The Bear Brook Watershed in Maine: Multi-decadal whole-watershed experimental acidification     

Kaizad F. Patel  Ivan J. Fernandez  Sarah J. Nelson  Stephen A. Norton  Cheryl J. Spencer 《水文研究》2021,35(5):e14147

The Bear Brook Watershed in Maine (BBWM) is a long-term research site established to study the response of forest ecosystem function to environmental disturbances of chronic acidic deposition and ecosystem nitrogen enrichment. Starting in 1989, the West Bear (treated) watershed received bimonthly applications of ammonium sulfate [(NH₄)₂SO₄] fertilizer from above the canopy, whereas East Bear (reference) received ambient deposition. The treatments were stopped in 2016, marking the beginning of the recovery phase. Research at the site has focused on soils, streams, and vegetation. Here, we describe data collected over three decades at the BBWM—input and stream output nutrient fluxes, quantitative soil pits and soil chemistry, and soil temperature and moisture.  相似文献   

全二维气相色谱-电子捕获检测器测定复杂基质土壤中24种有机氯和拟除虫菊酯类农药     

时磊  孙艳艳  沈小明  吕爱娟  蔡小虎  刘娇  沈加林 《岩矿测试》2020,39(6):856-865

目前针对环境样品中有机氯和拟除虫菊酯类农药的检测方法主要有气相色谱法和气相色谱-质谱法（GC-MS），由于气相色谱法采用电子捕获检测器从而具有较高的灵敏度，在污染物的环境行为研究中得到广泛应用，GC-MS法的定性效果好，但检测灵敏度相对偏低。本文研究了2018年土壤详查江苏地区样品中有机氯农药和拟除虫菊酯的残留状况，结果显示，即使经过多次净化仍有20%的样品存在假阳性或基质干扰现象。为了提高定性准确度，同时保证检测灵敏度，实验建立了复杂基质土壤中20种有机氯农药和4种拟除虫菊酯的全二维气相色谱-电子捕获检测器检测方法，最终选择中等极性的TG-35MS为第一色谱柱，非极性的（DB-1）为第二色谱柱，将鲜样与无水硫酸钠混合均匀后，以正己烷-丙酮（1：1，V/V）为提取剂进行索氏提取，采用全二维气相色谱-电子捕获检测器进行检测，外标法定量。各物质的质量浓度均在1.0~500μg/L内与其峰面积呈线性关系，相关系数均大于0.995，检出限为0.02~0.17μg/kg。用标准加入法进行回收实验，测得回收率为80.7%~103.5%，测定值的相对标准偏差（n=6）为1.84%~10.12%。本方法将高灵敏度检测器与全二维色谱相结合，在保证检测灵敏度的同时增加了峰容量，有效去除了基质干扰。相比2018年土壤详查参考方法HJ 835—2017的检出限0.02~0.09mg/kg（全扫模式），本方法检出限显著降低，且操作简单，可为复杂基质样品中的痕量超痕量检测提供参考。  相似文献   

Hypo‐elastic and hyper‐elastic equations of soils          下载免费PDF全文

Koichi Hashiguchi 《国际地质力学数值与分析法杂志》2018,42(13):1554-1564

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非饱和土中剪切S波的传播特性分析          下载免费PDF全文

柳鸿博  周凤玺 《地震工程学报》2020,42(4):960-966

基于对非饱和多孔介质的研究成果,考虑孔隙中的液相和气相的相互影响,研究非饱和土地基中剪切S波的传播特性。通过非饱和土中固相、液相和气相的质量平衡方程、动量平衡方程和非饱和土有效应力原理,建立问题的弹性波动方程,经过理论推导给出非饱和土中剪切S波的弥散特征方程。通过数值算例分析剪切S波的波速和衰减系数随饱和度、频率和固有渗透系数等因素的变化规律。结果表明,剪切S波的波速几乎不受饱和度的影响,但其随着频率的增大而减小,随着固有渗透系数的增大先不变后增大;剪切S波的衰减系数随着饱和度和频率的增加均增大,而随着固有渗透系数的增大先不变后增大最后减小。  相似文献   

Fully coupled elastoplastic hydro-mechanical analysis of unsaturated porous media using a meshfree method     

Omid Ghaffaripour  Golnaz A. Esgandani  Arman Khoshghalb  Babak Shahbodaghkhan 《国际地质力学数值与分析法杂志》2019,43(11):1919-1955

This paper presents the first application of an advanced meshfree method, ie, the edge-based smoothed point interpolation method (ESPIM), in simulation of the coupled hydro-mechanical behaviour of unsaturated porous media. In the proposed technique, the problem domain is spatially discretised using a triangular background mesh, and the polynomial point interpolation method combined with a simple node selection scheme is adopted for creating nodal shape functions. Smoothing domains are formed on top of the background mesh, and a constant smoothed strain, created by applying the smoothing operation over the smoothing domains, is assigned to each smoothing domain. The deformation and flow models are developed based on the equilibrium equation of the mixture, and linear momentum and mass balance equations of the fluid phases, respectively. The effective stress approach is followed to account for the coupling between the flow and deformation models. Further coupling among the phases is captured through a hysteretic soil water retention model that evolves with changes in void ratio. An advanced elastoplastic constitutive model within the context of the bounding surface plasticity theory is employed for predicting the nonlinear behaviour of soil skeleton. Time discretisation is performed by adopting a three-point discretisation method with growing time steps to avoid temporal instabilities. A modified Newton-Raphson framework is designed for dealing with nonlinearities of the discretised system of equations. The performance of the numerical model is examined through a number of numerical examples. The state-of-the-art computational scheme developed is useful for simulation of geotechnical engineering problems involving unsaturated soils.  相似文献   

深厚软土场地基岩地震动反演——以天津波为例          下载免费PDF全文

梁建文  张萍  何颖 《世界地震工程》2020,(3):001-11

根据天津波地表加速度记录和相应实测场地钻孔资料，采用等效线性化方法模拟土体非线性，进行了深厚软土场地基岩地震动反演，研究了频率截断对深厚软土场地基岩地震动反演的影响，为天津波地表加速度记录提供了相应的基岩地震动输入。研究表明:不同截断频率情况下，反演得到的基岩地震动峰值和反应谱曲线形状均相差悬殊，但反演后再正演所得到的地面运动与原地表记录相比，加速度时程曲线形状和峰值大小、反应谱曲线形状和峰值大小均非常接近；可根据工程需要对地表加速度记录进行不同频率的截断，反演得到所需强度的基岩地震动。  相似文献   

海底表层土导热系数变化规律的试验研究          下载免费PDF全文

何旭涛  林晓波  徐建良  李世强  杨婧荷  徐海宁 《海洋学研究》2020,38(1):20-26

基于热探针法原理,测试了在杭州湾以东陆架区取得的28个海底表层柱状样0.2、1.0和1.8 m处的导热系数,结合激光粒度分析结果,比较了研究区6种土导热系数的大小,发现含砂量大于10%的粗粒土拥有较大的导热系数。土质类型相同时,含水量和干密度对其导热系数影响显著。杭州湾沉积区、混合沉积区,陆架砂质沉积区表层土导热系数的平均值分别是:1.25、1.45 和1.46 W·m^-1·K^-1,呈现出由近岸向外海增大的趋势。而土样导热系数在垂向的变化表明:水深、埋深等空间分布因素对海洋土的热物性没有直接影响。  相似文献   

Evaporation from seasonally frozen bare and vegetated ground at various groundwater table depths in the Ordos Basin,Northwest China     

Zaiyong Zhang  Wenke Wang  Chengcheng Gong  Zhoufeng Wang  Lei Duan  Tian‐chyi Jim Yeh  Peiyuan Yu 《水文研究》2019,33(9):1338-1348

In cold climates, the process of freezing–thawing significantly affects the ground surface heat balance and water balance. To better understand the mechanism of evaporation from seasonally frozen soils, we performed field experiments at different water table depths on vegetated and bare ground in a semiarid region in China. Soil moisture and temperature, air temperature, precipitation, and water table depths were measured over a 5‐month period (November 1, 2016, to March 14, 2017). The evaporation, which was calculated by a mass balance method, was high in the periods of thawing and low in the periods of freezing. Increased water table depth in the freezing period led to high soil moisture in the upper soil layer, whereas lower initial groundwater levels during freezing–thawing decreased the cumulative evaporation. The extent of evaporation from the bare ground was the same in summer as in winter. These results indicate that a noteworthy amount of evaporation from the bare ground is present during freezing–thawing. Finally, the roots of Salix psammophila could increase the soil temperature. This study presents an insight into the joint effects of soil moisture, temperature, ground vegetation, and water table depths on the evaporation from seasonally frozen soils. Furthermore, it also has important implications for water management in seasonally frozen areas.  相似文献   

A plasticity constitutive model for unsaturated,anisotropic, nonexpansive soils     

Panagiotis Sitarenios  Michael Kavvadas 《国际地质力学数值与分析法杂志》2020,44(4):435-454

The paper describes and evaluates an incremental plasticity constitutive model for unsaturated, anisotropic, nonexpansive soils (CMUA). It is based on the modified Cam-Clay (MCC) model for saturated soils and enhances it by introducing anisotropy (via rotation of the MCC yield surface) and an unsaturated compressibility framework describing a double dependence of compressibility on suction and on the degree of saturation of macroporosity. As the anisotropic and unsaturated features can be activated independently, the model is downwards compatible with the MCC model. The CMUA model can simulate effectively: the dependence of compressibility on the level of developed anisotropy, uniqueness of critical state independent of the initial anisotropy, an evolving compressibility during constant suction compression, and a maximum of collapse. The model uses Bishop's average skeleton stress as its first constitutive variable, favouring its numerical implementation in commercial numerical analysis codes (eg, finite element codes) and a unified treatment of saturated and unsaturated material states.  相似文献   

Application of HVSR to estimating thickness of laterite weathering profiles in basalt     

Stephen Nelson  John McBride 《地球表面变化过程与地形》2019,44(7):1365-1376

Lateritic weathering profiles (LWPs) are widespread in the tropics and comprise an important component of the Critical Zone (CZ). The Hawaiian Islands make an excellent natural laboratory for examining the tropical CZ, where the bedrock composition (basalt) is nearly uniform and rainfall varies greatly. This natural laboratory is employed to assess the utility of the HVSR (horizontal/vertical spectral ratio) method to characterize the shear-wave velocity (V_s) structure of LWPs, particularly the depth to the contact between saprolite and basalt bedrock. LWP thicknesses determined from HVSR provide good agreement with multi-channel analysis of surface waves (MASW) profiles, well logs and outcrop. LWP thicknesses may be estimated from the fundamental mode equation or through forward models. Prior knowledge about the subsurface from well, outcrop, and MASW profiles may greatly aid modeling in some cases. For the 3.2 to 1.8 Ma Koolau Volcano on Oahu, the downward rate of advance of the weathering front varies from 0.004 to 0.041 m/ka. For the 0.44 to 0.10 Ma Kohala Volcano (Big Island of Hawaii) rates vary from 0.013 to 0.047 m/ka. Simple H/V spectra develop in areas where the combined effects of time and elevated rainfall produce thick LWPs with a flat base and a general absence of core stones with an ideal layered geometry. Abundant buried core stones violate the assumption of simple layered geometries and scatter acoustic energy, leading to uninterpretable results. This is common where low rainfall and a young basaltic substrate leave abundant core stones as well as an undulating contact between saprolite and bedrock. Velocity inversions (high V_s intervals within low V_s saprolite) may also be present and originate from relatively intact bedrock horizons or mineralogical changes within saprolite. At Kohala, a gibbsite-rich horizon produces such a velocity inversion due to enhanced weathering and subsequent collapse of saprolite in a discrete horizon. © 2019 John Wiley & Sons, Ltd.  相似文献