首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   33篇
  免费   6篇
  国内免费   1篇
大气科学   1篇
地球物理   23篇
地质学   13篇
海洋学   2篇
自然地理   1篇
  2021年   2篇
  2018年   1篇
  2017年   2篇
  2016年   2篇
  2015年   5篇
  2013年   2篇
  2012年   4篇
  2011年   6篇
  2010年   2篇
  2009年   2篇
  2008年   1篇
  2007年   3篇
  2006年   2篇
  2005年   1篇
  2004年   2篇
  2003年   1篇
  2002年   1篇
  2001年   1篇
排序方式: 共有40条查询结果,搜索用时 15 毫秒
1.
2.
3.
4.
The removal of chemical oxygen demand (COD) and phenol from olive oil mill wastewaters (OOMW) was investigated experimentally by using conventional Fenton (CFP) and Fenton type processes (FTP) with zero valent iron (ZVI). Different operational parameters such as initial pH, Fe2+, Fe0, and H2O2 concentrations were examined. Kinetic studies in terms of COD and phenol removals for both CFP and FTP were performed. The original pH value (4.6) of OOMW for CFP was found as the optimum pH. The determined optimum conditions are [Fe2+] = 1500 mg L?1, [H2O2] = 1750 mg L?1, and pH = 4.6 for CFP; [Fe0] = 2000 mg L?1, [H2O2] = 2000 mg L?1, and pH = 3 for FTP. 82.4% COD and 62% phenol removals were performed under the optimum conditions by CFP, while 82% COD and 63.4% phenol were removed by FTP. According to the results of kinetic studies, it was observed that COD and phenol were removed by FTP more rapidly, compared to CFP. Consequently, it was determined that both CFP and FTP were effective processes for the pretreatment of OOMW.  相似文献   
5.
The feasibility of pilot‐scale mineralization of organic pollutants in wastewaters using the Electro‐Fenton® process is demonstrated. The treatment was applied in a continuous‐flow reactor, to solutions of nitrobenzene, 2,4‐D and benzoic acid and to actual wastewaters from a fine chemicals company along with a pulp and paper company. The results showed mineralization yields from 60 to 84% by simply applying the Electro‐Fenton® process. When a subsequent exposure to sunlight was carried out (Helielectro‐Fenton method), this mineralization almost went to completion, except for the effluent from the fine chemicals industry.  相似文献   
6.
In the present study, the effects of initial COD (chemical oxygen demand), initial pH, Fe2+/H2O2 molar ratio and UV contact time on COD removal from medium density fiberboard (MDF) wastewater using photo‐assisted Fenton oxidation treatment were investigated. In order to optimize the removal efficiency, batch operations were carried out. The influence of the aforementioned parameters on COD removal efficiency was studied using response surface methodology (RSM). The optimal conditions for maximum COD removal efficiency from MDF wastewater under experimental conditions were obtained at initial COD of 4000 mg/L, Fe2+/H2O2 molar ratio of 0.11, initial solution pH of 6.5 and UV contact time of 70 min. The obtained results for maximum COD removal efficiency of 96% revealed that photo‐assisted Fenton oxidation is very effective for treating MDF wastewater.  相似文献   
7.
Fenton氧化膜-生物反应器出水中丙烯腈的实验研究   总被引:4,自引:0,他引:4  
采用膜-生物反应器和Fenton氧化组合工艺对丙烯腈废水进行处理。从GC/MS测量结果来看,膜-生物反应器出水中主要物质为2,6双(二甲基 乙基) 4 酚、苯二甲酸和硝基苯二甲酸,均为生物难降解有机物,使出水不能达标。后续Fenton氧化工艺处理膜生物反应器出水,可以使COD含量等指标达到所要求的排放标准。经过膜 生物处理与Fenton法结合的优化工艺,COD去除率达到80%~88%,BOD5去除率达到98%,出水水质可达排放标准。Fenton氧化工艺的最佳工艺条件为:pH值为3 4,硫酸亚铁的投加量为700mg/L,双氧水的投加量为600mg/L。  相似文献   
8.
在原位氧化过程中,实际场地地下水和含水介质的物化特征是影响氧化效果的重要因素,而目前对此影响的研究较少。以某场地实际高盐强酸性复合苯系污染地下水为研究对象,以地下水中2-硝基-4-甲氧基苯胺(2-nitro-4-methoxyaniline,2-N)和3-硝基-4-甲氧基苯胺(3-nitro-4-methoxyaniline,3-N)为特征污染物,探究芬顿(Fenton)试剂原位氧化特征,并研究液相环境因素(初始H2O2浓度、初始Fe2+浓度、初始pH值、初始醋酸(Acetic acid,HAc)浓度、初始SO42-浓度)以及含水层介质对Fenton法去除2-N和3-N的影响。结果显示:(1)Fenton法去除2-N和3-N效果显著,且在初始液相条件为c(H2O2)=7 mmol/L、c(Fe2+)=4 mmol/L、pH=4、c(HAc)=0 mg/L和c(SO42-)=0 mmol/L时去除效果最佳;(2)各因素对Fenton法氧化2-N和3-N的影响不同,加入H2O2和Fe2+使2-N和3-N去除率上升,增大HAc浓度使2-N和3-N去除率下降;(3)含水层介质对2-N和3-N具有一定吸附性,且对3-N的吸附性强于2-N,二者在本实验中最大吸附态占比分别为29%和42%,而吸附态的存在会抑制Fenton法对2-N和3-N的去除;(4)矿物分析结果显示介质含有少量黄铁矿,在硫酸环境下,介质腐蚀溶解释放Fe2+,在达到一定浓度后,无需额外添加Fe2+即可完成Fenton反应进而去除2-N和3-N。  相似文献   
9.
增强型(或工程)地热系统是指从地壳深部低孔渗的干热岩体中,采用人工工程方法形成储层,经济地采出具有相当数量的热能.这种早期被称之为干热岩的技术首次在美国新墨西哥州芬登山得到示范.本文以芬登山增强型地热系统为例,通过综述其发展历程,论述了增强型地热系统钻井与储层激发、工质流动与储层测试、储层性能评价等关键问题,总结了从芬登山增强型地热系统研究中获得的认识和启示.芬登山地热项目发展的经验表明,增强型地热储层是通过重新打开本来存在、但被密封的、多重连通的节理组,或通过水力压裂创造新的流动通道和换热面,利用复杂裂隙网络中的流循环,从储层系统中开采热能.芬登山实践表明,在稳态条件下增强型地热系统的持续运行是可能的,芬登山地热项目对世界和我国深层地热发展具有重要指导意义.  相似文献   
10.
The degradation reactions of two monoazo pigments, namely, Red 53:1 and Red 48:2, by Fenton, photo‐Fenton and UV/H2O2 systems have been studied. The efficiencies of the Fenton reactions increased with temperature, but the formation of solid agglomerates was observed when the reactions were carried out above 50°C indicating a coagulant action of Fe+2 or Fe+3. Photo‐Fenton reactions irradiated by sunlight presented the best rate constants for cleavage of the azo bond and the naphthalene rings. The UV/H2O2 system exhibited the highest efficiency with respect to the consumption of H2O2. The presence of a carbonyl group in the ortho position of the naphthol ring hampered the oxidation of pigment Red 48:2 by hydroxyl radicals. This finding may be explained in terms of the acceptor character of the COOH group, and suggests the formation of a complex containing two six‐membered rings between Fe+3 and the pigment molecule.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号