自动电位滴定技术精确测定铜矿石中高含量铜的方法研究   总被引：2，自引：2，他引：0  

赵怀颖  吕庆斌  巩爱华  孙红宾  马新荣 《岩矿测试》2015,34(6):672-677

铜矿石中百分含量铜的分析通常采用手动目视滴定法,该方法借助化学指示剂判定终点,存在终点判断和人为操作等误差,精密度、可靠性相对较差。基于此,本文建立了精确测定铜矿石中高含量铜的分析方法,采用智能型自动电位滴定仪自动判定终点,高分辨加液器精确控制硫代硫酸钠标准溶液加入量至0.001 m L,并且通过加大碘化钾用量使得滴定中产生的碘化亚铜被高浓度的I-溶解,消除对碘的吸附影响。本法应用于铜含量为24.2%~59.09%的铜精矿、黄铜矿、铅黄铜国家标准物质分析,相对标准偏差(RSD,n=10)0.3%,极差仅为0.13%、0.21%、0.29%,优于手动目视滴定法。本法提高了铜矿石分析的自动化程度,适用于精确测定铜含量大于0.5%尤其是10%以上的铜矿石。  相似文献   

不同取代位置羧甲基壳聚糖的核磁共振波谱和电位滴定分析     

王远红  王聪  于明明  张秀丽  姜廷福  刘潇潇  孟适秋  吕志华 《中国海洋大学学报(自然科学版)》2011,(Z1):359-364

本文制备了O-羧甲基壳聚糖、N-羧甲基壳聚糖和N,O-羧甲基壳聚糖,并采用核磁共振波谱以及电位滴定方法对不同取代位置羧甲基壳聚糖取代度进行了分析。结果表明,核磁共振碳谱及DEPT谱可以确定羧甲基壳聚糖中羧甲基的取代位置,电位滴定法可以确定O-位羧甲基、N-位羧甲基以及总羧甲基的取代度,是一种简单易行的方法。  相似文献   

SHORT COMMUNICATION MODEL SELECTION BY THE PROGRAM MINIGLASS IN COMPLEX FORMATION STUDIES     

ALVAROIZQUIERDO  JOSE-LUISBELTRAN 《地理学报(英文版)》1988,(Z1)

The model selection from EMF data of pH titration curves has been studied for binary and ternarysystems(Ni~(2+)-glycine and Ni~(2+)-methionine-taurine respectively)by using the MINIGLASSprogram.Comparison between experimental and calculated titration curves with this interactive programindicates the presence(and the pH range)of the different species in equilibrium.  相似文献   

氢醌滴定法测定金矿石中金的不确定度评定   总被引：5，自引：4，他引：5  

陈爱平陈志慧  王苏明王烨 《岩矿测试》2006,25(4):360-364

以氢醌滴定法测定金矿石中贵金属金的实例进行不确定度评定。测量结果的不确定度由配制金标准母液、金标准工作液、氢醌滴定液浓度、称样质量、滴定样品所用氢醌溶液体积等所引入的不确定度分量组成。在对各个不确定度分量进行量化的基础上，通过合成得到测量结果的标准不确定度，再乘以95％置信概率下的扩展因子2，得到测量结果的扩展不确定度。  相似文献   

酸碱滴定法测定天然石膏中的碳酸盐(无水碳酸)   总被引：3，自引：0，他引：3  

蔡玉曼  陆丽君  周泳德  高孝礼 《江苏地质》2007,31(2):127-129

建立了用溴百里酚蓝—酚红作指示剂,酸碱滴定法测定天然石膏中碳酸盐的方法。在确定了试验条件的基础上,对石膏国家一级标准物质GBW03109a和GBE03110分析,相对标准偏差分别为0.08%、1.05%;分析3个天然石膏样品,相对标准偏差分别为1.47%、1.67%和0.25%;对试样进行加标回收,回收率在95.53%～97.02%之间;方法检出限为0.15%。表明用该方法测试,结果准确可靠。  相似文献   

名铁矿中三氧化二铝含量测定的方法研究   总被引：1，自引：0，他引：1  

赵琪 《地质与勘探》2002,38(4):71-72

名铁矿试样经碱熔,直接分离铁,再酸化,中和后用六次甲基四胺沉淀铝与络合物,沉淀酸溶,用氟盐取代－EDTA容量法测定三氧化二铝。该法充分消除了铁的干扰,使滴定终点比DZG93－012（铬铁矿操作规程－氟盐取代）－EDTA容量法测定三氧化二铝）方法的滴定终点更清晰,准确,结果重现性好。  相似文献   

库伦滴定法测定岩矿试样中氯     

候磊  金秉慧 《岩矿测试》1990,9(3):178-183

本文提出用电生Ag~ 库伦滴定岩矿样品中痕量氯的方法。经对电解液组成、不同电解电流下的电流效率、干扰元素的分离等进行了实验研究,确定了最佳分析条件。实验结果表明:当测定氯量≥100μg时,回收率达99.5～99.9％,相对标准偏差0.33～0.03％;测定氯量≥10μg,回收率为98.6～98.9％;相对标准偏差2.5～0.58%;方法准确,重现性好,操作简便。用岩石和土壤一级标准物质检验及参加建材一级标准物质协作定值,结果满意。  相似文献   

配位滴定法同时测定金属离子浓度的研究     

乔延江  王英华  刘友谊 《吉林大学学报(地球科学版)》1994,(3)

将多元校正分析法应用于配位滴定中，以ＥＤＴＡ为滴定剂，玻璃电极为指示电极，饱和甘汞电极为参比电极。依据电位滴定原理，对混合三组分：Ｃｕ￣（２＋）、Ｃｄ￣（２＋）、Ｚｎ￣（２＋）、及Ｃｕ￣（２＋）、ＣＯ￣（２＋）、Ｎｉ￣（２＋）进行测定，各金属离子之间的△ｌｏｇＫ在０．０４～２．３４之间，计算误差一般小于土１０％。  相似文献   

Determination of cadmium(II), copper(II), manganese(II) and nickel(II) species in Antarctic seawater with complexing resins   总被引：1，自引：0，他引：1  

Raffaela Biesuz  Giancarla Alberti  Girolamo D'Agostino  Emanuele Magi  Maria Pesavento 《Marine Chemistry》2006,101(3-4):180-189

The strong species of cadmium(II), copper(II), manganese(II) and nickel(II) in an Antarctic seawater sample are investigated by a method based on the sorption of metal ions on complexing resins. The resins compete with the ligands present in the sample to combine with the metal ions. Two resins with different adsorbing strengths were used. Very stable metal complexes were investigated with the strong sorbent Chelex 100 and weaker species with the less strong resin, Amberlite CG-50. Strong species were detected for three of the considered metal ions, but not for Mn(II). Cu(II) is completely linked to species with a side reaction coefficient as high as log α_M(I) = 11.6 at pH = 7.3. The ligand concentration was found to be similar to that of the metal ion, and the conditional stability constant was around 10²⁰ M^− 1. In the considered sample, only a fraction of the metal ions Cd(II) and Ni(II) is bound to the strong ligands, with side reaction coefficients equal to log α_M(I) = 5.5 and 6.5 at pH = 7.3 for Cd(II) and Ni(II), respectively. These findings were confirmed by the test with the weaker sorbent Amberlite CG-50. It can be calculated from the sorption equilibria that neither Mn(II) nor Ni(II) is adsorbed on Amberlite CG-50 under the considered conditions and, in fact, only a negligible fraction of Mn(II) and Ni(II) was adsorbed. A noticeable fraction of Cd(II) was adsorbed on Amberlite CG-50, meaning that cadmium(II) is partially linked to weak ligands, possibly chloride, while no copper(II) was adsorbed on this resin, confirming that copper(II) is only combined in strong species. These results are similar, but not identical, to those obtained for other seawater samples examined in previous investigations.  相似文献   

Use of an optical oxygen sensor to measure dissolved oxygen in seawater     

Hiroshi Hasumoto  Tsuneo Imazu  Toshiaki Miura  Kazuhiro Kogure 《Journal of Oceanography》2006,62(1):99-103

The use of an optical oxygen sensor to measure dissolved oxygen in seawater was investigated. The sensor is based on the dynamic quenching of an oxygen-sensitive fluorochrome embedded in the tip. Dissolved oxygen in seawater samples collected from eight stations at depths ranging from 3000 to 6000 m was analyzed both with the optical sensor and by the Winkler titration method. The two sets of data did not differ significantly. The stability and simplicity of the method and the good agreement of the results with those of the titration method indicate that the sensor would be useful for fieldwork.  相似文献