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1.
针对三塘湖盆地的主力烃源岩二叠系芦草沟组泥质烃源岩开展封闭体系和半开放体系热模拟实验,前者将干酪根密封在金管中开展实验、后者直接对烃源岩样品进行压机半开放体系热解模拟,对实验中生成气体的组分和稳定碳同位素进行分析。实验结果显示,两种热解方法以无机气体生成为主,包括CO2、H2、H2S 和 N2等,其中 CO2含量最丰富,这与样品干酪根中丰富的氧含量一致。半开放体系模拟实验温度达到480℃时,气态烃的含量达40.64%,其中甲烷含量达到26.10%,封闭体系中随着模拟温度升高烃类气体产物的碳同位素呈现先变轻后变重的趋势,但同位素分馏程度不大, CH4气体的δ13C 值分布在-40.2‰~-46.6‰之间, C2H6分布在-34.3‰~-38.0‰之间, C3H8分布在-33.6‰~-36.0‰之间,而CO2气体δ13C值分布在-32.8‰~-28.8‰之间。三塘湖盆地针对气藏的勘探已经有所发现,但有关气藏的地球化学特征报道较少,该工作中的模拟实验结果可为三塘湖盆地深入的气藏地球化学勘探提供基础数据。  相似文献   
2.
Kerogen plays an important role in shale gas adsorption, desorption and diffusion. Therefore, it is necessary to characterize the molecular structure of kerogen. In this study, four kerogen samples were isolated from the organic-rich shale of the Longmaxi Formation. Raman spectroscopy was used to determine the maturity of these kerogen samples. High-resolution transmission electron microscopy (HRTEM), 13C nuclear magnetic resonance (13C NMR) , X-ray diffraction (XRD) and Fourier transform infrared (FT-IR) spectroscopy were conducted to characterize the molecular structure of the shale samples. The results demonstrate that VReqv of these kerogen samples vary from 2.3% to 2.8%, suggesting that all the kerogen samples are in the dry gas window. The macromolecular carbon skeleton of the Longmaxi Formation kerogen is mainly aromatic (fa’=0.56). In addition, the aromatic structural units are mainly composed of naphthalene (23%), anthracene (23%) and phenanthrene (29%). However, the aliphatic structure of the kerogen macromolecules is relatively low (fal*+falH=0.08), which is presumed to be distributed in the form of methyl and short aliphatic chains at the edge of the aromatic units. The oxygen-containing functional groups in the macromolecules are mainly present in the form of carbonyl groups (fac=0.23) and hydroxyl groups or ether groups (falO=0.13). The crystallite structural parameters of kerogen, including the stacking height (Lc=22.84 ?), average lateral size (La=29.29 ?) and interlayer spacing (d002=3.43 ?), are close to the aromatic structural parameters of anthracite or overmature kerogen. High-resolution transmission electron microscopy reveals that the aromatic structure is well oriented, and more than 65% of the diffractive aromatic layers are concentrated in the main direction. Due to the continuous deep burial, the longer aliphatic chains and oxygen-containing functional groups in the kerogen are substantially depleted. However, the ductility and stacking degree of the aromatic structure increases during thermal evolution. This study provides quantitative information on the molecular structure of kerogen samples based on multiple research methods, which may contribute to an improved understanding of the organic pores in black shale.  相似文献   
3.
在辽河盆地各构造单元中以西部凹陷湖泊沉积持续时间最长,是研究辽河盆地沙河街组页岩气成藏的良好地区.本次在大量的资料收集、整理和分析的基础上,对辽河盆地西部凹陷沙河街组页岩气成藏地质条件进行初步分析,结果表明:本区的暗色泥岩主要发育在半深湖—深湖环境中,暗色泥岩具有厚度大、连续性强、分布广的特点.有机质丰度较高,TOC平均值在2.18%左右.干酪根类型以II型为主,偏向产气.有机质成熟度基本大于0.59%,表明泥页岩已基本进入大量排烃阶段.脆性矿物总量达到43.1%~61.5%,有利于页岩气开采.在页岩气成藏的地质因素分析基础上,综合研究认为,清水洼陷是沙河街组页岩气富集的有利区域.  相似文献   
4.
公繁浩  黄欣  陈树旺  郑月娟  张健  苏飞 《地质通报》2013,32(8):1322-1328
内蒙古西乌珠穆沁旗地区广泛出露下二叠统寿山沟组暗色泥页岩.选取该组塔宾庙林场剖面的烃源岩样品,进行有机质丰度、类型、成熟度等有机地球化学特征研究,初步对其生烃潜力进行评价.研究表明,西乌旗地区下二叠统寿山沟组暗色泥页岩的有机质丰度达到了中等—好烃源岩标准;有机质来源以高等植物为主,干酪根类型以Ⅲ型为主.有机质热演化进入高成熟—过成熟演化阶段,是潜在的烃(特别是气)源岩,系上古生界重要的烃源岩勘探层系之一.  相似文献   
5.
Eight lacustrine Type I kerogen samples from the Songliao Basin were pyrolyzed using the Rock-Eval equipment, and parallel first-order reaction models including the model with a single frequency factor and a discrete distribution of activation energies (SFF model) and the model with multiple frequency factors and a discrete distribution of activation energies (MFF model) were adopted to analyze kinetic characteristics of hydrocarbon generation of the Type I kerogen samples. The results show that the MFF and SFF models can satisfactory simulate hydrocarbon generation under laboratory conditions and the Type I kerogen shows relatively concentrated activation energy distributions (activation energies of MFF model range from 190 kJ/mol to 250 kJ/mol, activation energies of SFF model range from 220 kJ/mol to 240 kJ/mol), which indicates a homogeneous chemical bond structure of the Type I kerogen. The hydrocarbon generated curves from Type I kerogen were calculated by using the two models with a linear heating rate (3.3 K/Ma). It indicates that the hydrocarbon generation potentials (reaction fractions) are underestimated by using the SFF model during the kerogen thermal degradation for the components with chemical bond of lower and higher activation energies, while this problem can be avoided by using the MFF model. The calculated temperatures for 50% transformation ratio (TR) of all samples differ by as much as 20 °C. For the SFF model, the hydrocarbon generation curve obtained by using the weighted averaged kinetic parameters and the SFF model almost includes every curve calculated by using its own kinetic parameters. While the curve obtained by using the weighted averaged kinetic parameters and the MFF model cannot include every curve for all samples, it lies at the position of the averaged curve of all samples. The application of the MFF model in Songliao Basin shows that if TR 10% is taken as the onset of hydrocarbon generation, the threshold depth of hydrocarbon generation is about 1700 m, which is consistent with other geochemical parameters, such as S1/TOC, S1/(S1 + S2) and HC/TOC.  相似文献   
6.
To understand more fully the mode of preservation of organic matter in marine sediments, laboratory sulfurisation of intact cells of the cultured microalga Nannochloropsis salina was performed using inorganic polysulfides in seawater at 50°C. Solvent extractable and non-extractable materials were analysed by GC–MS and Py–GC–MS, respectively, to study the incorporation of sulfur into the microalgal organic matter. No GC-amenable sulfur-containing compounds were found in the extracts apart from some minor thiophenes with a phytanyl carbon skeleton. The residue after extraction and hydrolysis contained abundant macromolecular sulfur-containing moieties as revealed by the presence of dominant C28–C32 thiols, thiophenes, thianes and thiolanes in the flash pyrolysates. These products are thought to be formed from moieties derived from sulfurisation of C28–C32 diols and alkenols, characteristic lipids of N. salina. C1–C2 alkylated thiophenes were also found in the pyrolysates and probably result from moieties formed upon sulfurisation of carbohydrates. The highly resistant biomacromolecule (algaenan) synthesised by N. salina remains unaffected by sulfurisation. The non-hydrolysable residue isolated from the sulfurised N. salina thus comprises algaenan and (poly)sulfide-bound long alkyl chains. The sulfurisation experiments show that both selective preservation of algaenans and lipid and carbohydrate “vulcanisation” can be involved in the preservation of algal organic matter in marine environments.  相似文献   
7.
Molecular evidence for life in the 3.5 billion year old Warrawoona chert   总被引:1,自引:1,他引:0  
The biological origin of organic matter in the oldest siliceous sediments (cherts) is still debated. To address this issue, the insoluble organic matter (kerogen) was isolated from a chert of the Warrawoona group. The chemical structure of the kerogen was investigated through a combination of analytical techniques including solid-state 13C nuclear magnetic resonance and pyrolysis. Although dominated by aromatic hydrocarbons, the pyrolysate comprises a homologous series of long chain aliphatic hydrocarbons characterized by odd-over-even carbon number predominance. This distribution is only consistent with a biological origin. As kerogen must be contemporaneous of the solidification of the chert, this observation should be regarded as an evidence for the presence of life on Earth, 3.5 By ago.  相似文献   
8.
封闭体系有机质与有机碳氢氮恢复动力学研究   总被引:3,自引:0,他引:3  
在封闭体系的条件下,对典型的Ⅰ、Ⅱ、Ⅲ型干酪根在热演化过程中的损失进行生烃动力学研究,获得了Ⅰ、Ⅱ、Ⅲ型干酪根的总量、有机碳、氢以及氮质量损失动力学参数。用Kinetics软件计算了封闭体系干酪根有机碳丰度、氢碳原子比和氮碳原子比的恢复系数。认为在对高成熟—过成熟干酪根进行生烃评价时,Ⅰ、Ⅲ型干酪根残余有机碳丰度需要进行恢复,而Ⅱ型干酪根残余有机碳丰度不需要恢复。三种类型干酪根的氢碳原子比均需要进行恢复。  相似文献   
9.
王万春  吉利明 《地球化学》1998,27(5):507-513
对现代松粉的在热模拟过程中生成的甲烷,乙烷,丙烷及干酪根碳同位素分析表明,低温阶段(250℃以下)松粉热模拟生成的甲烷相对较高温阶段生成的甲烷更富集^13C,松粉热模拟残余干酪根松粉原样稍微富集^12C,反映低温阶段的热模拟产物主要来源于相对富集^13C的松粉原生质,高温阶段(300℃以上)松粉热模拟生成的甲烷,乙烷,丙烷的δ^13C值随温度升高而富集^13C,松粉热模拟残余干酪根的碳同位素组成没  相似文献   
10.
采用一系列温和的化学降解法对松辽盆地南部嫩江组烃源岩的干酪根进行连续的选择性化学降解,并对不同降解产物进行色谱—同位素比值质谱分析。研究表明碱性水解和脱硫产物以一元脂肪酸和正构烷烃为主,其中正构烷烃碳同位素分布曲线呈现一定的“负倾”(即随碳数增加呈现逐渐贫13C)趋势;一元脂肪酸以C16和C18为主,具有明显的偶碳优势,与同碳数的正构烷烃具有相似的碳同位素组成。氧化产物则以一元脂肪酸和α,ω 二元脂肪酸为主,一元脂肪酸低碳数部分呈现“负倾”趋势,高碳数部分则呈现“正倾”的趋势;α,ω 二元脂肪酸与低碳数的一元脂肪酸具有相似的分布,表明它们可能具有相同的母源。对比研究表明JL 30抽提物中正构烷烃可能存在混源的影响,其碳同位素组成是多源混合的结果。  相似文献   
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