问题的方法,通过比较不同KeelingPlot方法分析该方法在研究大气CO2背景特征中的意义。着重讨论δ13C在研究大气C...  相似文献   

平顶山煤田十三矿二1煤层厚度特征及山西组聚煤规律探讨   总被引：1，自引：0，他引：1  

李惠杰  张云中  胡盛  李建欣 《中国煤炭地质》2011,(8):28-31,37

通过对平顶山煤田十三矿二1煤层厚度特征及沉积环境等相关资料的整理、分析,认为二1煤厚度大、煤质好,但区内中部出现较大范围的分叉区,表现为煤层厚度变薄直至尖灭,其分叉型式属二分式。根据二1煤层的形成机制及其变化规律认为,影响厚度变化的主要因素为原生沉积环境,后期构造及大占砂岩的冲刷影响仅限于局部。该研究对矿井生产具有一定的指导意义。  相似文献   

西北冰洋表-底层碳动力学耦合作用的同位素(¹³C,₂₃₄Th)指示     

张润  陈敏  马嫱  曹建平  邱雨生 《海洋学报(英文版)》2015,34(6):26-33

The coupling of upper ocean-benthic carbon dynamics in the ice-free western Arctic Ocean(the Chukchi Sea and the Canada Basin) was evaluated during the late July–early September 2003 using natural stable(13C) and radioactive(238U-234Th) isotope tracers. POC export flux estimated from 234Th/238 U disequilibria and dissolved CO2 concentration([CO2(aq)]) pointed out that the strengthened biological pump in the Chukchi Shelf have significantly lowered [CO2(aq)] and altered the magnitude of isotopic(12C/13C) fractionation during carbon fixation in the surface ocean. Further, d13 C signatures of surface sediments(d13Csed) are positively correlated to those of weighted d13 CPOC in upper ocean(d13Csed =13.64+1.56×d13CPOC, r2=0.73, p0.01), suggesting that the POC isotopic signals from upper ocean have been recorded in the sediments, partly due to the rapid export of particles as evidenced by low residence times of the highly particle-reactive 234 Th from the upper water column. It is suggested that there probably exists an upper ocean-benthic coupling of carbon dynamics, which likely assures the sedimentary d13 C record an indicator of paleo-CO2 in the western Arctic Ocean.  相似文献   

Isolated Archosaur teeth from the green sandstone capping the Coralline Limestone (Bagh Group) of the Narmada valley: Evidence for the presence of pre‐Late to Late Maastrichtian abelisaurids in India          下载免费PDF全文

Guntupalli V.R. Prasad  Vishal Verma  Pooja Grover  Rajkumari Priyadarshini  Ashok Sahni  Ranjit S. Lourembam 《Island Arc》2016,25(6):410-420

Recent field prospecting in the Cretaceous sequences of the lower Narmada valley has led to the discovery of three isolated archosaur teeth from the upper part of marine Cretaceous rocks of the Bagh Group. The specimens were recovered by surface prospecting from an oyster‐bearing green sandstone bed occurring at the top of the Coralline Limestone (Coniacian) from a site near Phutibawri village, Dhar District, Madhya Pradesh, India. Of the three teeth recovered from this horizon, two are identified with abelisaurid dinosaurs and the third one with an indeterminate crocodile. The abelisaurid teeth conform to the premaxillary and maxillary tooth morphology of Majungasaurus and Indosuchus. Earlier reports of abelisaurid dinosaurs from India are from the Upper Cretaceous (Maastrichtian) Lameta Group of Jabalpur, Pisdura (Central India) and Balasinor (Western India) and Upper Cretaceous (Late Maastrichtian) Kallamedu Formation (South India). As no associated age diagnostic fossils are found, the specimens described here are considered to represent pre‐Late to Late Maastrichtian age based on the known ages of the underlying and overlying formations. The new finds, therefore, document stratigraphically the oldest occurrence of abelisaurid dinosaurs known from the Indian subcontinent.  相似文献   

Application of a Bayesian model to infer the contribution of coalbed natural gas produced water to the Powder River,Wyoming and Montana          下载免费PDF全文

Jason M. Mailloux  Kiona Ogle  Carol D. Frost 《水文研究》2014,28(4):2361-2381

The Powder River Basin (PRB) of Wyoming and Montana contains significant coal and coal bed natural gas (CBNG) resources. CBNG extraction requires the production of large volumes of water, much of which is discharged into existing drainages. Compared to surface waters, the CBNG produced water is high in sodium relative to calcium and magnesium, elevating the sodium adsorption ratio (SAR). To mitigate the possible impact this produced water may have on the quality of surface water used for irrigation, the State of Montana passed water anti‐degradation legislation, which could affect CBNG production in Wyoming. In this study, we sought to determine the proportion of CBNG produced water discharged to tributaries that reaches the Powder River by implementing a four end‐member mixing model within a Bayesian statistical framework. The model accounts for the ⁸⁷Sr/⁸⁶Sr, δ¹³C_DIC, [Sr] and [DIC] of CBNG produced water and surface water interacting with the three primary lithologies exposed in the PRB. The model estimates the relative contribution of the end members to the river water, while incorporating uncertainty associated with measurement and process error. Model results confirm that both of the tributaries associated with high CBNG activity are mostly composed of CBNG produced water (70–100%). The model indicates that up to 50% of the Powder River is composed of CBNG produced water downstream from the CBNG tributaries, decreasing with distance by dilution from non‐CBNG impacted tributaries from the point sources to ~10–20% at the Montana border. This amount of CBNG produced water does not significantly affect the SAR or electrical conductivity of the Powder River in Montana. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

饲料中豆粕含量对军曹鱼幼鱼碳、氮稳定同位素分馏的影响     

张泽钊  周晖  施钢  陈刚 《广东海洋大学学报》2013,(6):30-36

配制全鱼粉饲料（以鱼粉为蛋白源）、10%豆柏饲料（用豆柏蛋白10%鱼粉）、20%豆柏饲料（用豆柏蛋白20%鱼粉）等3种等氮等能饲料，分别投喂体质量21.34± 1.54g的幼鱼24 d，研究饲料中豆柏蛋白含量对 军曹鱼幼鱼碳、氮稳定同位素分馈的影响。结果表明，随着养殖时间的延长，各饲料组军曹鱼δ13C逐渐上升，δ15N逐渐下降，虽然δ13C和δ15N变化速度上有差异，但除20%豆柏饲料组肌肉的δ15N外，其他各饲料组肌肉和 全鱼在实验结束时均已与饲料达到同位素平衡;军曹鱼肌肉和全鱼的△13^C和△15^N值均随饲料中豆柏蛋白含量 的增加而加大，△13C从4.19‰增加到5.04‰， △15N从0.18‰。增加到 2.20‰,军警鱼金鱼和肌肉的△13C和△15N 相似，但在同位素值变化速度上有差异，因此，在进行生态学营养级研究（长时间尺度）时，肌肉可以代表军警鱼的同位素特征，而在进行生理学研究（短时间尺度）时，肌肉的同位素变化则不能代表军警鱼的同位素变化。  相似文献   

Spatial and temporal variations of sedimented organic matter in Xiaohai Lagoon, Hainan Island   总被引：1，自引：1，他引：0  

LIU Xingjian  GE Chendong 《海洋学报(英文版)》2012,31(3):74-86

The characteristics of grain-size,total organic carbon(TOC) and total nitrogen(TN) contents,TOC/TN ratios,stable carbon isotope(δ13C) and 210 Pb dating were measured in six sediment cores from the Xiaohai Lagoon.The results show distinct spatial and temporal variations in sedimentation patterns.The sediments are dominated by clayey silt,sandy silt and by silty sand in the southern,middle lagoon and the northern lagoon,respectively.TOC and TN contents decline from south to north.Sedimentation rates,determined by 210 Pb dating,tend to decrease from south to middle.However,the determination of sedimentation rate in the north is difficult.These spatial variations are related to the variations in sediment sources and hydrodynamic conditions in the Xiaohai Lagoon.The variations of organic matter signatures can be divided into two stages in the cores from the southern and middle lagoon.Before 1988,the organic matter signatures are relatively stable.The contribution of terrestrial organic carbon sources varies between 60% and 85%.After 1988,the organic matter signatures demonstrate significant variations.TOC and TN contents increase rapidly,TOC/TN ratios decrease,δ13C values shift to higher and the contribution of terrestrial organic carbon sources decreases to 40%-50%.The contributions of phytoplankton organic matter have increased in the sediment since 1988.Increasing aquaculture activities have had a significant impact on organic matter signatures since 1988.The sedimentation rates have increased rapidly in the southern and middle lagoon since 1988 due to the anthropogenic activities which include aquaculture,mining and deforestation.These activities have caused eutrophication and increased siltation in the southern and middle lagoon.  相似文献   

Nature and role of CO2 in some hot and cold HCO3/Na/CO2-rich Portuguese mineral waters: a review and reinterpretation     

José M. Marques  Paula M. M. Carreira  Luís Aires-Barros  Rui C. Graça 《Environmental Geology》2000,40(1-2):53-63

 At the northern part of the Portuguese mainland, the upflow zone of several hot and cold HCO₃/Na/CO₂-rich mineral waters is mainly associated with important NNE–SSW faults. Several geochemical studies have been carried out on thermal and non-thermal hydromineral manifestations that occur along or near these long tectonic alignments. The slight chemical differences that exist between these meteoric hot and cold HCO₃/Na/CO₂-rich mineral waters seem to be mainly caused by CO₂. δ¹³C_(TIDC) values observed in these groundwaters range between –6.00 and –1.00‰ versus V-PDB (V denotes Vienna, the site of the International Atomic Energy Agency; PDB originates from the CaCO₃ of the rostrum of a Cretaceous belemnite, Belemnitella americana, collected in the Peedee formation of South Carolina, USA) indicating a deep-seated (mantle) origin for most of the CO₂. Nevertheless, in the case of the heavier δ¹³C_(TIDC) values, the contribution of metamorphic CO₂ or the dissolution of carbonate rock levels at depth cannot be excluded. Concerning the hot waters, the lack of a positive ¹⁸O-shift should be attributed to water-rock interaction in a low temperature environment, rather than to the isotopic influence of CO₂ on the δ¹⁸O-value of the waters. Received: 9 August 1999 · Accepted: 8 March 2000  相似文献   

Change of Organic δ13C in Ornithogenic Sediments of the Xisha Archipelago, South China Sea and its Implication for Ecological Development     

WU Libin  LIU Xiaodong  XU Liqiang 《《地质学报》英文版》2017,91(3):1109-1119

Organic carbon isotopes in sediments have been frequently used to identify the source of organic matter.Here we present a study of organic δ~(13)C on two sediment profiles influenced by guano from Guangjin and Jinqing islands in the Xisha Archipelago,South China Sea.Organic matter from ornithogenic coral sand sediments has two main sources,guano pellets and plant residues,and their organic δ~(13)C(δ~(13)C_(OM)) are significantly different.Organic carbon δ~(13)C_(guano) is much higher thanδ~(13)C_(plants),and δ~(13)C_(OM)of bulk samples is intermediate.Based on a two-end-member mixing model,the proportions of guano-and plant-derived organic matter in the bulk samples were reconstructed quantitatively.The results showed that seabirds began to inhabit the islands around approximately1200-1400 AD,and that guano pellets have been an important source of soil organic matter since then.With the accumulation of guano-derived nutrients,plants began to develop prosperously on the islands in the last 200 years,which is reflected by the significant increase of plant-derived organic matter in the upper sediment layer.However,guano-derived organic matter decreased greatly in recent decades,indicating a rapid decrease in seabird population.Our results show that organic δ~(13)C can be effectively used to quantitatively determine different source contributions of OM to bulk ornithogenic coral sand sediments.  相似文献   

龙须菜和扁江篱多糖的组成及其抗肿瘤效果   总被引：22，自引：0，他引：22  

邓志峰  纪明侯 《海洋与湖沼》1995,26(6):575-581

于１９８５－１９８７年期间用冷水和热水对采集于青岛的龙须菜和扁江篱的琼胶型多糖进行提取。两海藻的热水提取多糖都通过ＤＥＡＥ－ＳｅｐｈａｄｅｘＡ５０色谱桩用热水和不同浓度ＮａＣｌ深液前后进行洗脱分级。龙须菜和扁江篱多糖的主要级分分别为０．５ｍｏｌ／Ｌ和１．０ｍｏｌ／ＬＮａＣｌ洗脱级分。对各级分做化学分析及ＩＲ和＾１３ＣＮＭＲ光谱分析。结果表明，龙须菜多糖由琼二糖、琼胶糖前体和６－ＯＣＨ３－琼二糖组成  相似文献