Drying increases organic colloidal mobilization in the karst vadose zone: Evidence from a 15-year cave-monitoring study     

Jin Liao  Chaoyong Hu  Xiuli Li  Jiaoyang Ruan 《水文研究》2021,35(4):e14163

Understanding the hydrological processes of colloids within the karst vadose zone is vital to the security of karst groundwater and providing appropriate paleohydrological explanations of colloid-facilitated metals in speleothem. This study addresses the mobilization mechanisms driving colloidal organic matter (COM) transport in the karst vadose zone using a 15-year long monthly monitoring dataset from a cave drip point (HS4) in Heshang Cave, Qingjiang Valley, China. Variations in COM concentrations were reported as the fluorescence difference values of raw and filtered (<0.22 μm) samples at an excitation wavelength of 320 nm and emission wavelength of ~400 nm. A fluorescence humification index (HIX) lower than 0.8 and an autochthonous index (BIX) higher than 1.2 indicated that the origin of COM was mainly from the karst vadose zone, rather than the soil zone. The COM concentration varied from 0.001 to 0.038 Raman Unit (RU), with evident seasonal fluctuations. Rising limbs for COM values occurred prior to rising limbs within a dripwater hydrograph; moreover, the COM peak values corresponding to the beginning of the increasing hydrograph generally suggested that the mobilization of COM reflected the movement of the air–water interface (AWI) in the karst vadose zone rather than rainfall intensity or flow velocity. COM peak values were positively correlated with the antecedent drying duration and negatively correlated with HIX values. These phenomena may be explained by the increased amount of organic matter that was aggregated and absorbed on the surface of carbonate in the karst vadose zone during a longer drying duration. Moreover, the longer drying duration was also beneficial to autochthonous biological activity, which subsequently decreased the HIX value of the organic matter in the karst vadose zone. The movement of AWI and the drying duration are both controlled by the outside weather conditions. This study is therefore conducive to evaluating the security of karst groundwater in response to climate change, and challenges prevailing paleoclimate interpretations of colloid-facilitated metal abundance timeseries reported from speleothems.  相似文献   

从水体到沉积物:探寻有机质的沉积过程及其意义          下载免费PDF全文

蔡进功  曾翔  韦海伦  宋明水  王学军  刘庆 《古地理学报》2019,21(1):49-66

自然界中有机质分布广泛、类型多样且性质各异,不论在水体还是在沉积物(岩)中都扮演着重要的角色。因此,探讨各类型有机质聚集和沉积过程的差异性,对深化认识有机质沉积特征和演化规律具有重要的意义。生物体在生长过程中产生了许多有机质,包括生物体自身、生物残体、动物排泄物以及生物分泌的有机分子等,各类型有机质的性质差异极大。由于研究方法的不同,可将海洋中有机质划分为颗粒有机质(particulate organic matter,POM)和溶解有机质(dissolved organic matter,DOM),而DOM又可划分为胶体有机质(colloidal organic matter,COM)和真溶解有机质;从聚合体形式上看,又有海雪和悬浮体等存在形式。进一步分析发现有机质的形态包括生物体、生物残体、排泄物和有机质聚合体等,并且各类型有机质与无机矿物以不同的形式共存。此外,DOM与POM间存在一定的转化关系。这些性质和特征架起了不同类型有机质间聚集和沉积的桥梁。在沉积物(岩)中通过粒度或密度分级分离及孢粉相分析,也发现不同类型的有机质,如生物体、生物残体和无定形等,它们常与特定的无机矿物共生,如无定形多富集在黏粒级颗粒中,而生物体和生物残体多富集在粗颗粒中。进一步溯源发现沉积物(岩)中的各类有机质与生物有机质或海洋中有机质的类型极具相似性,这些特征展现各类型有机质在沉积过程中的差异性。综合有机质的形态、性质以及与矿物共生关系,认为有机质可通过机械沉积、化学沉积和生物沉积等3种不同的方式沉积保存,其中机械沉积的有机质以惰性的生物残体为主,化学沉积的有机质以活性极强的无定形为主,生物沉积有机质以活性较强的微生物和粘附物为主。有机质沉积方式及有机质特征、矿物—有机质间关系和保存条件的差异,决定了有机质的演化命运的不同,进而对有机质生烃以及碳循环产生重要的影响,因而应引起人们的高度关注。  相似文献   

烃源岩不同性质有机酸的分离及其检测方法     

杜佳宗  何蓓  蔡进功  雷天柱  刘庆  谢忠怀 《高校地质学报》2020,26(5):540-548

烃源岩中的有机酸来源于有机质，但有机质具有不同的赋存形式，有机酸具有不同性质，这将影响有机酸与不同赋存有机质的关系，进而影响分离和检测方法。文章在总结前人对有机质赋存形式和有机酸性质等特征的基础上，提出烃源岩中的有机酸并以非单一的形式存在，具有水溶性、脂溶性和难溶性有机酸三种类型，游离有机质中存在水溶性和脂溶性有机酸，而结合有机质中存在水溶性、脂溶性和难溶性有机酸。因此在检测方法上需采取分步分离的方法，且根据有机酸的性质选取合适的检测方法，即水溶性有机酸利用离子色谱检测，索氏抽提得到的脂溶性有机酸利用气相色谱—质谱检测，通过酸解抽提残渣得到的难溶性有机酸利用红外光谱检测，全面系统地认识烃源岩中有机酸含量和类型等特征。这对进一步探讨烃源岩各种类型有机酸特征和演化规律，深化烃源岩有机质生烃以及有机—无机相互作用等机理都具有重要意义。  相似文献   

黔北镇远牛蹄塘组黑色页岩沉积环境与有机质富集关系   总被引：1，自引：0，他引：1  

夏鹏  付勇  杨镇  郭川  黄金强  黄明勇 《地质学报》2020,94(3):947-956

通过矿物组分、主量元素、微量元素、碳氧同位素等特征，分析了黔北地区镇远县ZX井牛蹄塘组黑色页岩的岩相类型和不同岩相页岩的沉积环境及其与有机质富集间的关系。结果表明，牛蹄塘组下段以硅质页岩为主，TOC含量4. 96%~10. 10%；上段以富泥硅质页岩为主，TOC含量1. 43%~9. 04%。下段硅质页岩沉积于水流停滞的深水陆棚环境，沉积古水体为贫氧的还原状态；上段富泥硅质页岩沉积时期，仍为贫氧的还原环境，但水体滞留程度、还原性较下段硅质页岩沉积期弱。贫氧的还原环境是影响牛蹄塘组黑色页岩有机质富集的主要因素，热液作用和陆源碎屑对牛蹄塘组黑色页岩有机质富集的影响较小。  相似文献   

苔藓生物结皮层腐殖质组成变化特征研究          下载免费PDF全文

闫德仁  张胜男  吴振廷 《干旱区地理》2019,42(6):1354-1358

腐殖质组成是表征土壤化学性质的主要指标之一，在某种程度对评价风沙土的发育过程具有意义。采集了不同气候区沙地沙漠苔藓生物结皮层样品，采用重铬酸钾容量法和光密度法测定了苔藓结皮层腐殖质组成含量和胡敏酸吸光特性。结果表明：随着干燥指数的增加，苔藓结皮层有机质含量由14.93 g·kg^-1降低到9.89 g·kg^-1，腐殖酸总量由5.1 g·kg^-1降低到2.0 g·kg^-1，胡敏酸含量由2.9 g·kg^-1降低到 0.7 g·kg^-1，富里酸含量由2.2 g·kg^-1降低到1.3 g·kg^-1，胡敏酸与富里酸比值（HA/FA）由1.32降低到0.54，E₄/E₆比值则由4.28增加到5.83。苔藓结皮层腐殖质组成含量及胡敏酸吸光特性具有地带性变化趋势，并影响着生物结皮层及流动风沙土的发育演变过程。  相似文献   

Sedimentary and geochemical characterization of Middle–Late Miocene formations in the Neogene Tsugaru Basin,Japan by means of DTH27‐1 well sediment analysis     

Paolo Martizzi  Shun Chiyonobu  Hiroyuki Arato 《Island Arc》2020,29(1)

Middle–Late Miocene age siliceous formations outcropping along the northwestern side of Honshu Island are considered prospective source rocks for hydrocarbons. An analysis of geophysical, sedimentological, and geochemical properties is essential to evaluate the formations' source potential, and to understand the factors that determined the accumulation and preservation of organic matter. This study investigates the Middle–Late Miocene geological record of the Tsugaru back‐arc basin, located in the western part of Aomori prefecture, through an analysis of a 200 m long portion of a core from the DTH27‐1 well; this core is composed of the diatomaceous siltstones of the Akaishi Formation and the siliceous mudstones of the Odoji Formation. Sedimentological and geophysical characterization showed that the Akaishi Formation's diatomaceous siltstones are mostly massive and bioturbated, have low magnetic susceptibility, and demonstrate moderate natural radioactivity. Although the Odoji Formation's siliceous mudstones are massive, they have exceedingly low magnetic susceptibility and high natural radioactivity. Geochemical data from a Rock‐Eval Pyrolysis such as total organic carbon and generative potential (S1 + S2) revealed that, in the Tsugaru area, only the Odoji Formation is a likely prospective source rock for hydrocarbons. On the other hand, T_max values indicate that both the formations are thermally immature for generating hydrocarbons. The difference between the Akaishi and Odoji Formation in the sedimentological facies, in terms of the degree of bioturbation and the organic carbon content, indicates variations in lithological properties, such as porosity and grain size; moreover, this difference indicates a variation in the paleo‐oxygenation of bottom waters, with the transition from oxygen‐deficient conditions in the Middle Miocene to the more oxygenated conditions in the Late Miocene. Both the lithological and paleo‐environmental factors possibly influenced the organic richness in the two formations.  相似文献   

Relationship Between Electrical Properties and Sedimentary Environment of the Longmaxi Formation Shale, Southern Sichuan     

YANG Kai  ZHANG Bing  WANG Xuben  HE Lanfang  YANG Hongyu  WANG Pengwan  TANG Jialin  DENG Jixin  ZHANG Cong 《《地质学报》英文版》2020,94(5):1531-1546

The Lower Silurian Longmaxi Formation in the south of Sichuan is a key player in the exploration and development of shale gas in China. Due to a highly complex topographic area, electromagnetic methods (EM) become important exploration means in this area. Many studies have been conducted on the shale mineral composition and electrical properties of shale, however, the correlation between sedimentary environments and the electrical properties of shale remain poorly understood. The electrical properties and sedimentary environment of the organic-rich shale of the Longmaxi Formation have been studied by means of X-ray diffraction, organic geochemistry, scanning electron microscopy and complex resistivity measurements. The discovered high quartz content of the Longmaxi Formation shale results in low resistivity. Deep-water shelf biogenic quartz contributes lower resistivity more than that of shallow-water terrigenous quartz. The deep-water anoxic and organic sedimentary environment led to major enrichment of pyrite, leading to a high polarization effect in shale. We present the correlation between the lithofacies types and electrical properties of Longmaxi Formation. The mixed siliceous shale lithofacies is the most favorable among the three lithofacies, which is characterized by high total organic carbon (TOC) content, high brittleness mineral content, high polarization and low resistivity (“three high and one low”). This feature is an effective identification of shale gas reservoirs by electromagnetic prospecting. Our study can provide constraints on electrical parameters of rocks for electromagnetic “sweet spot” exploration of shale gas, and so this has important geological significance to shale gas exploration and development.  相似文献   

秋季连续打捞蓝藻对水-气界面温室气体通量的影响     

荀凡  杜先  陈新芳  刘高飞  齐天赐  冯慕华 《湖泊科学》2020,32(6):1707-1722

在巢湖西北半湖近岸带设置大型围隔研究秋季连续打捞蓝藻对湖泊温室气体通量的影响，应用YL-1000型大型仿生式水面蓝藻清除设备进行原位打捞蓝藻，通过便携式温室气体分析仪-静态箱法对大型围隔内水-气界面CH₄、CO₂通量特征及其影响因素进行观测.结果表明：对比未打捞区，蓝藻连续打捞下打捞区水体中叶绿素a（Chl.a）、悬浮物（SS）浓度不断下降，两者削减率分别为72%、85%，Chl.a、SS浓度分别下降到29.6±2.5 μg/L、12.5±1.2 mg/L，打捞对围隔内颗粒态物质去除效果十分明显；打捞过程中水体溶解性有机物（DOM）中微生物代谢类腐殖质（C1）、类蛋白（C3）显著下降趋势，打捞区C1、C3组分（0.18±0.02、0.06±0.01 RU）强度明显低于未打捞区（0.26±0.05、0.12±0.03 RU），打捞能有效控制藻源性溶解性有机质释放.同时，打捞区水-气界面CH₄通量呈显著下降趋势，未打捞区CH₄通量平均值（17.473±1.514 nmol/（m²·s））为打捞区（7.004±4.163 nmol/（m²·s））近2倍，CH₄通量与Chl.a、C1、C3组分均呈显著正相关，水体中藻源性溶解态有机质对CH₄通量具有促进作用；打捞区CO₂释放通量呈显著上升趋势，打捞区CO₂吸收通量（-0.200±0.069 μmol/（m²·s））明显低于未打捞区（-0.344±0.017 μmol/（m²·s）），CO₂通量与Chl.a、温度均呈显著负相关.秋季打捞对CH₄、CO₂综合日平均通量减排量值为0.275±0.076 mol/（m²·d）（以CO₂当量计）.研究结果揭示了巢湖秋季连续打捞蓝藻过程对水-气界面温室气体具有显著减排作用，且能在一定程度上减缓蓝藻水华与湖泊富营养化、气候变暖之间的恶性循环，为湖泊碳循环和蓝藻水华灾害防控提供科学数据支撑和理论参考.  相似文献   

油页岩成矿作用研究中的关键方法和技术          下载免费PDF全文

刘招君  孟庆涛  贾建亮 《古地理学报》2019,21(1):127-142

油页岩作为一种重要的非常规油气资源,如何有效地利用油页岩成矿作用研究中的关键方法和技术实现油页岩的综合识别与评价极其重要。油页岩识别的关键技术主要包括基于岩石学的地质识别、精确的地球化学指标识别、测井技术的垂向高分辨率快速识别和地震技术的三维空间定量刻画。先进的测试技术、创新的理论方法以及高品质地球物理资料的二次开发利用将不断提升油页岩从定性到定量预测识别的精度。油页岩成矿作用研究的关键方法是从古构造条件、古气候条件、古地理条件以及古湖泊环境等地质因素入手,探讨其综合作用下有机质来源、保存条件及成岩作用的变化,由定性向半定量—定量地精细刻画油页岩中有机质聚集过程,从而有效地预测油页岩的展布及其富集规律。由于文中材料以中国陆相含油页岩盆地的研究成果为主,而陆相成因油页岩的识别特征及成因机制可能与海相等成因存在差异,因此,仍需油页岩地质学家不断深入研究与总结。希望此文对页岩油、页岩气及烃源岩研究也具有一定的借鉴意义。  相似文献   

利用偏光显微镜反射光系统观察黑色生油岩电子探针薄片中的生烃母质特征     

郑庆华  刘行军  刘乔  梁秀玲  张小龙  左琴  杨开艳  马婷  许锋 《岩矿测试》2020,39(3):442-450

鄂尔多斯盆地上三叠统延长组长7油层组的黑色泥岩、油页岩等黑色生油岩薄片中的生烃母质,因黑色石油、沥青等黑色有机质的覆盖或不透明,导致其在偏光显微镜透射光系统下观察常局部或整体呈现为黑色。因此,建立一种黑色生油岩薄片中生烃母质有效观察的方法,对致密油、页岩油的生烃研究具有重要的理论和实际意义。本文提出了一种利用电子探针薄片和偏光显微镜的反射光系统观察黑色生油岩中生烃母质特征的方法。该方法能够克服黑色生油岩薄片中生烃母质因被黑色有机质覆盖或不透明,而在偏光显微镜的透射光系统下局部或整体呈黑色的弊端,能够对生烃母质的大小、形态、结构、分布和物质成分等特征进行整体且清晰的观察。实践表明,本文提出的利用偏光显微镜反射光系统观察黑色生油岩电子探针薄片中生烃母质特征的方法,简单有效,易在致密油、页岩油的生烃研究领域推广使用。  相似文献