岩溶水硝酸盐污染原位修复试验     

叶进霞  夏春英  卜鸿志 《中国岩溶》2020,39(2):173-179

岩溶含水层的极不均一性特征使岩溶水溶质运移受构造、裂隙空间及其发育方向控制；因环境条件复杂，开展岩溶水污染原位修复技术难度较大，截止目前，国内尚未系统地开展岩溶含水层水污染原位修复研究工作。文章选择鲁中南山区典型岩溶发育及硝酸盐污染地段，施工组合钻孔建设修复试验工程，采用“乙醇+葡萄糖”液态碳源和“聚乙烯醇+淀粉颗粒”固态反应器分别进行岩溶水硝酸盐污染原位修复试验。结果表明:浓度500 mg?L－1、1 000 mg?L－1的“乙醇+葡萄糖”反硝化溶液对硝酸盐浓度的降解率分别为6.45 %和21.52 %；单位长度组成材料“聚乙烯醇3 kg+淀粉颗粒3 kg”、“聚乙烯醇2 kg+淀粉颗粒4 kg”的两种反硝化固态反应器对硝酸盐浓度的降解率分为33.91%和34.96%。试验证明在裂隙型岩溶地区采用孔组方案进行地下水污染原位修复技术可行、且能取得较显著效果。修复工程布设方式和试验成果对类似地区开展岩溶地下水污染原位修复具一定借鉴意义。   相似文献   

Spatial and Temporal Distribution of Dust‐Bound Trace Metal Elements around Kuhdasht Watershed Area in Iran     

Hamid Alipour  Ahmad Jalalian  Naser Honarjoo  Norair Tommanian  Fereidoon Sarmadian 《洁净——土壤、空气、水》2019,47(10)

Dust, as a source of trace metal elements, affects the health of society. The spatial and temporal concentrations of dust‐bound trace metals (Cd, Pb, Ni, Zn, Cu, and Mn) in Kuhdasht watershed (456 km²), Lorestan Province, Iran, is investigated. Dust is collected using glass traps placed in ten research stations in the region. The spatial and temporal distribution of dust trace metals are plotted using ARC‐GIS. The highest and the lowest concentrations of Zn (9751150 mg kg^?1), Pb (46.352.9 mg kg^?1), and Cd (2.443.30 mg kg^?1) are obtained in winter, of Ni (98110 mg kg^?1) and Cu in autumn (16.053.5 mg kg^?1), and of Mn in summer (385505 mg kg^?1). The spatial concentrations of dust‐bound trace metals indicate all, except Cu, show a decreasing trend from the mountains toward the plains, similar to that of soil and of dust, except for Zn, which shows higher concentrations in dust than in soil. The potential sources of dust‐bound trace metals and their rate of contamination are also investigated using the enrichment and contamination factors. The major sources of Cd and Zn in the dust of watershed are due to anthropogenic activities or from activities outside the borders.  相似文献   

角闪石成分对东天山铜镍矿床岩浆过程的指示意义     

方林茹  唐冬梅  秦克章  牛艳杰  毛亚晶  康珍 《岩石学报》2019,35(7):2061-2085

图拉尔根、香山和天宇、白石泉岩浆铜镍硫化物矿床分别位于新疆东天山的觉罗塔格构造带和中天山地块,角闪石在这些矿床中均以贯通矿物产出。本研究通过这些矿床角闪石的主量和微量元素含量,讨论两个构造单元成矿岩浆的性质和演化过程。四个矿床的角闪石种属主要为韭闪石、镁绿钙闪石、浅闪石、钛闪石、钙镁闪石和镁闪石,结晶温度区间为940～1080℃,压力区间为250～450MPa,相当于11～15km的深度。图拉尔根和香山矿床的角闪石结晶温度和压力均相对较低(平均分别为1027℃、318MPa和1013℃、313MPa),可能与其所处的觉罗塔格构造带断裂发育,成矿母岩浆易于侵位到较浅处结晶有关。四个矿床角闪石结晶时岩浆的含水量均较高(4%左右),可能是俯冲交代作用导致的地幔源区本身水含量较高以及角闪石结晶较晚共同作用的结果。相较于觉罗塔格构造带的图拉尔根和香山矿床(0 ΔNNO 1. 7),角闪石氧逸度计指示中天山地块天宇和白石泉矿床的氧逸度变化范围大且偏低(分别是-0. 6 ΔNNO 1. 7和-0. 4 ΔNNO 1. 8)。中天山铜镍矿床的氧逸度特征及相对觉罗塔格构造带较低的微量元素Ce/Pb比值指示其岩浆侵位过程中受到的古老地块的混染作用较强。以上研究表明角闪石虽是玄武质岩浆中较晚结晶的矿物,但能为示踪铜镍矿床岩浆演化提供重要线索。  相似文献   

Groundwater contaminant source identification based on iterative local update ensemble smoother          下载免费PDF全文

YANG Ai-lin  JIANG Si-min  LIU Jin-bing  JIANG Qian-yun  ZHOU Ting  ZHANG Wen 《地下水科学与工程》2020,8(1):1-9

Identification of the location and intensity of groundwater pollution source contributes to the effect of pollution remediation, and is called groundwater contaminant source identifcation. This is a kind of typical groundwater inverse problem, and the solution is usually ill-posed. Especially considering the spatial variability of hydraulic conductivity field, the identification process is more challenging. In this paper, the solution framework of groundwater contaminant source identification is composed with groundwater pollutant transport model (MT3DMS) and a data assimilation method (Iterative local update ensemble smoother, ILUES). In addition, Karhunen-Loève expansion technique is adopted as a PCA method to realize dimension reduction. In practical problems, the geostatistical method is usually used to characterize the hydraulic conductivity feld, and only the contaminant source information is inversely calculated in the identifcation process. In this study, the identification of contaminant source information under Kriging K-field is compared with simultaneous identification of source information and K-field. The results indicate that it is necessary to carry out simultaneous identification under heterogeneous site, and ILUES has good performance in solving high-dimensional parameter inversion problems.  相似文献   

Geographical information system-based groundwater quality index assessment of northern part of Kolkata,India for drinking purpose     

Suranjana Banerji  Deblina Mitra 《国际地球制图》2019,34(9):943-958

Groundwater is a resource under stress. In both developed and developing countries, it has been found that increasing human influence has led to the contamination of the groundwater resource. To understand the magnitude of this problem, a study was conducted in 58 wards within Northern part of Kolkata, India, where water samples from tube wells were collected and analysed on essential drinking water quality parameters, prescribed by WHO. Using Principal component analysis, and Water quality index mapping, the aforementioned results have been interpreted. This has helped to depict that not only is the groundwater unsuitable for drinking, but that the parametric values have a tendency to increase abruptly within the shortest of ranges, indicating urban pollution as the root cause of contamination. This paper shall thus discuss the spatial change in groundwater quality in northern Kolkata and suggest measures which might be implemented to secure a sustainable future for the city.  相似文献   

中国东北新生代火山区CO_2释放规模与成因     

赵文斌  郭正府  刘嘉麒  张茂亮  孙玉涛  雷鸣  马琳  李菊景 《岩石学报》2021,37(4):1255-1269

板片俯冲过程将地表碳带入地球内部,火山作用将深部碳输送至地球外部圈层,两者构成了地球深部碳循环的主要方式,进而影响了地史时期的气候变化。我国东北新生代火山活动被认为是太平洋板片深俯冲作用的产物,板片俯冲导致岩浆源区强烈的碳酸盐组分交代作用,进而使东北亚上地幔成为一个新生代时期的巨型深部碳库,它的活动和释放将会对全球的气候与环境变化造成重要影响。然而,有关该深部碳库向当今大气圈输送CO_2气体的规模及其演化过程尚不清楚,从而影响了进一步定量评估该碳库在全球变化研究中的地位和作用。针对上述科学问题,本文对我国东北长白山、五大连池和阿尔山火山释放CO_2气体的规模与成因进行了研究。结果表明,东北新生代火山区的土壤CO_2释放通量介于9.6～41.2g·m~(-2)·d~(-1)之间,每年向当今大气圈释放CO_2气体约为2.1Mt(其中,长白山火山区为0.94Mt,五大连池火山区为1.2Mt)。气体地球化学研究证实,长白山与五大连池火山气体均起源于太平洋板片深俯冲环境;但是,与长白山相比,五大连池火山气体具有较高比例壳源组分贡献。阿尔山火山气体的成分与长白山和五大连池火山区存在着明显的差异,它们以N_2为主( 95%),并且其δ~(15)N_(N_2)值高于空气值(1.3‰～1.9‰),~3He/~4He比值较低(0.14～0.18R_A),δ~(13)C_(CO_2)较轻(-13.7‰～-6.2‰),表明壳源富氮有机沉积物的贡献占比较大的比例。上述特征进一步表明,阿尔山火山气体在上升经过地下水时可能滞留了较长时间,混染了大量的陆壳组分,其源区并未受到太平洋板片俯冲物质的显著影响。  相似文献   

Arsenic contamination caused by roxarsone transformation with spatiotemporal variation of microbial community structure in a column experiment          下载免费PDF全文

Liu Ya-ci  Zhang Zhao-ji  Zhao Xin-yi  Wen Meng-tuo  Cao Sheng-wei  Li Ya-song 《地下水科学与工程》2021,9(4):304-316

Arsenic contamination from roxarsone in livestock manure is common, and livestock manure continuously accumulates in the open environment. Evaluations of the environmental processes of As mobilization and transformation are critical for predicting the fate of As compounds after roxarsone degradation. In this study, spatiotemporal variations in As species and microbial community structure were characterized using laboratory column experiments with background soil collected from Yanggu County (northern Shandong Plain, China), a region of intense poultry production. Organic and inorganic arsenic were detected by high-performance liquid chromatography (HPLC) and HPLC with hydride generation atomic fluorescence spectrometry (HPLC-HG-AFS), respectively. High-throughput sequencing technology was used to describe microbial diversity. Results showed that roxarsone was transformed completely within 7 days, and As(Ⅲ) and As(Ⅴ) were the major degradation products. The concentration of As(Ⅲ) was much lower than that of As(Ⅴ). The As(Ⅲ) concentration increased significantly after Day 14, whereas the As(Ⅴ) concentration increased significantly after Day 84, indicating that As(Ⅲ) was initially produced. The microbial community structure changed significantly as roxarsone transformed into various As compounds. A critical and dominant bacterial strain, norank_f__Family_XVⅢ, was found to be related to the degradation of roxarsone into As(Ⅲ). This study improves our understanding of the fate of As species released from poultry litter to soil and groundwater, which is a threat to human health and environment.  相似文献   

参数空间变异性下地下水污染监测网多目标优化机制研究   总被引：1，自引：0，他引：1  

骆乾坤  吴剑锋  杨运  钱家忠 《地质论评》2015,61(3):570-578

基于野外实际含水层参数存在空间变异性的客观事实,研发概率Pareto遗传算法(Probabilistic Pareto genetic algorithm,PPGA),用于求解考虑含水层参数空间变异性下地下水污染监测网多目标优化设计问题。PPGA在ε-改进非劣支配遗传算法(epsilon-dominance non-dominated sorted genetic algorithm II,ε-NSGAII)的基础上通过添加概率择优排序和概率拥挤度技术,寻求考虑参数空间变异条件下地下水污染监测网模拟—优化耦合模型的Pareto最优解。将优化结果与蒙特卡洛(Monte Carlo,MC)模拟分析结果进行对比,验证优化结果的可靠性。算例求解结果表明:在求解考虑参数空间变异性条件下地下水污染监测网多目标优化设计问题时,PPGA优化所得Pareto最优解变异性小,可靠性高,可为决策者提供一系列稳定可靠的监测方案。  相似文献   

Arsenic accumulation in the roots of Helianthus annuus and Zea mays by irrigation with arsenic-rich groundwater: Insights from synchrotron X-ray fluorescence imaging     

《Chemie der Erde / Geochemistry》2015,75(2):261-270

The aim of this study was to investigate the accumulation of arsenic (As) in and on roots of Zea mays (maize) and Helianthus annuus (sunflower) by means of synchrotron-based micro-focused X-ray fluorescence imaging (μ-XRF). Plant and soil samples were collected from two field sites in the Hetao Plain (Inner Mongolia, China) which have been regularly irrigated with As-rich groundwater. Detailed μ-XRF element distribution maps were generated at the Fluo-beamline of the Anka synchrotron facility (Karlsruhe Institute of Technology) to assess the spatial distribution of As in thin sections of plant roots and soil particles. The results showed that average As concentrations in the roots (14.5–27.4 mg kg⁻¹) covered a similar range as in the surrounding soil, but local maximum root As concentrations reached up to 424 mg kg⁻¹ (H. annuus) and 1280 mg kg⁻¹ (Z. mays), respectively. Importantly, the results revealed that As had mainly accumulated at the outer rhizodermis along with iron (Fe). We therefore conclude that thin crusts of Fe-(hydr)oxides cover the roots and act as an effective barrier to As, similar to the formation of Fe plaque in rice roots. In contrast to permanently flooded rice paddy fields, regular flood irrigation results in variable redox conditions within the silty and loamy soils at our study site and fosters the formation of Fe-(hydr)oxide plaque on the root surfaces.  相似文献   

Distribution of heavy metals in soils of Port Harcourt and its environs,Niger Delta,Nigeria   总被引：1，自引：0，他引：1  

Minapuye I Odigi  Lucky O. Ukren  Hycienth O. Nwankwoala 《中国地球化学学报》2011,30(4):415-421

Geochemical evaluation of the distribution of heavy metals in soils of Port Harcourt and its environs in the Niger Delta region is presented in respect of anthropogenic factor and index of geoaccumulation. Sixteen (16) soil samples were collected from two horizons (0-10 cm and 100 cm) from the various grids and analyzed. The geo-chemical analyses showed the vertical and horizontal distributions of heavy metals. The results showed the ranges of the metals determined as follows: Pb (6.86-2.49)×10-6, with an average of 4.63×10-6; Cd (0.05-0.00)×10-6, with an average of 0.02×10-6, As (0.01-0.00)×10-6, with an average of 0.00×10-6. Cu (15.36-10.80) ×10-6, with an average of 13.36×10-6, and V (1.36-0.20)×10-6, with an average of 0.94×10-6. Quantification of the degree of pollution was carried out using anthropogenic factor (AF) and index of geoaccumulation (Igeo). The Igeo values of 0.06, 0.02 and 0.00 for Pb, Cd and As, respectively indicate low-level contamination while Zn (1.14) and V (1.40) show me-dium-level contamination. The sources of contamination are attributed to urbanized anthropogenic activities. The majority of the samples analyzed show that the AF values are less than 1 with the exception of vanadium (V) whose AF values range from 2.73 to 13.60×10-6. Vanadium is more enriched than As, Cd, Pb, and Cu. The order of degrees of anthropogenic contamination and index of geoaccumulation in the soil is V >Zn >Pb >Cu >Cd >AS. Metals were retained near the top soil and their concentrations in the deepest horizons were lower and normal for uncontaminated soils. Metal concentrations in the top soil horizons were significantly related to distance from the industrial and hu-man activities.  相似文献