Atmospheric Reactive Nitrogen Cycle and Stable Nitrogen Isotope Processes: Progresses and Perspectives   总被引：1，自引：1，他引：0  

Tao Zhou  Zhuang Jiang  Lei Geng 《地球科学进展》2019,34(9):922-935

Oxidized reactive nitrogen in the atmosphere mainly consists of nitrogen oxides (NO _X =NO+NO₂, NO₃) and nitric acid. The atmospheric cycling of NO _X influences the formation of ozone and hydroxyl radicals that are important for atmospheric oxidation capacity. Nitric acid, the final product of NO _X oxidation, not only is an important component of particulate pollutants, but also has a direct impact on the ecosystem through dry and wet deposition. The stable nitrogen isotope (δ¹⁵N) shows the potential to study reactive nitrogen cycle, and to trace the emission, transport and deposition of reactive nitrogen from local to global scales. Here, we reviewed previous studies using δ¹⁵N to investigate NO _X emission and atmospheric reactive nitrogen cycle, and discuss the uncertainties of δ¹⁵N signatures of different NO _X sources from two aspects: NO _X generation mechanism and NO _X collection methods. We also discussed the nitrogen isotope fractionation and the consequences during the conversions of NO _y molecules. We ended up with discussions on the possibility of using δ¹⁵N to trace NO _X emissions. Although there are still large uncertainties in quantifying and tracing NO _X emissions using nitrogen stable isotopes, such isotope tool is efficient enough to trace reactive nitrogen cycles in the atmosphere. On the basis of this, we proposed that we can combine atmospheric chemistry transmission models with isotope tracers to improve our understanding of regional and global atmospheric reactive nitrogen cycle regarding the fluxes of different emission sources, their atmospheric transformation, etc.  相似文献   

Three-dimensional active earth pressure from cohesive backfills with tensile strength cutoff     

Zheng-Wei Li  Tian-Zheng Li  Xiao-Li Yang 《国际地质力学数值与分析法杂志》2020,44(7):942-961

Most of previous analyses on the active earth pressure were performed in two-dimensional cases using the Mohr-Coulomb (M-C) failure function to describe the soil strength. However, all failures of retained slopes indicate a somewhat three-dimensional (3D) feature, and the M-C function is found to overestimate the tensile strength of cohesive soil. In this work, a kinematic limit analysis–based approach is developed for computing the 3D active earth pressure resulting from cohesive backfills. The concept of tensile strength cutoff is adopted to implement the reduction or elimination of tensile strength from the strength envelope. An extended 3D horn failure mechanism that is associated with the modified strength envelope is developed to characterize the collapse of retained slopes. The resultant of active earth pressure is evaluated from the work rate balance equation and expressed as an unfactored coefficient. The obtained results indicate that less support provided by the wall is required when allowing the existence of soil cohesion and 3D effects and that eliminating the tensile strength can observably increase the active earth pressure, especially for the backfill with a great level of cohesion.  相似文献   

基于STIRPAT模型的内蒙古沙漠化地区环境压力分析     

樊胜岳  刘文文  周宁 《中国沙漠》2019,39(3):117-125

实现经济与生态环境的协调发展，已经成为当前治理沙漠化的巨大挑战。如何定量分析人类活动和自然条件对环境的影响，是当前环境经济学界研究的热点问题。以内蒙古自治区71个沙漠化县为研究对象，以1986—2010年为研究区间做面板空间计量实证分析。选取了人口、富裕度、技术水平、风速和降水作为环境基础指标构建STIRPAT模型，从环境压力内在驱动角度定量分析不同的自然因素和人为因素对沙漠化地区环境的综合影响。结果表明：在观测数据范围内，富裕度、技术水平、风速和降水是内蒙古自治区环境压力的主要驱动因素；富裕度每增加1%，环境压力显著增加0.096%；技术水平每变化1%，将引起环境压力相应发生0.084%的变化；风速和降水每变动1%分别使得沙漠地区环境压力显著地增加0.640%和减少0.216%。  相似文献   

Effects of long-term cyclic horizontal loading on bucket foundations in saturated loose sand     

《Applied Ocean Research》2019

A 1-g model experimental study was conducted to investigate the accumulated rotations and unloading stiffness of bucket foundations in saturated loose sand. One-way horizontal cyclic loading was applied to model bucket foundations with embedment ratios 0.5 and 1.0. Up to 10⁴ cycles of loading were applied at a frequency of 0.2 Hz varying load amplitudes. The accumulated rotation of the bucket foundations increased with the number of cycles and the load amplitudes. Empirical equations were proposed to describe the accumulated rotation of the foundations. The unloading stiffness of foundations increased with the number of cycles but decreased with an increase in load amplitude. The initial unloading stiffness of L/D = 1.0 (L is skirt length; D is foundation diameter) was approximately twice that of L/D = 0.5. Excess pore water pressure difference of 50% was observed between L/D = 0.5 and 1.0. The suction and static capacity of the bucket increased with increase of bucket embedment ratio with a difference of 69.5% and 73.6% respectively between L/D = 0.5 and 1.0.  相似文献   

大气负荷对新疆地区地壳形变和地面重力变化的影响     

王海涛  王斌  王伟  章传银 《大地测量与地球动力学》2019,39(2):189-194

基于ECMWF全球大气模型和中国地面气候资料日值数据集中新疆及周边的气象站气压数据，根据弹性地壳形变理论，采用移去-恢复法，利用负荷格林函数法和球谐函数法，计算新疆及周边区域2011~2015年大气负荷变化对地壳垂直、水平形变的影响，同时采用大气导纳方法计算大气变化对地面重力的影响。结果表明，大气负荷对新疆地区垂直形变的影响达到cm级，对地面重力的影响可达10 μGal；大气负荷影响具有明显的季节性。  相似文献   

迁入地资源环境压力指标体系构建与评价——以贵州省纳雍县为例     

郑钧宁  徐红 《测绘通报》2020,(8):126-130

选取贵州省纳雍县为易地扶贫迁入地研究对象，构建了评价指标体系，对迁入地资源环境压力进行了评价；同时应用层次分析法确定指标权重，计算资源环境压力，并将结果划分为相对高、中、低压力区3个等级。分析结果表明，纳雍县整体资源较为贫乏，生态环境较为脆弱，人均资源量较少，造成资源环境整体压力较大；由贫困发生率与资源环境评价值作相关分析，资源环境压力与贫困发生率呈弱负相关性。  相似文献   

地震断层对管道压溃压力的影响          下载免费PDF全文

余建星  袁祺伟  余杨  王华昆  王彩妹  赵岩 《世界地震工程》2020,(2):180-190

利用有限元软件ABAQUS,结合用户自定义Python程序,开展地震断层作用下深海管道局部变形和压溃过程的数值模拟。分析均质土体和随机分布土体模型的地震断层位移大小对管道局部变形的影响,并分析断层诱发的局部挤压变形对管道压溃压力的影响。研究表明:相比于断层走向与管道轴线方向垂直的走滑断层,断层走向与管道轴线方向夹角为45°的走滑断层作用下管道的压溃压力较小,且当断层走向为管道轴线方向逆时针旋转45°时,左旋走滑断层作用下管道的压溃压力低于右旋走滑断层作用下的管道压溃压力。断层位移相同时,管道径厚比越大,压溃压力越小。考虑土壤随机性时,由于APIX65钢制管道刚性较大,且管道两侧土体内聚力和摩擦角分散于均质土壤土体参数均值两侧,因此断层作用过程中管道受到的土压力在均质土壤模型中的土压力数值处上下波动。  相似文献   

花岗岩残积土动态冲击性能的SHPB试验研究     

刘新宇  张先伟  岳好真  孔令伟  徐超 《岩土力学》2020,41(6):2001-2008

为研究花岗岩残积土的动态冲击性能，开展了高速冲击下的分离式霍普金森压杆（SHPB）试验，与常规应变率下的试验结果比较，分析了高应变率对花岗岩残积土的应力?应变特性和强度的影响。结果表明：低、高应变率下的花岗岩残积土的?-?a（轴向应力?轴向应变）曲线均呈现出软化型。随着应变率 增加，?-?a曲线向?a增大的方向移动，破坏应变?af增加。但高应变率下?af增加的程度更加明显。花岗岩残积土的峰值强度普遍具有应变率依赖性，二者可用直线关系拟合，但低、高应变率下的拟合关系并不一致。提出了率敏性因子m定量评价依赖性强弱。研究发现，随着应变率的提高，强度的应变率依赖性减弱，低应变率下的m为26.694，而高应变率下仅为0.013。相关试验结果指出，高速冲击荷载对土体总体有害。工程中应该采取合理措施控制冲击荷载的危害。该研究有助于深化花岗岩残积土动态冲击性能的理解，为相关工程的施工与设计提供技术参考。  相似文献   

大洋地幔橄榄岩-铬铁矿中的金刚石和深地幔再循环     

杨经绥 《地质力学学报》2020,26(5):731-741

全球多地蛇绿岩型地幔橄榄岩和铬铁矿中发现微粒金刚石，并在中国西藏南部和俄罗斯乌拉尔北部的蛇绿岩铬铁矿中发现原位产出的金刚石，认为是地球上金刚石的一种新的产出类型，不同于金伯利岩型金刚石和超高压变质型金刚石。它们与呈斯石英假象的柯石英、高压相的铬铁矿和青松矿等高压矿物以及碳硅石和单质矿物等强还原矿物伴生，指示蛇绿岩中的这些矿物组合形成于深度150~300 km或者更深的地幔。金刚石具有很轻的C同位素组成（δ13C-18‰~-28‰），并出现多种含Mn矿物和壳源成分包裹体。研究认为它们曾是早期深俯冲的地壳物质，达到>300 km深部地幔或地幔过渡带后，经历了熔融并产生新的流体，后者在上升过程中结晶成新的超高压、强还原矿物组合，通过地幔对流或地幔柱作用被带回到浅部地幔，由此建立了一个俯冲物质深地幔再循环的新模式。蛇绿岩型地幔橄榄岩和铬铁矿中发现金刚石等深部矿物，质疑了蛇绿岩铬铁矿形成于浅部地幔的已有认识，引发了一系列新的科学问题，提出了新的研究方向。   相似文献   

Volatile element chemistry during accretion of the earth     

《Chemie der Erde / Geochemistry》2020,80(1):125594

We review some issues relevant to volatile element chemistry during accretion of the Earth with an emphasis on historical development of ideas during the past century and on issues we think are important. These ideas and issues include the following: (1) whether or not the Earth accreted hot and the geochemical evidence for high temperatures during its formation, (2) some chemical consequences of the Earth’s formation before dissipation of solar nebular gas, (3) the building blocks of the Earth, (4) the composition of the Earth and its lithophile volatility trend, (5) chemistry of silicate vapor and steam atmospheres during Earth’s formation, (6) vapor - melt partitioning and possible loss of volatile elements, (7) insights from hot rocky extrasolar planets. We include tabulated chemical kinetic data for high-temperature elementary reactions in silicate vapor and steam atmospheres. We finish with a summary of the known and unknown issues along with suggestions for future work.  相似文献