Origin of sulphate in the unsaturated zone and groundwater of a loess aquifer     

Yin Long  Tianming Huang  Fen Zhang  Zhenbin Li  Baoqiang Ma  Yiman Li  Zhonghe Pang 《水文研究》2021,35(4):e14166

The use of the sulphate mass balance (SMB) between precipitation and soil water as a supplementary method to estimate the diffuse recharge rate assumes that the sulphate in soil water originated entirely from atmospheric deposition; however, the origin of sulphate in soil and groundwater is often unclear, especially in loess aquifers. This study analysed the sulphur (δ³⁴S-SO₄) and oxygen (δ¹⁸O-SO₄) isotopes of sulphate in precipitation, water-extractable soil water, and shallow groundwater samples and used these data along with hydrochemical data to determine the sources of sulphate in the thick unsaturated zone and groundwater of a loess aquifer. The results suggest that sulphate in groundwater mainly originated from old precipitation. When precipitation percolates through the unsaturated zone to recharge groundwater, sulphates were rarely dissolved due to the formation of CaCO₃ film on the surface of sulphate minerals. The water-extractable sulphate in the deep unsaturated zone (>10 m) was mainly derived from the dissolution of evaporite minerals and there was no oxidation of sulphide minerals during the extraction of soil water by elutriating soil samples with deionized water. The water-extractable concentration of SO₄ was not representative of the actual SO₄ concentration in mobile soil water. Therefore, the recharge rate cannot be estimated by the SMB method using the water-extractable concentration of SO₄ in the loess areas. This study is important for identifying sulphate sources and clarifying the proper method for estimating the recharge rate in loess aquifers.  相似文献   

黄土洞室掘进深度与围岩位移变化规律研究     

时卫民  王鹏  赵尚毅 《岩土工程技术》2020,(2):70-75

应用PLAXIS 2D/3D有限元分析软件,对某黄土洞室进行了二维、三维分步掘进、三维一次掘进等工况的弹塑性有限元分析,研究分析了不同工况下洞室围岩位移的变化规律,并对掌子面的空间效应进行了分析。分析结果表明,二维与三维分步计算的最终位移基本一致,可以用二维的计算结果来估算洞室开挖的最终位移。三维分步掘进的分析表明,不同埋深的洞室其位移比的变化规律基本一致,当L/B<1时(L为掘进深度,B为洞室跨度),位移比呈线性增加;当L/B>1时,位移比呈非线性增加;当L/B>3时,其最大位移接近最终位移。掌子面的空间效应分析表明,在掌子面处的位移约为最终位移的1/3,距掌子面0.5倍跨度处的位移约为最终位移的2/3,距掌子面2.5倍跨度处的位移基本达到了最终位移。  相似文献   

金矿立体地球化学探测模型与深部钻探验证   总被引：1，自引：0，他引：1  

王学求  张必敏  于学峰  杨德平  夏勇  谭亲平  刘耀文  张苏坤  田密  刘汉粮  李瑞红  韩志轩  熊玉新  吴慧  张宝云 《地球学报》2020,41(6):869-885

深部资源地球化学探测科学问题的的焦点是元素大深度垂向迁移机理和立体地球化学探测模型的建立。本文以胶东蚀变岩型金矿和贵州水银洞卡林型金矿钻孔岩芯和地表联合取样获得的数据, 建立千米深度立体地球化学探测模型。蚀变岩型金矿立体地球化学模型显示, Au、S和Hg与金矿密切相关, 分布模式既有相似性又有差异性, Au的立体几何分布模式兼具矿化剂元素S和远程指示元素Hg的双重特征, 金异常和矿化剂元素硫与矿体倾斜方向一致, 反映了成矿过程中流体沿控矿构造的轴向运移; 金异常与类气体元素汞在垂向上一致, 而且出现从矿体到地表的连续贯通式异常, 反映了流体沿微裂隙和纳米孔的垂向迁移。卡林型金矿立体地球化学模型显示, Au、As、Sb、Hg、Tl和S在不整合面都显示高含量特征, 与深部层状主矿体分布一致; 在矿体上覆地层中都存在弱异常, 显示了明显的成矿流体沿隐伏微小断裂垂向迁移特点; 所不同的是Sb和Tl元素在不整合面附近显示了最高的元素含量, 而Sb和Hg在近地表均显示了明显高的异常特征。立体几何模型清晰地显示了矿体的展布特征和范围, 而且金及其伴生元素垂向迁移在地表形成清晰异常, 为利用金及伴生元素和矿化剂元素进行深部矿体三维预测提供了重要依据, 对指导深部金矿勘查发挥了重要作用。针对胶东蚀变岩型金矿地表完全被土壤覆盖区的穿透性地球化学微细粒级土壤采样, 金属活动态提取分析圈定的异常, 经深部钻探验证, 胶东焦家成矿带五一村3200 m钻探, 在2428.00~3234.16 m深度发现6层矿化体, 其中高品位矿体位于2854 m深度; 上宫金矿地表基岩出露, 采集断层泥或裂隙岩石样品, 可以清晰探测深部异常, 经2000 m钻探, 在1312 m处发现高品位金铅锌银矿体; 贵州水银洞采集地表细粒级土壤, 能够直接有效地揭示深部金矿体, 经500~1500 m钻探验证, 在300~1500 m深度新增金资源量203 t。  相似文献   

Interplay of S and As in Mekong Delta sediments during redox oscillations   总被引：1，自引：1，他引：0  

Van T.H.Phan  Fabrizio Bardelli  Pierre Le Pape  Raoul-Marie Couture  Alejandro Fernandez-Martinez  Delphine Tisserand  Rizlan Bernier-Latmani  Laurent Charlet 《地学前缘(英文版)》2019,10(5):1715-1729

The cumulative effects of periodic redox cycling on the mobility of As,Fe,and S from alluvial sediment to groundwater were investigated in bioreactor experiments.Two particular sediments from the alluvial floodplain of the Mekong Delta River were investigated:Matrix A(14 m deep)had a higher pyrite concentration than matrix B(7 m deep)sediments.Gypsum was present in matrix B but absent in matrix A.In the reactors,the sediment suspensions were supplemented with As(Ⅲ)and SO_4~(2-),and were subjected to three full-redox cycles entailing phases of nitrogen/CO_2,compressed air sparging,and cellobiose addition.Major differences in As concentration and speciation were observed upon redox cycling.Evidences support the fact that initial sediment composition is the main factor controlling arsenic release and its speciation during the redox cycles.Indeed,a high pyrite content associated with a low SO_4~(2-)content resulted in an increase in dissolved As concentrations,mainly in the form of As(Ⅲ),after anoxic half-cycles;whereas a decrease in As concentrations mainly in the form of As(Ⅴ),was instead observed after oxic half-cycles.In addition,oxic conditions were found to be responsible for pyrite and arsenian pyrite oxidation,increasing the As pool available for mobilization.The same processes seem to occur in sediment with the presence of gypsum,but,in this case,dissolved As were sequestered by biotic or abiotic redox reactions occurring in the Fe—S system,and by specific physico-chemical condition(e.g.pH).The contrasting results obtained for two sediments sampled from the same core show that many complexes and entangled factors are at work,and further refinement is needed to explain the spatial and temporal variability of As release to groundwater of the Mekong River Delta(Vietnam).  相似文献   

近六百年来长江三角洲地区城镇空间与城镇体系格局演变分析     

覃丽君  金晓斌  蒋宇超  薛樵风  成一农  龙瀛  杨绪红  周寅康 《地理研究》2019,38(5):1045-1062

基于历史文献、古地图和现代遥感数据,引入历史学古代城镇形态复原方法,复原（提取）明代以来长江三角洲地区113座城镇7个时间断面（1461年、1820年、1930年、1970年、1980年、2000年和2010年）下的城镇边界,采用扩张速率、扩张效率、首位度指数和位序-规模法则,分析了近六百年来区域城镇空间与城镇体系等级规模演变格局。取得以下研究结果：\mathrm{①}研究时段内,区内城镇用地总规模由205.98 km²增加到6442.19 km²,扩大了31.27倍;城镇扩张经历了萌芽阶段（明清时期）、起步阶段（民国至改革开放前夕）、成长阶段（改革开放至2000年）和加速阶段（2000—2010年）,城镇扩张速率不断加快,但扩张效率有待提升;\mathrm{②}在城镇等级规模空间格局上,明清时期南京与苏州为区内的一级城镇,民国后,上海逐渐取代其地位,从五级城镇发展成为区域核心城镇,四级以上城镇主要集中在长江干流沿岸和太湖流域,五级以下城镇大多集中在安徽;城镇体系呈首位型分布,城镇首位度较高,且改革开放后的城镇首位度较明清与民国时期要高,不同等级规模城镇之间差距扩大,大城镇优势较强。近30年,长江沿岸城镇发展加速,苏锡常都市圈、南京都市圈等逐渐形成并快速发展。  相似文献   

1976-2016年青藏高原地区通达性空间格局演变   总被引：1，自引：0，他引：1  

高兴川  曹小曙  李涛  吕敏娟 《地理学报》2019,74(6):1190-1204

青藏高原地区是地球上最独特的地理—生态—人口—交通单元,区域内交通网络的发展特征及规律是人地关系协同发展的一个重要切入点,对青藏高原地区交通网络开展研究具有重要意义。据此,分析1976-2016年青藏高原地区交通网络演化特征,并以省会、地级市、县级市和县城为节点,采用网络分析的时间距离计算模型探讨其通达性演变过程。研究表明：① 青藏高原地区交通网络复杂性、区域连通性增强,初步形成格状交通网络;② 青藏高原地区中心城市、县城之间的平均最短通达时间已极大缩短至11.89 h、18.84 h,呈自东向西逐渐增大的空间格局,时空收敛效应显著,通达性变化程度与其初始值有关;③ 中心城市为该地区的发展极,其与周围城市通达状况有极大提高,可达时间平均值下降到16.49 h;④ 中心城市和县城交通圈演变过程一致,青藏高原地区各地到最近城市、县城的通达时间不断缩小,沿重要交通干线已形成中心城市4 h、县城2 h短时交通圈连片分布格局,湟水河谷地、一江两河地区逐渐形成交通廊道,乡镇对外交通联系得到改善。  相似文献   

基于手机数据的北京市城市与近郊交互模式挖掘     

彭卉  杜云艳  易嘉伟  刘张  王会蒙 《地球信息科学学报》2019,21(1):97-106

在城镇化进程中,城市与近郊之间通过职住、货运、游憩等活动产生越来越紧密的交互联系,对于这些交互联系的准确识别和定量刻画,是理解城乡空间关系的重要手段,也能为城市的资源有效配置与合理规划提供重要的现状信息。本文通过对全北京在一日之内的手机信令数据所反映的人群移动轨迹的深入分析,融合城市的POI信息形成顾及人类活动时空信息的空间交互类型推断。以北京市为例,对城市中心与近郊之间远距离的强交互进行定性、定量和定位的探索。本文发现了北京市多尺度下空间交互模式和距离衰减规律,判断了城乡异常交互类型,对比了城乡之间和城市内部的交互模式的异同,以及基于交互类型视角提取了城乡异常交互的空间特征。研究认为,基于手机信令数据,利用停留点提取和高斯核密度估计的空间交互类型推断有效地发现了北京市周末的远距离出行类型特点,提取了其空间交互强度和空间特征,揭示了基于人类活动的北京市周末城乡交互模式。  相似文献   

生态地理学概念界定及其经典案例分析     

傅声雷  傅伯杰 《地理科学》2019,39(1):70-79

对生态地理学的概念进行了详细讨论和辨析,并将它与相近学科如生物地理学、生态地理区划、宏生态学等进行了比较分析,界定了生态地理学的概念。研究认为：生态地理学是生态学和地理学的交叉学科,是研究生态系统各组分关系和生态过程的地理空间分布格局或/和时间演变规律及其与地理环境耦合机制的学科。生态地理学的目的是揭示不同环境梯度下或不同时间尺度上生态系统各组分关系和生态过程的普适性规律及其成因。同时,结合国内外野外实验平台介绍,在全球变化等研究领域列举了经典案例进行分析：① 全球不同气候带森林凋落物分解和碳汇功能的研究;② 中国不同陆地生态系统碳通量和碳汇功能研究;③ 中国东北样带和南北样带陆地生态系统的脆弱性与适应性研究;④ 中国北方草地样带尺度的生态系统生态学研究。主要目的是在辨析生态地理学概念的基础上指出未来发展方向,推动生态地理学的发展。  相似文献   

四川米易海塔地区混合岩型铀矿流体包裹体特征     

郭锐  陈友良  刘凯鹏  郑玉文  胡漾 《矿物学报》2020,40(2):137-148

混合岩型铀矿是康滇地轴上最有希望取得找矿突破的铀矿类型,海塔地区的铀矿化即是该类型铀矿的典型代表。本文针对区内的长英质脉矿石、富晶质铀矿石英脉矿石和含矿热液石英脉中的石英流体包裹体进行了研究。结果表明,海塔地区混合岩型铀矿的成矿作用可分为2个阶段:早期混合岩化热液成矿阶段为高温、中低盐度流体,流体包裹体均一温度集中在380~540℃,盐度变化范围为16.15%~23.18%NaCl eqv,是区内铀成矿的主要阶段;晚期热液叠加改造成矿阶段为中低温、低盐度流体,流体包裹体均一温度集中在140~220℃,盐度变化范围为5.56%~23.18%NaCleqv,是区内富铀矿的形成阶段。流体包裹体的气相成分测试表明,长英质脉矿石石英包裹体中以CH4、CO2为主,其次为H2O和N2;而富晶质铀矿石英脉及含矿热液石英脉石英包裹体中以H2为主,部分含有CO2、CH4、H2O。氢、氧同位素研究表明,早期混合岩化成矿阶段的成矿流体可能为岩浆水与变质水的混合,而晚期热液叠加改造成矿阶段成矿流体中可能有大气降水的加入。  相似文献   

Spatial patch structure and adaptive strategy for desert shrub of Reaumuria soongorica in arid ecosystem of the Heihe River Basin     

Li  Wei  Li  Xiaoyan  Huang  Yongmei  Wang  Pei  Zhang  Cicheng 《地理学报(英文版)》2019,29(9):1507-1526

In many arid ecosystems, vegetation frequently occurs in high-cover patches interspersed in a matrix of low plant cover. However, theoretical explanations for shrub patch pattern dynamics along climate gradients remain unclear on a large scale. This context aimed to assess the variance of the Reaumuria soongorica patch structure along the precipitation gradient and the factors that affect patch structure formation in the middle and lower Heihe River Basin (HRB). Field investigations on vegetation patterns and heterogeneity in soil properties were conducted during 2014 and 2015. The results showed that patch height, size and plant-to-patch distance were smaller in high precipitation habitats than in low precipitation sites. Climate, soil and vegetation explained 82.5% of the variance in patch structure. Spatially, R. soongorica shifted from a clumped to a random pattern on the landscape towards the MAP gradient, and heterogeneity in the surface soil properties (the ratio of biological soil crust (BSC) to bare gravels (BG)) determined the R. soongorica population distribution pattern in the middle and lower HRB. A conceptual model, which integrated water availability and plant facilitation and competition effects, was revealed that R. soongorica changed from a flexible water use strategy in high precipitation regions to a consistent water use strategy in low precipitation areas. Our study provides a comprehensive quantification of the variance in shrub patch structure along a precipitation gradient and may improve our understanding of vegetation pattern dynamics in the Gobi Desert under future climate change.

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