Regional soil organic carbon prediction model based on a discrete wavelet analysis of hyperspectral satellite data     

《International Journal of Applied Earth Observation and Geoinformation》2020

Most studies have the achieved rapid and accurate determination of soil organic carbon (SOC) using laboratory spectroscopy; however, it remains difficult to map the spatial distribution of SOC. To predict and map SOC at a regional scale, we obtained fourteen hyperspectral images from the Gaofen-5 (GF-5) satellite and decomposed and reconstructed the original reflectance (OR) and the first derivative reflectance (FDR) using discrete wavelet transform (DWT) at different scales. At these different scales, as inputs, we selected the 3 optimal bands with the highest weight coefficient using principal component analysis and chose the normalized difference index (NDI), ratio index (RI) and difference index (DI) with the strongest correlation with the SOC content using a contour map method. These inputs were then used to build regional-scale SOC prediction models using random forest (RF), support vector machine (SVM) and back-propagation neural network (BPNN) algorithms. The results indicated that: 1) at a low decomposition scale, DWT can effectively eliminate the noise in satellite hyperspectral data, and the FDR combined with DWT can improve the SOC prediction accuracy significantly; 2) the method of selecting inputs using principal component analysis and a contour map can eliminate the redundancy of hyperspectral data while retaining the physical meaning of the inputs. For the model with the highest prediction accuracy, the inputs were all derived from the wavelength range of SOC variations; 3) the differences in prediction accuracy among the different prediction models are small; and 4) the SOC prediction accuracy using hyperspectral satellite data is greatly improved compared with that of previous SOC prediction studies using multispectral satellite data. This study provides a highly robust and accurate method for predicting and mapping regional SOC contents.  相似文献   

广西土壤有机质空间变异特征及其影响因素研究   总被引：2，自引：0，他引：2  

钟聪  李小洁  何园燕  邱微文  李杰  张新英  胡宝清 《地理科学》2020,40(3):478-485

基于广西第二次土壤普查的270个土壤剖面资料,结合1∶50万数字化土壤类型图、土地利用类型图和气象监测数据等资料,利用地统计学和逐步回归分析等方法对广西表层土壤有机质空间变异特征及其影响因素进行了探究。结果表明：广西表层土壤有机质平均含量为3.11±2.19%,变异系数为70.72%,空间分布呈北高南低的趋势。广西表层土壤有机质空间分布受到自然和人为因素的共同影响,土壤类型、成土母质、海拔、土地利用、气候和坡度6个环境因子对全区土壤有机质含量变异的综合解释能力为47.9%。其中,土壤类型是最重要的影响因素,能独立解释其变异的36.0%,海拔和成土母质分别能独立解释28.5%和15.8%。气温对广西土壤有机质空间分布的影响比降水量更加显著,从而造成了广西土壤有机质整体呈南低北高的趋势。同时,土壤有机质对气温的敏感性在一定程度上受到降雨量的制约。此外,研究区农业耕作管理等因素对土壤有机质的影响也不容忽视。  相似文献   

秋季连续打捞蓝藻对水-气界面温室气体通量的影响     

荀凡  杜先  陈新芳  刘高飞  齐天赐  冯慕华 《湖泊科学》2020,32(6):1707-1722

在巢湖西北半湖近岸带设置大型围隔研究秋季连续打捞蓝藻对湖泊温室气体通量的影响，应用YL-1000型大型仿生式水面蓝藻清除设备进行原位打捞蓝藻，通过便携式温室气体分析仪-静态箱法对大型围隔内水-气界面CH₄、CO₂通量特征及其影响因素进行观测.结果表明：对比未打捞区，蓝藻连续打捞下打捞区水体中叶绿素a（Chl.a）、悬浮物（SS）浓度不断下降，两者削减率分别为72%、85%，Chl.a、SS浓度分别下降到29.6±2.5 μg/L、12.5±1.2 mg/L，打捞对围隔内颗粒态物质去除效果十分明显；打捞过程中水体溶解性有机物（DOM）中微生物代谢类腐殖质（C1）、类蛋白（C3）显著下降趋势，打捞区C1、C3组分（0.18±0.02、0.06±0.01 RU）强度明显低于未打捞区（0.26±0.05、0.12±0.03 RU），打捞能有效控制藻源性溶解性有机质释放.同时，打捞区水-气界面CH₄通量呈显著下降趋势，未打捞区CH₄通量平均值（17.473±1.514 nmol/（m²·s））为打捞区（7.004±4.163 nmol/（m²·s））近2倍，CH₄通量与Chl.a、C1、C3组分均呈显著正相关，水体中藻源性溶解态有机质对CH₄通量具有促进作用；打捞区CO₂释放通量呈显著上升趋势，打捞区CO₂吸收通量（-0.200±0.069 μmol/（m²·s））明显低于未打捞区（-0.344±0.017 μmol/（m²·s）），CO₂通量与Chl.a、温度均呈显著负相关.秋季打捞对CH₄、CO₂综合日平均通量减排量值为0.275±0.076 mol/（m²·d）（以CO₂当量计）.研究结果揭示了巢湖秋季连续打捞蓝藻过程对水-气界面温室气体具有显著减排作用，且能在一定程度上减缓蓝藻水华与湖泊富营养化、气候变暖之间的恶性循环，为湖泊碳循环和蓝藻水华灾害防控提供科学数据支撑和理论参考.  相似文献   

针铁矿对湖泊草、藻来源可溶有机质的非均质吸附     

章奇  居琪  李健欣  曹驰程  江和龙  张晖 《湖泊科学》2020,32(4):1041-1049

为探究富营养化湖泊中自生源可溶有机质(DOM)在泥水界面的吸附行为,以马来眼子菜(Potamogeton malaianus)和铜绿微囊藻(Microcystis aeruginosa)释放的DOM为代表,考察针铁矿对草、藻源DOM中不同组分的吸附特征.三维荧光平行因子分析表明类富里酸组分C1和类胡敏酸组分C4的含量很低,而类蛋白物质(类酪氨酸组分C2和类色氨酸组分C3)分别占草、藻源DOM荧光组成的70%和93%. 2种DOM均可被针铁矿吸附,吸附过程符合伪一级动力学.通过等温线拟合发现针铁矿吸附藻源DOM的非线性更强,饱和吸附量(23.77 mg/g)高于草源DOM(19.10 mg/g).特别地,类蛋白组分呈现非线性吸附,而类腐殖物质的吸附近似线性,且针铁矿对于DOM各荧光组分的吸附量顺序为:C3C2 C4 C1,此非均质吸附特征与DOM组分的初始含量、分子大小、芳香性及有效吸附位点有关.红外光谱证实氨基、羧基和羟基是吸附过程中的重要官能团.因此,草、藻源DOM显著改变了针铁矿表面的有机物质组成,影响湖泊沉积物的生物地球化学行为.  相似文献   

Drying increases organic colloidal mobilization in the karst vadose zone: Evidence from a 15-year cave-monitoring study     

Jin Liao  Chaoyong Hu  Xiuli Li  Jiaoyang Ruan 《水文研究》2021,35(4):e14163

Understanding the hydrological processes of colloids within the karst vadose zone is vital to the security of karst groundwater and providing appropriate paleohydrological explanations of colloid-facilitated metals in speleothem. This study addresses the mobilization mechanisms driving colloidal organic matter (COM) transport in the karst vadose zone using a 15-year long monthly monitoring dataset from a cave drip point (HS4) in Heshang Cave, Qingjiang Valley, China. Variations in COM concentrations were reported as the fluorescence difference values of raw and filtered (<0.22 μm) samples at an excitation wavelength of 320 nm and emission wavelength of ~400 nm. A fluorescence humification index (HIX) lower than 0.8 and an autochthonous index (BIX) higher than 1.2 indicated that the origin of COM was mainly from the karst vadose zone, rather than the soil zone. The COM concentration varied from 0.001 to 0.038 Raman Unit (RU), with evident seasonal fluctuations. Rising limbs for COM values occurred prior to rising limbs within a dripwater hydrograph; moreover, the COM peak values corresponding to the beginning of the increasing hydrograph generally suggested that the mobilization of COM reflected the movement of the air–water interface (AWI) in the karst vadose zone rather than rainfall intensity or flow velocity. COM peak values were positively correlated with the antecedent drying duration and negatively correlated with HIX values. These phenomena may be explained by the increased amount of organic matter that was aggregated and absorbed on the surface of carbonate in the karst vadose zone during a longer drying duration. Moreover, the longer drying duration was also beneficial to autochthonous biological activity, which subsequently decreased the HIX value of the organic matter in the karst vadose zone. The movement of AWI and the drying duration are both controlled by the outside weather conditions. This study is therefore conducive to evaluating the security of karst groundwater in response to climate change, and challenges prevailing paleoclimate interpretations of colloid-facilitated metal abundance timeseries reported from speleothems.  相似文献   

Relationship Between Electrical Properties and Sedimentary Environment of the Longmaxi Formation Shale, Southern Sichuan     

YANG Kai  ZHANG Bing  WANG Xuben  HE Lanfang  YANG Hongyu  WANG Pengwan  TANG Jialin  DENG Jixin  ZHANG Cong 《《地质学报》英文版》2020,94(5):1531-1546

The Lower Silurian Longmaxi Formation in the south of Sichuan is a key player in the exploration and development of shale gas in China. Due to a highly complex topographic area, electromagnetic methods (EM) become important exploration means in this area. Many studies have been conducted on the shale mineral composition and electrical properties of shale, however, the correlation between sedimentary environments and the electrical properties of shale remain poorly understood. The electrical properties and sedimentary environment of the organic-rich shale of the Longmaxi Formation have been studied by means of X-ray diffraction, organic geochemistry, scanning electron microscopy and complex resistivity measurements. The discovered high quartz content of the Longmaxi Formation shale results in low resistivity. Deep-water shelf biogenic quartz contributes lower resistivity more than that of shallow-water terrigenous quartz. The deep-water anoxic and organic sedimentary environment led to major enrichment of pyrite, leading to a high polarization effect in shale. We present the correlation between the lithofacies types and electrical properties of Longmaxi Formation. The mixed siliceous shale lithofacies is the most favorable among the three lithofacies, which is characterized by high total organic carbon (TOC) content, high brittleness mineral content, high polarization and low resistivity (“three high and one low”). This feature is an effective identification of shale gas reservoirs by electromagnetic prospecting. Our study can provide constraints on electrical parameters of rocks for electromagnetic “sweet spot” exploration of shale gas, and so this has important geological significance to shale gas exploration and development.  相似文献   

Microstructure Evolution of Organic Matter and Clay Minerals in Shales with Increasing Thermal Maturity     

GU Yuantao  LI Xiaoxi  YANG Shuguang  WAN Quan 《《地质学报》英文版》2020,94(2):280-289

As the two important components of shale, organic matter(OM) and clay minerals are usually thought to strongly influence the hydrocarbon generation, enrichment and exploitation. The evolution process of OM and clay minerals as well as their interrelationship over a wide range of thermal maturities are not completely clear. Taking Yanchang(T_3y), Longmaxi(S_1l) and Niutitang(?_1n) shales as examples, we have studied the microstructure characteristics of OM and clay minerals in shales with different thermal maturities. The effects of clay minerals and OM on pores were reinforced through sedimentation experiments. Using a combination of field emission scanning electron microscopy(FESEM) and low-pressure N_2 adsorption, we investigated the microstructure differences among the three shales. The results showed that both OM and clay minerals have strong effects on pores, and small mesopore(2–20 nm) is the dominant pore component for all three samples. However, the differences between the three samples are embodied in the distribution of pore size and the location. For the T_3y shale, clay minerals are loosely arranged and develop large amounts of pores, and fine OM grains often fill in intergranular minerals or fractures. Widespread OM pores distribute irregularly in S_1l shale, and most of the pores are elliptical and nondirectional. The ?_1n shale is characterized by the preferred orientational OM-clay aggregates, and lots of pores in the composites are in the mesopore range, suggesting that over maturity lead to the collapse and compaction of pores under huge pressure of strata. The results of the current research imply that with increasing thermal maturity, OM pores are absent at low maturity(T_3y), are maximized at high maturity(S_1l) and are destroyed or compacted at over-mature stage(?_1n). Meanwhile, clay minerals have gone through mineral transformation and orientational evolution. The interaction of the two processes makes a significant difference to the microstructure evolution of OM and clay minerals in shale, and the findings provide scientific foundation in better understanding diagenetic evolution and hydrocarbon generation of shale.  相似文献   

Dissolved organic matter in surface runoff in the Loess Plateau of China: The role of rainfall events and land-use     

Zhongwu Li  Hao Peng  Binggeng Xie  Chun Liu  Xiaodong Nie  Danyang Wang  Mei Huang  Haibing Xiao  Lin Shi  Xuqin Zhang  Jieyu Jiang 《水文研究》2020,34(6):1446-1459

Exploring the chemical characterization of dissolved organic matter (DOM) is important for understanding the fate of laterally transported organic matter in watersheds. We hypothesized that differences in water-extractable organic matter (WEOM) in soils of varying land uses and rainfall events may significantly affect the quality and the quantity of stream DOM. To test our hypotheses, characteristics of rainfall-runoff DOM and WEOM of source materials (topsoil from different land uses and gullies, as well as typical vegetation) were investigated at two adjacent catchments in the Loess Plateau of China, using ultraviolet–visible absorbance and excitation emission matrix fluorescence with parallel factor analysis (PARAFAC). Results indicated that land-use types may significantly affect the chemical composition of soil WEOM, including its aromaticity, molecular weight, and degree of humification. The PARAFAC analysis demonstrated that the soils and stream water were dominated by terrestrial/allochthonous humic-like substances and microbial transformable humic-like fluorophores. Shifts in the fluorescence properties of stream DOM suggested a pronounced change in the relative proportion of allochthonous versus autochthonous material under different rainfall patterns and land uses. For example, high proportions of forestland could provide more allochthonous DOM input. This study highlights the relevance of soils and hydrological dynamics on the composition and fluxes of DOM issuing from watersheds. The composition of DOM in soils was influenced by land-use type. Precipitation patterns influenced the proportion of terrestrial versus microbial origins of DOM in surface runoff. Contributions of allochthonous, terrestrially derived DOM inputs were highest from forested landscapes.  相似文献   

Response of soil aggregate disintegration to the different content of organic carbon and its fractions during splash erosion     

Hairu Li  Gang Liu  Ju Gu  Hong Chen  Hongqiang Shi  Mohamed A. M. Abd Elbasit  Feinan Hu 《水文研究》2021,35(2):e14060

Aggregate disintegration is a critical process in soil splash erosion. However, the effect of soil organic carbon (SOC) and its fractions on soil aggregates disintegration is still not clear. In this study, five soils with similar clay contents and different contents of SOC have been used. The effects of slaking and mechanical striking on splash erosion were distinguished by using deionized water and 95% ethanol as raindrops. The simulated rainfall experiments were carried out in four heights (0.5, 1.0, 1.5 and 2.0 m). The result indicated that the soil aggregate stability increased with the increases of SOC and light fraction organic carbon (LFOC). The relative slaking and the mechanical striking index increased with the decreases of SOC and LFOC. The reduction of macroaggregates in eroded soil gradually decreased with the increase of SOC and LFOC, especially in alcohol test. The amount of macroaggregates (>0.25 mm) in deionized water tests were significantly less than that in alcohol tests under the same rainfall heights. The contribution of slaking to splash erosion increased with the decrease of heavy fractions organic carbon. The contribution of mechanical striking was dominant when the rainfall kinetic energy increased to a range of threshold between 9 J m⁻² mm⁻¹ and 12 m⁻² mm⁻¹. This study could provide the scientific basis for deeply understanding the mechanism of soil aggregates disintegration and splash erosion.  相似文献   

Using Mesoproterozoic sedimentary geochemistry to reconstruct basin tectonic geography and link organic carbon productivity to nutrient flux from a Northern Australian large igneous Province     

Bo Yang  Alan S. Collins  Grant M. Cox  Amber J. M. Jarrett  Steven Denyszyn  Morgan L. Blades  Juraj Farkaš  Stijn Glorie 《Basin Research》2020,32(6):1734-1750

The Beetaloo Sub-basin, northern Australia, is considered the main depocentre of the 1,000-km scale Mesoproterozoic Wilton package of the greater McArthur Basin – the host to one of the oldest hydrocarbon global resources. The ca. 1.40–1.31 Ga upper Roper Group and the latest Mesoproterozoic to early Neoproterozoic unnamed group of the Beetaloo Sub-basin, together, record ca. 500 million years of depositional history within the North Australia Craton. Whole-rock shale Sm–Nd and Pb isotope data from these sediments reveal sedimentary provenance and their evolution from ca. 1.35 to 0.85 Ga. Furthermore, these data, together with shale major/trace elements data from this study and pyrolysis data from previous publications, are used to develop a dynamic tectonic geography model that links the organic carbon production and burial to an enhanced weathering of nutrients from a large igneous province. The ca. 1.35–1.31 Ga Kyalla Formation of the upper Roper Group is composed of isotopically evolved sedimentary detritus that passes up, into more isotopically juvenile Pb values towards the top of the formation. The increase in juvenile compositions coincides with elevated total organic carbon (TOC) contents of these sediments. The coherently enriched juvenile compositions and TOC the upper portions of the Kyalla Formation are interpreted to reflect an increase in nutrient supply associated with the weathering of basaltic sources (e.g. phosphorous). Possible, relatively juvenile, basaltic sources include the Wankanki Supersuite in the western Musgraves and the Derim Derim–Galiwinku large igneous province (LIP). The transition into juvenile, basaltic sources directly before a supersequence-bounding unconformity is here interpreted to reflect uplift and erosion of the Derim Derim–Galiwinku LIP, rather than an influx of southern Musgrave sources. A new baddeleyite crystallisation age of 1,312.9 ± 0.7 Ma provides both a tight constraint on the age of this LIP, along with its associated magmatic uplift, as well as providing a minimum age constraint for Roper Group deposition. The unconformably overlying lower and upper Jamison sandstones are at least 300 million years younger than the Kyalla Formation and were sourced from the Musgrave Province. An up-section increase in isotopically juvenile compositions seen in these rocks is interpreted to document the progressive exhumation of the western Musgrave Province. The overlying Hayfield mudstone received detritus from both the Musgrave and Arunta regions, and its isotopic geochemistry reveals affinities with other early Neoproterozoic basins (e.g. Amadeus, Victoria and Officer basins), indicating the potential for inter-basin correlations.  相似文献