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1.
龙门上仓铅锌矿是广东省上仓式沉积改造型铅锌矿的典型矿床。通过对龙门上仓铅锌矿的矿床特征进行研究,综合前人的研究成果,归纳总结出该矿床的成矿要素,并且对矿床的成矿模式进行了初步探讨。研究表明,由大赛坝组构成槽部的开阔向斜以及南西翼帽子峰组层间破碎带构成的控矿构造是该矿的必要成矿要素。矿床成因属于岩浆热液—沉积改造型。 相似文献
2.
To improve the usefulness and accuracy of modeling Earth's anthrobiogeochemical metal cycles, global maps at approximately 1° × 1° are produced of the concentrations and masses of Fe, Al, Cu, and Zn contained in continental sediments and soils. The maps generated utilize inverse distance weighting (IDW) and cokriging to generate new estimates for geospatially weighted mean global concentrations for these metallic micronutrients. Sediment metal concentration maps are generated from IDW of sediment samples; global soil maps are produced via cokriging upon an underlying parent rock dataset composed of both surface bedrock and sediment samples. Derived are independent estimates for the global mean concentrations in continental sediments (Fe = 3.1 wt.%, Al = 6.1 wt.%, Cu = 45 μg/g, Zn = 86 μg/g) and soils (Fe = 2.5 wt.%, Al = 3.9 wt.%, Cu = 17 μg/g, Zn = 50 μg/g). While continental sediment concentrations for Cu are within the range of previous estimates, Zn concentrations are relatively higher, ~ 20 μg/g above previous estimates. Fe and Al are slightly depleted (~ 1 wt.%) in continental sediments relative to previous estimates, likely ascribable to sampling bias and error inherent in the comparative methodologies. Besides an estimated global mean, metal concentrations in soils are also broken down by FAO soil group. Metal masses in sediments and soils remain within 30% of previous, non-spatial estimates. These maps also illustrate the discernable spatial variability across the Earth's surface. Despite data gaps, maps of metal mass show regional patterns such as the high quantities of Al in the soils and biomass of the Amazonia and Congo regions. Concentrations of metals are relatively high in the anthrosols of China. Finally, this analysis highlights those areas for which generating and providing publically available geochemical data should be prioritized. For instance, gypsisols, lixisols, and nitisols have little to no analytical data available on metal contents. A sensitivity analysis suggests that the most poorly constrained soil metal concentrations occur in the thick, old tropical soils of central Africa and the anthrosols of eastern China. 相似文献
3.
A multi‐element ion‐pair extraction method was described for the preconcentration of Cd(II), Co(II), Cr(III), Cu(II), Fe(III), Mn(II), Ni(II), Pb(II), and Zn(II) ions in environmental samples prior to their determinations by flame atomic absorption spectrometry (FAAS). As an ion‐pair ligand 2‐(4‐methoxybenzoyl)‐N′‐benzylidene‐3‐(4‐methoxyphenyl)‐3‐oxo‐N‐phenyl‐propono hydrazide (MBMP) was used. Some analytical parameters such as pH of sample solution, amount of MBMP, shaking time, sample volume, and type of counter ion were investigated to establish optimum experimental conditions. No interferences due to major components and some metal ions of the samples were observed. The detection limits of the proposed method were found in the range of 0.33–0.9 µg L?1 for the analyte ions. Recoveries were found to be higher than 95% and the relative standard deviation (RSD) was less than 4%. The accuracy of the procedure was estimated by analyzing the two certified reference materials, LGC6019 river water and RTC‐CRM044 soil. The developed method was applied to several matrices such as water, hair, and food samples. 相似文献
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The influence of salinity on the solubility of Zn and Cd sulphides in the Scheldt estuary 总被引:2,自引:0,他引:2
In the estuary of the river Scheldt, where an oxygen gradient exists in addition to the salinity gradient, redox processes will be of major importance for trace metal mobilisation. In this study, the influence of salinity and pH on the redox processes of dissolved Zn and Cd sulphides is investigated together with the effects on the ratio of the dissolved Zn and Cd concentrations. The speciation of these metals is calculated with the chemical equilibrium programme
+. Zn sulphides are oxidised at lower oxygen concentrations than Cd sulphides, due to lower stability constants, causing a sudden increase or peak in the dissolved Zn/Cd ratio. The formation of dissolved Cd chloride complexes when oxidation occurs at high salinities (S=15) increases the mobility of Cd, causing a decrease in the Zn/Cd peak of the total dissolved concentrations. The peak is three to four times smaller at S=15 than when oxidation occurs at S=2. The simple model calculations compare very well with field data. The Scheldt estuary is suitable to illustrate these calculations. In the 1970s, the anoxic part of the estuary reached S=15–20, but since the early 1980s it has dropped to S=2–10. Historic data on metals in the estuary from 1978, 1987 and the 1990s were used to compare with the equilibrium calculations. The increase of the dissolved Zn/Cd peak at low salinity as a consequence, of the decreasing anoxic region is confirmed well by the data. The good agreement between model calculations and field data is a proof of the extreme importance of redox processes for the solubility of Zn and Cd sulphides in the estuary. 相似文献
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7.
Pasquale Crea Concetta De Stefano Demetrio Milea Silvio Sammartano 《Marine Chemistry》2008,112(3-4):142-148
The results of a potentiometric investigation (by ISE-H+, glass electrode) on the speciation of phytate ion (Phy12−) in an ionic medium simulating the major components (Na+, K+, Ca2+, Mg2+, Cl− and SO42−) of natural seawater, at different salinities and t = 25 °C, are reported. The work was particularly aimed at determining the possible formation of mixed Ca2+–Mg2+–phytate ion pairs, and to establish how including the formation of these mixed species would affect the speciation modeling in seawater media. After testing various speciation models, that considering the formation of the MgCaH3Phy5−, MgCaH4Phy4−, Mg2CaH3Phy3− and Mg2CaH4Phy2− species was accepted, and corresponding stability constants were determined at two salinities (S = 5, 10). A discussion is reported both on the choice of the experimental conditions and on the possibility to extend these results to those typical of real seawater. A detailed procedure is also described to demonstrate that the stability of these species is higher than that statistically predicted. As reported in literature, a parameter, namely log X, has been determined in order to quantify this extra stability for the formation of each mixed species at various salinities. For example, at S = 10, log X113 = 2.67 and log X114 = 1.37 for MgCaH3Phy5− and MgCaH4Phy4− (statistical value is log Xstat = 0.60), and log X213 = 6.11 and log X214 = 2.15 for Mg2CaH3Phy3− and Mg2CaH4Phy2− (log Xstat = 1.43), respectively. Results obtained also showed that the formation of these species may occur even in conditions of low salinity (i.e. low concentration of alkaline earth cations) and low pH (i.e., more protonated ligand). 相似文献
8.
采用分子动力学模拟,研究了西藏拉果错盐湖卤水中阴、阳离子以及水分子间的相互作用行为。以盐湖卤水等温蒸发过程中粒子浓度变化的四个阶段为研究对象,分别计算了不同体系的扩散系数、配位数、均方位移和径向分布函数。计算结果表明,液相浓度越低时,H2O分子对各离子之间的相互作用有抑制作用,液相中离子浓度越高时,SO42-易与CO32-竞争Li+形成离子对,从而影响盐湖卤水中Li+的富集。本文研究结果对盐湖卤水中Li+的迁移行为作出了机理解释,为盐湖卤水提锂的发展奠定了理论基础。 相似文献
9.
Ruchi Mishra 《Planetary and Space Science》2006,54(2):188-199
Dispersion relation, resonant energy transferred, growth rate and marginal instability criteria for the electrostatic ion-cyclotron wave with general loss-cone distribution in low-β anisotropic, homogeneous plasma in the auroral acceleration region are discussed by investigating the trajectories of the charged particles. Effects of the parallel electric field, ion beam velocity, steepness of the loss-cone distribution and temperature anisotropy on resonant energy transferred and growth rate of the instability are discussed. It is found that the effect of the parallel electric field is to stabilize the wave and enhance the transverse acceleration of ions whereas the effect of steepness of loss-cone, ion beam velocity and the temperature anisotropy is to enhance the growth rate and decrease the transverse acceleration of ions. The steepness of the loss-cone also introduces a peak in the growth rate which shifts towards the lower side of the perpendicular wave number with the increasing steepness of the loss-cone. 相似文献
10.