Atmospheric Reactive Nitrogen Cycle and Stable Nitrogen Isotope Processes: Progresses and Perspectives   总被引：1，自引：1，他引：0  

Tao Zhou  Zhuang Jiang  Lei Geng 《地球科学进展》2019,34(9):922-935

Oxidized reactive nitrogen in the atmosphere mainly consists of nitrogen oxides (NO _X =NO+NO₂, NO₃) and nitric acid. The atmospheric cycling of NO _X influences the formation of ozone and hydroxyl radicals that are important for atmospheric oxidation capacity. Nitric acid, the final product of NO _X oxidation, not only is an important component of particulate pollutants, but also has a direct impact on the ecosystem through dry and wet deposition. The stable nitrogen isotope (δ¹⁵N) shows the potential to study reactive nitrogen cycle, and to trace the emission, transport and deposition of reactive nitrogen from local to global scales. Here, we reviewed previous studies using δ¹⁵N to investigate NO _X emission and atmospheric reactive nitrogen cycle, and discuss the uncertainties of δ¹⁵N signatures of different NO _X sources from two aspects: NO _X generation mechanism and NO _X collection methods. We also discussed the nitrogen isotope fractionation and the consequences during the conversions of NO _y molecules. We ended up with discussions on the possibility of using δ¹⁵N to trace NO _X emissions. Although there are still large uncertainties in quantifying and tracing NO _X emissions using nitrogen stable isotopes, such isotope tool is efficient enough to trace reactive nitrogen cycles in the atmosphere. On the basis of this, we proposed that we can combine atmospheric chemistry transmission models with isotope tracers to improve our understanding of regional and global atmospheric reactive nitrogen cycle regarding the fluxes of different emission sources, their atmospheric transformation, etc.  相似文献   

基于转录组测序对两种氮素营养条件下多形微眼藻氮代谢途径的解析     

李迎  米铁柱  乔玲  甄毓 《海洋与湖沼》2019,50(6):1241-1251

探究微藻的氮代谢通路对了解其对不同氮源利用的分子机制具有重要意义。本研究利用Illumina高通量测序技术对两种氮素营养条件下(硝酸氮和尿素)多形微眼藻的转录组进行分析,通过基因功能注释及数字基因表达谱分析,研究了多形微眼藻细胞内氮代谢的调控机制。结果检测出15种参与氮代谢的酶,对应76个编码基因,构建了多形微眼藻的氮代谢通路图。其中10个酶编码基因在两种不同氮素营养条件下存在差异表达,最显著的是谷氨酸合成酶、谷氨酸脱氢酶和谷氨酰胺合成酶相关基因。有机氮源(尿素)实验组中,多形微眼藻细胞内的硝酸盐还原酶、亚硝酸盐还原酶等基因的差异表达明显高于无机氮源(硝酸钠)实验组,表明当环境中的氮源为尿素时,会对多形微眼藻细胞内硝酸盐的转化和利用有一定影响。本研究初步阐述了硝酸盐、尿素的吸收转运对多形微眼藻细胞内氮代谢的影响机制,可为硅藻在不同氮素营养条件下的吸收利用机制及氮代谢响应研究提供依据。  相似文献   

The GEOMON network of Czech catchments provides long-term insights into altered forest biogeochemistry: From acid atmospheric deposition to climate change     

Filip Oulehle  Milan Fischer  Jakub Hruška  Tomáš Chuman  Pavel Krám  Tomáš Navrátil  Miroslav Tesař  Miroslav Trnka 《水文研究》2021,35(5):e14204

In 1994, a network of small catchments (GEOMON) was established in the Czech Republic to determine input–output element fluxes in semi-natural forest ecosystems recovering from anthropogenic acidification. The network consists from 16 catchments and the primary observations of elements fluxes were complemented by monitoring of biomass stock, element pools in soil and vegetation, and the main water balance components. Over last three decades, reductions of SO₂, NO_x and NH₃ emissions were followed by sulphur (S) and nitrogen (N) deposition reductions of 75% and 30%, respectively. Steeper declines of strong acid anion concentrations compared to cations (Ca, Mg, Na, K, NH₄) in precipitation resulted in precipitation pH increase from 4.5 to 5.2 in bulk precipitation and from 4.0 to 5.1 in spruce throughfall. Stream chemistry responded to changes in deposition: S leaching declined. However at majority of catchments soils acted as a net source of S to runoff, delaying recovery. Stream pH increased at acidic streams (pH < 6) and aluminium concentration decreased. Stream nitrate (NO₃) concentration declined by 60%, considerably more than N deposition. Stream NO₃ concentration was tightly positively related to stream total dissolved nitrogen to total phosphorus (P) ratio, suggesting the role of P availability on N retention. Trends in dissolved organic carbon fluxes responded to both acidification recovery and to runoff temporal variation. An exceptional drought occurred between 2014 and 2019. Over this recent period, streamflow decreased by ≈ 40% on average compared to 1990s, due to the increases of soil evaporation and vegetation transpiration by ≈ 30% and declines in precipitation by ≈ 15% on average across the elevational gradient. Sharp decreases of stream runoff at catchments <650 m a.s.l. corresponded to areas of recent forest decline caused by bark beetle infestation on drought stressed spruce forests. Understanding of the interactions among legacies of acidification and eutrophication, drought effects on the water cycle and forest disturbance dynamics is requisite for effective management of forested ecosystems under anthropogenic influence.  相似文献   

波浪作用下沉积物中氮、磷释放速率的试验研究     

张严严  房文艳  许国辉  任宇鹏  许兴北 《中国海洋大学学报(自然科学版)》2020,50(4):102-110

湖泊或海湾中的沉积物吸附氮(N)、磷(P)等元素所形成的沉积层成为水体富营养化的內源。在波浪作用下,尤其是强浪作用下,沉积物中的N、P会通过内源释放作用大量进入水体中。本文在自制的U型水槽中开展实验,采用不同水头差来模拟波浪的循环荷载作用,研究了沉积层中的N、P在静置固结状态(Ⅰ)、加波未液化状态(Ⅱ)、加波液化状态(Ⅲ)下的释放规律,并给出该试验条件下的沉积物释放速率的拟合方程。试验结果表明:沉积物中总氮(TN)和溶解性总氮(TDN)的释放速率会随着水动力作用的增强而增加;总磷(TP)、溶解性总磷(TDP)和活性磷酸盐(SRP)的释放速率也随着水动力作用增强而增加,但水体中悬浮物(SS)含量过高会限制其释放速率。  相似文献   

Spatial and Temporal Distribution of Dust‐Bound Trace Metal Elements around Kuhdasht Watershed Area in Iran     

Hamid Alipour  Ahmad Jalalian  Naser Honarjoo  Norair Tommanian  Fereidoon Sarmadian 《洁净——土壤、空气、水》2019,47(10)

Dust, as a source of trace metal elements, affects the health of society. The spatial and temporal concentrations of dust‐bound trace metals (Cd, Pb, Ni, Zn, Cu, and Mn) in Kuhdasht watershed (456 km²), Lorestan Province, Iran, is investigated. Dust is collected using glass traps placed in ten research stations in the region. The spatial and temporal distribution of dust trace metals are plotted using ARC‐GIS. The highest and the lowest concentrations of Zn (9751150 mg kg^?1), Pb (46.352.9 mg kg^?1), and Cd (2.443.30 mg kg^?1) are obtained in winter, of Ni (98110 mg kg^?1) and Cu in autumn (16.053.5 mg kg^?1), and of Mn in summer (385505 mg kg^?1). The spatial concentrations of dust‐bound trace metals indicate all, except Cu, show a decreasing trend from the mountains toward the plains, similar to that of soil and of dust, except for Zn, which shows higher concentrations in dust than in soil. The potential sources of dust‐bound trace metals and their rate of contamination are also investigated using the enrichment and contamination factors. The major sources of Cd and Zn in the dust of watershed are due to anthropogenic activities or from activities outside the borders.  相似文献   

Soil Respiration Dynamics and Influencing Factors in Typical Steppe of Inner Mongolia under Long-term Nitrogen Addition     

DU Wei  WU Shanmei  NIE Cheng  LI Yue  SHAO Rui  LIU Yinghui  SUN Nan 《资源与生态学报(英文版)》2019,10(2):155-162

We investigated soil respiration (Rs) dynamics and influencing factors under different nitrogen (N) addition levels (0, 2, 4, 8, 16, 32 g m^-2 yr^-1) on typical grassland plots in Inner Mongolia. We measured soil respiration, temperature, moisture and nutrients. We found that N addition did not change dynamic characteristics of Rs; daily and seasonal dynamics followed a single peak curve. N addition reduced Rs during the growing season. Rs under N2, N4, N8, N16 and N32 treatments decreased by 24.00%, 21.93%, 23.49%, 30.78% and 28.20% in the growing season, respectively, compared to the N0 treatment. However, Rs in the non-growing season was not different across treatments. Rs was significantly positively correlated with soil temperature and moisture and these two factors accounted for 72%-97% and 74%-82% of variation in Rs, respectively. The soil respiration temperature sensitivity (Q₁₀) was between 2.27 and 4.16 and N addition reduced Q₁₀ except in the N8 treatment.  相似文献   

珠江口淇澳岛滨海湿地沉积环境演化及其对人类活动的响应   总被引：1，自引：1，他引：0  

叶翔  李靖  王爱军 《海洋学报》2018,40(7):79-89

滨海湿地作为人类活动和全球变化反应最为敏感的区域，其沉积记录可以反映出周边地区环境变化及人类活动信息。珠江口淇澳岛滨海湿地钻孔分析结果表明，在中全新世期间淇澳岛附近海域为河口湾环境，在风化层以上开始出现淤积，但在4 200 a BP前后受极冷气候的影响，沉积物粗化；自2 500 a BP以来，沉积环境相对稳定，在小冰期期间略有变化。沉积速率计算结果显示:淇澳岛附近海域自中全新世高海面以来的平均沉积速率为0.29 cm/a，4 160~2 500 a BP、2 500 a BP-1488年、1488-1893年、1893-1986年、1990-2007年期间的平均沉积速率分别为:0.17 cm/a、0.23 cm/a、0.35 cm/a、1.37 cm/a和5.94 cm/a，沉积速率逐渐增大，反映了珠江三角洲演化过程中沉积相与沉积环境的变化；1986-1990年期间的海堤建造极大地扰动了该钻孔上部的沉积过程，在工程施工期间共沉积了厚度约112 cm的沉积层，而在海堤建成后，沉积速率也显著增大。沉积物总有机碳、总氮和C/N值的垂向分布表明，在4 160~2 500 a BP期间受海洋环境影响较大，沉积物中有机碳以海源为主，2 500 a BP以来沉积物中碳、氮含量明显增大，C/N也相应变大，有机碳主要来源于陆源输入，但在小冰期期间海源有机碳贡献略有所增大；近百年来由于受人类活动影响显著，陆源有机碳的贡献快速增加。  相似文献   

Wintertime rates of net primary production and nitrate and ammonium uptake in the southern Benguela upwelling system     

RF Flynn  JM Burger  K Pillay 《African Journal of Marine Science》2018,40(3):253-266

The elevated levels of primary productivity associated with eastern boundary currents are driven by nutrient- rich waters upwelled from depth, such that these regions are typically characterised by high rates of nitrate-fuelled phytoplankton growth. Production studies from the southern Benguela upwelling system (SBUS) tend to be biased towards the summer upwelling season, yet winter data are required to compute annual budgets and understand seasonal variability. Net primary production (NPP) and nitrate and ammonium uptake were measured concurrently at six stations in the SBUS in early winter. While euphotic zone NPP was highest at the stations nearest to the coast and declined with distance from the shore, a greater proportion was potentially exportable from open-ocean surface waters, as indicated by the higher specific nitrate uptake rates and f-ratios (ratio of nitrate uptake to total nitrogen consumption) at the stations located off the continental shelf. Near the coast, phytoplankton growth was predominantly supported by ammonium despite the high ambient nitrate concentrations. Along with ammonium concentrations as high as 3.6 µmol l^–1, this strongly suggests that nitrate uptake in the inshore SBUS, and by extension carbon drawdown, is inhibited by ammonium, at least in winter, although this has also been hypothesised for the summer.  相似文献   

Pre‐ and post‐impoundment nitrogen in the lower Missouri River          下载免费PDF全文

Dale W. Blevins  Donald H. Wilkison  Shelley L. Niesen 《水文研究》2014,28(4):2535-2549

Large water‐sample sets collected from 1899 through 1902, 1907, and in the early 1950s allow comparisons of pre‐impoundment and post‐impoundment (1969 through 2008) nitrogen concentrations in the lower Missouri River. Although urban wastes were not large enough to detectably increase annual loads of total nitrogen at the beginning of the 20^th century, carcass waste, stock‐yard manure, and untreated human wastes measurably increased ammonia and organic‐nitrogen concentrations during low flows. Average total‐nitrogen concentrations in both periods were about 2.5 mg/l, but much of the particulate‐organic nitrogen, which was the dominant form of nitrogen around 1900, has been replaced by nitrate. This change in speciation was caused by the nearly 80% decrease in suspended‐sediment concentrations that occurred after impoundment, modern agriculture, drainage of riparian wetlands, and sewage treatment. Nevertheless, bioavailable nitrogen has not been low enough to limit primary production in the Missouri River since the beginning of the 20^th century. Nitrate concentrations have increased more rapidly from 2000 through 2008 (5 to 12% per year), thus increasing bioavailable nitrogen delivered to the Mississippi River and affecting Gulf Coast hypoxia. The increase in nitrate concentrations with distance downstream is much greater during the post‐impoundment period. If strategies to decrease total‐nitrogen loads focus on particulate N, substantial decreases will be difficult because particulate nitrogen is now only 23% of total nitrogen in the Missouri River. A strategy aimed at decreasing particulates also could further exacerbate land loss along the Gulf of Mexico, which has been sediment starved since Missouri River impoundment. In contrast, strategies or benchmarks aimed at decreasing nitrate loads could substantially decrease nitrogen loadings because nitrates now constitute over half of the Missouri's nitrogen input to the Mississippi. Ongoing restoration and creation of wetlands along the Missouri River could be part of such a nitrate‐reduction strategy. Published 2013. This article is a U.S. Government work and is in the public domain in the USA.  相似文献   

有机化学物质碳氮稳定同位素系列标准物质研制     

李科  张琳  刘福亮  贾艳琨 《岩矿测试》2020,39(5):753-761

实验室和研究人员所使用的碳、氮同位素标准物质一般由国际原子能机构(IAEA)获得,然而近年来,随着碳氮同位素在实验室质量监控、方法评价、仪器校准等方面的广泛应用,市场需求量不断增加, IAEA研制的碳、氮同位素标准物质的种类与数量逐渐不能满足科学研究快速发展的需求。我国急需研制适应当今分析技术水平的有机质碳氮同位素国家标准物质用以进行质量监控、方法评价、仪器校准。为保证量值传递精度,本文研制了4个有机化学物质的碳氮稳定同位素标准物质,其中3个为尿素样品,1个为L-谷氨酸。经检验4种标准物质的均匀性通过F值检验,标准物质的δ~(13)C和δ~(15)N值经过一年的稳定性检验,特征量值变化在测量方法允许的不确定度范围内,由此判定δ~(13)C和δ~(15)N值稳定性良好。由包括研制单位实验室在内的12家实验室协同定值,采用高温燃烧-气体同位素质谱法测定了δ~(13)C和δ~(15)N值,系列标准物质δ~(13)C和δ~(15)N认定值区间呈梯度分布,δ~(13)C值为-40‰～0‰,δ~(15)N值为-10‰～30‰,涵盖了我国天然样品中有机质碳氮稳定同位素组成范围;研制的系列标准物质δ~(13)C的定值扩展不确定度不大于0.08‰,δ~(15)N的定值扩展不确定度不大于0.09‰,定值水平与国际标准物质相当。该系列标准物质已被国家质检总局批准为国家一级标准物质,批准号为GBW04494～GBW04497。可被用于地质、生态、环境等多种样品δ~(13)C和δ~(15)N比值测定时的分析监控、仪器校准、方法评价、质量保证和质量监控。  相似文献