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1.
Dissolved pollutants in stormwater are a main contributor to water pollution in urban environments. However, many existing transport models are semi-empirical and only consider one-dimensional flows, which limit their predictive capacity. Combining the shallow water and the advection–diffusion equations, a two-dimensional physically based model is developed for dissolved pollutant transport by adopting the concept of a ‘control layer’. A series of laboratory experiments has been conducted to validate the proposed model, taking into account the effects of buildings and intermittent rainfalls. The predictions are found to be in good agreement with experimental observations, which supports the assumption that the depth of the control layer is constant. Based on the validated model, a parametric study is conducted, focusing on the characteristics of the pollutant distribution and transport rate over the depth. The hyetograph, including the intensity, duration and intermittency, of rainfall event has a significant influence on the pollutant transport rates. The depth of the control layer, rainfall intensity, surface roughness and area length are dominant factors that affect the dissolved pollutant transport. Finally, several perspectives of the new pollutant transport model are discussed. This study contributes to an in-depth understanding of the dissolved pollutant transport processes on impermeable surfaces and urban stormwater management.  相似文献   
2.
刘敏  姜会明  姜天龙 《地理科学》2020,40(12):2037-2045
按照粮食的产销情况,将全国划分为3类粮食功能区域,利用固定效应模型和门槛效应模型分析了农机投入对农业绿色全要素生产率(GTFP)的影响及门槛效应的区域差异。结果表明:农机投入对农业GTFP的影响程度存在区域异质性,农机投入对粮食主销区农业GTFP提升的促进作用最大,粮食产销平衡区次之,粮食主产区最小;农机投入对农业GTFP的影响路径亦存在区域差异,粮食主产区和产销平衡区的农机投入通过促进农业技术效率和农业技术进步进而推动农业GTFP提升,粮食主销区的农机投入通过促进农业技术进步推动农业GTFP提升;农机投入对粮食主产区农业GTFP的影响存在双门槛效应,对粮食主销区和产销平衡区农业GTFP的影响存在单门槛效应。  相似文献   
3.
由于缺乏长期观测资料,前人对山东半岛邻近海域海水溶解氧的时间变化和空间分布特征的研究较少。本文基于威海刘公岛海洋牧场于2016年7月20日至2017年3月14日期间,利用生态环境实时在线观测系统获得的底层海水的温度、盐度、水深、溶解氧数据,分析了该牧场海水溶解氧浓度的时间变化特征及其影响因素,并探讨了低氧灾害发生的可能性。结果表明在观测期间,该牧场海水溶解氧浓度以季节变化为主,冬季最大、夏季最小,其中2月份平均值最高,约为10.86mg/L,8月份平均值最低,约为5.91mg/L。同时海水溶解氧浓度也存在显著的小时变化和日变化,且变化幅度于8月份最大、3月份最小。影响海水溶解氧浓度变化的主要因素是海水温度,溶解氧浓度随着温度的季节性变化而变化。夏季,水体分层会使溶解氧浓度发生大幅度的降低,大风过程对于溶解氧浓度也有一定的影响,通过打破夏季的季节性温跃层使水体发生垂向混合从而为海底提供氧气,但大风过程之后的几天会出现溶解氧浓度降低的现象。本次研究发现刘公岛海洋牧场在观测期间不存在低氧现象。  相似文献   
4.
赵晓玲  朱玲玲 《地下水》2020,(1):46-47,146
阜阳是安徽省人口最多的市,工农业生产主要取用地下水,总硬度是该市浅层地下水主要超标组分之一。近5年来,该市浅层地下水总硬度平均值呈现缓慢增高的趋势,标准差亦在缓慢增加,近两年总硬度数值间差异明显增大。利用spss软件,分析近年浅层地下水的pH、TDS、总碱度、氯化物与总硬度的相关关系,结果可知:pH、TDS、总碱度、氯化物与总硬度都存在极显著的线性相关关系,其中,仅有pH与总硬度是负相关,其余均为正相关关系,总碱度与总硬度为低度线性相关,TDS、氯化物与总硬度呈中度线性相关。结合阜阳市浅层地下水的埋藏条件、补给来源、监测井的地理位置和地下水开采历史,得出该市浅层地下水总硬度升高主要与人为污染和地下水超采有关,外来的污染物来源主要是农业污染和生活污染。  相似文献   
5.
提出一种确定不等式约束Partial EIV模型解及精度评定的新方法,在总体最小二乘准则下,将附有不等式约束的Partial EIV模型转换为标准最优化问题。采取WHP拟牛顿修正的SQP方法求解,并利用SUT法对参数估值进行精度评定,可以减小迭代次数、提高收敛速度,且精度评定方法简单有效。  相似文献   
6.
加权总体最小二乘法是理论上估计EIV模型参数相对严密的方法,其迭代过程中涉及的矩阵运算较为耗时,在处理大量级数据时尤其明显。PEIV模型有助于提高加权总体最小二乘法的计算效率。本文基于PEIV模型和经典最小二乘准则给出了一种加权总体最小二乘法算法,算法的推导过程简洁,易于理解,迭代过程中无需重构矩阵,减少了矩阵运算量。最后通过仿真试验验证了算法的可靠性。试验结果表明,本文算法可以取得与现有算法相同的参数估计精度且计算效率更高。  相似文献   
7.
The Lower Silurian Longmaxi Formation in the south of Sichuan is a key player in the exploration and development of shale gas in China. Due to a highly complex topographic area, electromagnetic methods (EM) become important exploration means in this area. Many studies have been conducted on the shale mineral composition and electrical properties of shale, however, the correlation between sedimentary environments and the electrical properties of shale remain poorly understood. The electrical properties and sedimentary environment of the organic-rich shale of the Longmaxi Formation have been studied by means of X-ray diffraction, organic geochemistry, scanning electron microscopy and complex resistivity measurements. The discovered high quartz content of the Longmaxi Formation shale results in low resistivity. Deep-water shelf biogenic quartz contributes lower resistivity more than that of shallow-water terrigenous quartz. The deep-water anoxic and organic sedimentary environment led to major enrichment of pyrite, leading to a high polarization effect in shale. We present the correlation between the lithofacies types and electrical properties of Longmaxi Formation. The mixed siliceous shale lithofacies is the most favorable among the three lithofacies, which is characterized by high total organic carbon (TOC) content, high brittleness mineral content, high polarization and low resistivity (“three high and one low”). This feature is an effective identification of shale gas reservoirs by electromagnetic prospecting. Our study can provide constraints on electrical parameters of rocks for electromagnetic “sweet spot” exploration of shale gas, and so this has important geological significance to shale gas exploration and development.  相似文献   
8.
Exploring the chemical characterization of dissolved organic matter (DOM) is important for understanding the fate of laterally transported organic matter in watersheds. We hypothesized that differences in water-extractable organic matter (WEOM) in soils of varying land uses and rainfall events may significantly affect the quality and the quantity of stream DOM. To test our hypotheses, characteristics of rainfall-runoff DOM and WEOM of source materials (topsoil from different land uses and gullies, as well as typical vegetation) were investigated at two adjacent catchments in the Loess Plateau of China, using ultraviolet–visible absorbance and excitation emission matrix fluorescence with parallel factor analysis (PARAFAC). Results indicated that land-use types may significantly affect the chemical composition of soil WEOM, including its aromaticity, molecular weight, and degree of humification. The PARAFAC analysis demonstrated that the soils and stream water were dominated by terrestrial/allochthonous humic-like substances and microbial transformable humic-like fluorophores. Shifts in the fluorescence properties of stream DOM suggested a pronounced change in the relative proportion of allochthonous versus autochthonous material under different rainfall patterns and land uses. For example, high proportions of forestland could provide more allochthonous DOM input. This study highlights the relevance of soils and hydrological dynamics on the composition and fluxes of DOM issuing from watersheds. The composition of DOM in soils was influenced by land-use type. Precipitation patterns influenced the proportion of terrestrial versus microbial origins of DOM in surface runoff. Contributions of allochthonous, terrestrially derived DOM inputs were highest from forested landscapes.  相似文献   
9.
根据2017年7月和9月在山东威海褚岛北部海域现场测量的COD_(Mn)(Chemical oxygen demand)值和水体表观光学量,结合COMS(Communication,OceanMeteorological Satellite)上搭载的传感器GOCI(Geostationary Ocean Color Imager)所提供的有色可溶性有机物(Chromophoric dissolved organic matter,CDOM)产品,利用星地同步观测数据对现有的基于遥感反射比反演CDOM的模式进行验证,确定适合该海域的CDOM浓度遥感反演模式;通过对测试海域化学需氧量与遥感反演的水体CDOM浓度相关性分析,建立利用CDOM反演COD_(Mn)的遥感模式,并将该模式应用于测试海域LANDSAT 8/OLI(Operational Land Imager)遥感图像上,获取该海域COD_(Mn)浓度专题图,基于这些专题图分析了测试海域COD_(Mn)时空分布特征。结果表明:(1)基于GOCI产品的CDOM浓度值随时间和站点动态变化大,离岸越近数值越高,同一地点水体前后相差近1 h的数值变化也较大;(2)基于LANDSAT 8/OLI遥感数据反演的COD_(Mn)浓度时间动态变化大,总体来看褚岛附近水体的COD_(Mn)含量相对较低,褚岛以北海域水体COD_(Mn)含量有所增加,褚岛西侧水体的COD_(Mn)含量较东侧水体COD_(Mn)含量来说整体偏高。  相似文献   
10.
In order to understand the differences in the suspended sediment and total dissolved solid (TDS) yield patterns between the glacial and non‐glacial catchments at the headwaters of Urumqi River, northwestern China, water samples were collected from a glacier catchment and an empty cirque catchment within the region, during three melting seasons from 2006 to 2008. These samples were analyzed to estimate suspended sediment and TDS concentrations, fluxes and erosion rates in the two adjoining catchments. There were remarked differences in suspended sediment and TDS yield patterns between the two catchments. Suspended sediment concentrations were controlled mainly by the sediment source, whereas TDS concentrations were primarily related to the hydrologic interaction with soil minerals. Generally, the glacial catchment had much higher suspended sediment and TDS yields, together with higher denudation rates, than the non‐glacial catchment. Overall, glacial catchment was mainly dominated by physical denudation process, whereas the non‐glacial catchment was jointly influenced by physical and chemical denudation processes. The observed differences in material delivery patterns were mainly controlled by the runoff source and the glacial processes. The melting periods of glacier and snow were typically the most important time for the suspended sediment and TDS yields. Meanwhile, episodic precipitation events could generate disproportionately large yields. Subglacial hydrology dynamics, glaciers pluck and grind processes could affect erodibility, and the large quantities of dust stored on the glacier surface provided additional sources for suspended sediment transport in the glacial catchment. These mechanisms imply that, in response to climate change, the catchment behaviour will be modified significantly in this region, in terms of material flux. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   
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