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1.
Five marine fish species were collected from the Natuna Island, South China Sea to investigate the occurrence of polybrominated diphenyl ethers (PBDEs), polychlorinated biphenyls (PCBs), dichlorodiphenyltrichloroethane and its metabolites (DDTs). Concentrations of PBDEs, PCBs, and DDTs in marine fish ranged from 2.85 to 7.82, 14.3 to 48.1, and 7.99 to 40.3 ng/g lipid weight, respectively. Higher concentrations of PBDEs, PCBs, and DDTs were observed in Snakefish (Trachinocephalus myops), which might be attributed to their different feeding and living habits. PCBs were the predominant POPs in all marine fish, followed by DDTs and PBDEs. BDE 47 and PCB 153 were the predominant congener of PBDEs and PCBs, respectively. Compositional distribution of DDTs indicated the possible presence of fresh input sources around the Natuna Island. The ratios of o,p′-DDT/p,p′-DDT being less than 1 in fish samples suggested that DDT contributions from dicofol seemed considerably low. New input sources of DDT in South China Sea are worth further research.  相似文献   
2.
Four bacterial isolates (two resistant and two sensitive to chromium) were isolated from soil contaminated with tannery effluents at Jajmau (Kanpur), India, and were identified by 16S rDNA gene sequencing as Stenotrophomonas maltophilia, Exiguobacterium sp., Pantoea sp., and Aeromonas sp. Biosorption of chromium by dried and living biomasses was determined in the resistant and sensitive isolates. The effect of pH, initial metal concentration, and contact time on biosorption was studied. At pH 2.5 the living biomass of chromium resistant isolate Exiguobacterium sp. ZM‐2 biosorbed maximum amount of Cr6+ (29.8 mg/g) whereas the dried biomass of this isolate biosorbed 20.1 mg/g at an initial concentration of 100 mg/L. In case of chromate sensitive isolates, much difference was not observed in biosorption capacities between their dried and living biomasses. The maximum biosorption of Cr3+ was observed at pH 4.5. However, biosorption was identical in resistant and sensitive isolates. The data on chromium biosorption were analyzed using Langmuir and Freundlich isotherm model. The biosorption data of Cr6+ and Cr3+ from aqueous solution were better fitted in Langmuir isotherm model compared to Freundlich isotherm model. Metal recovery through desorption was observed better with dried biomasses compared to the living biomasses for both types of chromium ions. Bioaccumulation of chromate was found higher in chromate resistant isolates compared to the chromate sensitive isolates. Transmission electron microscopy confirmed the accumulation of chromium in cytoplasm in the resistant isolates.  相似文献   
3.
Currently, nanotechnology has gained much interest due to the unique properties of nanomaterials in science and technology. Different types of metallic nanoparticles are routinely synthesized. However, their release into the aquatic environments is a major ecotoxicological concern. In this scenario, it is important to study the potential impact of engineered nanoparticle in aquatic organisms especially freshwater microcrustaceans, such as Ceriodaphnia cornuta. In this study, ZnO NPs were synthesized using the aqueous leaf extracts of Musa paradisiaca and physico-chemically characterized by UV–Vis spectroscopy, X-ray diffraction (XRD), Fourier transform infra red (FTIR), scanning electron microscopy (SEM) and atomic force microscopy (AFM). UV–Vis spectroscopy recorded the absorbance peak of ZnO NPs at 338 nm. XRD analysis showed the various Bragg’s reflection peaks at 100, 002, 101, 102, 110, 103, 200, 112, 201, 004 and 202 lattice planes. FTIR spectroscopy outlined sharp intense peaks at 3416 cm−1, 1388 and 1416 cm−1. SEM showed the spherical shape of ZnO NPs with mean particle size of 23.3 nm. AFM confirmed the spherical shape, nanosize and 3D topography of NPs. The ecotoxicity of ZnO NPs was tested on the freshwater crustacean C. cornuta. ZnO NPs were comparatively less toxic than zinc acetate. ZnO NPs caused 42% mortality of C. cornuta at 50 μg mL−1. However, 80% mortality was observed at 50 μg mL−1 of zinc acetate after 24 h. Light and confocal laser scanning microscopic images evidenced the uptake and accumulation of ZnO NPs in the gut of C. cornuta at 50 μg mL−1 after 24 h. Structural deformities were observed on C. cornuta after treatment with 50 μg mL−1 of ZnO NPs. Overall, this study describes the potential impact of the biologically synthesized ZnO NPs in comparison with zinc acetate in the freshwater crustacean C. cornuta.  相似文献   
4.
Selenium (Se) may cause reproductive toxicity, yet the characteristics of Se bioaccumulation in aquatic food webs are understudied. Stream biofilms were grown in two reaches of Mud River, West Virginia (WV), including one downstream of a coal mine complex and an adjacent, unmined watershed. Mined stream biofilms contained significantly higher Se concentrations compared to unmined biofilms. An inverse relationship between water Se concentrations and biofilm accumulation factors was observed; mined-stream biofilms had an average bioconcentration factor (BCF) of 688 ± 350 fold while unmined-stream biofilms had an average BCF of 14505 ± 2700 fold.  相似文献   
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6.
In order to control and remediate arsenic (As) contaminated soil, sediment or water, fungi are used to investigate their potential accumulation and volatilization of As. In this study, after cultivation for 2 days, the dry weights of mycelia for Trichoderma asperellum, Fusarium oxysporum and Penicillium janthinellum all show an increased trend when the As(V) concentration ranges from 0–50, 0–50, 0–80 mg/L, respectively. When the culture system is loaded with 2500 μg As(V), which represents 50 mg/L As, and cultivated for 5 days, P. janthinellum presents the highest efficiency of 87.0 μg/g for As bioaccumulation, and the order of the efficiency for As bioaccumulation is P. janthinellum > T. asperellum > F. oxysporum. However, the order of the amount of volatilized As is F. oxysporum > P. janthinellum > T. asperellum, and the highest amount of volatilized As is observed for F. oxysporum at 181.0 μg. Thus, the ability of As bioaccumulation and biovolatilization for T. asperellum and P. janthinellum is reported for the first time in this study.  相似文献   
7.
In the present study, we sought to determine the concentration of several trace elements (total and organic mercury, selenium, cadmium, lead, arsenic, copper, chromium, iron, manganese, molybdenum, vanadium and zinc) in muscle tissue of gilthead seabream (Sparus aurata), an edible finfish species that is widely cultured in the Mediterranean area. The phenomenon of bioaccumulation and bioamplification (especially of mercury) was investigated by comparing farmed fish with wild specimens of the same species. Farmed specimens showed mercury and arsenic concentrations significantly lower than wild specimens, and no relationship was found between mercury concentration and body size. The lower level of methylmercury in farmed fish has important implications for consumer health.  相似文献   
8.
极地区域由于其独特的地理位置和自然条件,是对全球气候变化和环境污染响应和反馈最为敏感的区域之一,在全球气候变化和环境污染研究中占据重要地位。HBCDs作为一种新型持久性有机污染物,近几年受到国际社会的广泛关注。文章对HBCDs特性及近几年来极地、中低纬度区域HBCDs研究进行了综述,对比分析了环境中大气、水体、土壤、沉积物、植被和生物等多介质中HBCDs赋存水平,探讨了其异构体在多介质中的浓度分配差异,并对其可能原因给出解释,论证了HBCDs污染防治及其进一步环境行为研究对人类健康及生态环境安全的重要意义。  相似文献   
9.
The rapid and high bioaccumulation of mercury in marine mammals and its spatial and temporal variations have been a major puzzle in the Arctic. While extensive efforts have been focussed on the monitoring and chemistry of atmospheric mercury depletion events, a recent mass budget estimate of mercury in the Arctic suggests that we have overlooked the role of the ocean itself. Only through focussed studies on Hg dynamics in the Arctic Ocean under a changing climate are we going to understand what the risk of mercury is to those marine ecosystems and the people who rely on them.  相似文献   
10.
We monitored the concentrations of copper, lead and cadmium in seawater, in suspended particulate matter (SPM) and in bacteria, phyto- and zooplankton communities separated from abiogenic particles, over a one year cycle in two coupled Mediterranean coastal ecosystems (Little Bay (LiB) and Large Bay (LaB)). Metals were present in seawater in the order Cu > Pb > Cd in both bays and showed important variations within the same month than among months. In LiB, their concentrations were between 0.62 and 2.82 μg Cu l−1, 0.16 and 19 μg Pb l−1 and 0.007 and 0.14 μg Cd l−1, respectively, whereas in LaB, they were between 0.23 and 2.11 μg Cu l−1, 0.09 and 0.76 μg Pb l−1 and not detected and 0.65 μg Cd l−1. SPM play an important role on metal adsorption, especially for copper. Bioaccumulation factors showed that bacteria and phytoplankton accumulate metals whereas zooplankton tends to biodiminish them in the plankton food web.  相似文献   
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