First Multi‐Isotopic (Pb‐Nd‐Sr‐Zn‐Cu‐Fe) Characterisation of Dust Reference Materials (ATD and BCR‐723): A Multi‐Column Chromatographic Method Optimised to Trace Mineral and Anthropogenic Dust Sources     

Aubry Vanderstraeten  Steeve Bonneville  Stefania Gili  Jeroen de Jong  Wendy Debouge  Philippe Claeys  Nadine Mattielli 《Geostandards and Geoanalytical Research》2020,44(2):307-329

Atmospheric dust is an integral component of the Earth system with major implications for the climate, biosphere and public health. In this context, identifying and quantifying the provenance and the processes generating the various types of dust found in the atmosphere is paramount. Isotopic signatures of Pb, Nd, Sr, Zn, Cu and Fe are commonly used as sensitive geochemical tracers. However, their combined use is limited by the lack of (a) a dedicated chromatographic protocol to separate the six elements of interest for low‐mass samples and (b) specific reference materials for dust. Indeed, our work shows that USGS rock reference materials BHVO‐2, AGV‐2 and G‐2 are not applicable as substitute reference materials for dust. We characterised the isotopic signatures of these six elements in dust reference materials ATD and BCR‐723, representatives of natural and urban environments, respectively. To achieve this, we developed a specific procedure for dust, applicable in the 4–25 mg mass range, to separate the six elements using a multi‐column ion‐exchange chromatographic method and MC‐ICP‐MS measurements.  相似文献   

Temporal and Spatial Dynamics Analysis of Grassland Ecosystem Pressure in Kazakhstan     

WEN Xin  YAN Huimin  XIE Xiaoping  DU Wengpeng  LAI Chenxi  ZHEN Lin 《资源与生态学报(英文版)》2019,10(6):667-675

Affected by climate change and policy factors, Kazakhstan is the country with the most severe ecological degradation and grassland conflicts in Central Asia. Therefore, studying the state of grassland carrying resources in Kazakhstan is particularly important for understanding the responses of grassland ecosystems to climate change and human activities. Based on Kazakhstan's remote sensing data and animal husbandry statistics, this study analyzes the patterns of changes in grassland ecosystems in Kazakhstan based on the supply and consumption of these ecosystems. The results show that: 1) From 2003 to 2017, the number of livestock raised in Kazakhstan showed a trend of sustained and steady growth. Due to freezing damage, the scale of livestock farming decreased in 2011, but a spatial difference in the livestock farming structure was not obvious. 2) The fluctuation of grassland supply in Kazakhstan has increased, while the consumption due to animal husbandry has also continued to increase, resulting in an increasing pressure on the grassland carrying capacity. 3) Between 2003 and 2017, the overall grassland carrying status of Kazakhstan have been abundant, but the grassland carrying pressure index has shown a steadily increasing trend, the grassland carrying pressure is growing, and it is mainly determined by grassland productivity. The greater pressure in lower Kyzylorda state, the southern Kazakhstan state of the cultivated land and the northern Kazakhstan state has gradually expanded to include the agro-pastoral zone and the semi-desert zone.  相似文献   

Locality Attributes and Networks Serving to Reveal Amazonian Urbanization beyond the Cities     

Ana Paula Dal'Asta  Silvana Amaral 《Geographical review》2019,109(2):199-223

Beyond the Amazonian cities, distinct spatial units arranged in networks compose an extended urban space, usually invisible to government agencies and public polities. This article empirically reveals this space by studying the localities’ characteristics and connections. In southwestern Pará, Brazil, 236 communities were sampled using field expeditions. Variables related to the locality organization, history, health and education services, urban infrastructure, and land use were explored in a fuzzy cluster analysis. Local production and consumption flows were considered in the locality network analysis. The fuzzy analysis allowed identifying a hierarchy of localities for which the geographical location influences the spatial distribution patterns of five groups. On the other hand, consumption and production networks identified different locality's articulations, with persistent dependence on cities. These results characterize extensive urbanization at the local level and highlights the participation of the local populations configuring the Amazonian territory.  相似文献   

贵州安龙县耕地土壤几种有效态与对应全量、pH值、有机质的相关分析          下载免费PDF全文

鲍大忠  游桂芝  袁盛博 《贵州地质》2020,37(4):546-550

为了掌握快速路瓶颈路段异质交通流的演变规律，以缓解交通拥堵，本文以快速路上匝道瓶颈路段为研究对象，构建了考虑安全距离的改进NaSch上匝道模型，利用数值仿真，对不同场景交通流演化过程进行系统性研究。仿真结果显示：在不同条件下，异质交通流中自动驾驶车辆比例的增加对瓶颈路段交通运营状态影响结果各异。在自由流阶段，自动驾驶车辆比例的增加对快速路瓶颈路段运营通行能力的增加无显著影响，自动驾驶车辆比例取0.9时，瓶颈路段运营通行能力反而降低了2.48%；在交通拥堵状态下，当异质交通流中自动驾驶车辆比例达到0.7及以上时，才有助于交通拥堵的消散，且其临界值随交通拥堵状态程度的提高而增大；当交通密度达到100 veh/km以上时，自动驾驶车辆比例的增加无法实质性改善瓶颈路段交通拥堵状态。研究结果可为异质交通流环境下的快速路上匝道瓶颈路段的治堵策略提供理论依据。  相似文献   

GBW10010a大米标准物质复(研)制及数据特征     

杨榕  顾铁新  潘含江  刘妹  周国华 《岩矿测试》2020,39(6):866-877

随着我国对生态文明建设的重视，自然资源综合调查势在必行，对生物标准物质亦提出了新的需求。当前相关调研工作已经大面积开展，自然资源综合调查、农产品与食品安全评价都需要对生物样品元素组成进行准确测试，需要以生物标准物质作为生物成分测试量值比对和溯源的基础，因此对生物基体标准物质的需求量大幅增加。大米作为主要粮食之一，其食品安全日益受到重视，对大米中的化学成分进行准确的分析测试具有重要的现实意义，因而对大米标准物质的需求量尤为突出，但目前大米成分分析标准物质已供不应求。本文严格按照《标准物质定值的通用原则及统计学原理》（JJF 1343—2012）和《地质分析标准物质的研制》（JJF 1646—2017）等相关规范要求，开展了GBW10010a大米成分分析标准物质的复（研）制工作，包括样品采集、加工制备、均匀性检验、稳定性检验、多家实验室协作定值测试及不确定度评定等关键环节。结果表明：本次复（研）制的大米标准物质定值成分多样、量值准确可靠，符合国家一级标准物质的要求。GBW10010a共定值54项主微量元素，包括Ag、Al、As、B、Ba、Be、Bi、Ca、Cd、Ce、Co、Cr、Cs、Cu、Dy、Er、Eu、Fe、Gd、Ge、Hg、Ho、K、La、Li、Ho、Mg、Mn、Mo、N、Na、Nb、Nd、Ni、P、Pb、Pr、Rb、S、Sb、Sc、Se、Si、Sm、Sr、Tb、Th、Tl、Tm、U、V、Y、Yb、Zn，其中的39项元素给出了标准值及不确定度，包括Ag、Al、As、B、Ba、Ca、Cd、Ce、Co、Cs、Cu、Dy、Er、Fe、Hg、K、Li、Mg、Mn、Mo、N、Na、Nd、Ni、P、Pb、Pr、Rb、S、Sb、Se、Si、Sm、Sr、Tb、Tl、Y、Yb、Zn；15项元素提供参考值，包括Be、Bi、Cr、Eu、Gd、Ge、Ho、Ho、La、Nb、Sc、Th、Tm、U、V。与原有GBW10010大米标准物质相比较，GBW10010a中As、Cd、Co、Cr、Cu、Hg、Mn、Mo、Ni、Zn等重金属元素含量显著下降，其中Cd、Cu、Zn降幅较大，分别下降约39%、43%、38.7%，一定程度上反映了农田生态环境的改善。本批标准物质定值元素总数量增加了6项，新增定值元素Ag、Nb（Nb给出参考值），并且各项元素不确定度范围整体上有所缩小，如Al、Cd、Cu、Fe、K、Mg、Mo、Na、P、Pb、Se、Zn等对生物易有影响的重要元素，表明了地质分析测试方法技术的进步及定值水平的提高。本批标准物质定值元素涵盖了具有生物效应的大部分主微量元素，适用于农业生态环境地球化学调查与评价、生物样品测试、农产品质量与食品安全评价样品测试时的分析仪器校正、分析方法评价和分析质量监控等多个领域。  相似文献   

Determination of Radiogenic 87Sr/86Sr and Stable δ88/86SrSRM987 Isotope Values of Thirteen Mineral,Vegetal and Animal Reference Materials by DS‐TIMS     

Jean‐Michel Brazier  Anne‐Dsire Schmitt  Eric Pelt  Damien Lemarchand  Sophie Gangloff  Tho Tacail  Vincent Balter 《Geostandards and Geoanalytical Research》2020,44(2):331-348

This work presents new ⁸⁷Sr/⁸⁶Sr and δ^88/86Sr_SRM987 isotopic values of thirteen mineral, vegetal and animal reference materials. Except for UB‐N, all our results are consistent with previously published data. Our results highlight intermediate precisions among the best presently published and a non‐significant systematic shift with the calculated δ^88/86Sr_SRM987 mean values for the three most analysed reference materials in the literature (i.e., IAPSO, BCR‐2 and JCp‐1). By comparison with the literature and between two distinct digestions, a significant bias of δ^88/86Sr_SRM987 values was highlighted for two reference materials (UB‐N and GS‐N). It has also been shown that digestion protocols (nitric and multi‐acid) have a moderate impact on the δ^88/86Sr_SRM987 isotopic values for the Jls‐1 reference materials suggesting that a nitric acid digestion of carbonate can be used without significant bias from partial digestion of non‐carbonate impurities. Different δ^88/86Sr_SRM987 values were measured after two independent Sr/matrix separations, according to the same protocol, for a fat‐rich organic reference material (BCR‐380R) and have been related to a potential post‐digestion heterogeneity. Finally, the δ^88/86Sr_SRM987 value differences measured between animal‐vegetal and between coral‐seawater reference materials agree with the previously published results, highlighting an Sr isotopic fractionation along the trophic chain and during carbonate precipitation.  相似文献   

High‐Precision Measurement of 187Os/188Os Isotope Ratios of Nanogram to Picogram Amounts of Os in Geological Samples by N‐TIMS using Faraday Cups Equipped with 1013 Ω Amplifiers     

Guiqin Wang  Hauke Vollstaedt  Jifeng Xu  Wengui Liu 《Geostandards and Geoanalytical Research》2019,43(3):419-433

N(¹⁸⁷Os)/N(¹⁸⁸Os) ratios of six geological reference materials were measured using static Faraday cups (FCs) with 10¹³ Ω amplifiers by N‐TIMS. Our results show that the repeatability precision was 2–3‰ (2 RSD, n = 3), when taking ~ 1 g of BHVO‐2 with 76 pg g^?1 of Os mass fraction and ~ 2 g of BCR‐2 with 21 pg g^?1 of Os mass fraction for each sample, whether measured by FCs or by secondary electron multiplier. The repeatability precision measured by FCs was 1–0.2‰ (2 RSD, n = 3) when taking ~ 1 g of BIR‐2 with 350 pg g^?1 of Os mass fraction, ~ 1 g of WGB‐1 with 493 pg g^?1 of Os mass fraction or ~ 0.5 g of WPR‐1 with 13.3 ng g^?1 of Os mass fraction for each sample, which is much better than those measured by secondary electron multiplier. Instead, when taking ~ 2 g of AGV‐2 with 4 pg g^?1 Os mass fraction, the repeatability precision measured by secondary electron multiplier is 3–4‰ (RSD, n = 3), which is better than those measured by FCs. Of the six reference materials analysed, WPR‐1 and BIR‐1a are the most homogeneous with regard to Os isotopic composition (2 RSD of 0.08% and 0.23%, respectively) when test portion masses are 0.5–1 g.  相似文献   

基态位涡径向分布对浅水涡旋系统演变的影响分析Part Ⅱ:扰动发展和结构变化          下载免费PDF全文

刘爽  钟玮  刘宇迪 《地球物理学报》2018,61(9):3592-3606

本文在基态位涡（Potential Vorticity，PV）径向分布和基态涡旋强度对热带气旋（Tropical Cyclone，TC）类涡旋系统稳定性特征影响的研究基础上，结合理想试验和数值模拟诊断分析基态PV径向分布对扰动增长和系统结构变化的影响.基于线性正压浅水模型，设计三种典型基态PV中空结构下基态涡旋强度对系统稳定性影响的敏感性试验.结果表明：基态涡旋的强度主要影响稳定性的强弱，强度越强，不稳定增长率越大，而基态PV径向分布对系统最不稳定波动性质起着决定作用.分析不同波数下扰动的发展及不同波数间扰动的相互作用可知，对于宽且实的PV环，系统稳定性主要取决于低波数不稳定，且最不稳定波数扰动的发展具有明显的优势地位；对于窄且空的PV环，系统稳定性主要取决于高波数不稳定，且多个高波数下增长最快模态的不稳定增长率值十分接近.利用模态线性叠加法讨论扰动增长对系统结构变化的影响表明：最不稳定波数的扰动发展对系统结构变化有关键影响，而多个波数的扰动不稳定增长相当时，不同波数的扰动发生相互作用从而影响系统结构变化.最后，利用实际个例模拟资料分析基态PV径向分布及其变化对TC结构和强度的影响表明：TC内核区出现的多边形眼墙结构与当前时刻基态PV径向分布所决定的最不稳定波数有很好的对应关系，同时基态PV径向分布变化所反映出的系统动力稳定性强弱与TC强度发展阶段具有很好的相关性.  相似文献   

科尔沁湿草甸参考作物蒸散发模拟分析     

李霞  刘廷玺  段利民  王冠丽  童新  周亚军  杨晓君 《中国沙漠》2020,40(2):134-143

为探明气候变化下干旱半干旱地区湿草甸参考作物蒸散发(ET₀)影响因子,使用FAO 56 P-M模型对科尔沁湿草甸ET₀进行模拟,利用涡度相关系统对模型的适用性进行评价,并通过通径分析及指标敏感性分析对ET₀的影响因子进行辨识。结果表明:(1)小时尺度模拟精度最高,日尺度次之,月尺度较差,小时尺度上晴、阴、雨3种天气条件下模拟效果不同,晴天最优,阴雨天较差。(2)ET₀年内变化呈单峰曲线状,生长季明显高于非生长季,集中在3—10月,占全年89.79%。生长季典型晴天ET₀逐小时分布特征遵循倒“U”单峰型变化规律。(3)通径分析结果显示,对ET₀的通径系数以及对回归方程估测可靠程度E的总贡献均表现为VPD(饱和水汽压差) > T_min(最低气温) > R_n(冠层表面净辐射)>u₂(2 m高度风速),即VPD为影响ET₀最重要的因子;指标敏感性分析中,在去除VPD后引起的E变化最大,说明ET₀对VPD的变化最为敏感,其次为u₂、T_min和R_n。  相似文献   

气举反循环钻进井壁稳定及适用性探讨          下载免费PDF全文

郑伯乐  郑秀华  段晨阳  叶宏宇 《探矿工程》2020,47(6):13-18

气举反循环工艺具有钻进效率高、携带岩屑能力强、防漏效果好以及钻头寿命长等优点，同时还可以提高流体矿产的产能。但是一般认为气举反循环钻进抽吸作用会产生负压，不利于井壁稳定，不宜在松散地层应用。本文通过计算气举反循环钻进环空水力参数，并从环空压力以及冲洗液流态、流速等方面探讨研究气举反循环钻进中井壁稳定及其适用性，指出通过选取合适的钻具组合以及调节冲洗液性能，可使气举反循环工艺对不同地层的适应性更广。  相似文献